File name: Pandora145s1_Toronto-Scarborough_20240606_L2Fit_fout2c9d20230821p1-8.txt
File generation date: 20241123T080128.7Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c9p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 145
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora145_OF_v5d20190718.txt
Instrument calibration file used: Pandora145s1_CF_v9d20230821.txt
Level 1 file used: Pandora145s1_Toronto-Scarborough_20240606_L1_smca1c9d20230821p1-8.txt
Full location name: University of Toronto - Scarborough
Short location name: Toronto-Scarborough
Country of location: Canada
Location latitude [deg]: 43.7843
Location longitude [deg]: -79.1874
Location altitude [m]: 137
Local noon date: 20240606
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: field cal for autumn2023 ff, based on Session 8(7)
First and last pixel inside fitting window: 226 368
Nominal wavelengths inside fitting window [nm]: 305.0462 305.1870 305.3278 305.4686 305.6094 305.7502 305.8910 306.0317 306.1725 306.3132 306.4539 306.5947 306.7354 306.8761 307.0167 307.1574 307.2981 307.4387 307.5794 307.7200 307.8606 308.0012 308.1418 308.2824 308.4230 308.5635 308.7041 308.8446 308.9851 309.1256 309.2661 309.4066 309.5471 309.6876 309.8281 309.9685 310.1089 310.2494 310.3898 310.5302 310.6706 310.8110 310.9513 311.0917 311.2320 311.3724 311.5127 311.6530 311.7933 311.9336 312.0739 312.2141 312.3544 312.4947 312.6349 312.7751 312.9153 313.0555 313.1957 313.3359 313.4761 313.6162 313.7564 313.8965 314.0366 314.1767 314.3168 314.4569 314.5970 314.7370 314.8771 315.0171 315.1572 315.2972 315.4372 315.5772 315.7172 315.8572 315.9971 316.1371 316.2770 316.4169 316.5569 316.6968 316.8367 316.9765 317.1164 317.2563 317.3961 317.5360 317.6758 317.8156 317.9554 318.0952 318.2350 318.3747 318.5145 318.6542 318.7940 318.9337 319.0734 319.2131 319.3528 319.4925 319.6321 319.7718 319.9114 320.0511 320.1907 320.3303 320.4699 320.6095 320.7490 320.8886 321.0282 321.1677 321.3072 321.4467 321.5862 321.7257 321.8652 322.0047 322.1441 322.2836 322.4230 322.5625 322.7019 322.8413 322.9807 323.1200 323.2594 323.3988 323.5381 323.6774 323.8167 323.9561 324.0954 324.2346 324.3739 324.5132 324.6524 324.7917 324.9309
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20240606T130624.6Z 8923.546118 181 1 1.91 2 54.76 91.24 52.66 86.90 0.00 1 0.00 1 0 17 9.102e-03 5.889e-03 2.219e-03 1.178e-03 2.545297e-01 5.963421e-04 3.109830e-03 -6.000000e+00 5.157099e-03 232.40 -2.00 3.57 -2.00 315.94 0.00e+00 1.548631e-04 6.101856e-05 3.527214e-05 -6.000000e+00 2.239051e-04 283.48 -2.00 20.00 -2.00 315.24 0.00e+00 1.728 0.000 302.00 328.00 3 1.4045e+00 1.5580e-03 2.1888e-02 -6.0000e+00 1.2967e-02 2.1243e-02 1.7342e-03 1.3497e-02 -6.0000e+00 1.4035e-02 -4.5945e-03 9.9764e-04 6.5524e-03 -6.0000e+00 8.3294e-03 8.7182e-04 4.6013e-04 1.8012e-03 -6.0000e+00 3.5394e-03 1.7176e-02 -9.3078e-05 3.1113e-05 1.9878e-05 -6.0000e+00 2.2651e-04 9.1252e-04 0.0000e+00 12 1 1 12 1 1 32.14 18.21 0.33 0.00091 0.00021 26 426 1 5 0 70.380 22.61 15.00 18.21 28.24 24.3 1100.00 392 -1144 315 -3252 -2671 -4592 -1822 -742 1469 -637 -594 -1588 -1094 -596 198 -90 -607 1048 -251 1645 584 1316 565 1013 661 298 230 425 159 -246 831 2025 1833 -132 -1459 -1957 -1182 -808 74 -466 -848 -1312 -547 -831 3 -408 -283 -261 -928 -2 423 676 867 999 621 1039 577 858 309 538 540 958 947 1204 390 -13 -478 -494 814 283 108 20 133 197 207 175 99 -226 263 -261 -607 -1044 -2036 -1541 -1426 -898 -502 -217 -98 118 365 421 258 644 775 384 406 629 36 41 -430 -832 42 302 -511 -780 -486 -1031 -227 -91 211 -82 123 238 138 378 494 286 451 -14 -346 -18 69 264 649 410 614 1203 564 611 108 68 -6 -33 -112 -296 151 -34 -183 -251 -364 -555 -287 80 -261 73 -737 -521 -928 -378 -159 348 -164 -149 -402 -287 -179 67 -32 -224 393 -99 662 229 536 234 416 289 136 106 183 67 -101 357 873 863 -63 -686 -879 -571 -427 44 -299 -600 -926 -396 -608 2 -296 -201 -180 -660 -1 295 508 656 797 514 832 476 704 248 446 438 830 857 1123 370 -12 -416 -413 706 261 106 21 137 196 201 158 84 -188 223 -231 -585 -1077 -2191 -1714 -1634 -1066 -607 -271 -123 144 424 460 275 650 821 435 476 792 48 53 -546 -1004 48 356 -623 -978 -633 -1369 -313 -130 308 -118 176 327 185 485 626 366 598 -19 -498 -26 95 361 863 539 783 1506 736 830 151 95 -9 -48 -168 -458 233 -53 -292 -392 -565 -852 -427
SS 20240606T131047.6Z 8923.549161 184 1 30.10 2 53.97 92.02 51.89 87.59 0.00 1 0.00 1 0 17 8.092e-03 5.271e-03 2.902e-03 1.125e-03 2.521485e-01 5.648179e-04 3.066794e-03 -6.000000e+00 4.585269e-03 232.40 -2.00 3.57 -2.00 316.78 0.00e+00 1.961961e-04 7.094597e-05 5.574222e-05 -6.000000e+00 1.990614e-04 283.48 -2.00 20.00 -2.00 316.05 0.00e+00 1.696 0.000 302.00 328.00 3 3.8150e+00 1.4939e-03 2.1592e-02 -6.0000e+00 1.1530e-02 4.4100e-02 1.6704e-03 1.3438e-02 -6.0000e+00 1.2478e-02 -4.7355e-03 9.8006e-04 6.5230e-03 -6.0000e+00 7.4057e-03 -2.2289e-03 4.7222e-04 1.7918e-03 -6.0000e+00 3.1472e-03 1.5819e-03 4.3492e-05 3.0216e-05 1.9130e-05 -6.0000e+00 2.0138e-04 3.3762e-04 0.0000e+00 10 0 0 10 0 0 99.99 18.21 0.18 0.00034 0.00066 101 101 1 5 0 297.990 22.61 15.00 18.21 28.49 24.3 1100.00 -36 -607 -131 -1824 -3526 -1794 -962 748 1639 757 -1573 -558 -928 316 -26 211 -1096 323 -195 1272 736 321 364 305 421 303 326 -130 341 -188 1331 1392 2159 -446 -1323 -2202 -2210 -1014 -233 -584 -751 -976 -1065 -873 -348 -520 -821 -480 -913 -183 496 700 898 894 367 1141 1056 728 607 398 633 606 1325 1392 618 275 -428 -628 807 194 506 129 32 451 237 37 -357 -613 106 -248 -719 -780 -1971 -1354 -1158 -712 -400 -236 26 203 414 284 86 559 669 361 502 668 224 -5 -335 -740 -176 66 -607 -666 -538 -631 -245 180 94 -141 162 122 -17 392 414 363 147 -103 -238 -74 74 223 707 251 483 965 508 440 129 -159 -110 27 4 -265 74 -100 -129 21 -211 -487 -214 -5 -94 -21 -277 -471 -221 -124 107 263 130 -270 -94 -177 68 -6 58 -316 95 -55 365 218 94 107 96 140 105 113 -42 111 -60 438 495 762 -169 -466 -811 -810 -427 -118 -324 -458 -622 -700 -578 -228 -341 -529 -299 -557 -110 311 473 639 672 286 897 789 545 477 310 502 480 1133 1279 578 236 -338 -513 634 176 472 126 32 427 226 31 -294 -473 83 -206 -678 -761 -2084 -1477 -1349 -834 -494 -302 34 252 473 315 87 570 669 400 577 854 292 -7 -431 -873 -206 79 -750 -873 -734 -848 -342 267 141 -214 251 176 -24 506 528 483 210 -150 -358 -110 106 308 974 331 598 1254 666 620 181 -230 -161 40 7 -425 122 -169 -221 35 -338 -752 -339
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