File name: Pandora145s1_Toronto-Scarborough_20240725_L2Fit_fout2c8d20221111p1-8.txt File generation date: 20240726T053102.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 145 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora145_OF_v5d20190718.txt Instrument calibration file used: Pandora145s1_CF_v8d20221111.txt Level 1 file used: Pandora145s1_Toronto-Scarborough_20240725_L1_smca1c8d20221111p1-8.txt Full location name: University of Toronto - Scarborough Short location name: Toronto-Scarborough Country of location: Canada Location latitude [deg]: 43.7843 Location longitude [deg]: -79.1874 Location altitude [m]: 137 Local noon date: 20240725 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 4 for field cal VP 20221111 First and last pixel inside fitting window: 226 368 Nominal wavelengths inside fitting window [nm]: 305.0546 305.1954 305.3363 305.4771 305.6179 305.7586 305.8994 306.0402 306.1809 306.3217 306.4624 306.6031 306.7438 306.8845 307.0252 307.1659 307.3065 307.4472 307.5878 307.7284 307.8691 308.0097 308.1503 308.2908 308.4314 308.5720 308.7125 308.8531 308.9936 309.1341 309.2746 309.4151 309.5556 309.6961 309.8365 309.9770 310.1174 310.2578 310.3982 310.5386 310.6790 310.8194 310.9598 311.1001 311.2405 311.3808 311.5212 311.6615 311.8018 311.9421 312.0823 312.2226 312.3629 312.5031 312.6433 312.7836 312.9238 313.0640 313.2042 313.3444 313.4845 313.6247 313.7648 313.9049 314.0451 314.1852 314.3253 314.4654 314.6054 314.7455 314.8856 315.0256 315.1656 315.3057 315.4457 315.5857 315.7256 315.8656 316.0056 316.1455 316.2855 316.4254 316.5653 316.7052 316.8451 316.9850 317.1249 317.2647 317.4046 317.5444 317.6842 317.8240 317.9639 318.1036 318.2434 318.3832 318.5229 318.6627 318.8024 318.9422 319.0819 319.2216 319.3612 319.5009 319.6406 319.7802 319.9199 320.0595 320.1991 320.3387 320.4783 320.6179 320.7575 320.8971 321.0366 321.1761 321.3157 321.4552 321.5947 321.7342 321.8737 322.0131 322.1526 322.2920 322.4315 322.5709 322.7103 322.8497 322.9891 323.1285 323.2678 323.4072 323.5465 323.6859 323.8252 323.9645 324.1038 324.2431 324.3824 324.5216 324.6609 324.8001 324.9393 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240725T125313.1Z 8972.536957 300 1 4.21 2 60.61 90.58 69.83 246.19 0.00 1 0.00 1 0 25 2.607e-02 1.322e-02 1.348e-02 3.413e-03 3.628410e-01 1.719889e-03 4.406946e-03 -6.000000e+00 1.480789e-02 232.69 -2.00 3.57 -2.00 317.51 0.00e+00 1.025501e-03 2.626087e-04 6.577613e-04 -6.000000e+00 6.521094e-04 287.30 -2.00 20.00 -2.00 316.71 0.00e+00 2.028 0.000 302.00 328.00 3 3.3657e+00 4.5970e-03 2.8148e-02 -6.0000e+00 3.7214e-02 3.8047e-02 5.1666e-03 1.9309e-02 -6.0000e+00 4.0224e-02 -3.8756e-02 3.1652e-03 9.3428e-03 -6.0000e+00 2.3921e-02 1.7129e-02 1.6075e-03 2.5426e-03 -6.0000e+00 1.0210e-02 1.4950e-03 -5.2438e-05 8.9943e-05 2.4565e-05 -6.0000e+00 6.4875e-04 -1.3033e-02 1.1002e-04 12 9 9 12 1 1 95.63 18.11 0.34 -0.01303 -0.01343 5 43 1 5 0 700.390 22.71 15.00 18.11 27.16 24.7 1100.00 7805 -8297 4984 -2211 8805 -4272 7869 6147 -338 -2529 -6001 -3806 -3797 1899 2031 4019 -1269 2430 -671 3799 -572 2509 145 3395 133 -1182 -314 -2770 -4169 -5368 154 -2457 -242 -4086 -4377 -8754 -4847 -4044 -324 79 314 -94 283 -2 913 91 -643 -190 -1006 32 159 1165 2200 3003 1958 2466 1941 1649 7 -145 1470 2411 2787 2847 2155 -739 -1068 -2520 -90 -5 1746 642 1698 941 973 -1234 -3002 -4283 -4309 -3066 -2217 -1608 -1556 -822 -152 54 287 952 1061 549 -226 -2272 -3654 -3312 -1876 -95 440 1569 677 1052 231 -1029 -1197 -1178 -703 -407 311 12 1114 980 2155 2075 1991 1010 -179 -793 -707 -207 -644 444 -6 441 621 977 344 -129 -1311 -443 93 -73 -703 -919 -1224 -1498 -563 -423 422 662 370 915 470 -412 -74 567 -803 445 -204 637 -330 567 510 -34 -279 -681 -429 -494 254 321 711 -252 490 -147 832 -135 566 34 821 33 -309 -83 -708 -1089 -1398 41 -697 -75 -1405 -1411 -2786 -1602 -1434 -135 37 161 -51 149 -1 484 49 -347 -107 -569 18 89 709 1415 1920 1320 1691 1376 1173 5 -101 1021 1784 2140 2265 1781 -587 -831 -1937 -71 -5 1566 612 1606 862 875 -1015 -2383 -3258 -3417 -2610 -2031 -1561 -1637 -854 -167 61 342 1171 1258 662 -255 -2500 -3910 -3394 -2014 -107 530 2011 915 1414 307 -1257 -1402 -1393 -868 -532 404 16 1531 1403 3282 3156 3075 1482 -254 -1096 -964 -292 -937 660 -9 657 931 1406 491 -176 -1787 -593 129 -107 -1059 -1441 -1893 -2412 -923 -710 718 1147 651 1560 795 -671 -119 SS 20240725T125818.5Z 8972.540492 303 1 29.98 2 59.69 91.47 70.63 247.19 0.00 1 0.00 1 0 17 1.045e-02 5.346e-03 8.234e-04 2.104e-04 3.384237e-01 1.060745e-04 4.092753e-03 -6.000000e+00 5.931939e-03 232.69 -2.00 3.57 -2.00 317.50 0.00e+00 2.335444e-04 1.618836e-05 8.887630e-05 -6.000000e+00 2.612600e-04 287.30 -2.00 20.00 -2.00 316.69 0.00e+00 1.973 0.000 302.00 328.00 3 -1.0379e-02 2.8391e-04 2.6870e-02 -6.0000e+00 1.4908e-02 1.7092e-02 3.1916e-04 1.8087e-02 -6.0000e+00 1.6116e-02 -1.1593e-02 1.9612e-04 8.7720e-03 -6.0000e+00 9.5841e-03 2.1977e-03 9.9305e-05 2.3961e-03 -6.0000e+00 4.0886e-03 4.8321e-02 -2.7095e-04 5.5636e-06 2.3594e-05 -6.0000e+00 2.6007e-04 -1.2557e-02 2.9837e-06 10 0 0 10 0 0 47.73 18.12 0.30 -0.01256 -0.01459 1438 1438 1 5 0 20.840 22.71 15.00 18.12 27.58 24.7 1100.00 -1012 -1195 -311 -2967 -3916 -5017 -2744 -1330 50 -1343 -2944 -3102 -1900 -1251 -200 -591 -513 -121 -142 924 391 214 41 325 217 254 -118 -289 -993 -420 575 1399 1830 -142 -1741 -2520 -2441 -1097 -305 -458 -734 -702 -523 -743 86 -285 -370 -302 -665 -100 699 831 982 993 651 1168 941 727 431 527 788 1095 1248 1551 548 190 -297 -549 713 391 288 104 20 341 203 43 -54 -620 -23 -348 -615 -880 -1812 -1477 -1400 -1013 -469 -335 43 175 489 382 125 645 662 451 361 597 110 -60 -287 -700 -227 96 -530 -695 -613 -916 -265 -1 90 -42 133 135 121 411 501 335 268 -47 -281 -121 52 235 812 380 474 1126 630 588 202 -123 -46 1 -80 -208 17 -54 -173 -175 -191 -531 -210 -79 -105 -28 -266 -311 -378 -215 -117 5 -145 -319 -342 -237 -183 -34 -114 -96 -24 -29 197 86 47 9 77 55 68 -32 -74 -238 -98 144 385 556 -47 -545 -755 -791 -378 -127 -212 -379 -381 -294 -425 48 -162 -209 -167 -366 -55 406 491 617 664 455 832 647 502 310 372 566 791 989 1258 460 158 -230 -413 559 334 258 98 19 311 183 36 -42 -453 -17 -302 -573 -869 -1849 -1565 -1583 -1167 -569 -401 52 213 551 414 131 646 702 507 432 761 146 -80 -375 -878 -261 112 -680 -902 -829 -1245 -377 -2 135 -66 201 200 172 567 682 454 389 -71 -431 -182 75 345 1122 528 621 1450 880 855 300 -190 -73 2 -132 -353 29 -93 -299 -307 -320 -890 -339 SS 20240725T130841.7Z 8972.547705 306 1 29.98 2 57.82 93.31 72.28 249.20 0.00 1 0.00 1 0 17 9.598e-03 5.386e-03 6.561e-04 1.958e-04 3.196744e-01 9.889935e-05 3.886974e-03 -6.000000e+00 5.448691e-03 232.69 -2.00 3.57 -2.00 317.25 0.00e+00 2.101270e-04 1.404849e-05 7.542612e-05 -6.000000e+00 2.399752e-04 287.30 -2.00 20.00 -2.00 316.44 0.00e+00 1.871 0.000 302.00 328.00 3 -1.7946e-02 2.6322e-04 2.5442e-02 -6.0000e+00 1.3693e-02 1.3307e-02 2.9525e-04 1.7093e-02 -6.0000e+00 1.4803e-02 -9.8067e-03 1.7808e-04 8.2926e-03 -6.0000e+00 8.8033e-03 2.2325e-03 8.8640e-05 2.2660e-03 -6.0000e+00 3.7556e-03 5.5381e-02 -2.4242e-04 5.1989e-06 2.3304e-05 -6.0000e+00 2.3887e-04 -1.2701e-02 2.7589e-06 10 0 0 10 0 0 28.08 18.13 0.32 -0.01270 -0.01452 1522 1522 1 5 0 19.680 22.71 15.00 18.13 28.85 24.4 1100.00 -866 -806 -676 -2681 -3819 -4159 -2462 -695 189 -1108 -2527 -2584 -1760 -1086 207 -302 -318 -27 -99 954 449 252 216 290 446 428 20 -296 -832 -409 618 1414 1870 78 -1655 -2304 -2357 -1070 -262 -488 -668 -715 -517 -711 37 -336 -364 -366 -673 -98 644 779 1046 987 646 1095 895 700 492 501 761 1046 1239 1525 524 203 -363 -566 611 403 153 81 -34 267 243 86 37 -579 80 -237 -620 -881 -1768 -1498 -1380 -1036 -437 -333 47 185 469 344 137 663 690 413 395 574 108 -55 -352 -714 -225 98 -546 -684 -601 -898 -298 13 109 -37 148 134 129 450 511 322 273 -28 -271 -138 59 224 780 351 462 1116 646 594 235 -102 -53 26 -63 -212 0 -35 -206 -156 -225 -548 -235 -82 -85 -75 -289 -364 -373 -230 -72 22 -142 -324 -335 -258 -185 41 -62 -68 -6 -23 232 113 63 54 78 128 129 6 -86 -225 -108 173 433 629 26 -571 -758 -841 -405 -120 -248 -377 -396 -296 -414 21 -195 -208 -206 -401 -58 375 493 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