File name: Pandora145s1_Toronto-Scarborough_20240806_L2Fit_fout2c8d20221111p1-8.txt
File generation date: 20240807T052901.2Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c8p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 145
Spectrometer number: 1
Processing software version used: BlickP v1.8.59
Instrument operation file used: Pandora145_OF_v5d20190718.txt
Instrument calibration file used: Pandora145s1_CF_v8d20221111.txt
Level 1 file used: Pandora145s1_Toronto-Scarborough_20240806_L1_smca1c8d20221111p1-8.txt
Full location name: University of Toronto - Scarborough
Short location name: Toronto-Scarborough
Country of location: Canada
Location latitude [deg]: 43.7843
Location longitude [deg]: -79.1874
Location altitude [m]: 137
Local noon date: 20240806
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: based on session 4 for field cal VP 20221111
First and last pixel inside fitting window: 226 368
Nominal wavelengths inside fitting window [nm]: 305.0546 305.1954 305.3363 305.4771 305.6179 305.7586 305.8994 306.0402 306.1809 306.3217 306.4624 306.6031 306.7438 306.8845 307.0252 307.1659 307.3065 307.4472 307.5878 307.7284 307.8691 308.0097 308.1503 308.2908 308.4314 308.5720 308.7125 308.8531 308.9936 309.1341 309.2746 309.4151 309.5556 309.6961 309.8365 309.9770 310.1174 310.2578 310.3982 310.5386 310.6790 310.8194 310.9598 311.1001 311.2405 311.3808 311.5212 311.6615 311.8018 311.9421 312.0823 312.2226 312.3629 312.5031 312.6433 312.7836 312.9238 313.0640 313.2042 313.3444 313.4845 313.6247 313.7648 313.9049 314.0451 314.1852 314.3253 314.4654 314.6054 314.7455 314.8856 315.0256 315.1656 315.3057 315.4457 315.5857 315.7256 315.8656 316.0056 316.1455 316.2855 316.4254 316.5653 316.7052 316.8451 316.9850 317.1249 317.2647 317.4046 317.5444 317.6842 317.8240 317.9639 318.1036 318.2434 318.3832 318.5229 318.6627 318.8024 318.9422 319.0819 319.2216 319.3612 319.5009 319.6406 319.7802 319.9199 320.0595 320.1991 320.3387 320.4783 320.6179 320.7575 320.8971 321.0366 321.1761 321.3157 321.4552 321.5947 321.7342 321.8737 322.0131 322.1526 322.2920 322.4315 322.5709 322.7103 322.8497 322.9891 323.1285 323.2678 323.4072 323.5465 323.6859 323.8252 323.9645 324.1038 324.2431 324.3824 324.5216 324.6609 324.8001 324.9393
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20240806T172922.8Z 8984.728736 315 1 28.96 2 27.41 183.53 40.19 141.61 0.00 1 0.00 1 0 17 9.735e-03 7.147e-03 4.283e-03 2.705e-03 1.638485e-01 1.376601e-03 2.002261e-03 -6.000000e+00 5.520501e-03 232.23 -2.00 3.57 -2.00 315.25 0.00e+00 3.366052e-04 1.238991e-04 4.154503e-05 -6.000000e+00 2.437342e-04 287.54 -2.00 20.00 -2.00 314.55 0.00e+00 1.126 0.000 302.00 328.00 3 5.9809e+00 3.5742e-03 1.4183e-02 -6.0000e+00 1.3857e-02 2.9371e-02 3.9633e-03 8.6648e-03 -6.0000e+00 1.4981e-02 3.6330e-03 2.2710e-03 4.2038e-03 -6.0000e+00 8.9141e-03 -2.5724e-03 1.0204e-03 1.1630e-03 -6.0000e+00 3.8105e-03 3.7382e-04 -1.3903e-04 7.2139e-05 1.3517e-05 -6.0000e+00 2.4221e-04 -1.6769e-02 1.7109e-05 11 8 0 10 0 0 92.06 17.96 0.40 -0.01677 -0.01781 8 8 1 5 0 3618.740 22.61 15.00 17.96 30.26 24.9 1100.00 2286 -617 485 -2269 -968 -3628 -2521 -40 2003 -336 -1064 -1802 -719 -1399 1294 487 -961 335 796 1980 648 1067 135 1009 -721 1376 -201 -268 -373 -709 737 923 1721 15 -1085 -2204 -2942 -668 -57 -27 -27 -567 -278 -679 8 88 -208 -704 -1074 -1219 -210 547 438 1226 652 1409 988 659 -95 190 278 318 1428 1733 782 208 -1042 -1200 115 356 602 707 787 1058 88 -263 -781 -2528 -1186 -774 -704 -866 -1659 -1809 -933 -817 -178 373 403 764 954 116 -1088 -199 -656 -36 301 552 661 71 209 -550 -846 -852 -656 -833 -266 -585 -182 676 676 621 564 -193 -314 -34 -443 -725 276 182 -60 566 847 241 760 416 -28 730 17 259 34 29 -448 161 -197 75 201 530 214 -361 -197 -954 -529 662 -184 159 -718 -259 -918 -653 -11 623 -113 -348 -575 -246 -540 500 207 -422 147 358 904 308 494 63 488 -371 719 -107 -134 -169 -332 349 422 833 8 -519 -1087 -1437 -367 -38 -19 -21 -461 -231 -572 7 72 -168 -546 -803 -888 -156 431 362 1052 577 1249 897 599 -85 167 251 283 1357 1747 800 194 -952 -1034 101 329 616 758 851 1109 88 -237 -675 -2040 -947 -686 -648 -878 -1813 -2047 -1042 -985 -226 459 501 981 1133 135 -1146 -193 -659 -39 336 679 873 94 258 -629 -971 -1000 -789 -1068 -353 -762 -245 947 996 927 809 -258 -406 -41 -518 -882 357 239 -82 772 1126 330 977 511 -35 875 20 327 44 39 -610 223 -272 109 302 813 335 -558 -294 -1389 -744
SS 20240806T183913.5Z 8984.777240 356 1 29.41 2 31.84 216.64 35.14 168.29 0.00 1 0.00 1 0 17 8.251e-03 5.992e-03 2.578e-03 1.720e-03 1.681821e-01 8.748827e-04 2.068812e-03 -6.000000e+00 4.679607e-03 232.23 -2.00 3.57 -2.00 315.01 0.00e+00 2.472912e-04 7.554130e-05 2.234768e-05 -6.000000e+00 2.066036e-04 287.54 -2.00 20.00 -2.00 314.35 0.00e+00 1.176 0.000 302.00 328.00 3 5.1774e+00 2.2638e-03 1.4731e-02 -6.0000e+00 1.1746e-02 3.3507e-02 2.5094e-03 8.9265e-03 -6.0000e+00 1.2699e-02 -6.4616e-04 1.4347e-03 4.3309e-03 -6.0000e+00 7.5559e-03 -1.2331e-03 6.4012e-04 1.1944e-03 -6.0000e+00 3.2305e-03 7.8878e-04 6.8487e-05 4.5315e-05 1.3776e-05 -6.0000e+00 2.0529e-04 -1.6710e-02 6.4092e-05 10 0 0 10 0 0 99.84 17.93 0.31 -0.01671 -0.01620 12 12 1 5 0 2450.510 22.61 15.00 17.93 29.72 25.2 1100.00 714 -49 928 -1735 -2833 -2416 -929 887 625 511 -2493 -980 -1618 -351 968 -91 -416 659 -187 1352 1077 186 248 838 1037 632 803 142 135 -6 936 1680 2166 242 -896 -1841 -2154 -718 -41 -608 -816 -433 -903 -810 -426 -487 -867 -283 -921 -588 427 373 598 327 442 1228 881 591 545 30 480 994 1547 1360 814 90 -538 -1132 -65 350 557 449 297 606 395 222 -542 -1155 -756 -507 -1186 -1096 -1672 -1244 -1172 -558 -252 83 396 349 414 275 -229 68 353 219 137 745 464 300 -202 -836 -643 -197 -663 -486 -584 -649 -14 214 483 582 456 -15 -150 -174 -38 -53 41 123 46 13 618 -140 534 309 451 458 398 323 5 -324 167 91 111 -41 182 115 -106 -122 -106 -761 -372 229 -16 302 -595 -844 -658 -258 271 215 186 -905 -339 -611 -135 411 -43 -200 316 -93 682 559 96 127 446 578 338 431 78 67 -3 447 840 1152 137 -472 -916 -1153 -403 -27 -447 -660 -362 -724 -655 -364 -415 -723 -225 -707 -438 325 303 509 272 377 1051 771 519 467 26 415 912 1524 1339 809 88 -472 -1009 -59 337 556 471 315 622 410 207 -485 -953 -623 -465 -1145 -1163 -1788 -1370 -1377 -663 -316 102 489 445 488 312 -234 68 367 234 162 906 608 391 -248 -1010 -723 -226 -789 -615 -769 -844 -18 301 675 824 655 -20 -193 -206 -47 -64 53 162 63 19 823 -191 684 378 549 543 497 405 6 -438 225 126 154 -60 259 169 -158 -180 -159 -1109 -524
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