File name: Pandora145s1_Toronto-Scarborough_20240808_L2Fit_fwvt1c9d20230821p1-8.txt File generation date: 20241123T091125.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 145 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora145_OF_v5d20190718.txt Instrument calibration file used: Pandora145s1_CF_v9d20230821.txt Level 1 file used: Pandora145s1_Toronto-Scarborough_20240808_L1_smca1c9d20230821p1-8.txt Full location name: University of Toronto - Scarborough Short location name: Toronto-Scarborough Country of location: Canada Location latitude [deg]: 43.7843 Location longitude [deg]: -79.1874 Location altitude [m]: 137 Local noon date: 20240808 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: field cal for autumn2023 ff, based on Session 8(7) First and last pixel inside fitting window: 1647 1796 Nominal wavelengths inside fitting window [nm]: 492.0731 492.1943 492.3153 492.4364 492.5575 492.6785 492.7995 492.9205 493.0415 493.1625 493.2834 493.4044 493.5253 493.6462 493.7671 493.8880 494.0088 494.1297 494.2505 494.3713 494.4921 494.6128 494.7336 494.8543 494.9751 495.0958 495.2165 495.3371 495.4578 495.5784 495.6990 495.8197 495.9402 496.0608 496.1814 496.3019 496.4224 496.5429 496.6634 496.7839 496.9044 497.0248 497.1452 497.2656 497.3860 497.5064 497.6267 497.7471 497.8674 497.9877 498.1080 498.2283 498.3485 498.4688 498.5890 498.7092 498.8294 498.9495 499.0697 499.1898 499.3100 499.4301 499.5502 499.6702 499.7903 499.9103 500.0303 500.1503 500.2703 500.3903 500.5103 500.6302 500.7501 500.8700 500.9899 501.1098 501.2296 501.3495 501.4693 501.5891 501.7089 501.8286 501.9484 502.0681 502.1878 502.3075 502.4272 502.5469 502.6665 502.7862 502.9058 503.0254 503.1450 503.2645 503.3841 503.5036 503.6231 503.7426 503.8621 503.9816 504.1010 504.2205 504.3399 504.4593 504.5786 504.6980 504.8174 504.9367 505.0560 505.1753 505.2946 505.4138 505.5331 505.6523 505.7715 505.8907 506.0099 506.1290 506.2482 506.3673 506.4864 506.6055 506.7246 506.8436 506.9627 507.0817 507.2007 507.3197 507.4387 507.5576 507.6766 507.7955 507.9144 508.0333 508.1522 508.2710 508.3899 508.5087 508.6275 508.7463 508.8650 508.9838 509.1025 509.2212 509.3399 509.4586 509.5773 509.6959 509.8146 509.9332 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240808T122103.0Z 8986.514618 121 1 30.75 2 68.57 88.20 110.63 69.91 0.00 1 0.00 1 0 15 3.806e-03 3.777e-03 1.417e-03 1.414e-03 5.210476e+03 8.749066e+01 3.584338e+02 -6.000000e+00 2.056464e+02 287.57 -2.00 20.00 -2.00 505.27 0.00e+00 6.568331e-04 3.866958e-05 4.420893e-05 -6.000000e+00 1.061912e-04 287.57 -2.00 20.00 -2.00 500.45 0.00e+00 1.940476e-01 2.746849e-02 3.480148e-02 -6.000000e+00 7.410140e-02 232.16 -2.00 3.57 -2.00 502.04 0.00e+00 2.711 0.000 489.00 513.00 1 7.8379e+00 2.1005e-03 4.9409e-03 -6.0000e+00 5.6715e-03 -1.0029e-02 5.4977e-04 8.5332e-04 -6.0000e+00 1.4956e-03 5.1178e-04 4.9124e-04 1.1610e-04 4.2155e-05 -6.0000e+00 3.2451e-04 -6.5614e-03 1.6653e-05 10 0 0 10 0 0 77.50 18.02 0.86 -0.00656 -0.00315 8 8 1 4 0 3843.570 22.71 15.00 18.02 29.26 24.7 1100.00 -983 -460 -249 169 473 655 847 529 657 419 -126 -115 -99 -694 -575 -376 17 5 -24 462 18 164 216 213 261 676 492 137 30 -358 -512 -557 133 -191 91 280 201 -175 -208 -105 -478 -402 198 184 322 418 239 204 -90 -277 -472 -987 -674 -445 -54 53 17 89 81 178 240 266 549 273 472 213 30 -13 -351 30 -395 -572 20 -210 163 -220 -116 -720 -269 -520 -534 -466 -420 -358 -402 84 53 -280 -67 -432 -183 128 517 367 526 11 284 -331 -582 -604 -748 -400 -151 -163 541 146 -226 -207 -481 -245 81 182 175 546 554 402 516 496 302 152 257 1 72 -104 364 255 360 125 229 -122 264 59 -266 -307 -188 -187 -6 279 99 75 239 447 431 474 139 -7 -53 -221 -641 -1098 -954 -452 -246 173 482 679 895 550 679 439 -131 -118 -99 -693 -571 -375 17 5 -25 483 19 172 226 224 276 712 517 143 30 -360 -507 -557 135 -197 97 298 211 -182 -214 -107 -490 -415 206 194 333 433 246 213 -92 -277 -470 -964 -649 -433 -55 54 17 90 84 183 248 269 556 277 487 216 30 -13 -344 29 -379 -554 20 -208 163 -218 -112 -689 -261 -505 -507 -447 -406 -349 -398 83 53 -279 -66 -431 -179 127 519 368 516 11 273 -311 -551 -562 -698 -370 -145 -160 542 146 -225 -202 -465 -239 81 183 173 542 552 403 523 504 304 151 257 1 71 -103 361 254 348 124 227 -118 259 57 -252 -289 -176 -179 -6 271 98 75 240 450 437 470 139 -7 -53 -213 -609 -1049 SQ 20240808T122524.8Z 8986.517648 124 1 29.64 2 67.78 88.94 109.93 70.75 0.00 1 0.00 1 0 15 3.796e-03 3.777e-03 7.747e-04 7.735e-04 4.800361e+03 4.754171e+01 3.447622e+02 -6.000000e+00 2.051308e+02 287.57 -2.00 20.00 -2.00 505.28 0.00e+00 6.574087e-04 2.116069e-05 4.332090e-05 -6.000000e+00 1.059247e-04 287.57 -2.00 20.00 -2.00 500.48 0.00e+00 1.820211e-01 1.501483e-02 2.983242e-02 -6.000000e+00 7.391715e-02 232.16 -2.00 3.57 -2.00 502.06 0.00e+00 2.622 0.000 489.00 513.00 1 6.6998e+00 1.1482e-03 4.6142e-03 -6.0000e+00 5.6574e-03 -1.0574e-02 3.0011e-04 7.6572e-04 -6.0000e+00 1.4919e-03 1.6200e-03 5.7624e-04 6.3630e-05 4.1239e-05 -6.0000e+00 3.2370e-04 -5.3501e-03 7.2552e-06 10 0 0 10 0 0 99.55 18.02 0.77 -0.00535 -0.00135 17 17 1 4 0 1743.240 22.71 15.00 18.02 29.39 24.7 1100.00 -803 -407 -219 256 548 515 659 648 596 362 -64 -150 -215 -391 -445 -356 -91 -157 266 370 191 33 218 221 219 437 331 105 -5 -624 -926 -424 -110 -142 340 713 133 -164 -363 -178 -423 21 216 275 442 370 239 129 -109 -360 -606 -885 -792 -681 -315 -55 209 34 336 124 235 286 467 588 354 164 67 -183 -203 -251 -505 -368 -131 65 21 142 -181 -522 -541 -460 -681 -381 -97 -261 -253 193 -33 -244 -224 -260 137 146 276 587 632 71 350 -168 -454 -775 -900 -595 -269 -68 379 108 -112 -353 -244 -377 -23 302 281 418 581 552 437 381 331 -8 -52 -111 -202 59 228 234 126 199 103 141 311 48 -418 -199 -232 -331 -107 292 323 111 336 354 401 400 233 237 -39 -327 -638 -810 -767 -395 -221 259 566 528 688 684 627 376 -65 -152 -220 -396 -449 -360 -93 -161 280 382 198 34 226 230 230 456 344 108 -5 -620 -937 -417 -111 -145 357 748 138 -168 -370 -180 -428 22 222 286 464 389 250 133 -111 -367 -597 -877 -776 -675 -313 -55 213 35 344 126 239 294 481 604 362 165 67 -179 -202 -246 -492 -361 -130 63 21 139 -179 -507 -520 -441 -659 -371 -95 -258 -247 190 -33 -240 -220 -257 136 147 276 582 631 70 335 -161 -426 -716 -833 -562 -256 -68 377 108 -110 -351 -240 -365 -22 301 283 423 590 563 439 384 331 -8 -52 -108 -197 57 224 230 125 196 102 138 302 45 -405 -190 -222 -315 -105 289 316 110 334 353 403 404 235 237 -38 -321 -616 -785 SQ 20240808T122952.4Z 8986.520745 127 1 30.51 2 66.98 89.71 109.20 71.60 0.00 1 0.00 1 0 22 3.589e-03 3.572e-03 1.071e-03 1.068e-03 4.889341e+03 6.615310e+01 3.449352e+02 -6.000000e+00 1.939032e+02 287.57 -2.00 20.00 -2.00 505.26 0.00e+00 5.597482e-04 2.916192e-05 3.974398e-05 -6.000000e+00 1.001284e-04 287.57 -2.00 20.00 -2.00 500.37 0.00e+00 1.755749e-01 2.084137e-02 3.090060e-02 -6.000000e+00 6.986405e-02 232.16 -2.00 3.57 -2.00 501.97 0.00e+00 2.536 0.000 489.00 513.00 1 7.3450e+00 1.5942e-03 4.5453e-03 -6.0000e+00 5.3473e-03 1.2463e-02 4.1713e-04 7.7759e-04 -6.0000e+00 1.4099e-03 8.6146e-04 6.2178e-04 8.7518e-05 4.0243e-05 -6.0000e+00 3.0598e-04 -5.8362e-03 1.9887e-05 10 0 0 10 0 0 49.06 18.02 0.80 -0.00584 -0.00152 11 11 1 4 0 2772.600 22.71 14.99 18.02 29.52 24.8 1100.00 -956 -298 -125 212 595 599 630 531 507 434 -13 -24 -36 -372 -617 -378 -51 -131 100 395 -14 -57 265 -42 403 523 380 15 97 -499 -852 -587 -150 -23 462 439 100 -36 -172 -81 -391 -13 172 228 288 436 182 171 -312 -214 -510 -920 -678 -543 -380 87 191 186 192 16 339 172 295 152 423 194 151 -281 -266 -358 -362 -276 -140 71 9 52 -226 -347 -541 -339 -524 -477 -203 -295 -223 -85 -100 -280 -259 -116 102 138 406 633 591 -8 36 -162 -285 -629 -805 -574 -290 -168 333 20 -294 -292 -237 -378 -52 149 433 420 529 641 512 496 579 262 -79 -46 -63 -38 200 105 32 220 159 -15 189 -80 -147 -185 -142 -157 -133 333 142 270 286 399 262 419 219 196 -198 -527 -541 -598 -949 -299 -126 222 614 630 676 575 546 460 -14 -25 -37 -374 -619 -381 -52 -138 104 415 -14 -60 278 -44 427 553 400 16 101 -503 -851 -588 -153 -24 490 466 105 -37 -176 -82 -399 -14 178 238 305 460 191 177 -318 -219 -506 -892 -670 -526 -380 90 195 191 196 17 345 177 303 156 430 194 153 -283 -265 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