File name: Pandora145s1_Toronto-Scarborough_20241024_L2Fit_fout2c9d20230821p1-8.txt File generation date: 20241123T101433.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 145 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora145_OF_v5d20190718.txt Instrument calibration file used: Pandora145s1_CF_v9d20230821.txt Level 1 file used: Pandora145s1_Toronto-Scarborough_20241024_L1_smca1c9d20230821p1-8.txt Full location name: University of Toronto - Scarborough Short location name: Toronto-Scarborough Country of location: Canada Location latitude [deg]: 43.7843 Location longitude [deg]: -79.1874 Location altitude [m]: 137 Local noon date: 20241024 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: field cal for autumn2023 ff, based on Session 8(7) First and last pixel inside fitting window: 226 368 Nominal wavelengths inside fitting window [nm]: 305.0462 305.1870 305.3278 305.4686 305.6094 305.7502 305.8910 306.0317 306.1725 306.3132 306.4539 306.5947 306.7354 306.8761 307.0167 307.1574 307.2981 307.4387 307.5794 307.7200 307.8606 308.0012 308.1418 308.2824 308.4230 308.5635 308.7041 308.8446 308.9851 309.1256 309.2661 309.4066 309.5471 309.6876 309.8281 309.9685 310.1089 310.2494 310.3898 310.5302 310.6706 310.8110 310.9513 311.0917 311.2320 311.3724 311.5127 311.6530 311.7933 311.9336 312.0739 312.2141 312.3544 312.4947 312.6349 312.7751 312.9153 313.0555 313.1957 313.3359 313.4761 313.6162 313.7564 313.8965 314.0366 314.1767 314.3168 314.4569 314.5970 314.7370 314.8771 315.0171 315.1572 315.2972 315.4372 315.5772 315.7172 315.8572 315.9971 316.1371 316.2770 316.4169 316.5569 316.6968 316.8367 316.9765 317.1164 317.2563 317.3961 317.5360 317.6758 317.8156 317.9554 318.0952 318.2350 318.3747 318.5145 318.6542 318.7940 318.9337 319.0734 319.2131 319.3528 319.4925 319.6321 319.7718 319.9114 320.0511 320.1907 320.3303 320.4699 320.6095 320.7490 320.8886 321.0282 321.1677 321.3072 321.4467 321.5862 321.7257 321.8652 322.0047 322.1441 322.2836 322.4230 322.5625 322.7019 322.8413 322.9807 323.1200 323.2594 323.3988 323.5381 323.6774 323.8167 323.9561 324.0954 324.2346 324.3739 324.5132 324.6524 324.7917 324.9309 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241024T125253.0Z 9063.536725 307 1 30.06 2 79.21 118.46 26.25 225.73 0.00 1 0.00 1 0 17 2.707e-01 5.056e-03 4.693e-02 1.286e-03 6.060336e-01 6.537898e-04 7.059628e-03 -6.000000e+00 1.490892e-01 224.52 -2.00 3.57 -2.00 320.59 0.00e+00 9.799851e-04 2.609801e-04 4.089501e-04 -6.000000e+00 6.566105e-03 280.11 -2.00 20.00 -2.00 320.03 0.00e+00 5.145 0.003 302.00 328.00 3 2.4583e-01 2.0107e-03 5.9623e-02 -6.0000e+00 3.6840e-01 4.1797e-02 2.6434e-03 3.2472e-02 -6.0000e+00 4.0112e-01 -9.5301e-03 2.6742e-03 1.6871e-02 -6.0000e+00 2.3909e-01 -8.5658e-03 1.3367e-03 5.3893e-03 -6.0000e+00 1.0317e-01 1.4250e-03 -4.9349e-04 3.3605e-05 5.3153e-05 -6.0000e+00 6.7217e-03 -7.6725e-03 0.0000e+00 10 0 0 10 0 0 30.13 18.30 0.33 -0.00767 -0.01138 284 284 1 5 0 105.810 23.01 15.00 18.30 19.78 24.4 1081.03 -106561 -104499 -81387 -93201 -94651 -91666 -86027 -91704 -78731 -70267 -79514 -55885 -46796 -33374 -41597 -9879 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221 684 455 479 -171 173 110 188 440 776 508 352 -188 -817 -275 -156 -512 -1056 -780 -1459 -222 138 369 207 387 440 -49 365 455 427 124 -105 -495 -106 6 232 839 117 152 1044 447 664 156 -278 -318 -403 -453 -818 265 47 -58 54 84 -668 516 SS 20241024T125822.3Z 9063.540536 310 1 30.02 2 78.35 119.51 26.97 227.96 0.00 1 0.00 1 0 17 1.929e-01 4.832e-03 3.147e-02 1.030e-03 5.691153e-01 5.213769e-04 6.698604e-03 -6.000000e+00 1.062642e-01 224.52 -2.00 3.57 -2.00 320.33 0.00e+00 1.035671e-03 1.902477e-04 3.362511e-04 -6.000000e+00 4.680012e-03 280.11 -2.00 20.00 -2.00 319.75 0.00e+00 4.793 0.002 302.00 328.00 3 2.3540e-01 1.5540e-03 5.5610e-02 -6.0000e+00 2.6258e-01 3.9873e-02 1.9626e-03 3.0208e-02 -6.0000e+00 2.8590e-01 -5.3702e-03 1.8895e-03 1.5464e-02 -6.0000e+00 1.7042e-01 -1.0694e-02 9.6429e-04 4.8490e-03 -6.0000e+00 7.3533e-02 2.0707e-03 -4.8118e-04 2.7076e-05 4.9954e-05 -6.0000e+00 4.7909e-03 -7.7223e-03 0.0000e+00 10 0 0 10 0 0 50.82 18.30 0.29 -0.00772 -0.01134 342 342 1 5 0 87.750 23.01 15.00 18.30 19.64 24.4 1080.75 -69770 -68516 -71494 -60644 -85152 -57443 -79647 -47474 -68636 -29912 -51669 -31884 -44178 -17391 -19895 -14843 -12500 -6051 -6981 -7787 -6749 -9235 -3899 -11202 124 -8633 -775 -9200 -4514 -8834 -2223 -1331 1487 -2177 -3110 -4102 -5164 -1496 -331 1573 -1001 760 -891 1347 604 1807 -1302 23 -329 880 1264 1546 1703 1524 1243 830 1310 168 751 -328 931 698 2259 1692 1803 693 84 -868 627 596 292 382 78 466 -105 15 -784 -881 -726 -130 -728 -606 -1619 -1332 -1316 -720 -135 100 489 482 908 356 131 236 369 255 372 583 388 120 -117 -822 -379 -77 -729 -910 -865 -1027 -264 166 143 275 199 259 20 307 385 229 149 -81 -307 -65 12 57 632 107 155 765 421 331 98 -309 -118 -147 -180 -241 44 25 -97 -37 79 -262 173 -589 -682 -805 -609 -984 -485 -912 -458 -952 -313 -696 -381 -741 -285 -420 -361 -334 -167 -213 -254 -228 -318 -132 -453 5 -402 -35 -432 -194 -409 -113 -80 101 -170 -234 -299 -416 -125 -34 194 -145 116 -147 223 102 307 -232 4 -62 171 270 370 446 436 349 244 399 52 225 -97 276 226 818 698 794 298 35 -368 283 314 160 220 46 278 -58 7 -356 -393 -351 -74 -451 -429 -1278 -1105 -1166 -632 -125 96 468 448 841 307 107 191 328 243 406 679 501 158 -145 -988 -408 -82 -854 -1059 -1055 -1334 -368 239 229 468 338 423 30 443 551 343 238 -137 -523 -107 19 88 923 162 223 1100 637 564 173 -582 -231 -285 -376 -534 93 56 -214 -79 168 -527 351 SS 20241024T130338.9Z 9063.544200 313 1 30.00 2 77.52 120.53 27.69 230.01 0.00 1 0.00 1 0 17 1.275e-01 4.606e-03 2.158e-02 8.525e-04 5.375298e-01 4.277712e-04 6.337484e-03 -6.000000e+00 7.021251e-02 224.52 -2.00 3.57 -2.00 320.07 0.00e+00 6.919472e-04 1.428233e-04 2.955477e-04 -6.000000e+00 3.092206e-03 280.11 -2.00 20.00 -2.00 319.47 0.00e+00 4.499 0.002 302.00 328.00 3 2.1572e-01 1.2516e-03 5.2246e-02 -6.0000e+00 1.7349e-01 3.9907e-02 1.5429e-03 2.8388e-02 -6.0000e+00 1.8890e-01 -8.2944e-03 1.4170e-03 1.4452e-02 -6.0000e+00 1.1260e-01 -8.5306e-03 7.3387e-04 4.4195e-03 -6.0000e+00 4.8587e-02 2.8715e-03 -4.8168e-04 2.2570e-05 4.3529e-05 -6.0000e+00 3.1654e-03 -7.9703e-03 0.0000e+00 11 1 0 11 8 0 40.03 18.31 0.31 -0.00797 -0.01159 406 406 1 5 0 73.890 23.01 14.99 18.31 19.73 24.6 1081.79 -49593 -47623 -39600 -47228 -45080 -54886 -41874 -46868 -25085 -30357 -17497 -34687 -15770 -22768 -11512 -13468 -3500 -8774 -2669 -4784 -4827 -1318 -7259 -2868 -4641 919 -5601 -3072 -5870 -1789 -5917 1273 344 -153 -3544 -3930 -4344 -943 580 -844 173 -1393 313 -938 1136 -738 294 -533 -1 63 1194 1172 1473 1080 812 1433 1029 816 248 218 422 1247 1329 2155 720 907 -178 -312 516 613 433 279 226 494 213 -298 -366 -1540 -328 -718 -494 -892 -1524 -1255 -1260 -867 -47 103 411 546 733 511 -13 461 280 377 150 781 290 225 -242 -708 -273 -35 -842 -766 -859 -930 -314 169 152 -7 295 119 54 213 435 183 201 -102 -386 -181 111 186 630 126 175 812 410 470 64 -180 -256 -87 -157 -186 45 -46 -113 -1 38 -273 137 -511 -570 -477 -609 -510 -657 -477 -651 -325 -459 -240 -606 -279 -545 -306 -439 -115 -333 -104 -201 -212 -56 -336 -140 -254 51 -342 -176 -330 -99 -394 93 27 -13 -302 -321 -388 -96 72 -131 30 -265 62 -193 230 -155 62 -115 0 15 299 302 412 330 265 483 362 289 86 74 145 462 556 1008 363 439 -83 -147 259 331 262 179 145 302 121 -164 -184 -763 -173 -414 -331 -686 -1207 -1044 -1119 -824 -47 106 425 548 683 441 -10 399 246 379 161 956 369 289 -314 -833 -289 -40 -972 -941 -1104 -1192 -429 255 238 -12 488 189 85 315 638 281 310 -168 -638 -289 171 294 949 185 243 1126 634 768 115 -322 -476 -169 -310 -392 98 -101 -251 -2 78 -555 267 SS 20241024T130905.8Z 9063.547984 316 1 30.02 2 76.68 121.59 28.45 232.05 0.00 1 0.00 1 0 17 9.115e-02 4.548e-03 1.526e-02 7.218e-04 5.128705e-01 3.602050e-04 6.101537e-03 -6.000000e+00 5.020581e-02 224.52 -2.00 3.57 -2.00 319.81 0.00e+00 7.159235e-04 1.105963e-04 3.073788e-04 -6.000000e+00 2.211089e-03 280.11 -2.00 20.00 -2.00 319.20 0.00e+00 4.235 0.001 302.00 328.00 3 1.9551e-01 1.0303e-03 4.9377e-02 -6.0000e+00 1.2406e-01 3.8156e-02 1.2491e-03 2.7078e-02 -6.0000e+00 1.3507e-01 -8.0337e-03 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