File name: Pandora145s1_Toronto-Scarborough_20241025_L2Fit_fwvt1c8d20221111p1-8.txt File generation date: 20241026T051107.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 145 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora145_OF_v5d20190718.txt Instrument calibration file used: Pandora145s1_CF_v8d20221111.txt Level 1 file used: Pandora145s1_Toronto-Scarborough_20241025_L1_smca1c8d20221111p1-8.txt Full location name: University of Toronto - Scarborough Short location name: Toronto-Scarborough Country of location: Canada Location latitude [deg]: 43.7843 Location longitude [deg]: -79.1874 Location altitude [m]: 137 Local noon date: 20241025 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 4 for field cal VP 20221111 First and last pixel inside fitting window: 1647 1796 Nominal wavelengths inside fitting window [nm]: 492.0874 492.2085 492.3296 492.4507 492.5718 492.6928 492.8138 492.9348 493.0558 493.1768 493.2978 493.4187 493.5397 493.6606 493.7815 493.9024 494.0232 494.1441 494.2649 494.3857 494.5065 494.6273 494.7481 494.8688 494.9895 495.1102 495.2309 495.3516 495.4723 495.5929 495.7136 495.8342 495.9548 496.0754 496.1959 496.3165 496.4370 496.5575 496.6780 496.7985 496.9190 497.0394 497.1598 497.2803 497.4007 497.5210 497.6414 497.7618 497.8821 498.0024 498.1227 498.2430 498.3632 498.4835 498.6037 498.7239 498.8441 498.9643 499.0845 499.2046 499.3248 499.4449 499.5650 499.6850 499.8051 499.9252 500.0452 500.1652 500.2852 500.4052 500.5251 500.6451 500.7650 500.8849 501.0048 501.1247 501.2446 501.3644 501.4842 501.6040 501.7238 501.8436 501.9634 502.0831 502.2029 502.3226 502.4423 502.5619 502.6816 502.8012 502.9209 503.0405 503.1601 503.2796 503.3992 503.5187 503.6383 503.7578 503.8773 503.9967 504.1162 504.2356 504.3551 504.4745 504.5939 504.7132 504.8326 504.9519 505.0712 505.1905 505.3098 505.4291 505.5484 505.6676 505.7868 505.9060 506.0252 506.1444 506.2635 506.3827 506.5018 506.6209 506.7400 506.8590 506.9781 507.0971 507.2161 507.3351 507.4541 507.5731 507.6920 507.8110 507.9299 508.0488 508.1677 508.2865 508.4054 508.5242 508.6430 508.7618 508.8806 508.9993 509.1181 509.2368 509.3555 509.4742 509.5929 509.7116 509.8302 509.9488 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241025T115158.6Z 9064.494429 265 1 29.70 2 89.54 107.72 24.86 165.16 0.00 1 0.00 1 0 22 1.591e-02 1.561e-02 9.656e-04 9.591e-04 1.230009e+04 6.178698e+01 7.843317e+02 -6.000000e+00 8.337924e+02 279.99 -2.00 20.00 -2.00 505.47 0.00e+00 5.099918e-03 2.608929e-05 2.676181e-04 -6.000000e+00 4.357267e-04 279.99 -2.00 20.00 -2.00 501.26 0.00e+00 1.018763e+00 1.797938e-02 1.075319e-01 -6.000000e+00 3.077717e-01 224.43 -2.00 3.57 -2.00 502.72 0.00e+00 19.853 0.153 489.00 513.00 1 4.3223e+00 1.3720e-03 3.6985e-02 -6.0000e+00 2.3513e-02 -6.6454e-02 3.4747e-04 3.0382e-03 -6.0000e+00 6.1973e-03 1.3685e-03 7.6076e-04 7.6888e-05 1.2954e-04 -6.0000e+00 1.3551e-03 4.1477e-04 -5.2827e-05 12 8 8 10 0 0 84.68 18.19 10.13 0.00041 0.00569 19 19 1 4 0 1562.620 22.90 15.00 18.19 16.29 25.6 1065.22 -5579 -3989 -2431 -763 51 963 1481 1762 1477 719 -287 -649 -1592 -1953 -2360 -1828 -979 13 1010 1052 792 995 1175 1419 1730 1577 1590 672 -613 -2417 -2892 -2119 -921 656 2064 1657 950 496 131 -109 215 905 1338 2038 2326 2305 2002 1443 578 -691 -1997 -2579 -2779 -1940 -544 912 1460 1406 1401 1104 1658 1842 2059 1954 1569 650 27 -246 -1082 -1468 -1763 -1396 -520 -28 -155 -508 -1514 -2113 -2403 -2214 -2093 -1248 -1381 -1044 -723 -399 -806 -899 -605 -498 332 1017 1981 2111 1664 1115 492 -880 -2215 -2825 -2923 -2120 -559 767 1106 396 -634 -1169 -1459 -757 140 1026 1757 2056 2572 2862 2957 2578 1528 895 114 -196 211 701 1037 941 646 522 708 264 -55 -759 -1760 -2113 -2047 -1488 -518 295 534 562 529 570 767 1104 892 239 -921 -2088 -2772 -2573 -4863 -3513 -2112 -680 47 887 1386 1660 1390 672 -267 -600 -1462 -1780 -2159 -1679 -908 11 936 984 743 935 1107 1348 1659 1521 1534 648 -580 -2247 -2679 -1970 -871 616 1974 1595 911 474 124 -103 206 876 1314 2026 2341 2246 1949 1452 578 -682 -1939 -2471 -2657 -1876 -540 891 1453 1414 1409 1113 1673 1878 2110 2006 1603 661 27 -247 -1082 -1452 -1743 -1388 -520 -28 -159 -516 -1522 -2104 -2381 -2183 -2076 -1241 -1384 -1054 -714 -395 -801 -888 -593 -490 327 1019 1999 2114 1631 1105 475 -839 -2096 -2648 -2753 -2036 -536 767 1139 398 -640 -1169 -1463 -770 144 1068 1835 2159 2702 3032 3087 2738 1633 947 119 -208 224 725 1081 988 685 555 752 283 -58 -797 -1852 -2228 -2171 -1611 -553 318 582 623 592 643 870 1254 1014 272 -1036 -2323 -3070 -2867 SQ 20241025T115455.4Z 9064.496474 269 1 30.19 2 89.04 108.23 24.74 166.76 0.00 1 0.00 1 0 22 1.040e-02 1.021e-02 4.732e-04 4.706e-04 1.371973e+04 3.080996e+01 9.068449e+02 -6.000000e+00 5.448520e+02 279.99 -2.00 20.00 -2.00 505.45 0.00e+00 4.927446e-03 1.279688e-05 2.702971e-04 -6.000000e+00 2.847605e-04 279.99 -2.00 20.00 -2.00 501.17 0.00e+00 1.160429e+00 8.865693e-03 1.071641e-01 -6.000000e+00 2.012228e-01 224.43 -2.00 3.57 -2.00 502.65 0.00e+00 18.793 0.129 489.00 513.00 1 3.1255e+00 6.7595e-04 3.4025e-02 -6.0000e+00 1.5371e-02 -6.5374e-02 1.7218e-04 3.0102e-03 -6.0000e+00 4.0545e-03 5.1915e-03 4.7460e-04 3.7267e-05 1.4192e-04 -6.0000e+00 8.8574e-04 1.2757e-02 -1.7030e-04 12 8 8 10 0 0 80.22 18.19 5.65 0.01276 0.01605 65 65 1 4 0 464.380 22.90 14.99 18.19 16.40 25.3 1065.11 -3208 -2312 -1092 -225 696 960 1466 1505 1234 682 190 -296 -725 -1194 -1307 -1166 -716 71 513 800 510 496 651 893 1108 1196 1011 468 -361 -1604 -2055 -1481 -637 317 1043 1095 454 44 -143 -321 -83 273 670 1099 1566 1400 1092 812 153 -552 -1440 -1912 -1948 -1522 -537 337 802 923 791 671 898 1270 1342 1238 820 493 22 -362 -756 -942 -1331 -1043 -356 -165 63 -327 -809 -1475 -1686 -1525 -1394 -1028 -745 -865 -531 -356 -581 -708 -555 -287 10 709 1175 1401 1226 804 421 -625 -1333 -1935 -2091 -1666 -656 161 706 256 -381 -842 -914 -634 100 639 1059 1318 1686 1901 1917 1744 1183 569 128 -77 86 307 749 711 402 448 453 250 77 -402 -1023 -1251 -1180 -963 -240 333 323 393 494 353 681 756 714 396 -546 -1311 -1774 -1727 -2760 -2021 -985 -203 639 900 1353 1403 1149 629 179 -278 -673 -1100 -1204 -1082 -652 66 489 769 493 481 613 847 1060 1150 974 449 -339 -1516 -1932 -1399 -594 306 1038 1059 437 43 -140 -315 -82 265 660 1097 1580 1423 1110 819 153 -543 -1385 -1867 -1893 -1453 -527 331 804 933 801 679 912 1300 1383 1279 844 501 22 -362 -752 -924 -1305 -1029 -354 -167 64 -331 -804 -1451 -1648 -1482 -1361 -1010 -735 -864 -537 -352 -575 -696 -558 -289 10 708 1188 1403 1232 785 399 -600 -1261 -1813 -1967 -1556 -637 160 723 258 -384 -840 -911 -642 103 665 1110 1387 1776 1965 2023 1873 1274 608 134 -79 88 318 783 748 428 477 483 268 82 -421 -1069 -1308 -1241 -1008 -257 360 346 428 542 392 758 845 798 441 -602 -1423 -1912 -1873 SQ 20241025T115749.0Z 9064.498484 273 1 30.03 2 88.54 108.73 24.64 168.34 0.00 1 0.00 1 0 22 8.731e-03 8.594e-03 4.584e-04 4.564e-04 1.298384e+04 2.972750e+01 8.720995e+02 -6.000000e+00 4.576389e+02 279.99 -2.00 20.00 -2.00 505.43 0.00e+00 4.382032e-03 1.236839e-05 2.408605e-04 -6.000000e+00 2.391692e-04 279.99 -2.00 20.00 -2.00 501.10 0.00e+00 1.180610e+00 8.599991e-03 9.833564e-02 -6.000000e+00 1.690781e-01 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