File name: Pandora145s1_Toronto-Scarborough_20241025_L2Fit_fwvt1c9d20230821p1-8.txt File generation date: 20241123T101733.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 145 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora145_OF_v5d20190718.txt Instrument calibration file used: Pandora145s1_CF_v9d20230821.txt Level 1 file used: Pandora145s1_Toronto-Scarborough_20241025_L1_smca1c9d20230821p1-8.txt Full location name: University of Toronto - Scarborough Short location name: Toronto-Scarborough Country of location: Canada Location latitude [deg]: 43.7843 Location longitude [deg]: -79.1874 Location altitude [m]: 137 Local noon date: 20241025 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: field cal for autumn2023 ff, based on Session 8(7) First and last pixel inside fitting window: 1647 1796 Nominal wavelengths inside fitting window [nm]: 492.0731 492.1943 492.3153 492.4364 492.5575 492.6785 492.7995 492.9205 493.0415 493.1625 493.2834 493.4044 493.5253 493.6462 493.7671 493.8880 494.0088 494.1297 494.2505 494.3713 494.4921 494.6128 494.7336 494.8543 494.9751 495.0958 495.2165 495.3371 495.4578 495.5784 495.6990 495.8197 495.9402 496.0608 496.1814 496.3019 496.4224 496.5429 496.6634 496.7839 496.9044 497.0248 497.1452 497.2656 497.3860 497.5064 497.6267 497.7471 497.8674 497.9877 498.1080 498.2283 498.3485 498.4688 498.5890 498.7092 498.8294 498.9495 499.0697 499.1898 499.3100 499.4301 499.5502 499.6702 499.7903 499.9103 500.0303 500.1503 500.2703 500.3903 500.5103 500.6302 500.7501 500.8700 500.9899 501.1098 501.2296 501.3495 501.4693 501.5891 501.7089 501.8286 501.9484 502.0681 502.1878 502.3075 502.4272 502.5469 502.6665 502.7862 502.9058 503.0254 503.1450 503.2645 503.3841 503.5036 503.6231 503.7426 503.8621 503.9816 504.1010 504.2205 504.3399 504.4593 504.5786 504.6980 504.8174 504.9367 505.0560 505.1753 505.2946 505.4138 505.5331 505.6523 505.7715 505.8907 506.0099 506.1290 506.2482 506.3673 506.4864 506.6055 506.7246 506.8436 506.9627 507.0817 507.2007 507.3197 507.4387 507.5576 507.6766 507.7955 507.9144 508.0333 508.1522 508.2710 508.3899 508.5087 508.6275 508.7463 508.8650 508.9838 509.1025 509.2212 509.3399 509.4586 509.5773 509.6959 509.8146 509.9332 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241025T115158.6Z 9064.494429 265 1 29.70 2 89.54 107.72 24.86 165.16 0.00 1 0.00 1 0 29 1.588e-02 1.558e-02 9.667e-04 9.602e-04 1.231754e+04 6.185409e+01 7.921142e+02 -6.000000e+00 8.323335e+02 279.99 -2.00 20.00 -2.00 505.47 0.00e+00 5.102771e-03 2.611542e-05 2.659278e-04 -6.000000e+00 4.350027e-04 279.99 -2.00 20.00 -2.00 501.25 0.00e+00 1.021611e+00 1.799693e-02 1.062524e-01 -6.000000e+00 3.074026e-01 224.43 -2.00 3.57 -2.00 502.72 0.00e+00 19.853 0.153 489.00 513.00 1 4.5369e+00 1.3735e-03 3.6958e-02 -6.0000e+00 2.3482e-02 -6.6696e-02 3.4778e-04 3.0263e-03 -6.0000e+00 6.1938e-03 1.1038e-03 1.7745e-03 7.6960e-05 1.3086e-04 -6.0000e+00 1.3530e-03 -1.3746e-03 1.0809e-05 12 8 8 10 0 0 84.04 18.19 10.37 -0.00137 0.01093 19 19 1 4 0 1562.620 22.90 15.00 18.19 16.29 25.6 1065.22 -5571 -3981 -2421 -760 52 967 1479 1763 1479 718 -288 -649 -1591 -1950 -2353 -1825 -977 13 1008 1050 789 992 1177 1421 1727 1573 1587 673 -609 -2411 -2885 -2112 -916 654 2065 1653 951 494 134 -105 214 904 1336 2035 2323 2301 1999 1440 577 -686 -1990 -2572 -2771 -1934 -541 910 1456 1403 1401 1104 1658 1841 2058 1950 1566 651 29 -247 -1078 -1466 -1758 -1392 -517 -26 -153 -504 -1509 -2108 -2398 -2206 -2090 -1242 -1379 -1043 -723 -398 -806 -899 -606 -500 329 1016 1979 2111 1661 1116 494 -877 -2211 -2820 -2920 -2120 -563 759 1104 394 -634 -1167 -1460 -760 136 1023 1753 2052 2567 2855 2950 2574 1527 893 116 -194 209 697 1035 939 648 525 707 264 -52 -756 -1757 -2110 -2045 -1490 -519 295 532 558 529 568 765 1105 893 241 -913 -2079 -2764 -2569 -4855 -3505 -2103 -677 47 891 1385 1662 1392 670 -268 -599 -1461 -1777 -2152 -1676 -906 12 934 982 741 933 1109 1350 1656 1518 1531 649 -576 -2241 -2672 -1964 -866 614 1975 1592 912 472 127 -100 206 875 1312 2024 2337 2243 1946 1396 577 -678 -1933 -2464 -2650 -1870 -537 889 1450 1411 1410 1113 1673 1878 2110 2003 1601 662 29 -247 -1078 -1451 -1739 -1385 -517 -26 -157 -513 -1518 -2099 -2376 -2176 -2074 -1235 -1382 -1054 -714 -395 -801 -888 -594 -491 325 1017 1998 2114 1629 1106 478 -836 -2092 -2644 -2751 -2037 -540 759 1137 396 -640 -1168 -1464 -773 141 1064 1831 2155 2698 3026 3081 2735 1633 946 121 -207 222 721 1079 986 687 558 751 283 -55 -794 -1850 -2225 -2170 -1613 -554 317 581 619 593 641 868 1256 1017 274 -1027 -2313 -3064 -2864 SQ 20241025T115455.4Z 9064.496474 269 1 30.19 2 89.04 108.23 24.74 166.76 0.00 1 0.00 1 0 22 1.038e-02 1.019e-02 4.734e-04 4.708e-04 1.373240e+04 3.083278e+01 9.124973e+02 -6.000000e+00 5.441142e+02 279.99 -2.00 20.00 -2.00 505.45 0.00e+00 4.927527e-03 1.279522e-05 2.689975e-04 -6.000000e+00 2.843663e-04 279.99 -2.00 20.00 -2.00 501.16 0.00e+00 1.159695e+00 8.866939e-03 1.061731e-01 -6.000000e+00 2.010171e-01 224.43 -2.00 3.57 -2.00 502.64 0.00e+00 18.793 0.129 489.00 513.00 1 3.3397e+00 6.7597e-04 3.4002e-02 -6.0000e+00 1.5355e-02 -6.5442e-02 1.7224e-04 3.0000e-03 -6.0000e+00 4.0517e-03 4.1903e-03 1.1319e-03 3.7263e-05 1.4251e-04 -6.0000e+00 8.8463e-04 9.7526e-03 -8.1930e-05 12 8 8 10 0 0 80.22 18.19 5.79 0.00975 0.01760 65 65 1 4 0 464.380 22.90 14.99 18.19 16.40 25.3 1065.11 -3202 -2311 -1094 -226 695 956 1463 1503 1233 684 192 -295 -721 -1191 -1303 -1165 -718 69 510 798 509 495 649 891 1106 1194 1010 467 -358 -1600 -2053 -1480 -638 313 1039 1092 453 43 -143 -321 -84 270 668 1095 1563 1397 1090 811 152 -551 -1439 -1908 -1946 -1523 -537 335 800 921 789 669 896 1268 1340 1236 819 491 22 -362 -756 -940 -1328 -1041 -355 -165 63 -327 -807 -1472 -1682 -1521 -1392 -1025 -743 -862 -530 -354 -580 -706 -554 -286 10 710 1174 1400 1224 803 420 -625 -1333 -1933 -2089 -1663 -653 162 707 257 -379 -839 -911 -632 102 640 1059 1318 1684 1898 1915 1743 1181 569 127 -77 87 307 749 710 402 447 453 249 77 -403 -1023 -1249 -1178 -960 -239 333 322 393 493 352 680 754 712 393 -547 -1311 -1772 -1725 -2753 -2019 -986 -204 638 896 1349 1400 1148 630 181 -277 -669 -1097 -1200 -1081 -653 64 487 767 491 480 610 844 1059 1147 972 448 -336 -1512 -1929 -1398 -595 303 1033 1056 450 42 -140 -315 -83 262 657 1093 1576 1420 1107 817 152 -542 -1383 -1862 -1890 -1452 -527 338 801 930 798 676 909 1297 1380 1276 842 499 22 -361 -751 -922 -1301 -1026 -352 -166 64 -330 -802 -1447 -1643 -1477 -1358 -1007 -732 -860 -537 -351 -574 -715 -557 -287 10 708 1186 1401 1228 783 398 -599 -1260 -1810 -1963 -1552 -635 161 723 259 -382 -837 -907 -639 105 666 1108 1386 1773 1962 2020 1870 1271 607 133 -79 89 319 782 747 427 475 483 267 81 -421 -1068 -1305 -1238 -1005 -255 360 345 427 541 390 758 843 796 437 -602 -1421 -1908 -1869 SQ 20241025T115749.0Z 9064.498484 273 1 30.03 2 88.54 108.73 24.64 168.34 0.00 1 0.00 1 0 22 8.719e-03 8.584e-03 4.583e-04 4.563e-04 1.299073e+04 2.964513e+01 8.758603e+02 -6.000000e+00 4.570594e+02 279.99 -2.00 20.00 -2.00 505.43 0.00e+00 4.380753e-03 1.237007e-05 2.396059e-04 -6.000000e+00 2.388662e-04 279.99 -2.00 20.00 -2.00 501.10 0.00e+00 1.180403e+00 8.593209e-03 9.754398e-02 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