File name: Pandora145s1_Toronto-Scarborough_20241029_L2Fit_fnvs5c9d20230821p1-8.txt File generation date: 20241123T101315.9Z Data description: Level 2 spectral fitting results file Data file version: fnvs5c9p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 145 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora145_OF_v5d20190718.txt Instrument calibration file used: Pandora145s1_CF_v9d20230821.txt Level 1 file used: Pandora145s1_Toronto-Scarborough_20241029_L1_smca1c9d20230821p1-8.txt Full location name: University of Toronto - Scarborough Short location name: Toronto-Scarborough Country of location: Canada Location latitude [deg]: 43.7843 Location longitude [deg]: -79.1874 Location altitude [m]: 137 Local noon date: 20241029 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: field cal for autumn2023 ff, based on Session 8(7) First and last pixel inside fitting window: 921 1466 Nominal wavelengths inside fitting window [nm]: 400.0239 400.1561 400.2882 400.4203 400.5524 400.6845 400.8166 400.9486 401.0807 401.2127 401.3447 401.4767 401.6087 401.7407 401.8727 402.0046 402.1366 402.2685 402.4004 402.5323 402.6642 402.7960 402.9279 403.0597 403.1915 403.3233 403.4551 403.5869 403.7187 403.8504 403.9822 404.1139 404.2456 404.3773 404.5090 404.6407 404.7723 404.9040 405.0356 405.1672 405.2988 405.4304 405.5619 405.6935 405.8250 405.9566 406.0881 406.2196 406.3511 406.4825 406.6140 406.7454 406.8769 407.0083 407.1397 407.2711 407.4025 407.5338 407.6652 407.7965 407.9278 408.0591 408.1904 408.3217 408.4529 408.5842 408.7154 408.8466 408.9778 409.1090 409.2402 409.3714 409.5025 409.6336 409.7648 409.8959 410.0270 410.1580 410.2891 410.4201 410.5512 410.6822 410.8132 410.9442 411.0752 411.2061 411.3371 411.4680 411.5989 411.7298 411.8607 411.9916 412.1225 412.2533 412.3842 412.5150 412.6458 412.7766 412.9074 413.0381 413.1689 413.2996 413.4303 413.5610 413.6917 413.8224 413.9531 414.0837 414.2143 414.3450 414.4756 414.6062 414.7367 414.8673 414.9979 415.1284 415.2589 415.3894 415.5199 415.6504 415.7809 415.9113 416.0417 416.1722 416.3026 416.4330 416.5633 416.6937 416.8240 416.9544 417.0847 417.2150 417.3453 417.4756 417.6058 417.7361 417.8663 417.9965 418.1267 418.2569 418.3871 418.5173 418.6474 418.7775 418.9077 419.0378 419.1679 419.2979 419.4280 419.5580 419.6881 419.8181 419.9481 420.0781 420.2080 420.3380 420.4680 420.5979 420.7278 420.8577 420.9876 421.1175 421.2473 421.3772 421.5070 421.6368 421.7666 421.8964 422.0262 422.1559 422.2857 422.4154 422.5451 422.6748 422.8045 422.9341 423.0638 423.1934 423.3231 423.4527 423.5823 423.7119 423.8414 423.9710 424.1005 424.2300 424.3596 424.4890 424.6185 424.7480 424.8774 425.0069 425.1363 425.2657 425.3951 425.5245 425.6538 425.7832 425.9125 426.0418 426.1712 426.3004 426.4297 426.5590 426.6882 426.8175 426.9467 427.0759 427.2051 427.3342 427.4634 427.5925 427.7217 427.8508 427.9799 428.1090 428.2380 428.3671 428.4961 428.6252 428.7542 428.8832 429.0122 429.1411 429.2701 429.3990 429.5279 429.6568 429.7857 429.9146 430.0435 430.1723 430.3012 430.4300 430.5588 430.6876 430.8164 430.9451 431.0739 431.2026 431.3313 431.4600 431.5887 431.7174 431.8460 431.9747 432.1033 432.2319 432.3605 432.4891 432.6177 432.7462 432.8748 433.0033 433.1318 433.2603 433.3888 433.5173 433.6457 433.7741 433.9026 434.0310 434.1594 434.2877 434.4161 434.5445 434.6728 434.8011 434.9294 435.0577 435.1860 435.3142 435.4425 435.5707 435.6989 435.8271 435.9553 436.0835 436.2116 436.3398 436.4679 436.5960 436.7241 436.8522 436.9802 437.1083 437.2363 437.3643 437.4923 437.6203 437.7483 437.8763 438.0042 438.1321 438.2601 438.3880 438.5158 438.6437 438.7716 438.8994 439.0272 439.1550 439.2828 439.4106 439.5384 439.6661 439.7939 439.9216 440.0493 440.1770 440.3047 440.4323 440.5600 440.6876 440.8152 440.9428 441.0704 441.1980 441.3255 441.4531 441.5806 441.7081 441.8356 441.9631 442.0906 442.2180 442.3454 442.4729 442.6003 442.7277 442.8550 442.9824 443.1097 443.2371 443.3644 443.4917 443.6190 443.7462 443.8735 444.0007 444.1279 444.2552 444.3824 444.5095 444.6367 444.7638 444.8910 445.0181 445.1452 445.2723 445.3994 445.5264 445.6535 445.7805 445.9075 446.0345 446.1615 446.2884 446.4154 446.5423 446.6693 446.7962 446.9231 447.0499 447.1768 447.3036 447.4305 447.5573 447.6841 447.8109 447.9376 448.0644 448.1911 448.3178 448.4446 448.5712 448.6979 448.8246 448.9512 449.0779 449.2045 449.3311 449.4577 449.5842 449.7108 449.8373 449.9639 450.0904 450.2169 450.3434 450.4698 450.5963 450.7227 450.8491 450.9755 451.1019 451.2283 451.3546 451.4810 451.6073 451.7336 451.8599 451.9862 452.1125 452.2387 452.3649 452.4912 452.6174 452.7436 452.8697 452.9959 453.1220 453.2482 453.3743 453.5004 453.6264 453.7525 453.8786 454.0046 454.1306 454.2566 454.3826 454.5086 454.6345 454.7605 454.8864 455.0123 455.1382 455.2641 455.3900 455.5158 455.6416 455.7675 455.8933 456.0191 456.1448 456.2706 456.3963 456.5221 456.6478 456.7735 456.8991 457.0248 457.1505 457.2761 457.4017 457.5273 457.6529 457.7785 457.9040 458.0296 458.1551 458.2806 458.4061 458.5316 458.6570 458.7825 458.9079 459.0333 459.1587 459.2841 459.4095 459.5348 459.6602 459.7855 459.9108 460.0361 460.1614 460.2866 460.4119 460.5371 460.6623 460.7875 460.9127 461.0379 461.1630 461.2882 461.4133 461.5384 461.6635 461.7886 461.9136 462.0387 462.1637 462.2887 462.4137 462.5387 462.6636 462.7886 462.9135 463.0384 463.1633 463.2882 463.4131 463.5379 463.6628 463.7876 463.9124 464.0372 464.1620 464.2867 464.4115 464.5362 464.6609 464.7856 464.9103 465.0350 465.1596 465.2843 465.4089 465.5335 465.6581 465.7827 465.9072 466.0318 466.1563 466.2808 466.4053 466.5298 466.6542 466.7787 466.9031 467.0275 467.1519 467.2763 467.4007 467.5250 467.6494 467.7737 467.8980 468.0223 468.1465 468.2708 468.3950 468.5193 468.6435 468.7677 468.8918 469.0160 469.1402 469.2643 469.3884 469.5125 469.6366 469.7606 469.8847 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Molecular iodine slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of molecular iodine slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Molecular iodine effective temperature [K] Column 39: Independent uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective molecular iodine fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for molecular iodine [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrogen dioxide effective temperature [K] Column 50: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 56: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Oxygen dimer effective temperature [K] Column 61: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 76: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 77: Iodine dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 78: Independent uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 79: Structured uncertainty of iodine dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 80: Common uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: rms-based uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 82: Iodine dioxide effective temperature [K] Column 83: Independent uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 84: Structured uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 85: Common uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 86: Effective iodine dioxide fitting wavelength [nm], -9=fitting not successful Column 87: Diffuse correction applied before fitting at effective fitting wavelength for iodine dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 88: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 89: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 90: Lower limit used for wavelength scaling [nm] Column 91: Upper limit used for wavelength scaling [nm] Column 92: Order of smoothing polynomial Column 93: Smoothing polynomial coefficient, order 0 Column 94: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 95: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: Smoothing polynomial coefficient, order 1 Column 99: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 100: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: Smoothing polynomial coefficient, order 2 Column 104: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 105: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: Smoothing polynomial coefficient, order 3 Column 109: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 110: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: Smoothing polynomial coefficient, order 4 Column 114: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 115: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: Mean value of measured data inside fitting window [same units as measurements] Column 119: Offset polynomial coefficient, order 0 Column 120: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 121: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: Wavelength change polynomial coefficient, order 0 Column 125: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 126: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: Wavelength change polynomial coefficient, order 1 Column 130: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 131: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 132: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 133: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 134: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 135: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 136: Resolution change polynomial coefficient, order 0 Column 137: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 138: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 139: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 140: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 141: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 142: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 143: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 144: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 145: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 146: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 147: Atmospheric variability [%], 999=no atmospheric variability was determined Column 148: Wavelength effective temperature [°C], 999=no effective temperature given Column 149: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 150: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 151: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 152: Number of bright count cycles Column 153: Number of dark count cycles Column 154: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 155: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 156: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 157: Integration time [ms] Column 158: Temperature at electronics board [°C], 999=no temperature signal Column 159: Spectrometer control temperature [°C], 999=no temperature signal Column 160: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 161: Temperature in head sensor [°C], 999=no temperature signal Column 162: Humidity in head sensor [%], -9=no humidity signal Column 163: Pressure in head sensor [hPa], -9=no pressure signal Columns 164-709: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 710-1255: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241029T115910.2Z 9068.499423 126 1 29.35 2 89.21 109.96 60.84 125.92 0.00 1 0.00 1 7 263 4.350e-02 3.277e-02 4.262e-03 3.451e-03 4.269620e+04 6.977976e+02 3.897497e+03 3.052243e+02 8.511803e+03 279.48 -2.00 20.00 -2.00 452.25 0.00e+00 -7.218727e-03 4.591131e-04 1.146434e-04 1.901358e-05 4.774516e-03 279.48 -2.00 20.00 -2.00 459.61 0.00e+00 3.370888e-03 3.287079e-05 2.371406e-05 1.301469e-05 3.966577e-04 222.20 -2.00 2.20 -2.00 445.62 0.00e+00 -3.406122e+06 4.891099e+05 6.496692e+05 1.877875e+05 6.288104e+06 261.32 -2.00 11.30 -2.00 461.82 0.00e+00 4.828061e+00 8.172410e-02 1.786410e-02 7.186057e-03 1.343699e+00 224.06 -2.00 3.57 -2.00 458.93 0.00e+00 5.793912e-05 1.085668e-05 4.383093e-06 9.583087e-07 1.647658e-04 279.48 -2.00 20.00 -2.00 459.44 0.00e+00 19.213 0.138 397.00 473.00 4 6.3265e+00 8.7722e-03 5.9351e-02 2.7951e-04 9.0420e-02 -1.7941e-01 9.1080e-03 1.2501e-02 4.0808e-04 9.5275e-02 2.1989e-02 2.7114e-03 1.6868e-03 1.0375e-04 2.7769e-02 1.6338e-01 1.0277e-03 4.0524e-04 1.1087e-05 1.0478e-02 -8.5622e-02 6.2738e-04 3.0902e-04 1.8307e-05 6.6536e-03 1.2156e-04 -1.1178e+00 8.0377e-03 1.4960e-03 2.3506e-04 8.2504e-02 -4.1907e-04 3.6650e-05 5.8460e-06 2.4212e-07 4.2428e-04 -1.1403e-05 4.8373e-05 1.0019e-05 3.1420e-07 5.7702e-04 1.2245e-02 -1.1320e-04 1.5802e+01 3.2117e-01 5.7066e-02 2.9237e-03 3.3794e+00 12 10 8 10 0 0 82.05 18.07 4.36 0.01224 0.00401 14 14 1 4 0 2096.300 22.80 14.99 18.07 16.63 25.3 1066.64 -1113 -2855 -1387 -6640 -1333 -6135 -3104 -6590 -60 129 4535 -1109 1180 2099 2516 4770 -590 4980 -457 5663 807 1959 -4319 -1405 -5699 -6084 -5301 -2112 2423 2833 7787 -1996 -2739 -8869 -7375 -8422 -3158 -7567 -508 417 1425 -3931 -4128 -4781 -5213 -659 -4456 -1946 -6818 -7040 -4985 -155 -3562 4306 3821 2023 -935 -988 -495 634 1514 1586 1699 2220 8390 2562 9603 5478 7723 3374 7323 4785 5225 -123 -3488 -7445 -8673 -8490 -5222 -3921 -3609 2398 1537 6105 4758 7416 7822 11067 7754 11021 8424 10951 4980 5214 7543 4801 8942 793 7519 725 3007 -2297 3654 722 5011 3152 6338 5686 6472 2675 3755 2471 1649 8401 3230 5750 1604 6343 4817 4706 2391 7116 4537 9391 3451 4852 5489 3419 4691 604 3476 -143 1812 -4717 -202 713 1029 0 1070 -656 1096 -3213 -613 -2645 -4591 -2457 -1042 1164 60 -3595 -4575 -4966 -8263 -6175 -6128 -2711 -5114 -547 -2104 943 488 1171 1711 -2225 1216 -1331 -2242 -841 -52 -3483 -3762 -11132 -6633 -8692 -6781 -4351 -2708 -1845 -1176 -1836 -7245 -4806 -7324 -3619 -3001 -155 -4932 -398 -4869 -3121 -3042 -2495 -4459 -3197 -554 -760 1523 -3524 -2399 -1276 -2659 -689 2214 -1199 173 -4082 -4484 -4699 -6695 -7400 -5178 -3577 -1486 586 -432 1804 -2639 -678 -2092 -3333 -6040 -4972 -3206 -976 -4078 -2787 -4064 -7041 -7430 -12357 -14087 -16332 -15944 -18824 -16657 -20056 -15574 -18704 -13546 -11769 -3092 -603 2929 2732 5503 3738 3429 2323 -1759 2869 -1881 -1456 1278 4944 4299 6907 4444 3205 344 -613 -2608 -1868 -3279 -3602 -300 -547 3309 1351 3187 3662 2487 1117 3028 -516 3924 5290 6151 6632 5667 7139 6326 7920 5064 9125 5460 6586 5175 7326 7793 5934 4856 7189 4215 1184 3341 3155 1847 -272 1834 2411 4939 3037 5069 3872 7617 3604 3665 4575 6926 4244 4478 4114 3186 5547 4541 6239 4510 5329 4455 5479 3892 5192 1843 3117 3499 3877 2278 -386 -1988 -2515 105 -1865 21 -1558 33 518 2987 -1219 -1606 -956 1286 -27 -769 -1394 -836 1554 -308 546 -1359 -1659 -2045 -568 -1608 -1608 -3454 -1009 -1780 313 -1292 -59 -313 304 654 695 629 -1274 383 460 900 -1066 -305 204 1779 -427 -2442 -2790 1106 1816 619 -535 -1744 -1377 -1542 -176 -2188 -1350 -1302 -1074 -752 -803 -2182 -1627 -500 -2115 -1826 -1889 -1673 -2139 -1815 -3741 -2958 -2954 -1936 -3449 -3486 -4194 -2443 -698 -1095 -1319 -2643 -3228 -2019 -197 19553 -165 -3741 -1570 -2591 -1175 -2179 -695 -1065 885 644 500 443 630 -315 540 366 245 763 -122 573 -1284 182 604 936 -605 -203 -1935 9 -53 1231 1378 621 587 -409 1133 590 2127 -167 1076 791 1540 670 -1181 -1185 -192 201 722 673 279 1101 -372 204 220 637 407 642 -213 213 -1187 -1246 -171 637 56 -1281 -1447 -1713 -286 -1829 -1263 -2131 -1655 -2318 -865 98 499 237 1040 11 894 469 178 1127 1077 361 -374 -176 -442 1906 1657 2163 1093 124 -379 -496 709 500 -176 -886 -1703 -1995 -1123 -725 196 1049 2927 2853 3178 599 -124 -52 -131 -482 -247 -35 1516 1788 419 56 -1459 -1143 -906 -391 -130 867 -127 301 -1040 -924 -358 -90 1164 -650 -1679 -804 -3881 -764 -3559 -1792 -3893 -35 75 2613 -649 685 1217 1456 2743 -345 2864 -268 3260 471 1131 -2521 -803 -3258 -3477 -3053 -1221 1396 1642 4456 -1166 -1567 -5076 -4556 -5208 -1935 -4790 -318 261 885 -2460 -2563 -2974 -3264 -406 -2757 -1194 -4235 -4358 -3098 -96 -2239 2647 2362 1251 -578 -609 -305 390 932 983 1059 1389 5165 1611 5948 3465 4871 2157 4594 3002 3255 -77 -2178 -4609 -5326 -5203 -3186 -2420 -2271 1505 976 3846 3029 4717 5014 7073 5016 7055 5434 6982 3232 3392 4873 3122 5732 520 4785 467 1918 -1494 2344 474 3296 2109 4194 3740 4222 1764 2468 1641 1108 5565 2178 3830 1081 4201 3207 3146 1625 4808 3126 6412 2409 3370 3793 2375 3231 418 2373 -98 1236 -3281 -139 495 717 0 748 -424 703 -2087 -396 -1729 -3022 -1624 -694 771 40 -2392 -3024 -3261 -5465 -4075 -4094 -1813 -3492 -372 -1451 647 338 811 1178 -1549 835 -921 -1563 -589 -36 -2467 -2621 -7753 -4484 -5935 -4657 -3034 -1925 -1324 -839 -1301 -5204 -3414 -5279 -2598 -2169 -112 -3656 -290 -3591 -2270 -2203 -1808 -3265 -2349 -410 -567 1121 -2625 -1784 -949 -1999 -522 1692 -936 134 -3147 -3387 -3502 -4975 -5519 -3907 -2532 -1058 419 -312 1292 -1914 -488 -1517 -2414 -4373 -3587 -2317 -703 -2997 -2054 -2997 -5141 -5300 -8795 -9912 -11504 -11273 -13501 -11773 -14264 -10873 -13273 -9627 -8623 -2299 -465 2313 2219 4487 3066 2762 1827 -1373 2182 -1469 -1158 1037 4059 3585 5709 3693 2639 279 -485 -2033 -1441 -2565 -2898 -245 -460 2787 1072 2683 3059 2082 870 2357 -414 3136 4258 4986 5403 4696 5945 5298 6597 4277 7554 4583 5486 4321 6059 6463 4992 4141 6114 3595 994 2713 2537 1487 -223 1526 2041 4162 2587 4308 3355 6571 3177 3243 4067 6098 3730 3901 3606 2813 4894 4121 5755 3971 4686 3922 4789 3428 4575 1671 2840 3200 3520 2053 -348 -1805 -2295 95 -1726 19 -1446 31 484 2785 -1167 -1549 -919 1220 -26 -732 -1335 -760 1412 -283 498 -1246 -1509 -1850 -506 -1435 -1441 -3153 -923 -1663 294 -1239 -57 -304 296 639 684 624 -1288 388 468 909 -1074 -303 202 1746 -428 -2512 -2917 1143 1880 647 -562 -1848 -1468 -1662 -190 -2397 -1482 -1440 -1198 -795 -854 -2357 -1763 -541 -2311 -1989 -2055 -1817 -2324 -2082 -4078 -3229 -3248 -2121 -3813 -3847 -4901 -2798 -784 -1221 -1465 -2969 -3660 -2293 -225 20365 -193 -4537 -1912 -3024 -1447 -2686 -849 -1304 1066 771 599 532 758 -384 659 452 305 960 -156 740 -1675 234 777 1202 -786 -264 -2559 12 -69 1609 1803 819 773 -538 1468 761 2701 -214 1381 1031 2026 894 -1601 -1614 -261 272 970 904 377 1479 -504 277 299 868 559 890 -300 301 -1705 -1801 -247 915 81 -1872 -2128 -2538 -422 -2742 -1898 -3232 -2505 -3522 -1303 147 749 357 1554 17 1347 708 269 1705 1641 556 -584 -275 -694 2934 2552 3333 1713 198 -618 -816 1164 828 -295 -1511 -2948 -3479 -1948 -1243 327 1706 4658 4545 5075 982 -209 -89 -226 -840 -430 -62 2622 3087 732 98 -2624 -1953 -1558 -673 -223 1488 -221 522 -1832 -1630 -629 -157 2015 SQ 20241029T204721.7Z 9068.866223 468 1 30.37 2 77.34 236.32 88.88 263.47 0.00 1 0.00 1 0 33 1.676e-03 1.569e-03 1.520e-03 1.452e-03 5.192266e+03 2.814128e+02 4.335817e+02 3.051895e+02 3.285925e+02 279.44 -2.00 20.00 -2.00 446.73 0.00e+00 -1.986311e-04 1.618317e-04 3.963035e-06 1.257785e-05 1.793765e-04 279.44 -2.00 20.00 -2.00 456.05 0.00e+00 3.860319e-04 1.276573e-05 2.631154e-06 1.309192e-05 1.487765e-05 224.15 -2.00 2.20 -2.00 437.75 0.00e+00 2.281560e+06 2.008237e+05 5.806517e+04 1.879798e+05 2.409489e+05 261.28 -2.00 11.30 -2.00 458.48 0.00e+00 4.993417e-01 3.893663e-02 3.071405e-03 7.827248e-03 5.196124e-02 224.03 -2.00 3.57 -2.00 455.38 0.00e+00 1.903087e-06 4.958987e-06 8.075670e-07 9.432286e-07 6.342381e-06 279.44 -2.00 20.00 -2.00 456.43 0.00e+00 4.439 0.002 397.00 473.00 4 7.3120e+00 1.5544e-03 1.1129e-02 3.2681e-04 1.6900e-03 4.2265e-02 1.9079e-03 2.3255e-03 1.9817e-04 2.1217e-03 -1.4016e-02 1.0540e-03 3.0976e-04 8.0656e-05 1.1672e-03 2.0822e-03 3.6224e-04 5.1031e-05 2.0095e-05 4.0294e-04 -6.0257e-04 1.8701e-04 3.1430e-05 1.1693e-05 2.0237e-04 4.3657e-04 -7.2755e-03 9.3292e-04 2.4951e-05 3.0111e-05 9.3278e-04 -3.4906e-05 1.4443e-05 7.5293e-07 2.5747e-07 1.6283e-05 5.2248e-05 1.9835e-05 1.0200e-06 3.0210e-07 2.2049e-05 -8.0720e-03 2.1138e-05 7.2039e-01 1.3856e-01 2.9038e-03 1.7997e-03 1.4553e-01 12 8 8 10 0 0 99.98 18.18 0.71 -0.00807 -0.01328 18 18 1 4 0 1686.890 22.90 15.00 18.18 22.41 24.4 1095.04 141 227 222 -191 -266 -644 -174 413 -180 -58 -241 -172 94 -162 -428 41 -86 -154 -61 -54 -146 322 113 275 126 -24 -235 296 -74 104 5 -11 227 402 -168 138 178 -309 -51 -61 -122 -7 -117 257 137 17 -36 -18 -221 278 -144 123 20 -115 76 98 89 -20 -58 -151 611 -172 11 177 150 352 184 -17 70 103 114 -9 -58 -9 -99 216 -351 -311 -381 -272 -200 34 -74 -66 -94 -74 180 274 140 147 231 107 38 -67 112 23 -181 -145 293 75 -11 208 130 9 51 161 -58 -120 -627 -171 227 -70 -135 330 184 130 127 171 21 243 -323 13 -237 -142 -207 -122 -122 -219 1 -171 131 -104 179 63 366 112 279 -40 55 -257 69 -44 393 293 -84 23 -123 57 -125 -6 -130 61 -231 11 -278 137 94 -223 -111 31 101 218 104 -18 -27 124 125 -177 41 -40 108 -179 -272 -328 289 -42 41 46 -135 39 178 -55 89 84 -64 6 -234 -217 235 53 8 -85 31 -133 -211 -159 264 -96 203 -171 144 -139 114 0 -141 -398 125 -428 89 5 -233 178 -159 -184 10 167 85 -91 -40 -180 -274 -205 -275 -158 83 -18 -76 -36 423 61 295 154 177 -110 293 -331 -209 -526 -152 22 104 110 41 71 -38 121 78 -111 -252 145 -126 120 -210 -143 -168 -95 57 -230 -89 82 -178 -246 86 -152 33 16 -38 -392 176 13 15 152 51 -183 -211 -112 -7 -405 -18 -90 -138 -140 27 291 5 123 -130 123 -29 219 46 42 9 218 156 -66 247 211 356 117 349 224 385 9 187 56 89 -80 79 306 66 -26 -88 103 254 104 -92 276 7 228 51 156 3 243 -216 -167 -127 11 -207 -116 222 52 110 -84 158 -59 433 218 222 116 115 35 -160 -6 -171 -1 -60 149 69 102 -22 256 169 -141 18 27 -372 -217 -6 -61 133 -182 84 281 -192 -209 -7 61 -200 -177 72 -24 155 -144 -22 -209 -23 8 135 153 1 134 -143 -13 99 112 -37 136 35 10 -97 -79 -32 -245 -242 -21 -22 123 262 105 -80 -141 -138 -306 -62 -158 114 105 -22 82 -100 -13 -111 67 214 115 85 184 -98 -140 -60 49 112 -21 189 -18 -206 176 188 79 69 -124 105 209 81 -73 -107 -133 80 -130 -130 -90 -126 -253 -63 -196 -157 18 -150 -134 86 54 6 83 -169 -64 -192 -126 -277 -108 82 97 -199 201 80 -56 227 9 228 31 -40 63 81 -66 -98 83 84 -164 -140 -59 -87 -141 211 -36 -47 272 48 29 -132 109 -217 89 87 91 3 46 -18 -21 -69 -210 -132 -41 185 24 91 42 -52 -66 92 119 -189 142 6 163 2 0 38 123 -13 271 -28 -104 -147 94 98 -86 109 -75 142 -81 107 60 29 84 -47 26 39 186 -110 -180 -42 -50 -92 103 -136 -86 102 169 161 -142 -195 -471 -131 306 -138 -44 -187 -132 72 -125 -331 32 -68 -121 -48 -42 -117 254 87 212 93 -18 -180 240 -60 86 4 -9 184 302 -122 99 135 -256 -42 -50 -102 -6 -93 202 109 13 -28 -14 -167 205 -112 102 16 -95 62 80 72 -16 -46 -120 499 -148 10 156 131 312 160 -15 63 92 100 -8 -51 -8 -81 166 -273 -236 -294 -212 -169 30 -67 -60 -82 -66 163 254 130 135 210 96 34 -61 102 21 -163 -130 257 65 -10 184 117 8 48 156 -56 -112 -562 -149 197 -62 -125 307 171 119 114 152 19 216 -295 12 -229 -133 -196 -115 -119 -211 1 -159 119 -92 156 55 324 102 256 -37 51 -238 63 -40 354 266 -76 22 -114 53 -115 -6 -117 53 -200 10 -250 126 86 -212 -107 30 98 213 101 -18 -25 114 116 -170 41 -39 100 -159 -222 -266 244 -37 38 44 -127 36 159 -48 80 77 -60 6 -218 -211 223 49 7 -76 28 -121 -198 -151 247 -88 182 -152 130 -132 109 0 -134 -361 110 -360 76 4 -201 162 -143 -169 9 151 77 -81 -36 -165 -240 -176 -239 -139 74 -16 -68 -31 345 47 213 110 129 -81 213 -235 -153 -385 -110 18 89 100 39 72 -39 124 76 -104 -216 124 -111 108 -197 -141 -170 -96 57 -224 -81 71 -149 -201 72 -131 31 15 -38 -393 172 12 14 139 48 -178 -209 -112 -7 -398 -18 -92 -141 -142 26 284 5 119 -129 119 -28 213 44 41 8 201 140 -57 214 184 332 113 339 209 361 9 183 56 88 -79 77 288 60 -24 -80 95 246 105 -92 280 7 222 51 152 3 253 -226 -173 -129 11 -210 -118 226 54 112 -84 155 -58 432 215 224 117 113 34 -157 -6 -174 -1 -62 153 69 99 -21 246 159 -134 17 27 -353 -210 -6 -62 134 -183 84 286 -193 -215 -8 65 -211 -182 72 -25 156 -142 -22 -220 -24 8 138 156 1 137 -147 -14 103 119 -40 147 38 11 -105 -86 -34 -267 -262 -24 -24 135 283 114 -87 -155 -151 -337 -68 -169 119 110 -23 83 -102 -14 -115 70 228 125 91 202 -108 -155 -65 54 122 -23 206 -20 -225 192 207 87 77 -141 116 238 94 -84 -121 -154 92 -151 -147 -103 -143 -288 -75 -225 -184 21 -179 -156 98 61 6 93 -192 -74 -226 -150 -330 -128 96 112 -231 233 93 -65 264 11 266 36 -48 76 100 -82 -121 102 103 -200 -172 -73 -106 -174 261 -44 -58 339 59 37 -165 137 -273 111 108 113 4 59 -23 -27 -88 -260 -163 -52 230 29 112 52 -66 -86 119 153 -244 184 8 209 3 -1 47 157 -16 325 -34 -126 -183 119 127 -113 144 -95 185 -105 137 77 38 110 -60 33 50 245 -145 -237 -53 -63 -118 131 -179 -111