File name: Pandora145s1_Toronto-Scarborough_20250322_L2Fit_fwvt1c9d20230821p1-8.txt File generation date: 20250323T053325.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 145 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora145_OF_v5d20190718.txt Instrument calibration file used: Pandora145s1_CF_v9d20230821.txt Level 1 file used: Pandora145s1_Toronto-Scarborough_20250322_L1_smca1c9d20230821p1-8.txt Full location name: University of Toronto - Scarborough Short location name: Toronto-Scarborough Country of location: Canada Location latitude [deg]: 43.7843 Location longitude [deg]: -79.1874 Location altitude [m]: 137 Local noon date: 20250322 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: field cal for autumn2023 ff, based on Session 8(7) First and last pixel inside fitting window: 1647 1796 Nominal wavelengths inside fitting window [nm]: 492.0731 492.1943 492.3153 492.4364 492.5575 492.6785 492.7995 492.9205 493.0415 493.1625 493.2834 493.4044 493.5253 493.6462 493.7671 493.8880 494.0088 494.1297 494.2505 494.3713 494.4921 494.6128 494.7336 494.8543 494.9751 495.0958 495.2165 495.3371 495.4578 495.5784 495.6990 495.8197 495.9402 496.0608 496.1814 496.3019 496.4224 496.5429 496.6634 496.7839 496.9044 497.0248 497.1452 497.2656 497.3860 497.5064 497.6267 497.7471 497.8674 497.9877 498.1080 498.2283 498.3485 498.4688 498.5890 498.7092 498.8294 498.9495 499.0697 499.1898 499.3100 499.4301 499.5502 499.6702 499.7903 499.9103 500.0303 500.1503 500.2703 500.3903 500.5103 500.6302 500.7501 500.8700 500.9899 501.1098 501.2296 501.3495 501.4693 501.5891 501.7089 501.8286 501.9484 502.0681 502.1878 502.3075 502.4272 502.5469 502.6665 502.7862 502.9058 503.0254 503.1450 503.2645 503.3841 503.5036 503.6231 503.7426 503.8621 503.9816 504.1010 504.2205 504.3399 504.4593 504.5786 504.6980 504.8174 504.9367 505.0560 505.1753 505.2946 505.4138 505.5331 505.6523 505.7715 505.8907 506.0099 506.1290 506.2482 506.3673 506.4864 506.6055 506.7246 506.8436 506.9627 507.0817 507.2007 507.3197 507.4387 507.5576 507.6766 507.7955 507.9144 508.0333 508.1522 508.2710 508.3899 508.5087 508.6275 508.7463 508.8650 508.9838 509.1025 509.2212 509.3399 509.4586 509.5773 509.6959 509.8146 509.9332 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250322T130359.1Z 9212.544434 221 1 29.53 2 71.54 107.34 76.58 201.43 0.00 1 0.00 1 0 15 3.707e-03 3.684e-03 1.523e-03 1.519e-03 2.153389e+03 8.423855e+01 1.592857e+02 -6.000000e+00 1.905580e+02 274.95 -2.00 20.00 -2.00 505.26 0.00e+00 8.935058e-04 4.021391e-05 5.127697e-05 -6.000000e+00 1.002519e-04 274.95 -2.00 20.00 -2.00 500.42 0.00e+00 4.112493e-01 2.949629e-02 1.850084e-02 -6.000000e+00 7.213288e-02 226.31 -2.00 3.57 -2.00 502.01 0.00e+00 3.118 0.001 489.00 513.00 1 7.8635e+00 2.2477e-03 4.8104e-03 -6.0000e+00 5.4991e-03 5.3311e-03 5.9262e-04 4.7908e-04 -6.0000e+00 1.4530e-03 4.6510e-04 1.1158e-04 1.2602e-04 2.6495e-05 -6.0000e+00 3.1574e-04 -6.7153e-03 4.6733e-05 10 0 0 10 0 0 99.89 18.42 0.74 -0.00672 -0.00594 10 10 1 4 0 2951.910 23.01 14.99 18.42 13.91 24.6 1100.00 -1069 -514 -295 -13 376 448 502 715 628 540 164 -43 -159 -112 -363 -320 -272 -173 202 130 210 275 112 125 145 508 525 11 148 -634 -706 -539 -125 28 380 427 141 -328 -397 -376 -346 230 359 236 441 233 15 323 -350 -242 -608 -740 -318 -663 -213 318 203 -123 238 41 477 246 247 300 117 602 216 -53 -317 -379 -501 -374 111 -60 -314 -41 -169 -284 -159 -264 -669 -479 -25 -403 -362 -34 -73 -1 -87 -495 30 -100 257 72 385 270 145 -235 -437 -605 -388 -519 -434 -192 470 440 -316 -146 -421 -170 11 356 353 623 635 755 234 626 233 87 69 -224 90 -149 276 69 184 256 338 -381 -11 -214 -387 -87 27 -183 -34 509 292 408 201 223 104 442 18 313 -9 -361 -891 -813 -1026 -501 -298 -13 386 469 535 767 672 569 171 -45 -161 -112 -361 -320 -276 -181 216 140 218 286 116 131 152 532 547 11 154 -638 -701 -538 -127 30 400 449 147 -338 -404 -395 -363 233 368 246 462 245 15 332 -356 -248 -605 -718 -304 -644 -213 327 206 -126 242 41 483 252 253 307 118 599 212 -54 -316 -373 -490 -368 110 -59 -309 -40 -167 -276 -152 -253 -649 -469 -24 -400 -350 -33 -71 -1 -84 -485 29 -100 261 73 385 265 140 -221 -416 -565 -362 -494 -414 -190 473 441 -314 -142 -407 -166 11 358 347 617 631 753 236 630 232 85 70 -221 89 -148 275 67 177 254 335 -367 -11 -206 -368 -82 26 -175 -32 489 285 401 199 221 105 443 18 311 -8 -342 -832 -759 SQ 20250322T154757.2Z 9212.658301 339 1 30.45 2 47.86 146.90 93.60 231.71 0.00 1 0.00 1 0 15 3.424e-03 3.402e-03 1.212e-03 1.209e-03 1.060983e+03 6.432547e+01 8.781706e+01 -6.000000e+00 1.760148e+02 274.96 -2.00 20.00 -2.00 505.24 0.00e+00 4.695538e-04 3.198088e-05 2.660157e-05 -6.000000e+00 9.259566e-05 274.96 -2.00 20.00 -2.00 500.39 0.00e+00 1.052720e-01 2.343703e-02 7.762825e-03 -6.000000e+00 6.664856e-02 226.32 -2.00 3.57 -2.00 501.99 0.00e+00 1.488 0.000 489.00 513.00 1 7.7571e+00 1.7867e-03 2.2867e-03 -6.0000e+00 5.0806e-03 8.3159e-03 4.7225e-04 2.1858e-04 -6.0000e+00 1.3431e-03 6.7064e-04 4.0422e-04 1.0062e-04 1.4565e-05 -6.0000e+00 2.9168e-04 -2.3828e-03 -1.0603e-05 10 0 0 10 0 0 99.89 18.17 0.74 -0.00238 0.00042 11 11 1 4 0 2767.480 22.80 15.00 18.17 10.05 23.9 1100.00 -937 -278 -211 -12 539 424 527 441 367 85 177 -111 -206 -242 -429 -335 37 -145 75 303 273 26 140 91 318 525 255 72 -45 -392 -736 -365 48 -60 394 509 34 -152 -222 -339 -247 -144 220 67 522 651 110 99 170 -232 -457 -969 -1087 -785 -388 36 154 43 -84 161 511 409 313 585 308 354 100 -12 -118 -96 -538 -566 83 -174 255 144 -163 -555 -419 -373 -303 -478 -84 -321 -40 -35 -148 -97 -258 24 -17 108 226 478 324 321 44 -56 -381 -461 -755 -431 -164 -308 384 211 -41 -185 -366 -184 48 84 75 403 349 439 515 268 233 51 -142 -55 163 180 156 112 122 118 186 161 219 -202 -369 -44 -201 -259 -82 235 362 59 322 226 184 450 263 -53 -169 -346 -349 -791 -905 -272 -214 -12 557 448 566 479 398 90 186 -116 -211 -243 -430 -338 38 -152 78 318 286 27 147 95 337 554 269 76 -47 -396 -734 -365 48 -62 416 539 36 -157 -227 -344 -251 -148 226 70 548 684 115 103 172 -238 -452 -940 -1044 -761 -388 36 156 44 -85 163 517 417 321 597 312 352 98 -12 -117 -94 -524 -555 82 -175 249 144 -160 -538 -402 -357 -292 -467 -82 -318 -39 -34 -144 -94 -252 23 -17 108 230 487 327 318 43 -53 -364 -433 -711 -412 -157 -308 389 212 -40 -180 -354 -179 47 82 75 401 349 441 520 270 232 50 -138 -54 159 178 150 108 117 116 184 154 214 -194 -349 -41 -187 -246 -80 225 350 58 315 223 182 447 262 -52 -164 -324 -331 -755 SQ 20250322T155726.4Z 9212.664889 343 1 29.23 2 46.96 149.88 94.90 233.23 0.00 1 0.00 1 0 8 3.553e-03 3.532e-03 1.415e-03 1.411e-03 1.090353e+03 7.516730e+01 9.297021e+01 -6.000000e+00 1.826570e+02 274.96 -2.00 20.00 -2.00 505.24 0.00e+00 4.763003e-04 3.734565e-05 3.002251e-05 -6.000000e+00 9.609315e-05 274.96 -2.00 20.00 -2.00 500.37 0.00e+00 9.636156e-02 2.739843e-02 7.645986e-03 -6.000000e+00 6.914592e-02 226.32 -2.00 3.57 -2.00 501.97 0.00e+00 1.463 0.000 489.00 513.00 1 8.0108e+00 2.0895e-03 2.2727e-03 -6.0000e+00 5.2713e-03 1.0112e-02 5.5247e-04 2.1594e-04 -6.0000e+00 1.3930e-03 5.2245e-04 8.5274e-05 1.1730e-04 1.5550e-05 -6.0000e+00 3.0265e-04 -4.4979e-03 2.4901e-05 10 0 0 10 0 0 95.66 18.17 0.85 -0.00450 -0.00391 8 8 1 4 0 3652.750 22.80 15.00 18.17 9.98 24.0 1100.00 -677 -333 -92 197 330 533 571 711 635 307 93 51 -77 -569 -392 -273 -45 -76 18 318 92 -5 22 131 182 695 135 -95 -10 -549 -837 -567 -124 -111 453 549 85 -120 69 -116 -222 -60 258 -106 335 610 189 77 -171 -118 -428 -980 -682 -747 -187 -4 -131 -87 410 263 92 144 299 342 86 280 173 -200 -643 -160 -429 -446 41 117 67 -40 19 -282 -547 -405 -670 -93 10 -135 25 117 -64 -16 -567 -47 14 72 227 439 631 147 9 -224 -320 -755 -725 -387 -454 30 381 73 -238 -176 -509 -569 304 -103 324 344 604 617 550 86 278 110 -75 253 -290 189 87 258 -3 211 139 195 200 -84 -145 -19 -181 -437 30 319 344 99 417 292 206 328 289 188 10 -451 -567 -656 -678 -325 -93 207 341 560 612 768 683 327 97 53 -78 -572 -393 -274 -46 -79 19 344 96 -5 23 137 192 728 142 -98 -10 -553 -833 -566 -126 -118 476 578 89 -123 73 -121 -233 -63 264 -111 350 637 197 79 -173 -120 -422 -947 -674 -720 -186 -4 -132 -89 414 264 93 146 305 348 87 277 175 -201 -639 -155 -415 -435 41 117 68 -40 19 -271 -523 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243.50 143.61 280.12 0.00 1 0.00 1 0 15 2.682e-03 2.664e-03 2.192e-04 2.186e-04 3.506948e+02 1.129984e+01 3.572753e+01 -6.000000e+00 1.379142e+02 274.98 -2.00 20.00 -2.00 505.24 0.00e+00 4.815294e-04 5.775287e-06 2.826497e-05 -6.000000e+00 7.254957e-05 274.98 -2.00 20.00 -2.00 500.36 0.00e+00 2.373821e-01 4.239603e-03 4.484014e-03 -6.000000e+00 5.221635e-02 226.33 -2.00 3.57 -2.00 501.96 0.00e+00 2.247 0.000 489.00 513.00 1 3.3317e+00 3.2332e-04 3.2520e-03 -6.0000e+00 3.9805e-03 1.3742e-02 8.5734e-05 1.8572e-04 -6.0000e+00 1.0523e-03 4.9946e-02 4.5392e-04 1.8269e-05 9.5625e-06 -6.0000e+00 2.2852e-04 -1.4916e-03 -1.4873e-05 10 0 0 10 0 0 99.81 18.11 0.80 -0.00149 0.00166 578 578 1 4 0 20.760 22.71 15.00 18.11 9.55 23.8 1100.00 -635 -328 -141 153 423 437 484 515 400 357 10 -33 -85 -255 -397 -281 -68 -43 90 280 60 65 127 77 223 333 278 -36 70 -382 -696 -319 -47 -123 259 383 82 -85 -172 -209 -217 -8 124 232 269 291 236 69 -196 -203 -477 -705 -570 -529 -246 -73 106 53 92 58 110 239 350 288 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20250322T210129.5Z 9212.876036 513 1 5.66 2 64.47 244.45 144.37 281.07 0.00 1 0.00 1 0 15 3.341e-03 3.321e-03 6.450e-05 6.440e-05 3.037039e+02 3.292346e+00 3.108660e+01 -6.000000e+00 1.717588e+02 274.98 -2.00 20.00 -2.00 505.25 0.00e+00 5.666994e-04 1.704060e-06 3.236728e-05 -6.000000e+00 9.035490e-05 274.98 -2.00 20.00 -2.00 500.45 0.00e+00 2.307176e-01 1.241139e-03 5.024294e-03 -6.000000e+00 6.502229e-02 226.33 -2.00 3.57 -2.00 502.04 0.00e+00 2.306 0.000 489.00 513.00 1 1.7467e-01 9.4655e-05 3.3589e-03 -6.0000e+00 4.9568e-03 9.0988e-04 2.5064e-05 1.9000e-04 -6.0000e+00 1.3101e-03 1.1635e+00 3.0596e-04 5.3682e-06 1.0232e-05 -6.0000e+00 2.8458e-04 -1.9922e-03 -4.1895e-07 10 0 0 10 0 0 63.83 18.11 0.81 -0.00199 0.00013 1990 1990 1 4 0 2.740 22.71 14.99 18.11 9.37 24.1 1100.00 -838 -480 -246 143 489 441 595 625 517 399 32 -51 -116 -353 -449 -350 -119 -37 115 313 94 70 191 120 274 376 340 4 29 -477 -819 -437 -130 -73 338 476 118 -65 -168 -206 -252 34 142 302 359 392 283 130 -142 -241 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-312 -73 251 209 189 311 279 326 427 318 139 -79 -337 -671 -670 SQ 20250322T210135.4Z 9212.876104 513 2 5.71 2 64.48 244.47 144.38 281.09 0.00 1 0.00 1 0 15 3.339e-03 3.323e-03 6.406e-05 6.396e-05 3.030893e+02 3.265740e+00 3.005870e+01 -6.000000e+00 1.716756e+02 274.98 -2.00 20.00 -2.00 505.26 0.00e+00 5.569976e-04 1.693153e-06 3.199086e-05 -6.000000e+00 9.031103e-05 274.98 -2.00 20.00 -2.00 500.46 0.00e+00 2.305761e-01 1.232923e-03 5.016457e-03 -6.000000e+00 6.499124e-02 226.33 -2.00 3.57 -2.00 502.05 0.00e+00 2.307 0.000 489.00 513.00 1 1.6149e-01 9.4024e-05 3.3586e-03 -6.0000e+00 4.9544e-03 9.0567e-04 2.4878e-05 1.9059e-04 -6.0000e+00 1.3095e-03 1.1789e+00 3.0998e-04 5.3357e-06 1.0042e-05 -6.0000e+00 2.8445e-04 -1.9902e-03 -1.0355e-06 10 0 0 10 0 0 73.94 18.11 0.81 -0.00199 0.00016 1990 1990 1 4 0 2.740 22.71 14.99 18.11 9.37 24.1 1100.00 -841 -478 -236 133 490 463 594 623 510 394 40 -39 -117 -364 -449 -353 -116 -41 114 314 90 45 197 124 284 376 332 -1 38 -458 -818 -442 -122 -86 362 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116 319 98 74 204 112 272 362 332 4 34 -454 -821 -436 -113 -76 343 489 123 -66 -174 -226 -264 49 150 289 367 390 284 129 -149 -239 -587 -861 -713 -608 -304 -5 127 121 159 151 194 303 436 386 312 189 51 -135 -218 -217 -451 -320 -8 -18 51 73 -123 -415 -451 -340 -482 -345 -89 -245 -163 -34 -27 -154 -218 -120 68 100 273 509 455 178 160 -157 -398 -695 -712 -433 -212 -86 317 173 -178 -201 -348 -328 -44 208 292 400 489 459 423 363 322 37 -26 44 -89 -88 227 132 47 215 179 43 234 37 -301 -229 -218 -315 -86 265 218 202 318 282 323 416 322 133 -90 -368 -697 -722 -814 -481 -244 137 509 464 619 657 534 394 39 -56 -132 -362 -447 -352 -131 -49 122 332 102 78 212 117 286 380 347 4 35 -458 -819 -436 -113 -77 360 514 128 -68 -177 -233 -272 50 155 301 385 409 296 132 -151 -241 -584 -837 -699 -590 -299 -6 129 123 162 153 197 310 446 395 317 189 51 -134 -214 -213 -443 -309 -8 -18 51 72 -120 -405 -437 -328 -470 -333 -86 -239 -162 -33 -26 -151 -214 -118 68 99 275 513 453 179 158 -154 -380 -653 -669 -414 -206 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155 492 446 585 611 510 382 26 -54 -124 -359 -454 -346 -115 -41 123 313 95 78 205 119 276 377 324 2 33 -466 -820 -438 -108 -73 341 487 122 -56 -169 -204 -269 35 136 285 376 387 294 139 -140 -232 -584 -862 -725 -620 -315 6 148 123 160 139 187 314 443 389 321 194 58 -136 -220 -227 -449 -312 -16 -24 48 84 -115 -407 -444 -357 -499 -322 -84 -257 -170 -30 -34 -156 -221 -122 76 95 268 507 446 177 163 -150 -397 -689 -711 -433 -217 -74 330 157 -179 -208 -369 -306 -48 201 303 403 504 473 438 363 326 39 -29 47 -84 -84 239 154 66 215 168 43 214 35 -305 -228 -220 -319 -82 250 214 193 310 264 328 418 332 139 -107 -357 -699 -731 -814 -470 -226 158 503 465 609 641 534 394 27 -56 -125 -365 -461 -353 -117 -43 128 330 100 83 216 124 288 393 336 2 34 -468 -813 -436 -110 -76 357 510 126 -57 -174 -209 -276 36 139 295 392 404 305 143 -144 -232 -578 -852 -707 -612 -314 7 149 125 162 140 189 319 451 395 324 196 57 -134 -215 -222 -437 -307 -15 -24 48 82 -112 -395 -428 -342 -484 -316 -81 -250 -168 -30 -34 -155 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-2.0318e-03 2.6092e-07 10 0 0 10 0 0 75.73 18.11 0.81 -0.00203 0.00007 1990 1990 1 4 0 2.740 22.71 14.99 18.11 9.39 24.2 1100.00 -848 -476 -242 146 498 457 593 621 499 395 54 -33 -117 -368 -447 -349 -117 -38 117 319 99 84 203 117 249 379 343 -10 20 -475 -822 -440 -126 -81 346 476 112 -70 -159 -221 -257 32 149 298 366 396 283 141 -139 -250 -587 -874 -717 -621 -315 -13 157 132 171 155 198 329 452 406 329 180 41 -140 -233 -226 -446 -317 -7 -30 62 86 -126 -408 -444 -353 -505 -326 -87 -237 -147 -32 -43 -166 -217 -115 68 98 256 497 444 180 167 -143 -390 -672 -719 -419 -222 -68 330 182 -172 -212 -369 -335 -38 211 305 408 496 470 442 356 324 49 -34 49 -91 -101 241 135 38 196 162 39 233 23 -313 -232 -220 -322 -82 257 200 193 310 288 327 415 339 137 -91 -363 -695 -698 -831 -463 -244 149 508 476 617 651 522 407 56 -34 -118 -374 -454 -356 -118 -40 122 336 105 89 214 122 260 395 356 -10 20 -476 -815 -437 -128 -84 361 498 116 -73 -164 -226 -264 33 152 308 382 413 294 144 -143 -250 -581 -863 -699 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1.3102e-03 1.1890e+00 2.8663e-04 5.3181e-06 1.0301e-05 -6.0000e+00 2.8459e-04 -2.1027e-03 1.0681e-06 10 0 0 10 0 0 86.22 18.11 0.81 -0.00210 -0.00011 1990 1990 1 4 0 2.740 22.71 15.00 18.11 9.39 24.2 1100.00 -852 -492 -238 133 495 439 589 599 502 387 43 -51 -118 -371 -451 -349 -128 -51 117 311 103 72 199 124 271 367 338 2 26 -480 -822 -429 -111 -87 336 476 115 -65 -165 -211 -259 34 141 295 378 397 296 139 -138 -249 -586 -864 -696 -622 -309 -11 141 124 160 137 192 329 441 403 333 186 44 -135 -235 -238 -449 -337 -17 -26 50 75 -109 -413 -457 -347 -501 -326 -73 -227 -149 -18 -39 -162 -211 -103 71 95 267 489 429 176 167 -147 -380 -685 -723 -435 -207 -68 335 162 -170 -215 -359 -325 -45 198 297 395 491 467 452 357 328 45 -42 40 -98 -91 230 128 40 190 156 31 222 34 -297 -229 -223 -316 -92 250 202 196 328 294 344 424 325 144 -88 -354 -701 -725 -821 -481 -236 134 509 451 617 633 529 401 44 -52 -120 -372 -451 -351 -130 -52 123 324 107 75 207 130 285 385 353 2 26 -484 -820 -429 -111 -89 353 502 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3.3741e-03 -6.0000e+00 4.9418e-03 8.5028e-04 2.4777e-05 1.9157e-04 -6.0000e+00 1.3061e-03 1.1901e+00 2.9762e-04 5.3146e-06 1.0371e-05 -6.0000e+00 2.8372e-04 -1.9945e-03 1.1702e-07 10 0 0 10 0 0 90.85 18.11 0.81 -0.00199 0.00007 1990 1990 1 4 0 2.740 22.71 15.00 18.11 9.39 24.2 1100.00 -836 -468 -240 146 492 441 574 611 502 385 33 -61 -128 -363 -448 -355 -130 -46 116 320 79 81 215 124 261 382 340 3 27 -480 -828 -448 -106 -80 343 474 117 -62 -173 -216 -258 43 147 278 373 392 300 150 -138 -237 -577 -869 -722 -609 -314 -10 140 115 153 135 179 306 444 393 312 168 54 -159 -227 -227 -445 -320 -10 -30 63 82 -108 -410 -461 -353 -488 -322 -89 -249 -166 -24 -28 -167 -206 -127 69 91 267 499 442 175 169 -156 -393 -684 -717 -429 -216 -85 326 164 -185 -200 -347 -327 -39 205 304 406 487 450 431 357 324 35 -25 48 -81 -83 240 122 50 215 166 29 216 32 -299 -223 -215 -320 -79 258 208 193 314 281 336 421 321 136 -85 -348 -698 -719 -807 -458 -238 147 506 454 602 645 529 399 34 -63 -130 -365 -448 -357 -132 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5.053671e-03 -6.000000e+00 6.490567e-02 226.33 -2.00 3.57 -2.00 502.04 0.00e+00 2.318 0.000 489.00 513.00 1 1.3536e-01 9.2808e-05 3.3764e-03 -6.0000e+00 4.9479e-03 7.8707e-04 2.4589e-05 1.9102e-04 -6.0000e+00 1.3078e-03 1.2077e+00 2.9533e-04 5.2658e-06 1.0420e-05 -6.0000e+00 2.8407e-04 -2.0179e-03 1.1241e-07 10 0 0 10 0 0 93.77 18.11 0.81 -0.00202 0.00003 1990 1990 1 4 0 2.740 22.71 15.00 18.11 9.39 24.2 1100.00 -830 -479 -242 155 488 444 595 603 504 390 27 -57 -130 -371 -461 -346 -115 -29 124 330 93 65 182 125 276 372 335 -1 22 -467 -818 -436 -114 -87 338 489 125 -62 -168 -211 -251 30 149 286 366 392 279 137 -143 -236 -582 -858 -713 -633 -318 -1 171 130 163 138 189 317 447 393 315 180 57 -136 -236 -223 -461 -331 -7 -41 45 77 -116 -424 -449 -346 -489 -320 -88 -238 -158 -25 -14 -160 -220 -108 75 101 272 505 455 174 173 -146 -393 -697 -710 -438 -209 -71 318 164 -181 -200 -347 -327 -59 196 290 395 490 461 430 341 314 43 -23 40 -90 -85 231 133 45 202 160 48 229 35 -308 -233 -221 -318 -76 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