File name: Pandora145s1_Toronto-Scarborough_20250426_L2Fit_fwvt1c9d20230821p1-8.txt
File generation date: 20250427T052437.3Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c9p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 145
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora145_OF_v5d20190718.txt
Instrument calibration file used: Pandora145s1_CF_v9d20230821.txt
Level 1 file used: Pandora145s1_Toronto-Scarborough_20250426_L1_smca1c9d20230821p1-8.txt
Full location name: University of Toronto - Scarborough
Short location name: Toronto-Scarborough
Country of location: Canada
Location latitude [deg]: 43.7843
Location longitude [deg]: -79.1874
Location altitude [m]: 137
Local noon date: 20250426
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: field cal for autumn2023 ff, based on Session 8(7)
First and last pixel inside fitting window: 1647 1796
Nominal wavelengths inside fitting window [nm]: 492.0731 492.1943 492.3153 492.4364 492.5575 492.6785 492.7995 492.9205 493.0415 493.1625 493.2834 493.4044 493.5253 493.6462 493.7671 493.8880 494.0088 494.1297 494.2505 494.3713 494.4921 494.6128 494.7336 494.8543 494.9751 495.0958 495.2165 495.3371 495.4578 495.5784 495.6990 495.8197 495.9402 496.0608 496.1814 496.3019 496.4224 496.5429 496.6634 496.7839 496.9044 497.0248 497.1452 497.2656 497.3860 497.5064 497.6267 497.7471 497.8674 497.9877 498.1080 498.2283 498.3485 498.4688 498.5890 498.7092 498.8294 498.9495 499.0697 499.1898 499.3100 499.4301 499.5502 499.6702 499.7903 499.9103 500.0303 500.1503 500.2703 500.3903 500.5103 500.6302 500.7501 500.8700 500.9899 501.1098 501.2296 501.3495 501.4693 501.5891 501.7089 501.8286 501.9484 502.0681 502.1878 502.3075 502.4272 502.5469 502.6665 502.7862 502.9058 503.0254 503.1450 503.2645 503.3841 503.5036 503.6231 503.7426 503.8621 503.9816 504.1010 504.2205 504.3399 504.4593 504.5786 504.6980 504.8174 504.9367 505.0560 505.1753 505.2946 505.4138 505.5331 505.6523 505.7715 505.8907 506.0099 506.1290 506.2482 506.3673 506.4864 506.6055 506.7246 506.8436 506.9627 507.0817 507.2007 507.3197 507.4387 507.5576 507.6766 507.7955 507.9144 508.0333 508.1522 508.2710 508.3899 508.5087 508.6275 508.7463 508.8650 508.9838 509.1025 509.2212 509.3399 509.4586 509.5773 509.6959 509.8146 509.9332
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250426T143808.4Z 9247.609819 232 1 29.72 2 44.89 119.77 39.90 144.17 0.00 1 0.00 1 0 15 3.719e-03 3.700e-03 1.013e-03 1.011e-03 1.710917e+03 5.595772e+01 1.323116e+02 -6.000000e+00 1.942965e+02 278.92 -2.00 20.00 -2.00 505.24 0.00e+00 4.659015e-04 2.700581e-05 2.812081e-05 -6.000000e+00 1.015546e-04 278.92 -2.00 20.00 -2.00 500.38 0.00e+00 6.579254e-02 1.966671e-02 1.232901e-02 -6.000000e+00 7.247996e-02 229.18 -2.00 3.57 -2.00 501.98 0.00e+00 1.410 0.000 489.00 513.00 1 7.3340e+00 1.5007e-03 2.3473e-03 -6.0000e+00 5.5314e-03 6.8913e-03 3.9630e-04 3.1746e-04 -6.0000e+00 1.4611e-03 1.0363e-03 5.3190e-04 8.3919e-05 1.9552e-05 -6.0000e+00 3.1690e-04 -2.6936e-03 8.9131e-06 12 1 1 12 1 1 99.94 18.30 0.74 -0.00269 0.00100 11 12 1 4 0 2475.910 22.80 15.00 18.30 15.93 24.8 1100.00 -1082 -341 -297 216 300 522 705 687 471 488 89 -95 -260 -257 -560 -306 -31 -146 129 253 176 89 405 200 361 384 356 157 -143 -487 -855 -299 -189 -51 237 415 176 -139 -237 -267 -201 48 135 359 152 512 215 220 -168 -222 -867 -1102 -849 -644 -312 -60 201 128 454 -59 382 236 461 532 346 267 -44 -39 -327 -200 -511 -142 -165 84 21 187 -302 -378 -521 -451 -580 -267 23 -306 -410 107 49 -98 -117 -162 -37 26 286 415 332 196 205 -122 -485 -458 -702 -539 -341 -84 290 299 -197 -343 -420 -430 -15 310 304 403 530 468 608 254 408 102 143 -45 -47 -112 300 140 162 110 218 -34 322 -43 -388 -184 -232 -227 -52 211 18 379 193 534 252 593 159 286 -238 -616 -644 -648 -1078 -332 -301 219 311 551 735 723 494 519 94 -98 -266 -258 -563 -309 -31 -153 135 267 186 94 426 212 384 407 376 164 -150 -492 -855 -300 -193 -53 252 441 185 -145 -243 -272 -205 49 140 376 162 542 227 228 -171 -227 -863 -1072 -815 -625 -312 -60 206 131 463 -61 389 243 475 547 352 268 -43 -38 -326 -196 -498 -139 -163 82 20 182 -298 -367 -502 -432 -561 -261 23 -294 -401 105 48 -96 -115 -159 -37 26 284 412 335 195 199 -115 -462 -429 -659 -515 -328 -84 287 294 -191 -337 -409 -423 -14 305 303 404 533 474 618 259 411 101 139 -44 -45 -109 291 135 157 107 210 -32 307 -41 -369 -173 -218 -217 -50 204 18 374 192 529 252 578 155 277 -232 -585 -600 -605
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SQ 20250426T144638.0Z 9247.615718 238 1 29.68 2 43.57 122.05 39.01 147.08 0.00 1 0.00 1 0 15 3.574e-03 3.561e-03 1.296e-03 1.293e-03 1.981991e+03 7.220041e+01 1.626676e+02 -6.000000e+00 1.867258e+02 278.93 -2.00 20.00 -2.00 505.24 0.00e+00 5.186589e-04 3.453990e-05 3.167054e-05 -6.000000e+00 9.759782e-05 278.93 -2.00 20.00 -2.00 500.37 0.00e+00 9.083731e-02 2.515991e-02 1.204526e-02 -6.000000e+00 6.964994e-02 229.18 -2.00 3.57 -2.00 501.97 0.00e+00 1.379 0.000 489.00 513.00 1 7.8521e+00 1.9198e-03 2.3375e-03 -6.0000e+00 5.3155e-03 6.8568e-03 5.0678e-04 3.3343e-04 -6.0000e+00 1.4040e-03 6.1800e-04 2.5689e-04 1.0743e-04 2.3835e-05 -6.0000e+00 3.0453e-04 -3.4652e-03 1.9960e-05 10 0 0 10 0 0 98.39 18.30 0.82 -0.00347 -0.00168 10 10 1 4 0 2967.060 22.80 14.99 18.30 15.78 25.0 1100.00 -1075 -380 135 279 474 345 742 680 431 575 245 -194 77 -382 -380 -399 -191 -95 170 389 -107 23 197 73 27 531 225 -25 -81 -389 -962 -269 146 -70 392 415 -51 -120 -261 -384 -97 -57 249 299 353 358 211 136 -236 -273 -676 -779 -954 -616 -415 206 201 48 38 220 38 345 344 499 222 195 -4 -232 -193 -438 -324 -416 20 -188 158 -42 87 -507 -144 -340 -227 -371 -104 -260 -390 94 -44 -194 -339 93 16 214 509 647 158 215 297 -139 -604 -328 -543 -627 -485 -379 484 -97 93 -256 -271 -513 151 9 441 312 722 429 241 298 -113 316 -53 113 -74 35 -39 188 203 213 62 60 354 -76 -345 -281 -228 -283 -156 284 249 134 378 217 266 556 74 263 275 -329 -553 -668 -1048 -375 138 284 493 367 774 715 452 615 259 -203 79 -387 -384 -406 -197 -100 178 410 -114 24 208 78 29 563 238 -26 -82 -395 -969 -271 150 -72 417 442 -54 -125 -268 -392 -99 -58 258 313 374 380 222 142 -241 -271 -676 -759 -922 -601 -417 206 205 49 39 225 39 354 355 513 226 196 -4 -227 -186 -433 -318 -411 19 -184 156 -41 86 -495 -139 -327 -220 -364 -99 -249 -380 92 -43 -190 -333 91 15 215 520 659 159 213 287 -131 -578 -307 -510 -601 -466 -379 474 -95 93 -250 -263 -504 150 9 435 311 719 431 244 302 -114 311 -51 112 -73 34 -37 180 195 204 59 58 334 -73 -327 -263 -213 -270 -148 273 242 131 372 214 264 554 74 260 266 -309 -511 -620
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