File name: Pandora145s1_Toronto-Scarborough_20250504_L2Fit_fout2c9d20230821p1-8.txt
File generation date: 20250505T052054.5Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c9p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 145
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora145_OF_v5d20190718.txt
Instrument calibration file used: Pandora145s1_CF_v9d20230821.txt
Level 1 file used: Pandora145s1_Toronto-Scarborough_20250504_L1_smca1c9d20230821p1-8.txt
Full location name: University of Toronto - Scarborough
Short location name: Toronto-Scarborough
Country of location: Canada
Location latitude [deg]: 43.7843
Location longitude [deg]: -79.1874
Location altitude [m]: 137
Local noon date: 20250504
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: field cal for autumn2023 ff, based on Session 8(7)
First and last pixel inside fitting window: 226 368
Nominal wavelengths inside fitting window [nm]: 305.0462 305.1870 305.3278 305.4686 305.6094 305.7502 305.8910 306.0317 306.1725 306.3132 306.4539 306.5947 306.7354 306.8761 307.0167 307.1574 307.2981 307.4387 307.5794 307.7200 307.8606 308.0012 308.1418 308.2824 308.4230 308.5635 308.7041 308.8446 308.9851 309.1256 309.2661 309.4066 309.5471 309.6876 309.8281 309.9685 310.1089 310.2494 310.3898 310.5302 310.6706 310.8110 310.9513 311.0917 311.2320 311.3724 311.5127 311.6530 311.7933 311.9336 312.0739 312.2141 312.3544 312.4947 312.6349 312.7751 312.9153 313.0555 313.1957 313.3359 313.4761 313.6162 313.7564 313.8965 314.0366 314.1767 314.3168 314.4569 314.5970 314.7370 314.8771 315.0171 315.1572 315.2972 315.4372 315.5772 315.7172 315.8572 315.9971 316.1371 316.2770 316.4169 316.5569 316.6968 316.8367 316.9765 317.1164 317.2563 317.3961 317.5360 317.6758 317.8156 317.9554 318.0952 318.2350 318.3747 318.5145 318.6542 318.7940 318.9337 319.0734 319.2131 319.3528 319.4925 319.6321 319.7718 319.9114 320.0511 320.1907 320.3303 320.4699 320.6095 320.7490 320.8886 321.0282 321.1677 321.3072 321.4467 321.5862 321.7257 321.8652 322.0047 322.1441 322.2836 322.4230 322.5625 322.7019 322.8413 322.9807 323.1200 323.2594 323.3988 323.5381 323.6774 323.8167 323.9561 324.0954 324.2346 324.3739 324.5132 324.6524 324.7917 324.9309
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250504T135514.8Z 9255.580032 253 1 30.74 2 50.05 107.48 109.92 34.20 0.00 1 0.00 1 0 17 1.004e-02 6.235e-03 5.041e-03 2.397e-03 2.260457e-01 1.201236e-03 2.783823e-03 -6.000000e+00 5.637786e-03 229.91 -2.00 3.57 -2.00 316.19 0.00e+00 1.336433e-04 1.306777e-04 6.033098e-05 -6.000000e+00 2.432598e-04 279.84 -2.00 20.00 -2.00 315.56 0.00e+00 1.554 0.000 302.00 328.00 3 5.5641e+00 3.1335e-03 1.9500e-02 -6.0000e+00 1.4107e-02 5.7565e-02 3.4952e-03 1.1898e-02 -6.0000e+00 1.5306e-02 -2.9693e-03 2.0238e-03 5.8282e-03 -6.0000e+00 9.0834e-03 -1.2084e-03 9.5349e-04 1.6256e-03 -6.0000e+00 3.8686e-03 3.2911e-04 -1.8391e-05 6.3942e-05 1.7663e-05 -6.0000e+00 2.4974e-04 -6.3563e-04 0.0000e+00 10 0 0 10 0 0 89.69 18.21 0.23 -0.00064 -0.00077 10 10 1 5 0 3073.670 22.80 15.00 18.21 23.59 25.5 1100.00 1291 1298 919 -2836 -2653 -3943 -2679 129 1263 523 -3172 491 -1923 -1233 -992 -384 -1183 552 -242 1582 922 8 894 769 988 881 720 -419 -942 -1471 1652 483 2235 37 -1505 -2834 -1570 -959 -467 209 -695 -463 -453 -1010 38 85 -906 -578 -1139 265 425 706 1253 1376 393 384 1592 612 485 -195 886 1029 1487 1461 384 -102 -348 -838 832 88 490 104 73 480 484 -64 -578 -1006 -487 -563 -1114 -864 -1685 -1629 -1142 -868 -115 -78 272 242 373 39 -113 -194 280 308 196 826 371 242 238 -909 -596 -252 -737 -570 -734 -869 -408 509 429 170 346 295 -243 4 -415 170 43 247 -146 354 333 566 638 476 509 971 330 712 286 -148 -97 -288 103 -273 190 55 -52 -52 -343 -1004 -162 232 256 187 -562 -453 -636 -448 24 258 114 -697 103 -458 -332 -303 -129 -412 194 -89 588 354 3 338 283 382 355 292 -175 -362 -545 622 197 972 16 -653 -1179 -697 -451 -264 128 -470 -324 -326 -738 27 61 -640 -393 -756 171 287 511 949 1094 325 322 1252 485 404 -162 741 855 1335 1406 376 -91 -284 -707 722 82 502 104 74 466 471 -56 -489 -794 -391 -510 -1061 -907 -1780 -1784 -1329 -1019 -142 -100 349 300 456 44 -121 -197 296 335 236 1031 500 323 297 -1120 -681 -294 -892 -730 -980 -1214 -556 731 651 264 515 408 -325 5 -509 216 59 341 -210 500 458 793 843 601 642 1201 411 946 401 -214 -141 -408 155 -435 309 86 -83 -80 -546 -1551 -241
SS 20250504T140444.4Z 9255.586625 259 1 31.98 2 48.42 109.59 109.00 36.26 0.00 1 0.00 1 0 17 1.292e-02 6.981e-03 6.533e-03 3.083e-03 2.225697e-01 1.542121e-03 2.715554e-03 -6.000000e+00 7.252744e-03 229.91 -2.00 3.57 -2.00 316.29 0.00e+00 6.339786e-04 1.702062e-04 4.020223e-05 -6.000000e+00 3.129070e-04 279.84 -2.00 20.00 -2.00 315.64 0.00e+00 1.504 0.000 302.00 328.00 3 6.0536e+00 4.0339e-03 1.8978e-02 -6.0000e+00 1.8148e-02 7.0964e-02 4.5055e-03 1.1686e-02 -6.0000e+00 1.9690e-02 -8.0624e-03 2.6140e-03 5.7158e-03 -6.0000e+00 1.1685e-02 -3.0521e-04 1.2271e-03 1.6469e-03 -6.0000e+00 4.9773e-03 2.1177e-04 3.1678e-05 8.2336e-05 1.7039e-05 -6.0000e+00 3.2123e-04 -1.5615e-03 0.0000e+00 11 8 0 10 0 0 97.57 18.22 0.22 -0.00156 -0.00132 8 8 1 5 0 3996.300 22.80 15.00 18.22 24.04 25.7 1100.00 -331 -724 1619 -3228 -4033 -3076 -2344 4432 979 294 -4990 -3000 -3940 -669 166 173 513 1332 -200 2112 366 -631 1565 983 2566 -1681 984 -156 -211 -465 544 2201 3018 457 -1880 -1791 -3529 -1063 -491 591 -363 178 -506 -484 -445 295 532 -53 -2150 -1513 474 1176 281 962 827 393 940 175 218 449 391 1182 1623 1416 694 -411 -1133 -1357 812 82 584 340 99 564 1064 205 -1695 -1272 -693 -1184 -1321 -1483 -2161 -1825 -432 -510 137 96 790 72 758 -491 -798 -168 2 -36 563 975 942 402 161 -859 -344 -333 -890 -711 -543 -297 215 196 526 498 485 116 -395 233 -378 -250 127 -98 204 266 377 176 1059 -162 44 422 190 -36 205 -190 -11 -103 40 -222 64 63 -177 381 -268 -417 -347 -62 -138 337 -662 -719 -505 -400 793 204 65 -1129 -658 -968 -181 47 53 163 430 -68 724 131 -223 543 361 977 -693 396 -59 -74 -171 190 809 1191 193 -748 -673 -1457 -496 -275 355 -241 122 -360 -347 -316 208 366 -35 -1424 -981 315 834 211 755 669 323 784 147 178 362 322 1034 1425 1333 662 -362 -981 -1123 686 74 581 355 104 570 1003 188 -1411 -979 -541 -1048 -1222 -1518 -2381 -1939 -483 -615 174 126 1038 92 892 -569 -835 -165 2 -41 652 1248 1214 515 206 -1019 -404 -375 -1106 -935 -743 -397 297 288 813 737 734 163 -543 295 -474 -326 177 -138 297 383 528 237 1424 -210 53 502 242 -50 294 -262 -16 -148 61 -358 98 100 -284 597 -432 -649 -523
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