File name: Pandora145s1_Toronto-Scarborough_20250521_L2Fit_fnvh3c9d20230821p1-8.txt File generation date: 20250522T052030.4Z Data description: Level 2 spectral fitting results file Data file version: fnvh3c9p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 145 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora145_OF_v5d20190718.txt Instrument calibration file used: Pandora145s1_CF_v9d20230821.txt Level 1 file used: Pandora145s1_Toronto-Scarborough_20250521_L1_smca1c9d20230821p1-8.txt Full location name: University of Toronto - Scarborough Short location name: Toronto-Scarborough Country of location: Canada Location latitude [deg]: 43.7843 Location longitude [deg]: -79.1874 Location altitude [m]: 137 Local noon date: 20250521 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: field cal for autumn2023 ff, based on Session 8(7) First and last pixel inside fitting window: 1190 1629 Nominal wavelengths inside fitting window [nm]: 435.0577 435.1860 435.3142 435.4425 435.5707 435.6989 435.8271 435.9553 436.0835 436.2116 436.3398 436.4679 436.5960 436.7241 436.8522 436.9802 437.1083 437.2363 437.3643 437.4923 437.6203 437.7483 437.8763 438.0042 438.1321 438.2601 438.3880 438.5158 438.6437 438.7716 438.8994 439.0272 439.1550 439.2828 439.4106 439.5384 439.6661 439.7939 439.9216 440.0493 440.1770 440.3047 440.4323 440.5600 440.6876 440.8152 440.9428 441.0704 441.1980 441.3255 441.4531 441.5806 441.7081 441.8356 441.9631 442.0906 442.2180 442.3454 442.4729 442.6003 442.7277 442.8550 442.9824 443.1097 443.2371 443.3644 443.4917 443.6190 443.7462 443.8735 444.0007 444.1279 444.2552 444.3824 444.5095 444.6367 444.7638 444.8910 445.0181 445.1452 445.2723 445.3994 445.5264 445.6535 445.7805 445.9075 446.0345 446.1615 446.2884 446.4154 446.5423 446.6693 446.7962 446.9231 447.0499 447.1768 447.3036 447.4305 447.5573 447.6841 447.8109 447.9376 448.0644 448.1911 448.3178 448.4446 448.5712 448.6979 448.8246 448.9512 449.0779 449.2045 449.3311 449.4577 449.5842 449.7108 449.8373 449.9639 450.0904 450.2169 450.3434 450.4698 450.5963 450.7227 450.8491 450.9755 451.1019 451.2283 451.3546 451.4810 451.6073 451.7336 451.8599 451.9862 452.1125 452.2387 452.3649 452.4912 452.6174 452.7436 452.8697 452.9959 453.1220 453.2482 453.3743 453.5004 453.6264 453.7525 453.8786 454.0046 454.1306 454.2566 454.3826 454.5086 454.6345 454.7605 454.8864 455.0123 455.1382 455.2641 455.3900 455.5158 455.6416 455.7675 455.8933 456.0191 456.1448 456.2706 456.3963 456.5221 456.6478 456.7735 456.8991 457.0248 457.1505 457.2761 457.4017 457.5273 457.6529 457.7785 457.9040 458.0296 458.1551 458.2806 458.4061 458.5316 458.6570 458.7825 458.9079 459.0333 459.1587 459.2841 459.4095 459.5348 459.6602 459.7855 459.9108 460.0361 460.1614 460.2866 460.4119 460.5371 460.6623 460.7875 460.9127 461.0379 461.1630 461.2882 461.4133 461.5384 461.6635 461.7886 461.9136 462.0387 462.1637 462.2887 462.4137 462.5387 462.6636 462.7886 462.9135 463.0384 463.1633 463.2882 463.4131 463.5379 463.6628 463.7876 463.9124 464.0372 464.1620 464.2867 464.4115 464.5362 464.6609 464.7856 464.9103 465.0350 465.1596 465.2843 465.4089 465.5335 465.6581 465.7827 465.9072 466.0318 466.1563 466.2808 466.4053 466.5298 466.6542 466.7787 466.9031 467.0275 467.1519 467.2763 467.4007 467.5250 467.6494 467.7737 467.8980 468.0223 468.1465 468.2708 468.3950 468.5193 468.6435 468.7677 468.8918 469.0160 469.1402 469.2643 469.3884 469.5125 469.6366 469.7606 469.8847 470.0087 470.1328 470.2568 470.3807 470.5047 470.6287 470.7526 470.8765 471.0004 471.1243 471.2482 471.3721 471.4959 471.6198 471.7436 471.8674 471.9911 472.1149 472.2387 472.3624 472.4861 472.6098 472.7335 472.8572 472.9808 473.1045 473.2281 473.3517 473.4753 473.5988 473.7224 473.8460 473.9695 474.0930 474.2165 474.3400 474.4634 474.5869 474.7103 474.8337 474.9571 475.0805 475.2039 475.3272 475.4505 475.5739 475.6972 475.8205 475.9437 476.0670 476.1902 476.3134 476.4366 476.5598 476.6830 476.8062 476.9293 477.0524 477.1755 477.2986 477.4217 477.5448 477.6678 477.7908 477.9139 478.0369 478.1598 478.2828 478.4058 478.5287 478.6516 478.7745 478.8974 479.0203 479.1431 479.2659 479.3888 479.5116 479.6344 479.7571 479.8799 480.0026 480.1253 480.2480 480.3707 480.4934 480.6161 480.7387 480.8613 480.9839 481.1065 481.2291 481.3517 481.4742 481.5967 481.7193 481.8418 481.9642 482.0867 482.2091 482.3316 482.4540 482.5764 482.6988 482.8211 482.9435 483.0658 483.1881 483.3104 483.4327 483.5550 483.6772 483.7995 483.9217 484.0439 484.1661 484.2883 484.4104 484.5326 484.6547 484.7768 484.8989 485.0210 485.1430 485.2650 485.3871 485.5091 485.6311 485.7530 485.8750 485.9969 486.1189 486.2408 486.3627 486.4846 486.6064 486.7283 486.8501 486.9719 487.0937 487.2155 487.3372 487.4590 487.5807 487.7024 487.8241 487.9458 488.0675 488.1891 488.3107 488.4324 488.5540 488.6755 488.7971 488.9187 489.0402 489.1617 489.2832 489.4047 489.5262 489.6476 489.7690 489.8905 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 45: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Oxygen dimer effective temperature [K] Column 50: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 56: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Ozone effective temperature [K] Column 61: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Fitted Ring spectrum, -9e99=no fitting done or fitting not successful Column 67: Independent uncertainty of fitted Ring spectrum, -9=fitting not successful Column 68: Structured uncertainty of fitted Ring spectrum, -9=fitting not successful Column 69: Common uncertainty of fitted Ring spectrum, -9=fitting not successful Column 70: rms-based uncertainty of fitted Ring spectrum, -9=fitting not successful Column 71: Effective Ring fitting wavelength [nm], -9=fitting not done or not successful Column 72: Diffuse correction applied before fitting at effective Ring fitting wavelength [%], 0=no diffuse correction applied, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 73: Lower limit used for wavelength scaling [nm] Column 74: Upper limit used for wavelength scaling [nm] Column 75: Order of smoothing polynomial Column 76: Smoothing polynomial coefficient, order 0 Column 77: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 78: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 79: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 80: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 81: Smoothing polynomial coefficient, order 1 Column 82: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 83: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 84: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 85: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 86: Smoothing polynomial coefficient, order 2 Column 87: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 88: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 89: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 90: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 91: Smoothing polynomial coefficient, order 3 Column 92: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 93: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 94: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 95: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 96: Smoothing polynomial coefficient, order 4 Column 97: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 98: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 99: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 100: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 101: Mean value of measured data inside fitting window [same units as measurements] Column 102: Offset polynomial coefficient, order 0 Column 103: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 104: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 105: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 106: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 107: Offset polynomial coefficient, order 1 Column 108: Independent uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful Column 109: Structured uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful Column 110: Common uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful Column 111: rms-based uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful Column 112: Wavelength change polynomial coefficient, order 0 Column 113: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 114: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 115: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 116: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 117: Wavelength change polynomial coefficient, order 1 Column 118: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 119: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 120: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 121: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 122: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 123: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 124: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 125: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 126: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 127: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 128: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 129: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 130: Atmospheric variability [%], 999=no atmospheric variability was determined Column 131: Wavelength effective temperature [°C], 999=no effective temperature given Column 132: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 133: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 134: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 135: Number of bright count cycles Column 136: Number of dark count cycles Column 137: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 138: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 139: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 140: Integration time [ms] Column 141: Temperature at electronics board [°C], 999=no temperature signal Column 142: Spectrometer control temperature [°C], 999=no temperature signal Column 143: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 144: Temperature in head sensor [°C], 999=no temperature signal Column 145: Humidity in head sensor [%], -9=no humidity signal Column 146: Pressure in head sensor [hPa], -9=no pressure signal Columns 147-586: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 587-1026: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- EO 20250521T231240.4Z 9272.967134 4 1 7.97 6 75.92 284.90 136.78 327.36 0.00 0 290.39 0 0 106 5.403e-03 5.278e-03 4.986e-03 4.927e-03 -8.447746e+02 8.805378e+02 8.054631e+01 -6.000000e+00 9.081537e+02 281.76 -2.00 20.00 -2.00 461.63 0.00e+00 -1.296706e-04 5.904873e-05 1.050948e-05 -6.000000e+00 6.436656e-05 281.76 -2.00 20.00 -2.00 461.26 0.00e+00 -5.871147e+04 7.125011e+04 4.463210e+03 -6.000000e+00 8.158117e+04 281.76 -2.00 20.00 -2.00 474.76 0.00e+00 -1.678737e-01 8.747302e-02 6.073191e-03 -6.000000e+00 1.002205e-01 281.76 -2.00 20.00 -2.00 472.08 0.00e+00 1.5044e+00 3.2170e+01 3.9971e-01 -6.0000e+00 3.3585e+01 461.82 0.00e+00 432.10 492.92 4 -2.8139e+00 5.7744e-03 3.2885e-04 -6.0000e+00 5.9075e-03 2.0932e-02 4.9619e-03 1.8006e-04 -6.0000e+00 4.9883e-03 -9.4302e-03 1.9708e-03 4.0446e-05 -6.0000e+00 2.2351e-03 1.2038e-03 6.7630e-04 2.2087e-05 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