File name: Pandora145s1_Toronto-Scarborough_20250627_L2Fit_fout2c9d20230821p1-8.txt
File generation date: 20250628T052944.6Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c9p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 145
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora145_OF_v5d20190718.txt
Instrument calibration file used: Pandora145s1_CF_v9d20230821.txt
Level 1 file used: Pandora145s1_Toronto-Scarborough_20250627_L1_smca1c9d20230821p1-8.txt
Full location name: University of Toronto - Scarborough
Short location name: Toronto-Scarborough
Country of location: Canada
Location latitude [deg]: 43.7843
Location longitude [deg]: -79.1874
Location altitude [m]: 137
Local noon date: 20250627
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: field cal for autumn2023 ff, based on Session 8(7)
First and last pixel inside fitting window: 226 368
Nominal wavelengths inside fitting window [nm]: 305.0462 305.1870 305.3278 305.4686 305.6094 305.7502 305.8910 306.0317 306.1725 306.3132 306.4539 306.5947 306.7354 306.8761 307.0167 307.1574 307.2981 307.4387 307.5794 307.7200 307.8606 308.0012 308.1418 308.2824 308.4230 308.5635 308.7041 308.8446 308.9851 309.1256 309.2661 309.4066 309.5471 309.6876 309.8281 309.9685 310.1089 310.2494 310.3898 310.5302 310.6706 310.8110 310.9513 311.0917 311.2320 311.3724 311.5127 311.6530 311.7933 311.9336 312.0739 312.2141 312.3544 312.4947 312.6349 312.7751 312.9153 313.0555 313.1957 313.3359 313.4761 313.6162 313.7564 313.8965 314.0366 314.1767 314.3168 314.4569 314.5970 314.7370 314.8771 315.0171 315.1572 315.2972 315.4372 315.5772 315.7172 315.8572 315.9971 316.1371 316.2770 316.4169 316.5569 316.6968 316.8367 316.9765 317.1164 317.2563 317.3961 317.5360 317.6758 317.8156 317.9554 318.0952 318.2350 318.3747 318.5145 318.6542 318.7940 318.9337 319.0734 319.2131 319.3528 319.4925 319.6321 319.7718 319.9114 320.0511 320.1907 320.3303 320.4699 320.6095 320.7490 320.8886 321.0282 321.1677 321.3072 321.4467 321.5862 321.7257 321.8652 322.0047 322.1441 322.2836 322.4230 322.5625 322.7019 322.8413 322.9807 323.1200 323.2594 323.3988 323.5381 323.6774 323.8167 323.9561 324.0954 324.2346 324.3739 324.5132 324.6524 324.7917 324.9309
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250627T131441.5Z 9309.551869 192 1 29.01 2 53.71 91.39 76.76 71.83 0.00 1 0.00 1 0 17 9.535e-03 6.162e-03 7.105e-03 2.858e-03 2.319883e-01 1.437262e-03 2.816546e-03 -6.000000e+00 5.414917e-03 232.98 -2.00 3.57 -2.00 316.68 0.00e+00 2.016379e-04 1.761378e-04 8.478245e-05 -6.000000e+00 2.365021e-04 285.40 -2.00 20.00 -2.00 315.92 0.00e+00 1.685 0.000 302.00 328.00 3 5.5859e+00 3.8026e-03 2.0834e-02 -6.0000e+00 1.3627e-02 4.5438e-02 4.2527e-03 1.2384e-02 -6.0000e+00 1.4737e-02 -2.3293e-03 2.4837e-03 5.9875e-03 -6.0000e+00 8.7516e-03 -3.7290e-03 1.1869e-03 1.6375e-03 -6.0000e+00 3.7208e-03 2.8253e-04 3.6606e-05 7.6790e-05 1.7313e-05 -6.0000e+00 2.3735e-04 1.0142e-03 0.0000e+00 10 0 0 10 0 0 99.99 17.91 0.27 0.00101 0.00129 14 14 1 5 0 2071.430 22.50 15.00 17.91 26.06 26.1 1100.00 -2785 2256 456 -1079 -1374 2085 -1050 1384 1111 -733 -2835 -2416 487 725 119 196 949 -1554 -1076 477 1652 -820 -1058 586 -105 242 231 -230 -422 2072 1046 552 2494 1287 -1056 -1370 -2660 -941 107 -886 -1308 -22 -343 -1483 277 -1180 -365 -310 -968 -367 -957 188 532 560 660 1164 1124 891 131 -45 583 1637 1060 2384 891 -128 -1166 -506 631 56 625 661 325 301 458 51 -457 -1503 -82 -1156 -927 -1402 -1599 -1157 -911 -355 289 94 670 173 703 -150 -228 -446 844 -195 349 642 407 -262 127 -578 -1026 -624 -646 -726 -659 -841 -42 173 326 -109 600 26 -248 -263 -13 -125 504 125 8 371 229 418 736 -90 644 573 321 667 -140 280 -57 138 117 -180 90 172 -222 -127 -52 -790 -362 -418 354 75 -169 -186 281 -154 203 185 -132 -504 -425 93 157 30 54 267 -460 -329 149 522 -260 -340 196 -37 89 86 -80 -135 622 333 190 914 499 -385 -476 -1016 -410 56 -505 -821 -14 -228 -1007 183 -794 -239 -196 -597 -222 -612 128 380 421 511 910 899 713 103 -35 462 1375 898 2136 815 -108 -979 -404 523 49 605 671 332 298 423 43 -368 -1141 -63 -1013 -842 -1415 -1730 -1293 -1009 -422 361 122 869 218 816 -172 -236 -438 858 -221 404 825 525 -360 163 -684 -1137 -707 -805 -960 -907 -1130 -59 255 509 -174 913 37 -345 -340 -17 -166 714 180 12 540 326 570 1012 -119 795 698 419 930 -193 395 -82 203 183 -299 143 281 -367 -205 -86 -1275 -564
SS 20250627T135859.2Z 9309.582629 216 1 31.30 2 45.76 99.73 69.37 78.69 0.00 1 0.00 1 0 17 1.059e-02 6.942e-03 5.256e-03 2.769e-03 2.004364e-01 1.399178e-03 2.443086e-03 -6.000000e+00 6.013163e-03 232.98 -2.00 3.57 -2.00 315.95 0.00e+00 2.218134e-04 1.453920e-04 3.266262e-05 -6.000000e+00 2.625935e-04 285.41 -2.00 20.00 -2.00 315.23 0.00e+00 1.431 0.000 302.00 328.00 3 5.9584e+00 3.6680e-03 1.7806e-02 -6.0000e+00 1.5132e-02 5.5011e-02 4.0824e-03 1.0684e-02 -6.0000e+00 1.6364e-02 -1.8993e-03 2.3465e-03 5.1735e-03 -6.0000e+00 9.7181e-03 -2.3719e-03 1.0801e-03 1.4193e-03 -6.0000e+00 4.1325e-03 2.6261e-04 -5.9191e-05 7.3790e-05 1.5557e-05 -6.0000e+00 2.6354e-04 -3.8182e-05 0.0000e+00 11 8 0 10 0 0 99.92 17.95 0.25 -0.00004 -0.00048 9 9 1 5 0 3477.440 22.61 15.00 17.95 26.66 26.0 1100.00 -849 5 -547 -449 -2063 1311 -5591 1471 -527 1112 -3975 66 -857 713 -353 -969 288 1124 1060 1061 929 -116 1372 -1007 1289 20 2159 -252 149 -215 2008 1150 1312 1089 -1845 -1471 -2929 -310 -948 569 -999 -1129 -713 -585 -832 -494 -1456 -586 -984 -650 483 552 1213 891 865 681 1613 203 840 62 1028 795 1477 1856 679 190 -1379 -1035 -202 184 413 675 -146 1364 203 -494 -898 -1587 -777 -729 -1101 -800 -1886 -1264 -912 -353 -332 -236 1309 139 755 -501 -137 -135 633 -349 1018 461 339 132 243 -826 63 -331 -908 -718 -740 -647 98 396 250 680 382 -123 -435 -10 -503 -620 76 283 178 -14 521 73 921 347 293 304 647 398 145 -85 -17 -395 -83 18 310 566 -223 -11 -44 -694 -734 -188 1 -135 -103 -415 238 -1136 313 -129 283 -1026 16 -232 215 -122 -337 101 401 391 404 363 -45 525 -415 546 9 943 -105 62 -85 811 499 561 486 -778 -637 -1277 -152 -565 363 -708 -831 -537 -443 -626 -370 -1074 -412 -672 -434 333 407 932 721 720 574 1376 175 703 51 868 719 1334 1783 662 169 -1214 -863 -174 168 416 710 -155 1385 196 -463 -752 -1238 -612 -644 -1018 -813 -2069 -1428 -1024 -425 -423 -292 1714 179 891 -581 -142 -132 640 -390 1159 585 434 179 306 -965 73 -396 -1121 -938 -1007 -860 135 573 383 987 568 -169 -584 -12 -617 -792 104 391 255 -19 718 96 1220 440 349 381 802 528 203 -122 -22 -550 -122 28 494 869 -350 -17 -70 -1059 -1087
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