File name: Pandora145s1_Toronto-Scarborough_20250628_L2Fit_fout2c9d20230821p1-8.txt
File generation date: 20250629T053759.0Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c9p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 145
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora145_OF_v5d20190718.txt
Instrument calibration file used: Pandora145s1_CF_v9d20230821.txt
Level 1 file used: Pandora145s1_Toronto-Scarborough_20250628_L1_smca1c9d20230821p1-8.txt
Full location name: University of Toronto - Scarborough
Short location name: Toronto-Scarborough
Country of location: Canada
Location latitude [deg]: 43.7843
Location longitude [deg]: -79.1874
Location altitude [m]: 137
Local noon date: 20250628
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: field cal for autumn2023 ff, based on Session 8(7)
First and last pixel inside fitting window: 226 368
Nominal wavelengths inside fitting window [nm]: 305.0462 305.1870 305.3278 305.4686 305.6094 305.7502 305.8910 306.0317 306.1725 306.3132 306.4539 306.5947 306.7354 306.8761 307.0167 307.1574 307.2981 307.4387 307.5794 307.7200 307.8606 308.0012 308.1418 308.2824 308.4230 308.5635 308.7041 308.8446 308.9851 309.1256 309.2661 309.4066 309.5471 309.6876 309.8281 309.9685 310.1089 310.2494 310.3898 310.5302 310.6706 310.8110 310.9513 311.0917 311.2320 311.3724 311.5127 311.6530 311.7933 311.9336 312.0739 312.2141 312.3544 312.4947 312.6349 312.7751 312.9153 313.0555 313.1957 313.3359 313.4761 313.6162 313.7564 313.8965 314.0366 314.1767 314.3168 314.4569 314.5970 314.7370 314.8771 315.0171 315.1572 315.2972 315.4372 315.5772 315.7172 315.8572 315.9971 316.1371 316.2770 316.4169 316.5569 316.6968 316.8367 316.9765 317.1164 317.2563 317.3961 317.5360 317.6758 317.8156 317.9554 318.0952 318.2350 318.3747 318.5145 318.6542 318.7940 318.9337 319.0734 319.2131 319.3528 319.4925 319.6321 319.7718 319.9114 320.0511 320.1907 320.3303 320.4699 320.6095 320.7490 320.8886 321.0282 321.1677 321.3072 321.4467 321.5862 321.7257 321.8652 322.0047 322.1441 322.2836 322.4230 322.5625 322.7019 322.8413 322.9807 323.1200 323.2594 323.3988 323.5381 323.6774 323.8167 323.9561 324.0954 324.2346 324.3739 324.5132 324.6524 324.7917 324.9309
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250628T130413.3Z 9310.544599 182 1 28.87 2 55.66 89.58 90.17 65.17 0.00 1 0.00 1 0 17 1.999e-02 6.999e-03 1.641e-02 5.075e-03 2.486578e-01 2.548226e-03 3.031344e-03 -6.000000e+00 1.135609e-02 232.99 -2.00 3.57 -2.00 317.37 0.00e+00 2.436876e-04 3.666363e-04 5.432696e-05 -6.000000e+00 4.959216e-04 285.49 -2.00 20.00 -2.00 316.58 0.00e+00 1.767 0.000 302.00 328.00 3 6.2873e+00 6.8169e-03 2.2091e-02 -6.0000e+00 2.8578e-02 4.2615e-02 7.6501e-03 1.3378e-02 -6.0000e+00 3.0899e-02 4.0274e-03 4.5892e-03 6.4664e-03 -6.0000e+00 1.8351e-02 -5.8106e-03 2.2690e-03 1.7813e-03 -6.0000e+00 7.8081e-03 1.2515e-04 4.0783e-04 1.3810e-04 1.8019e-05 -6.0000e+00 4.9751e-04 -2.7880e-03 0.0000e+00 11 8 0 10 0 0 99.99 18.01 0.12 -0.00279 0.00028 12 12 1 5 0 2405.190 22.61 15.00 18.01 32.34 26.6 1100.00 8674 -5295 -1287 -4192 -1143 -5518 -570 4689 6780 1457 8553 8250 -895 1270 4529 -1043 -3672 903 2106 766 -2920 995 -3932 1268 -844 6 -1659 -587 1503 494 131 4940 2290 -1045 -1161 117 -51 -1486 75 -158 -811 -1757 -1229 -110 -692 -1899 -967 -992 -2467 -471 1086 829 1066 1608 1174 282 611 -164 984 247 490 2379 892 1635 877 1080 -1029 -1975 107 -489 318 361 -100 1082 241 404 -936 -764 3 219 -411 -782 -1847 -1282 -335 -829 -520 165 940 -222 748 358 -77 697 -99 332 389 1012 414 655 -64 -1651 -402 118 -656 -388 -915 -982 -515 225 419 615 634 154 -292 -127 8 -414 -221 -568 -551 -12 779 213 475 129 -266 637 583 692 143 40 185 -50 65 70 -71 -39 -292 167 116 -369 -393 866 -671 -161 -510 -117 -553 -57 507 811 195 1041 1004 -134 213 843 -228 -853 207 496 190 -771 248 -1040 338 -243 2 -505 -166 381 122 34 1337 693 -343 -351 33 -16 -541 33 -81 -462 -972 -697 -62 -424 -1090 -584 -581 -1428 -265 633 522 653 1033 782 193 426 -115 665 166 336 1719 713 1393 760 854 -758 -1409 78 -415 296 351 -98 1014 213 319 -726 -552 2 168 -358 -758 -1939 -1389 -385 -958 -634 207 1178 -272 905 395 -77 658 -99 365 474 1269 562 876 -81 -2086 -466 140 -799 -500 -1234 -1386 -755 350 642 958 1021 232 -402 -162 10 -546 -312 -867 -867 -19 1164 307 647 168 -352 825 808 957 210 60 282 -79 109 116 -120 -68 -515 287 192 -631 -651
SS 20250628T131546.8Z 9310.552625 192 1 29.99 2 53.58 91.60 88.35 67.11 0.00 1 0.00 1 0 17 8.041e-03 5.546e-03 3.948e-04 1.959e-04 2.322834e-01 9.924978e-05 2.841950e-03 -6.000000e+00 4.567349e-03 232.99 -2.00 3.57 -2.00 316.13 0.00e+00 1.726631e-04 1.063600e-05 3.760564e-05 -6.000000e+00 1.994950e-04 285.49 -2.00 20.00 -2.00 315.39 0.00e+00 1.680 0.000 302.00 328.00 3 5.9752e-01 2.6040e-04 2.0811e-02 -6.0000e+00 1.1494e-02 2.6465e-03 2.9004e-04 1.2410e-02 -6.0000e+00 1.2428e-02 -9.4223e-04 1.6716e-04 6.0007e-03 -6.0000e+00 7.3812e-03 -3.4782e-04 7.7762e-05 1.6392e-03 -6.0000e+00 3.1397e-03 4.2335e-02 -3.3531e-05 5.2080e-06 1.8104e-05 -6.0000e+00 2.0014e-04 -1.2294e-03 0.0000e+00 10 0 0 10 0 0 99.76 18.05 0.34 -0.00123 -0.00148 1265 1265 1 5 0 23.700 22.61 15.00 18.05 32.52 26.8 1100.00 -607 -561 -342 -2162 -2756 -2893 -1183 316 1088 -63 -1551 -1624 -1094 -444 458 -166 -80 40 196 998 649 425 534 618 742 664 294 217 -150 287 1179 1762 2022 130 -1459 -1921 -2046 -750 -184 -501 -824 -871 -732 -896 -191 -531 -528 -522 -765 -165 657 684 933 822 562 963 799 625 378 478 715 976 1141 1356 381 52 -421 -491 738 432 204 30 10 353 278 144 12 -460 110 -279 -616 -920 -1814 -1462 -1276 -968 -425 -376 14 143 423 243 79 643 693 440 375 583 105 -42 -331 -665 -187 116 -517 -635 -573 -887 -249 24 159 1 163 137 60 399 458 289 265 6 -251 -111 52 252 885 381 488 1074 631 609 206 -112 -44 34 -66 -216 32 -56 -193 -169 -252 -577 -291 -114 -116 -72 -438 -530 -521 -220 65 232 -14 -350 -364 -271 -125 146 -54 -27 14 70 369 247 159 202 247 313 293 130 91 -57 105 451 720 895 61 -646 -810 -935 -366 -108 -325 -552 -609 -526 -652 -137 -383 -372 -356 -509 -115 447 501 719 629 445 772 656 514 304 380 580 847 1015 1292 370 47 -363 -405 630 401 199 31 11 350 274 127 10 -382 88 -252 -594 -933 -1990 -1578 -1471 -1143 -529 -463 17 179 490 269 83 639 720 480 432 747 139 -55 -427 -789 -216 137 -644 -803 -755 -1173 -342 36 234 2 237 192 81 517 586 369 363 8 -369 -162 73 342 1181 488 614 1323 833 825 283 -158 -63 50 -99 -330 50 -90 -314 -269 -387 -893 -436
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