File name: Pandora108s1_Toronto-West_20220424_L2Fit_fwvt1c6d20211104p1-8.txt File generation date: 20240820T111733.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v3d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20220424_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20220424 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1653 1802 Nominal wavelengths inside fitting window [nm]: 492.1141 492.2350 492.3559 492.4768 492.5976 492.7185 492.8393 492.9601 493.0809 493.2016 493.3224 493.4431 493.5638 493.6845 493.8052 493.9259 494.0466 494.1672 494.2878 494.4084 494.5290 494.6496 494.7701 494.8907 495.0112 495.1317 495.2522 495.3726 495.4931 495.6135 495.7339 495.8543 495.9747 496.0951 496.2154 496.3358 496.4561 496.5764 496.6967 496.8169 496.9372 497.0574 497.1776 497.2978 497.4180 497.5382 497.6583 497.7785 497.8986 498.0187 498.1388 498.2588 498.3789 498.4989 498.6189 498.7389 498.8589 498.9789 499.0988 499.2187 499.3387 499.4585 499.5784 499.6983 499.8181 499.9380 500.0578 500.1776 500.2973 500.4171 500.5368 500.6566 500.7763 500.8960 501.0156 501.1353 501.2549 501.3746 501.4942 501.6138 501.7333 501.8529 501.9724 502.0920 502.2115 502.3310 502.4504 502.5699 502.6893 502.8087 502.9281 503.0475 503.1669 503.2862 503.4056 503.5249 503.6442 503.7635 503.8827 504.0020 504.1212 504.2404 504.3596 504.4788 504.5980 504.7171 504.8363 504.9554 505.0745 505.1935 505.3126 505.4316 505.5507 505.6697 505.7887 505.9076 506.0266 506.1455 506.2645 506.3834 506.5023 506.6211 506.7400 506.8588 506.9776 507.0964 507.2152 507.3340 507.4527 507.5715 507.6902 507.8089 507.9276 508.0462 508.1649 508.2835 508.4021 508.5207 508.6393 508.7578 508.8764 508.9949 509.1134 509.2319 509.3504 509.4688 509.5873 509.7057 509.8241 509.9425 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220424T103942.6Z 8149.444243 115 1 40.86 2 87.57 74.38 70.33 152.27 0.00 1 0.00 1 0 22 5.187e-03 5.076e-03 1.496e-03 1.487e-03 1.816374e+04 1.077070e+02 1.205427e+03 -6.000000e+00 2.843093e+02 278.71 -2.00 20.00 -2.00 505.48 0.00e+00 2.631425e-03 4.105186e-05 1.663484e-04 -6.000000e+00 1.440788e-04 278.71 -2.00 20.00 -2.00 501.07 0.00e+00 1.178224e+00 2.902232e-02 1.260188e-01 -6.000000e+00 1.033272e-01 228.99 -2.00 3.57 -2.00 502.57 0.00e+00 14.950 0.065 489.00 513.00 1 5.5736e+00 2.2148e-03 2.5656e-02 -6.0000e+00 7.9075e-03 -4.8043e-02 5.5532e-04 3.3783e-03 -6.0000e+00 2.0566e-03 7.8219e-04 4.4722e-04 1.3264e-04 1.4070e-04 -6.0000e+00 5.2864e-04 -1.4380e-02 7.4000e-05 12 9 9 12 1 1 98.53 18.20 1.72 -0.01438 -0.01128 16 4 1 4 0 2392.500 23.64 15.00 18.20 12.60 25.3 1002.48 -700 -213 79 552 882 1079 1105 1076 1092 442 474 -17 -179 -281 -464 -443 -163 75 281 330 236 265 222 455 342 633 175 -153 -367 -797 -974 -933 -363 8 335 -245 6 -439 -152 -290 -27 -14 138 378 501 804 133 244 -126 -356 -838 -789 -940 -637 -16 -86 111 193 512 200 426 421 337 317 140 -87 -172 -463 -516 -646 -651 -679 -345 -83 -53 -435 -640 -824 -489 -908 -651 -490 -587 -80 -460 -375 -312 -22 -265 -106 251 476 664 729 665 109 110 -395 -525 -1474 -1277 -1200 -581 -190 -181 -311 -149 -294 -303 -199 -89 118 228 683 941 1011 1122 627 531 327 259 -130 335 250 426 476 345 580 137 430 86 -184 -370 -272 -367 99 258 184 228 225 227 297 556 305 308 121 -248 -610 -667 -549 -609 -189 73 485 795 993 1032 1012 1022 411 435 -16 -161 -252 -417 -402 -150 71 271 322 231 260 219 451 342 631 175 -151 -353 -751 -912 -885 -353 8 342 -253 6 -446 -153 -291 -27 -15 143 396 530 849 141 254 -129 -357 -823 -762 -908 -624 -16 -89 117 206 507 199 425 423 340 319 139 -86 -168 -478 -528 -656 -659 -693 -356 -80 -52 -421 -610 -829 -486 -903 -648 -490 -555 -77 -446 -365 -304 -21 -255 -102 242 464 649 701 620 105 103 -360 -471 -1323 -1156 -1123 -530 -182 -180 -314 -150 -294 -303 -201 -91 122 236 708 978 1062 1198 681 577 351 273 -135 344 259 444 499 364 610 145 452 90 -190 -380 -280 -383 105 279 203 256 241 246 324 609 335 338 131 -267 -649 -705 -583 SQ 20220424T111454.5Z 8149.468686 127 1 3.56 2 81.36 80.33 67.76 160.35 0.00 1 0.00 1 0 22 3.097e-03 3.075e-03 1.611e-03 1.609e-03 7.049471e+03 1.035409e+02 4.941391e+02 -6.000000e+00 1.696873e+02 278.71 -2.00 20.00 -2.00 505.33 0.00e+00 1.072287e-03 4.392715e-05 6.840950e-05 -6.000000e+00 8.602307e-05 278.71 -2.00 20.00 -2.00 500.68 0.00e+00 5.508814e-01 3.168701e-02 5.121550e-02 -6.000000e+00 6.175639e-02 228.99 -2.00 3.57 -2.00 502.24 0.00e+00 6.280 0.005 489.00 513.00 1 5.1088e+00 2.4212e-03 1.0024e-02 -6.0000e+00 4.7250e-03 -1.9421e-02 6.1950e-04 1.3341e-03 -6.0000e+00 1.2311e-03 4.5847e-03 2.0488e-03 1.5532e-04 6.6058e-05 -6.0000e+00 3.1576e-04 8.4748e-03 -1.6328e-04 12 1 1 12 1 1 -72.08 18.19 0.77 0.00847 0.02269 4 15 1 4 0 674.780 23.64 15.00 18.19 13.26 24.9 1005.13 -581 -337 34 240 228 598 580 311 498 143 476 -40 9 -407 -166 -241 -29 -67 228 285 -22 145 243 308 294 -2 -53 25 -165 -710 -325 -482 -226 -7 68 -110 376 -53 -110 99 -9 120 34 218 127 292 297 121 48 -407 -364 -462 -528 -420 -203 -166 225 104 359 223 332 309 299 324 127 -75 -263 -330 -295 -377 -494 -237 104 80 30 -185 -288 -360 -445 -501 -374 -383 -240 -162 -225 -304 -150 -362 -291 90 141 214 387 311 306 104 45 -438 -124 -733 -603 -657 -129 -91 119 -3 -182 -209 -329 -97 -135 -28 80 645 646 468 653 444 431 209 266 233 187 253 60 635 165 -143 -123 377 -71 25 -77 -372 -86 -48 81 -26 12 304 -77 283 447 294 -28 -76 -148 -201 -492 -391 -541 -320 34 243 226 601 592 320 508 145 473 -39 8 -394 -160 -234 -29 -68 235 298 -23 153 255 311 297 -2 -53 26 -166 -702 -317 -477 -229 -7 69 -113 380 -53 -110 103 -8 120 34 223 131 301 304 123 47 -412 -359 -447 -510 -412 -205 -165 226 105 363 226 337 315 305 330 128 -75 -259 -321 -296 -376 -491 -237 104 78 29 -179 -288 -354 -434 -490 -367 -378 -239 -156 -219 -298 -147 -355 -285 88 140 215 390 312 301 100 44 -420 -116 -682 -564 -631 -123 -90 121 -3 -183 -208 -328 -97 -138 -29 79 642 647 472 663 453 438 209 273 236 189 256 62 647 162 -140 -121 383 -72 25 -76 -365 -85 -48 79 -26 12 311 -80 294 466 308 -29 -79 -151 -201 -486 -386 SQ 20220424T112345.9Z 8149.474836 129 1 50.11 2 79.77 81.81 67.24 162.45 0.00 1 0.00 1 0 22 2.366e-03 2.326e-03 2.201e-04 2.197e-04 6.363456e+03 1.414071e+01 4.433110e+02 -6.000000e+00 1.296575e+02 278.71 -2.00 20.00 -2.00 505.32 0.00e+00 1.049974e-03 5.982846e-06 6.692475e-05 -6.000000e+00 6.571238e-05 278.71 -2.00 20.00 -2.00 500.65 0.00e+00 4.649235e-01 4.331618e-03 4.726576e-02 -6.000000e+00 4.714285e-02 228.99 -2.00 3.57 -2.00 502.22 0.00e+00 5.401 0.003 489.00 513.00 1 3.5820e+00 3.3004e-04 8.7607e-03 -6.0000e+00 3.6075e-03 -1.5012e-02 8.5216e-05 1.2020e-03 -6.0000e+00 9.3882e-04 2.4065e-02 2.6619e-04 2.1424e-05 6.0758e-05 -6.0000e+00 2.4115e-04 2.0570e-02 -1.7107e-04 10 0 0 10 0 0 99.38 18.19 0.73 0.02057 0.02242 512 100 1 4 0 97.850 23.64 15.00 18.19 13.46 24.9 1006.12 -442 -282 -31 186 235 499 538 408 446 203 134 -45 -148 -195 -225 -209 -116 102 149 45 121 181 107 255 284 131 82 52 -199 -397 -281 -387 -191 128 30 -91 28 -63 -144 -96 -14 69 117 271 274 328 267 133 31 -166 -303 -403 -461 -323 -114 -79 16 37 107 127 168 156 72 120 44 -29 -155 -178 -192 -291 -251 -288 -204 -95 -32 -253 -272 -279 -269 -358 -343 -305 -296 -99 -101 -149 -102 -28 -66 18 31 174 235 202 227 153 -54 -233 -255 -546 -507 -503 -320 -133 -229 -205 -144 -122 -104 0 -4 100 260 382 477 486 515 420 267 181 204 57 168 230 99 114 277 134 88 267 44 -71 -17 -100 -137 86 43 -50 153 167 137 149 219 128 39 -51 -215 -307 -375 -321 -415 -270 -31 190 246 493 540 412 447 201 131 -43 -152 -199 -229 -215 -113 101 151 46 124 186 110 263 295 136 84 52 -196 -382 -267 -373 -189 130 31 -95 29 -65 -146 -97 -14 70 121 282 288 345 279 137 32 -163 -290 -379 -432 -307 -112 -80 17 38 110 130 173 162 75 125 45 -30 -155 -175 -187 -281 -241 -279 -200 -94 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112 193 207 67 -18 -50 -164 -195 -223 -251 SQ 20220424T180946.2Z 8149.756785 322 6 9.90 2 32.75 204.60 97.89 249.55 0.00 1 0.00 1 0 15 1.733e-03 1.724e-03 1.993e-04 1.988e-04 1.315864e+03 1.143144e+01 9.507527e+01 -6.000000e+00 9.499349e+01 278.74 -2.00 20.00 -2.00 505.31 0.00e+00 4.089721e-04 5.424838e-06 2.543584e-05 -6.000000e+00 4.814410e-05 278.74 -2.00 20.00 -2.00 500.56 0.00e+00 -3.870064e-02 3.923470e-03 1.152498e-02 -6.000000e+00 3.454109e-02 229.02 -2.00 3.57 -2.00 502.16 0.00e+00 1.188 0.000 489.00 513.00 1 1.5331e-02 2.9970e-04 2.0238e-03 -6.0000e+00 2.6431e-03 -3.4344e-03 7.7639e-05 2.7421e-04 -6.0000e+00 6.8798e-04 1.6282e+00 4.2066e-04 1.9891e-05 1.5256e-05 -6.0000e+00 1.7667e-04 2.2440e-02 -1.9338e-04 10 0 0 10 0 0 10.27 18.28 0.93 0.02244 0.02536 540 106 2 4 0 17.730 23.72 15.00 18.28 26.87 26.1 1057.61 -349 -278 -57 93 141 398 385 349 365 151 74 -27 -128 -111 -141 -136 -101 85 123 46 130 160 67 183 233 69 43 53 -156 -285 -164 -285 -173 113 -14 -101 0 -39 -116 -86 13 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8149.801759 353 3 11.92 2 39.78 228.70 108.59 259.87 0.00 1 0.00 1 0 15 1.719e-03 1.717e-03 1.959e-04 1.954e-04 1.476642e+03 1.135567e+01 1.085531e+02 -6.000000e+00 9.421178e+01 278.75 -2.00 20.00 -2.00 505.32 0.00e+00 4.076704e-04 5.337484e-06 2.587900e-05 -6.000000e+00 4.774763e-05 278.75 -2.00 20.00 -2.00 500.54 0.00e+00 -1.846638e-02 3.862379e-03 1.239083e-02 -6.000000e+00 3.425647e-02 229.02 -2.00 3.57 -2.00 502.15 0.00e+00 1.300 0.000 489.00 513.00 1 1.3040e-01 2.9511e-04 2.1940e-03 -6.0000e+00 2.6213e-03 -3.3836e-03 7.6170e-05 3.0210e-04 -6.0000e+00 6.8232e-04 1.4260e+00 4.8124e-04 1.9514e-05 1.6639e-05 -6.0000e+00 1.7522e-04 2.2281e-02 -1.9289e-04 10 0 0 10 0 0 13.61 18.30 0.93 0.02228 0.02562 577 113 2 4 0 19.820 23.72 15.00 18.30 28.10 26.1 1058.59 -285 -277 -7 121 168 399 422 321 353 166 99 -16 -134 -123 -158 -146 -91 72 106 8 97 182 79 202 215 80 48 56 -110 -302 -156 -288 -156 123 -29 -130 -15 -15 -127 -92 2 35 75 170 206 247 216 97 79 -129 -204 -269 -342 -242 -86 -83 -35 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8149.801898 353 4 11.78 2 39.80 228.76 108.63 259.91 0.00 1 0.00 1 0 15 1.732e-03 1.727e-03 1.944e-04 1.938e-04 1.480139e+03 1.123316e+01 1.095457e+02 -6.000000e+00 9.492337e+01 278.75 -2.00 20.00 -2.00 505.32 0.00e+00 4.044812e-04 5.291197e-06 2.551742e-05 -6.000000e+00 4.810789e-05 278.75 -2.00 20.00 -2.00 500.54 0.00e+00 -1.687647e-02 3.830895e-03 1.220222e-02 -6.000000e+00 3.451440e-02 229.02 -2.00 3.57 -2.00 502.15 0.00e+00 1.300 0.000 489.00 513.00 1 1.1903e-01 2.9265e-04 2.1868e-03 -6.0000e+00 2.6411e-03 -3.4837e-03 7.5739e-05 2.9922e-04 -6.0000e+00 6.8744e-04 1.4422e+00 4.2275e-04 1.9350e-05 1.6760e-05 -6.0000e+00 1.7654e-04 2.2198e-02 -1.9088e-04 10 0 0 10 0 0 5.29 18.30 0.93 0.02220 0.02513 577 113 2 4 0 19.820 23.72 15.00 18.30 28.13 26.1 1058.59 -321 -259 -27 114 135 404 418 315 355 149 81 -15 -131 -127 -139 -139 -82 88 99 29 97 142 80 185 242 71 54 34 -115 -318 -156 -288 -162 118 -22 -111 13 -32 -135 -84 10 46 81 207 198 282 215 99 78 -119 -227 -251 -361 -252 -102 -85 -71 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20220424T191455.9Z 8149.802036 353 5 11.88 2 39.83 228.82 108.66 259.94 0.00 1 0.00 1 0 15 1.742e-03 1.736e-03 1.941e-04 1.936e-04 1.456338e+03 1.120614e+01 1.065123e+02 -6.000000e+00 9.547248e+01 278.75 -2.00 20.00 -2.00 505.32 0.00e+00 4.083348e-04 5.286268e-06 2.575759e-05 -6.000000e+00 4.838637e-05 278.75 -2.00 20.00 -2.00 500.55 0.00e+00 -1.358956e-02 3.825391e-03 1.231029e-02 -6.000000e+00 3.471444e-02 229.02 -2.00 3.57 -2.00 502.15 0.00e+00 1.301 0.000 489.00 513.00 1 1.1720e-01 2.9221e-04 2.1914e-03 -6.0000e+00 2.6564e-03 -3.4770e-03 7.5621e-05 2.9836e-04 -6.0000e+00 6.9143e-04 1.4443e+00 4.6636e-04 1.9333e-05 1.6490e-05 -6.0000e+00 1.7756e-04 2.2227e-02 -1.9174e-04 10 0 0 10 0 0 31.86 18.30 0.93 0.02223 0.02546 577 113 2 4 0 19.820 23.72 15.00 18.30 28.13 26.1 1058.59 -303 -270 -21 84 166 392 448 293 357 149 91 -25 -122 -123 -145 -158 -107 106 85 14 89 169 89 206 246 58 53 34 -124 -285 -146 -289 -182 109 -17 -121 2 -42 -134 -70 4 10 76 195 202 283 203 113 93 -144 -197 -283 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80 142 126 186 207 84 8 -71 -141 -234 -242 -248 SQ 20220424T192011.1Z 8149.805684 356 4 11.76 2 40.55 230.46 109.55 260.77 0.00 1 0.00 1 0 15 1.768e-03 1.759e-03 1.887e-04 1.882e-04 1.504139e+03 1.086235e+01 1.105314e+02 -6.000000e+00 9.687731e+01 278.75 -2.00 20.00 -2.00 505.30 0.00e+00 4.186654e-04 5.125323e-06 2.606060e-05 -6.000000e+00 4.909833e-05 278.75 -2.00 20.00 -2.00 500.55 0.00e+00 -2.120825e-02 3.716768e-03 1.244554e-02 -6.000000e+00 3.522522e-02 229.02 -2.00 3.57 -2.00 502.14 0.00e+00 1.315 0.000 489.00 513.00 1 6.8525e-02 2.8371e-04 2.2165e-03 -6.0000e+00 2.6955e-03 -3.1489e-03 7.3906e-05 3.0262e-04 -6.0000e+00 7.0161e-04 1.5139e+00 4.3516e-04 1.8819e-05 1.7141e-05 -6.0000e+00 1.8017e-04 2.2056e-02 -1.9074e-04 10 0 0 10 0 0 17.27 18.30 0.92 0.02206 0.02507 592 116 2 4 0 19.300 23.72 15.00 18.30 28.38 26.1 1059.41 -343 -263 -45 106 151 419 419 321 349 173 92 -34 -116 -131 -165 -145 -79 78 106 15 115 170 86 215 234 80 52 46 -128 -308 -178 -306 -175 121 -19 -129 -16 -52 -131 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20220424T203633.6Z 8149.858722 393 7 5.80 2 52.54 250.22 122.57 273.45 0.00 1 0.00 1 0 15 1.823e-03 1.813e-03 9.318e-05 9.288e-05 1.938245e+03 5.381940e+00 1.433456e+02 -6.000000e+00 9.990443e+01 278.75 -2.00 20.00 -2.00 505.21 0.00e+00 4.903476e-04 2.512848e-06 3.068947e-05 -6.000000e+00 5.063199e-05 278.75 -2.00 20.00 -2.00 500.42 0.00e+00 7.302852e-03 1.841175e-03 1.490924e-02 -6.000000e+00 3.632506e-02 229.03 -2.00 3.57 -2.00 501.99 0.00e+00 1.640 0.000 489.00 513.00 1 3.1271e-01 1.4080e-04 2.7333e-03 -6.0000e+00 2.7796e-03 -4.0516e-03 3.6758e-05 3.7248e-04 -6.0000e+00 7.2351e-04 1.1283e+00 4.4017e-04 9.2620e-06 2.3208e-05 -6.0000e+00 1.8580e-04 2.1723e-02 -1.8861e-04 10 0 0 10 0 0 -1.78 18.31 0.91 0.02172 0.02478 2259 443 1 4 0 2.400 23.83 15.00 18.31 26.71 26.2 1040.34 -307 -247 -42 114 165 427 448 351 373 186 101 -16 -93 -108 -131 -136 -94 90 118 33 108 171 86 189 232 80 29 48 -151 -323 -185 -304 -189 98 -45 -140 -20 -81 -149 -98 -10 29 88 207 204 256 209 91 50 -152 -240 -279 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251 100 79 181 52 -48 31 -67 -71 108 46 -62 96 165 113 171 166 92 18 -37 -165 -258 -256 -231 SQ 20220424T211911.4Z 8149.888326 412 4 5.95 2 59.96 258.98 129.77 281.37 0.00 1 0.00 1 0 15 1.781e-03 1.772e-03 2.107e-04 2.101e-04 2.481813e+03 1.261846e+01 1.791697e+02 -6.000000e+00 9.759323e+01 278.76 -2.00 20.00 -2.00 505.33 0.00e+00 5.389463e-04 5.745770e-06 3.443495e-05 -6.000000e+00 4.946142e-05 278.76 -2.00 20.00 -2.00 500.56 0.00e+00 6.557201e-02 4.155970e-03 2.028395e-02 -6.000000e+00 3.548633e-02 229.03 -2.00 3.57 -2.00 502.16 0.00e+00 1.989 0.000 489.00 513.00 1 1.8422e+00 3.1760e-04 3.3820e-03 -6.0000e+00 2.7154e-03 -3.1070e-03 8.1663e-05 4.9693e-04 -6.0000e+00 7.0685e-04 2.3134e-01 4.8449e-04 2.0918e-05 2.5208e-05 -6.0000e+00 1.8150e-04 2.1561e-02 -1.9134e-04 10 0 0 10 0 0 -3.10 18.32 0.88 0.02156 0.02492 600 118 1 4 0 9.600 23.83 14.99 18.32 26.01 26.2 1032.38 -291 -249 -11 122 166 416 422 314 367 181 114 -10 -91 -96 -107 -124 -77 74 125 25 106 142 69 188 219 34 35 73 -110 -287 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133 177 177 96 12 -64 -157 -241 -268 -221 SQ 20220424T215946.2Z 8149.916507 436 9 5.96 2 67.22 266.47 136.42 290.02 0.00 1 0.00 1 0 15 1.812e-03 1.800e-03 2.274e-04 2.269e-04 3.378641e+03 1.385130e+01 2.437814e+02 -6.000000e+00 9.929220e+01 278.76 -2.00 20.00 -2.00 505.32 0.00e+00 8.738098e-04 6.182544e-06 5.281797e-05 -6.000000e+00 5.032387e-05 278.76 -2.00 20.00 -2.00 500.60 0.00e+00 1.262523e-01 4.481770e-03 2.660681e-02 -6.000000e+00 3.610714e-02 229.03 -2.00 3.57 -2.00 502.18 0.00e+00 2.562 0.000 489.00 513.00 1 1.8907e+00 3.4202e-04 4.4345e-03 -6.0000e+00 2.7629e-03 -3.3842e-03 8.8548e-05 6.5133e-04 -6.0000e+00 7.1928e-04 2.0110e-01 6.0379e-04 2.2506e-05 3.5849e-05 -6.0000e+00 1.8467e-04 2.1188e-02 -1.9524e-04 10 0 0 10 0 0 1.10 18.31 0.85 0.02119 0.02538 541 106 1 4 0 10.670 23.72 15.00 18.31 24.80 26.0 1023.63 -257 -266 25 119 190 416 442 348 384 213 124 2 -78 -97 -116 -107 -70 131 130 33 91 141 68 171 203 17 47 64 -108 -330 -168 -283 -166 102 -58 -117 -57 -67 -140 -78 -16 36 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3.4589e-05 -6.0000e+00 2.0531e-04 2.1240e-02 -1.8734e-04 10 0 0 10 0 0 0.55 18.30 0.85 0.02124 0.02476 1632 320 1 4 0 3.400 23.72 15.00 18.30 25.01 25.9 1024.12 -333 -248 -21 115 215 458 460 363 419 200 141 -2 -92 -111 -162 -140 -87 102 134 46 112 181 94 200 249 99 63 15 -149 -343 -204 -340 -182 95 -33 -139 -33 -82 -179 -116 -34 23 97 243 238 286 220 96 71 -172 -267 -356 -426 -313 -132 -103 -37 17 60 130 139 157 51 99 18 -27 -118 -138 -141 -244 -186 -248 -188 -97 -67 -239 -257 -183 -189 -246 -247 -183 -226 -25 -80 -143 -109 -31 -35 3 37 149 203 146 183 111 -70 -189 -196 -384 -406 -394 -298 -131 -301 -246 -171 -97 -116 -5 -23 38 204 275 380 384 430 353 263 208 223 119 178 247 53 126 239 147 105 231 45 -37 14 -84 -51 92 66 -65 135 173 118 175 206 122 0 -34 -186 -217 -283 -261 -307 -234 -21 115 221 478 487 386 443 209 145 -2 -92 -110 -161 -140 -88 107 142 50 120 194 102 216 270 107 68 16 -153 -344 -202 -341 -188 101 -35 -151 -35 -87 -189 -122 -36 25 104 244 241 289 221 102 74 -175 -264 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-6.7448e-03 4.3585e-05 6.7630e-04 -6.0000e+00 7.8691e-04 7.7948e-01 4.9435e-04 1.0944e-05 3.5098e-05 -6.0000e+00 2.0207e-04 2.1183e-02 -1.8798e-04 10 0 0 10 0 0 7.77 18.30 0.84 0.02118 0.02461 1632 320 1 4 0 3.400 23.72 15.00 18.30 25.03 25.9 1024.12 -348 -245 -34 129 183 442 468 345 412 176 150 -8 -91 -112 -131 -135 -72 110 128 36 85 191 66 204 239 86 53 36 -148 -340 -199 -346 -178 92 -29 -146 -25 -65 -168 -113 -27 34 85 237 206 292 211 108 47 -159 -271 -362 -401 -311 -124 -115 -43 -6 45 103 126 152 66 123 4 -24 -115 -132 -156 -235 -183 -237 -181 -96 -37 -253 -255 -200 -175 -249 -234 -197 -218 -54 -81 -133 -115 -6 -60 27 37 146 201 148 184 87 -70 -191 -174 -401 -380 -390 -293 -128 -298 -221 -147 -106 -116 15 -37 49 202 286 380 371 429 340 265 196 245 109 187 247 64 111 229 127 81 251 61 -38 25 -64 -52 93 72 -82 144 158 130 155 189 100 14 -46 -181 -229 -296 -250 -318 -229 -33 128 187 458 491 364 432 182 154 -8 -91 -111 -129 -134 -72 114 135 39 90 204 70 219 257 93 56 38 -152 -338 -196 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445 9 5.86 2 71.05 270.18 139.74 295.17 0.00 1 0.00 1 0 15 1.838e-03 1.829e-03 1.985e-04 1.980e-04 3.916222e+03 1.219527e+01 2.802614e+02 -6.000000e+00 1.007174e+02 278.76 -2.00 20.00 -2.00 505.31 0.00e+00 6.977710e-04 5.390273e-06 4.507820e-05 -6.000000e+00 5.104828e-05 278.76 -2.00 20.00 -2.00 500.61 0.00e+00 1.975971e-01 3.908592e-03 2.995553e-02 -6.000000e+00 3.662962e-02 229.04 -2.00 3.57 -2.00 502.19 0.00e+00 3.042 0.000 489.00 513.00 1 1.4853e+00 2.9804e-04 5.0959e-03 -6.0000e+00 2.8028e-03 -6.1618e-03 7.7454e-05 7.4649e-04 -6.0000e+00 7.2979e-04 2.8090e-01 6.1636e-04 1.9557e-05 3.7996e-05 -6.0000e+00 1.8734e-04 2.1810e-02 -2.0707e-04 10 0 0 10 0 0 28.95 18.30 0.82 0.02181 0.02609 833 163 1 4 0 6.860 23.72 15.00 18.30 25.38 26.0 1025.89 -249 -197 29 164 182 412 440 365 392 197 134 2 -82 -82 -131 -121 -75 82 120 28 97 164 72 191 209 82 43 59 -132 -263 -148 -285 -161 81 -51 -167 -22 -65 -146 -124 -28 -3 73 201 167 265 194 70 45 -163 -231 -287 -382 -285 -116 -100 -57 -32 27 77 92 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20220424T222103.6Z 8149.931292 445 10 5.88 2 71.07 270.19 139.75 295.19 0.00 1 0.00 1 0 15 1.835e-03 1.818e-03 1.944e-04 1.939e-04 3.911951e+03 1.191797e+01 2.817230e+02 -6.000000e+00 1.005855e+02 278.76 -2.00 20.00 -2.00 505.29 0.00e+00 7.174387e-04 5.268380e-06 4.577959e-05 -6.000000e+00 5.098094e-05 278.76 -2.00 20.00 -2.00 500.58 0.00e+00 1.931621e-01 3.835889e-03 2.918724e-02 -6.000000e+00 3.658060e-02 229.04 -2.00 3.57 -2.00 502.15 0.00e+00 3.045 0.000 489.00 513.00 1 1.4567e+00 2.9224e-04 5.0752e-03 -6.0000e+00 2.7991e-03 -5.9591e-03 7.6286e-05 7.3365e-04 -6.0000e+00 7.2879e-04 2.8895e-01 6.1346e-04 1.9151e-05 4.0149e-05 -6.0000e+00 1.8709e-04 2.1645e-02 -2.0409e-04 10 0 0 10 0 0 36.44 18.30 0.82 0.02165 0.02590 833 163 1 4 0 6.860 23.72 15.00 18.30 25.38 26.0 1025.89 -250 -186 30 151 151 448 446 359 382 187 138 16 -91 -76 -135 -113 -60 76 105 26 100 150 89 179 208 74 52 56 -115 -275 -154 -292 -160 85 -46 -156 -23 -72 -166 -128 -44 17 69 190 187 253 184 73 68 -156 -230 -298 -385 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33 -56 130 171 149 203 226 146 7 -36 -180 -278 -313 -266 SQ 20220424T223252.1Z 8149.939492 449 2 19.88 2 73.20 272.22 141.54 298.31 0.00 1 0.00 1 0 15 2.341e-03 2.312e-03 1.755e-04 1.752e-04 4.318813e+03 1.092369e+01 3.066433e+02 -6.000000e+00 1.282946e+02 278.76 -2.00 20.00 -2.00 505.32 0.00e+00 8.991946e-04 4.773340e-06 5.576135e-05 -6.000000e+00 6.501864e-05 278.76 -2.00 20.00 -2.00 500.59 0.00e+00 2.193713e-01 3.465818e-03 3.337470e-02 -6.000000e+00 4.664471e-02 229.04 -2.00 3.57 -2.00 502.17 0.00e+00 3.406 0.001 489.00 513.00 1 2.7590e+00 2.6438e-04 5.7249e-03 -6.0000e+00 3.5693e-03 -6.2665e-03 6.8258e-05 8.2778e-04 -6.0000e+00 9.2903e-04 7.4285e-02 4.4455e-04 1.7276e-05 4.3282e-05 -6.0000e+00 2.3858e-04 2.1064e-02 -1.8268e-04 12 1 1 12 1 1 85.68 18.29 0.80 0.02106 0.02415 456 124 1 4 0 43.020 23.72 15.00 18.29 24.52 26.0 1018.24 -428 -318 -56 137 231 489 539 407 436 205 124 -8 -136 -180 -216 -177 -86 109 167 66 146 204 126 260 293 147 61 16 -214 -398 -279 -375 -204 122 0 -80 -1 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331 412 450 475 395 290 192 191 91 171 239 71 115 244 136 104 233 63 -42 24 -63 -74 81 50 -48 128 186 124 198 216 127 36 -47 -175 -269 -292 -305 SQ 20220424T223742.0Z 8149.942848 452 2 5.86 2 74.07 273.05 142.26 299.64 0.00 1 0.00 1 0 15 2.246e-03 2.224e-03 1.333e-04 1.330e-04 4.638543e+03 8.345532e+00 3.291363e+02 -6.000000e+00 1.231220e+02 278.76 -2.00 20.00 -2.00 505.33 0.00e+00 9.657489e-04 3.631120e-06 5.988601e-05 -6.000000e+00 6.239784e-05 278.76 -2.00 20.00 -2.00 500.62 0.00e+00 2.389658e-01 2.628910e-03 3.575535e-02 -6.000000e+00 4.476539e-02 229.04 -2.00 3.57 -2.00 502.20 0.00e+00 3.581 0.001 489.00 513.00 1 7.9789e-01 2.0054e-04 6.0530e-03 -6.0000e+00 3.4255e-03 -8.5156e-03 5.1792e-05 8.8572e-04 -6.0000e+00 8.9162e-04 5.1365e-01 5.2200e-04 1.3103e-05 4.5520e-05 -6.0000e+00 2.2897e-04 2.0247e-02 -1.7955e-04 10 0 0 10 0 0 -6.06 18.31 0.81 0.02025 0.02387 998 196 1 4 0 5.690 23.72 15.00 18.31 24.05 26.0 1015.29 -399 -257 -12 167 258 502 513 418 430 221 142 7 -123 -166 -178 -162 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