File name: Pandora108s1_Toronto-West_20220601_L2Fit_fout2c6d20211104p1-8.txt File generation date: 20240820T112734.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v3d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20220601_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20220601 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220601T105903.9Z 8187.457684 85 1 49.03 2 77.87 70.95 90.23 52.21 0.00 1 0.00 1 0 17 4.914e-01 4.328e-02 3.607e-01 3.146e-02 5.831859e-01 1.793660e-02 7.740011e-03 -6.000000e+00 3.001453e-01 232.01 -2.00 3.57 -2.00 321.03 0.00e+00 1.254739e-02 7.245729e-03 4.733973e-03 -6.000000e+00 1.516389e-02 282.87 -2.00 20.00 -2.00 320.43 0.00e+00 4.616 0.002 302.00 328.00 3 4.3360e+00 5.7981e-02 5.7464e-02 -6.0000e+00 7.5599e-01 5.1000e-01 6.9631e-02 3.4397e-02 -6.0000e+00 8.2279e-01 -6.4194e-01 5.2793e-02 2.0383e-02 -6.0000e+00 4.8239e-01 2.8279e-01 2.6329e-02 9.7618e-03 -6.0000e+00 2.0093e-01 3.3641e-05 -2.7553e-03 9.8617e-04 2.0057e-04 -6.0000e+00 1.4808e-02 2.0146e-03 1.3545e-05 12 8 8 10 0 0 99.88 18.42 1.42 0.00201 -0.01869 20 4 1 5 0 2451.100 23.83 15.00 18.42 30.56 26.0 997.51 -113427 900000 -125343 900000 -88443 900000 -44383 900000 -23375 -8034 900000 -64126 900000 -61639 900000 -5493 900000 59656 252179 108830 -21447 138868 1701 900000 -22050 900000 -33492 900000 -20168 202442 95908 1354 900000 3278 900000 -46129 208327 -19660 125862 -44 29055 26469 7170 85124 4055 66521 -8628 91240 -14220 50318 27244 41814 30775 20344 29394 7431 46889 -2383 31778 -13824 22776 -3129 19724 7821 9093 21548 -1196 28557 -9056 17482 -2569 4756 -2154 4959 6651 175 15611 -17246 10788 -15834 6871 -7543 1017 -6690 -454 -45 -1980 6589 -5526 5238 -8454 7334 -10417 2397 -6163 -5934 -1849 -5184 4691 -3935 5707 -3945 887 -6471 -1641 -2945 -1681 775 -3700 5680 -2190 3682 -4394 3905 -3818 -193 -713 118 2731 -622 4819 -372 7289 -1228 4930 -3699 3455 2560 -1451 2242 -929 4242 -1768 1195 -1398 1293 -1455 1119 737 -1665 827 -3111 -636 -7113 900000 -10678 900000 -4563 900000 -1358 900000 -715 -246 900000 -2478 900000 -3493 900000 -266 900000 1863 7716 3330 -1552 4249 93 900000 -1498 900000 -2517 900000 -1273 6194 2935 96 900000 277 900000 -5723 6374 -2174 4054 -5 2951 2932 988 5808 603 5595 -1502 6264 -2714 5383 3886 5630 4971 3839 5316 1676 7323 -590 5516 -3651 4325 -825 4636 2305 2794 5839 -388 6948 -3340 5602 -1107 2005 -975 1995 2447 62 4367 -6441 3299 -7252 2941 -4221 575 -4341 -293 -31 -1458 4652 -4415 3696 -6419 4440 -7080 1423 -4305 -4696 -1627 -5374 4898 -4584 5818 -4042 791 -6065 -1546 -3010 -1779 856 -4596 7135 -3265 5537 -7240 5754 -5761 -267 -984 166 3999 -991 7406 -588 10301 -1823 6621 -5210 4359 3294 -2108 3526 -1648 7640 -3516 2426 -3097 2942 -3509 2669 1782 -4003 1848 -6788 -1297 SS 20220601T110450.7Z 8187.461698 88 1 49.94 2 76.88 71.87 89.43 53.16 0.00 1 0.00 1 0 17 4.174e-01 1.857e-02 3.929e-01 1.855e-02 5.347141e-01 1.030503e-02 6.825983e-03 -6.000000e+00 2.487411e-01 232.01 -2.00 3.57 -2.00 321.01 0.00e+00 7.565549e-03 4.524439e-03 3.926563e-03 -6.000000e+00 1.154885e-02 282.87 -2.00 20.00 -2.00 320.41 0.00e+00 4.292 0.001 302.00 328.00 3 4.1905e+00 3.3760e-02 5.3233e-02 -6.0000e+00 6.2446e-01 7.1856e-02 4.3368e-02 3.3770e-02 -6.0000e+00 6.7559e-01 -5.9427e-02 3.9991e-02 2.0710e-02 -6.0000e+00 4.0045e-01 1.6616e-02 1.9497e-02 8.5724e-03 -6.0000e+00 1.6880e-01 6.2602e-05 -1.0988e-04 5.8467e-04 1.3541e-04 -6.0000e+00 1.1845e-02 7.5623e-05 1.1454e-04 12 8 8 10 0 0 99.95 18.42 0.28 0.00008 -0.00075 24 5 1 5 0 2080.410 23.83 15.00 18.42 31.02 26.0 999.96 -23447 -137011 900000 -132553 170727 900000 -67416 4610 -113761 -49356 -125045 900000 -62522 900000 49190 16553 71290 -24416 900000 -39410 168860 -15119 183126 -55470 83708 -28833 -28316 35513 -30878 144199 -20901 47522 -29515 67529 -10959 -5982 -4054 11186 4042 -2516 19020 -263 19370 -21989 30720 -14343 9576 -8565 8265 4779 2997 10956 -435 6766 -3360 7679 -4678 60337 4297 1242 9 1967 10122 -2461 7684 -2601 12459 -7062 5995 -104 384 2685 -1609 3241 -3855 4397 -9059 4274 -4631 -546 -3724 294 -2275 -3573 -378 -2492 3104 -198 3262 -2194 1182 -1432 -1006 598 -2345 2493 -3167 2807 -177 1985 -1311 -1846 -1555 -801 -1103 -3373 5 -1551 2722 289 1427 393 521 137 -226 735 -1595 2355 -1005 1244 -521 1050 -507 1382 -409 -612 101 -282 1860 -869 605 -1310 248 -1002 16 -738 -93 586 -32 1210 -439 708 -1058 -424 -2691 900000 -2710 3086 900000 -1218 83 -2198 -892 -2947 900000 -1130 900000 889 299 1289 -697 900000 -1475 3052 -472 3310 -2664 1513 -1192 -1191 828 -1312 2606 -977 1386 -1991 2019 -661 -339 -240 664 305 -238 1641 -29 1892 -3320 2886 -2124 1157 -1257 1068 668 464 1725 -83 1300 -754 1594 -1123 7833 936 277 2 491 2604 -799 2377 -880 3515 -2425 1940 -41 166 1194 -752 1386 -1651 1572 -3418 1385 -1762 -231 -1886 163 -1412 -2395 -261 -1888 2344 -161 2578 -1789 878 -1014 -670 389 -1703 1953 -3013 2854 -203 2268 -1479 -1916 -1483 -752 -1103 -3691 6 -1864 3368 403 2149 632 839 214 -334 1021 -2257 3318 -1558 1986 -860 1673 -794 2055 -595 -859 135 -386 2704 -1446 1078 -2524 490 -2105 36 -1738 -225 1433 -80 2897 -1023 1547 -2276 SS 20220601T111530.6Z 8187.469104 91 1 49.99 2 75.04 73.57 87.92 54.90 0.00 1 0.00 1 0 17 1.685e-01 8.107e-03 1.392e-01 4.496e-03 4.913141e-01 2.429232e-03 5.799856e-03 -6.000000e+00 9.949555e-02 232.01 -2.00 3.57 -2.00 320.80 0.00e+00 2.057697e-03 9.799943e-04 1.812050e-03 -6.000000e+00 4.322547e-03 282.87 -2.00 20.00 -2.00 320.17 0.00e+00 3.797 0.001 302.00 328.00 3 2.3931e+00 7.7481e-03 4.6631e-02 -6.0000e+00 2.4967e-01 -1.5088e-02 9.8080e-03 2.8628e-02 -6.0000e+00 2.6971e-01 -2.2577e-02 8.9099e-03 1.4701e-02 -6.0000e+00 1.6017e-01 2.7313e-04 4.4034e-03 4.3618e-03 -6.0000e+00 6.7454e-02 6.7084e-04 -4.0854e-04 1.4109e-04 6.2608e-05 -6.0000e+00 4.7542e-03 9.0415e-04 1.7991e-05 11 8 0 10 0 0 82.27 18.43 0.18 0.00090 -0.00217 159 31 1 5 0 314.300 23.93 15.00 18.43 31.66 25.9 1003.98 -85654 24721 -19696 -22001 -51669 -82217 -24873 -79632 -7880 -66711 29825 -65539 10491 -23533 11630 -9425 -15422 5290 -14513 7814 -13171 12822 -20630 8226 -12522 1277 -5860 -10664 -2056 -17939 6711 -9143 13715 -7920 -812 -10741 -4584 -3267 -1084 4885 -2096 3848 -2314 4435 -1947 2977 949 136 2154 -463 3328 -2471 4243 -165 4005 -225 2529 -609 274 -109 301 3188 1048 3824 -12 2826 -274 920 635 1309 1844 359 2187 -1142 743 -2482 3 -3916 -740 -2153 -1779 -1144 -2678 -917 -1859 962 -143 1806 647 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