File name: Pandora108s1_Toronto-West_20220605_L2Fit_fout2c6d20211104p1-8.txt File generation date: 20240820T113010.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v3d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20220605_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20220605 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220605T103326.5Z 8191.439890 74 1 50.26 2 81.96 66.35 116.83 8.93 0.00 1 0.00 1 0 17 6.742e-01 2.935e-02 4.494e-01 2.273e-02 9.582345e-01 1.408652e-02 1.079558e-02 -6.000000e+00 4.090481e-01 232.27 -2.00 3.57 -2.00 322.34 0.00e+00 8.688836e-03 8.243927e-03 1.640910e-03 -6.000000e+00 1.964713e-02 283.29 -2.00 20.00 -2.00 321.89 0.00e+00 6.685 0.006 302.00 328.00 3 1.1185e+00 5.6749e-02 8.5809e-02 -6.0000e+00 1.0330e+00 1.1994e+00 7.3539e-02 5.5922e-02 -6.0000e+00 1.1221e+00 -1.5795e+00 5.9046e-02 2.8569e-02 -6.0000e+00 6.5900e-01 6.2930e-01 2.7733e-02 1.1033e-02 -6.0000e+00 2.7605e-01 7.7634e-05 -2.0690e-03 6.4949e-04 1.7870e-04 -6.0000e+00 2.0450e-02 1.0048e-02 -4.8376e-05 12 8 8 10 0 0 41.89 17.83 0.33 0.01005 -0.00550 93 18 1 5 0 540.310 23.22 15.00 17.83 15.67 25.3 968.79 82300 900000 -10057 900000 -127866 900000 -153802 900000 -75242 900000 -128010 145219 129519 -76630 900000 -80612 900000 -51192 900000 -35710 900000 32616 117932 11289 -53877 77341 -72424 900000 -47625 900000 -29110 900000 99963 149025 141912 -14474 224921 -31877 900000 -7081 251068 7039 108135 31862 61621 164203 13953 111695 8753 330974 23839 119078 37426 62349 47280 26342 78228 900000 115001 -10845 100325 -4987 64403 22931 34620 20328 34394 22693 4048 35282 6547 44126 5818 27230 -3097 1408 5310 -12251 15078 -4588 14485 -6405 11806 -5942 9749 1620 3018 2772 -2021 7176 -8956 8174 -8995 -1025 -9132 619 -4169 -2250 -1008 -3695 59 -6265 1810 -8132 -1506 -6110 -1727 -2517 -3016 593 -1855 764 -2316 1244 -2045 3373 -1073 492 240 685 1169 460 4117 149 3417 182 3491 1309 1138 -287 -116 2414 -945 1092 -798 460 -996 457 57 100 -177 -1168 -964 1819 900000 -222 900000 -5328 900000 -6835 900000 -1663 900000 -4386 3210 2863 -2760 900000 -4348 900000 -2472 900000 -1518 900000 721 2607 266 -2323 1710 -3524 900000 -1692 900000 -1121 900000 2210 3294 3137 -624 4972 -1825 900000 -425 5550 424 2599 1565 2269 3630 809 2711 579 7317 1615 3695 2680 3787 3462 2376 4415 900000 4277 -1225 4073 -575 4416 2626 3832 2617 3901 2996 693 5104 1357 6669 1235 4389 -599 232 791 -2201 2384 -1047 3286 -2048 3534 -2254 3358 638 1218 1155 -876 2766 -3786 2778 -3548 -394 -4353 318 -2673 -1652 -822 -3187 47 -4786 1143 -5453 -990 -4478 -1280 -2046 -2750 605 -2222 987 -3223 1672 -2772 4211 -1414 665 345 1010 1692 638 5242 191 4118 221 4007 1617 1612 -484 -222 4947 -2145 2617 -2098 1260 -2840 1295 161 272 -448 -2744 -2143 SS 20220605T105112.3Z 8191.452226 80 1 50.03 2 78.99 69.22 116.28 13.38 0.00 1 0.00 1 0 17 6.185e-01 1.180e-02 3.180e-01 5.450e-03 7.658017e-01 3.132817e-03 8.794202e-03 -6.000000e+00 3.682590e-01 232.27 -2.00 3.57 -2.00 321.85 0.00e+00 7.499571e-03 1.765105e-03 2.539507e-03 -6.000000e+00 1.623838e-02 283.29 -2.00 20.00 -2.00 321.34 0.00e+00 5.046 0.002 302.00 328.00 3 7.9419e-01 1.1939e-02 6.6368e-02 -6.0000e+00 9.2391e-01 2.1350e-01 1.7340e-02 4.4753e-02 -6.0000e+00 9.9884e-01 -2.8457e-01 1.7868e-02 2.5773e-02 -6.0000e+00 5.9075e-01 1.0727e-01 8.1551e-03 1.0763e-02 -6.0000e+00 2.4743e-01 7.0844e-04 -9.4390e-04 1.5836e-04 1.6194e-04 -6.0000e+00 1.7786e-02 9.6914e-03 -8.4176e-05 12 8 8 10 0 0 -10.64 17.83 0.12 0.00969 0.00260 359 70 1 5 0 139.330 23.22 15.00 17.83 17.08 25.3 978.15 -178046 -242681 -97611 -273995 900000 -254831 900000 -183964 -67734 -139487 -84684 -76430 -162762 184322 -139779 219097 -115952 68613 -74315 64168 -39663 -35540 -23182 -64176 47426 -84703 92208 -56146 68433 -43962 7987 -8760 5164 17149 -20977 41859 -24880 31705 -9944 30406 -2095 22203 15893 7198 17388 -1780 29790 -5713 30576 630 23121 10953 15631 12668 8545 15067 2285 12681 -3374 10202 396 11249 5436 10161 9198 3263 8642 1208 8104 1470 5721 1944 4423 -413 -544 -197 -3001 -1027 -3468 1847 -2013 1382 -3167 21 -1738 -685 -351 -853 950 -937 787 -2283 -186 -1919 -698 -1025 -201 590 -396 32 -1380 -35 -1940 176 -2414 -1218 -1401 -1133 -35 -101 755 -296 913 -506 510 -276 843 -174 160 14 -121 1033 203 1177 -216 948 -210 1398 205 56 306 -148 301 -441 188 -591 241 -47 130 -231 76 21 -467 -1158 -3351 -519 -5412 900000 -3888 900000 -1713 -360 -1022 -450 -406 -2284 979 -2647 1164 -2478 365 -1337 354 -569 -495 -296 -1257 365 -2206 505 -1151 471 -903 125 -192 117 377 -638 724 -832 744 -402 1013 -104 966 769 393 885 -111 1452 -403 1646 48 1599 945 1429 1291 967 1665 293 1477 -445 1170 51 1446 837 1708 1671 635 1594 249 1715 379 1572 581 1287 -119 -144 -47 -692 -236 -913 550 -735 562 -1491 10 -919 -383 -205 -519 567 -555 431 -1211 -94 -1016 -411 -704 -160 538 -404 33 -1378 -32 -1601 140 -2075 -1104 -1337 -1164 -39 -127 1057 -452 1407 -774 743 -389 1183 -255 249 23 -194 1581 301 1670 -299 1260 -274 1869 311 97 588 -309 660 -1036 469 -1570 653 -130 358 -614 191 49 -1057 SS 20220605T105723.6Z 8191.456524 83 1 50.07 2 77.94 70.21 116.03 14.92 0.00 1 0.00 1 0 17 5.047e-01 6.996e-03 1.836e-01 3.660e-03 7.134509e-01 2.069840e-03 8.119142e-03 -6.000000e+00 2.980118e-01 232.27 -2.00 3.57 -2.00 321.61 0.00e+00 4.215145e-03 1.092020e-03 1.780982e-03 -6.000000e+00 1.297036e-02 283.29 -2.00 20.00 -2.00 321.08 0.00e+00 4.641 0.002 302.00 328.00 3 6.6241e-01 7.5156e-03 6.1056e-02 -6.0000e+00 7.4813e-01 1.0875e-01 1.0812e-02 4.1168e-02 -6.0000e+00 8.0841e-01 -1.3169e-01 1.1214e-02 2.2970e-02 -6.0000e+00 4.8007e-01 4.1538e-02 5.1926e-03 8.5004e-03 -6.0000e+00 2.0178e-01 1.2682e-03 -7.1678e-04 1.0729e-04 1.1566e-04 -6.0000e+00 1.4254e-02 9.3478e-03 -6.6679e-05 11 8 0 10 0 0 -2.59 17.84 0.16 0.00935 0.00396 500 98 1 5 0 100.110 23.22 15.00 17.84 17.77 25.3 982.86 -164859 -180790 -142581 -190501 -131003 -214527 -138089 -175286 -143169 -146508 -131420 -76639 -130046 -30017 -90117 -53234 -76926 -26479 -65013 -26674 -32603 -38135 -4293 -42897 -21221 -41891 488 -43461 -9128 -35829 -2933 -14802 -4596 4203 -13261 -158 -19528 8507 -8459 9495 -1758 2747 3803 5085 6372 3032 5813 -40 4515 1056 9374 5838 7991 5821 5370 5599 2980 3641 -1279 3793 741 5517 3411 5025 4081 2383 3041 780 3624 305 2819 283 854 -1005 -424 -672 -1743 -1472 -2387 -357 -1632 -662 -2033 -949 -1369 -425 -226 502 259 254 577 -669 -269 -918 -68 -332 774 712 90 -140 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