File name: Pandora108s1_Toronto-West_20220623_L2Fit_fwvt1c6d20211104p1-8.txt File generation date: 20240820T115220.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v3d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20220623_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20220623 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1653 1802 Nominal wavelengths inside fitting window [nm]: 492.1141 492.2350 492.3559 492.4768 492.5976 492.7185 492.8393 492.9601 493.0809 493.2016 493.3224 493.4431 493.5638 493.6845 493.8052 493.9259 494.0466 494.1672 494.2878 494.4084 494.5290 494.6496 494.7701 494.8907 495.0112 495.1317 495.2522 495.3726 495.4931 495.6135 495.7339 495.8543 495.9747 496.0951 496.2154 496.3358 496.4561 496.5764 496.6967 496.8169 496.9372 497.0574 497.1776 497.2978 497.4180 497.5382 497.6583 497.7785 497.8986 498.0187 498.1388 498.2588 498.3789 498.4989 498.6189 498.7389 498.8589 498.9789 499.0988 499.2187 499.3387 499.4585 499.5784 499.6983 499.8181 499.9380 500.0578 500.1776 500.2973 500.4171 500.5368 500.6566 500.7763 500.8960 501.0156 501.1353 501.2549 501.3746 501.4942 501.6138 501.7333 501.8529 501.9724 502.0920 502.2115 502.3310 502.4504 502.5699 502.6893 502.8087 502.9281 503.0475 503.1669 503.2862 503.4056 503.5249 503.6442 503.7635 503.8827 504.0020 504.1212 504.2404 504.3596 504.4788 504.5980 504.7171 504.8363 504.9554 505.0745 505.1935 505.3126 505.4316 505.5507 505.6697 505.7887 505.9076 506.0266 506.1455 506.2645 506.3834 506.5023 506.6211 506.7400 506.8588 506.9776 507.0964 507.2152 507.3340 507.4527 507.5715 507.6902 507.8089 507.9276 508.0462 508.1649 508.2835 508.4021 508.5207 508.6393 508.7578 508.8764 508.9949 509.1134 509.2319 509.3504 509.4688 509.5873 509.7057 509.8241 509.9425 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220623T095625.5Z 8209.414184 140 1 2.43 2 87.88 59.01 53.78 116.24 0.00 1 0.00 1 0 22 5.044e-03 5.006e-03 3.663e-03 3.653e-03 1.886438e+04 2.721622e+02 1.239630e+03 -6.000000e+00 2.834202e+02 285.05 -2.00 20.00 -2.00 505.40 0.00e+00 2.411550e-03 1.017194e-04 1.551428e-04 -6.000000e+00 1.422662e-04 285.05 -2.00 20.00 -2.00 500.81 0.00e+00 1.336630e+00 7.186209e-02 1.147395e-01 -6.000000e+00 1.006183e-01 232.96 -2.00 3.57 -2.00 502.35 0.00e+00 15.681 0.075 489.00 513.00 1 4.4160e+00 5.4931e-03 2.6639e-02 -6.0000e+00 7.7150e-03 -1.5243e-02 1.3824e-03 3.1833e-03 -6.0000e+00 2.0054e-03 2.2263e-03 1.0183e-03 3.2325e-04 1.3318e-04 -6.0000e+00 5.1436e-04 -6.0932e-03 -2.9470e-06 12 9 9 12 1 1 999.00 17.42 0.82 -0.00609 0.00097 1 9 1 4 0 1121.990 22.80 15.00 17.42 20.22 26.3 947.39 -309 -372 -50 297 880 1018 733 1095 758 694 598 326 -286 349 -469 -598 61 123 521 50 242 16 -258 948 278 -115 -419 -591 -527 -690 -1415 -354 -841 416 -454 -382 212 150 56 215 47 324 -209 374 143 666 290 529 -708 -519 -575 -1361 -1032 -462 -530 69 -112 463 469 204 948 646 171 -153 717 -429 321 -159 -568 -282 -172 -733 -289 50 -876 -428 -333 -118 -595 -648 -633 -703 -185 -165 196 -208 201 -339 98 586 393 128 226 571 314 556 65 -7 -591 -771 -683 -1157 -604 212 -28 -655 -50 -494 222 -259 -116 -52 56 947 314 872 439 376 151 649 162 -712 33 -57 565 159 -357 -145 278 -13 -274 -236 137 -172 -586 366 149 439 154 419 153 123 737 479 609 104 -41 -592 95 -572 -288 -338 -47 287 870 980 719 1076 744 673 573 309 -282 339 -460 -567 59 121 522 51 247 16 -266 973 289 -115 -417 -605 -526 -672 -1378 -346 -850 411 -462 -390 214 149 55 212 47 325 -213 385 149 690 300 538 -715 -510 -576 -1350 -1019 -461 -523 70 -116 477 484 211 979 673 180 -160 740 -441 323 -159 -563 -276 -168 -723 -287 50 -889 -427 -326 -113 -569 -618 -605 -678 -179 -161 194 -208 199 -337 97 573 389 128 227 561 300 531 60 -6 -527 -683 -611 -1076 -562 206 -29 -647 -51 -503 225 -255 -115 -53 56 949 318 889 457 397 160 672 165 -718 33 -57 567 161 -364 -148 282 -14 -276 -235 135 -169 -588 371 155 463 159 439 163 132 789 515 651 111 -43 -616 98 -593 SQ 20220623T095919.5Z 8209.416198 144 1 26.02 2 87.43 59.50 53.31 116.89 0.00 1 0.00 1 0 22 3.603e-03 3.541e-03 2.251e-04 2.244e-04 1.803028e+04 1.662991e+01 1.182323e+03 -6.000000e+00 2.024718e+02 285.05 -2.00 20.00 -2.00 505.42 0.00e+00 2.285171e-03 6.235947e-06 1.464445e-04 -6.000000e+00 1.016345e-04 285.05 -2.00 20.00 -2.00 500.85 0.00e+00 1.222029e+00 4.385420e-03 1.142570e-01 -6.000000e+00 7.188548e-02 232.96 -2.00 3.57 -2.00 502.39 0.00e+00 14.531 0.060 489.00 513.00 1 1.8112e+00 3.3534e-04 2.4418e-02 -6.0000e+00 5.5118e-03 -2.2007e-02 8.4139e-05 3.0978e-03 -6.0000e+00 1.4329e-03 3.5814e-02 8.0151e-04 2.0140e-05 1.2467e-04 -6.0000e+00 3.6746e-04 1.0673e-02 -1.1080e-04 12 1 1 12 1 1 84.12 17.42 1.02 0.01067 0.01623 393 149 1 4 0 65.600 22.80 15.00 17.42 20.23 26.3 947.49 -517 -272 84 409 537 831 847 676 678 367 224 14 -169 -284 -221 -162 -45 176 248 160 184 243 176 318 382 195 76 -54 -386 -674 -482 -568 -250 38 42 -107 -35 -135 -266 -204 -95 20 138 331 321 421 251 142 -84 -364 -621 -711 -668 -508 -167 -83 69 79 197 237 266 296 211 233 74 3 -197 -261 -372 -447 -423 -397 -326 -165 -97 -341 -418 -451 -423 -520 -467 -360 -373 -173 -196 -260 -204 -74 -50 123 160 320 418 411 456 303 21 -316 -502 -937 -826 -773 -576 -305 -309 -275 -265 -160 -173 -69 -87 59 277 490 637 722 803 533 330 163 151 102 243 401 304 261 351 237 95 253 -19 -156 -69 -201 -192 77 120 55 292 278 198 245 300 245 202 86 -171 -343 -476 -379 -473 -254 76 382 515 812 840 676 675 362 218 14 -161 -269 -209 -155 -44 175 252 164 190 252 183 333 377 193 75 -56 -389 -664 -471 -562 -254 37 42 -108 -35 -135 -263 -201 -95 20 140 339 332 436 258 145 -84 -355 -592 -708 -663 -483 -164 -84 70 81 203 244 275 308 220 243 76 3 -198 -259 -366 -436 -411 -388 -322 -165 -97 -338 -407 -433 -402 -493 -444 -344 -361 -169 -194 -259 -203 -73 -49 121 158 319 418 404 435 279 19 -291 -456 -847 -754 -686 -537 -298 -313 -282 -271 -162 -175 -71 -90 62 291 514 634 726 820 552 342 167 152 100 252 416 300 260 351 237 95 252 -19 -153 -71 -195 -189 77 123 57 308 298 215 268 330 270 222 94 -184 -365 -501 -401 SQ 20220623T100136.7Z 8209.417786 147 1 19.03 2 87.08 59.88 52.95 117.41 0.00 1 0.00 1 0 22 3.219e-03 3.156e-03 2.101e-04 2.094e-04 1.643361e+04 1.549287e+01 1.074814e+03 -6.000000e+00 1.808973e+02 285.05 -2.00 20.00 -2.00 505.39 0.00e+00 2.045686e-03 5.813948e-06 1.315190e-04 -6.000000e+00 9.080561e-05 285.05 -2.00 20.00 -2.00 500.80 0.00e+00 1.175879e+00 4.096437e-03 1.044265e-01 -6.000000e+00 6.422747e-02 232.96 -2.00 3.57 -2.00 502.33 0.00e+00 13.672 0.050 489.00 513.00 1 1.2265e+00 3.1307e-04 2.2555e-02 -6.0000e+00 4.9246e-03 -1.7287e-02 7.8704e-05 2.8194e-03 -6.0000e+00 1.2803e-03 7.3169e-02 8.8098e-04 1.9003e-05 1.1392e-04 -6.0000e+00 3.2831e-04 7.9197e-03 -9.5544e-05 10 0 0 10 0 0 45.60 17.42 0.95 0.00792 0.01403 581 114 1 4 0 31.960 22.80 15.00 17.42 20.28 26.3 947.83 -475 -315 57 280 444 688 734 598 584 280 159 6 -186 -183 -261 -128 -78 160 210 122 149 237 170 284 379 181 87 -56 -305 -570 -441 -463 -269 83 0 -103 -72 -132 -245 -185 -89 31 159 274 332 354 289 65 -12 -338 -509 -602 -628 -415 -178 -59 20 101 162 247 255 280 161 177 73 -51 -172 -261 -310 -437 -363 -380 -261 -145 -101 -302 -398 -406 -416 -415 -437 -326 -334 -158 -145 -267 -170 -79 0 96 182 268 385 328 351 252 -74 -285 -511 -778 -770 -686 -512 -260 -315 -250 -215 -166 -130 -71 -69 31 302 455 628 676 725 520 281 202 230 175 245 400 242 222 298 186 70 211 20 -184 -60 -223 -135 64 95 22 259 253 159 220 264 222 125 73 -166 -317 -425 -332 -420 -285 54 270 439 693 750 616 599 285 159 6 -183 -178 -254 -125 -78 164 206 120 148 235 170 284 381 183 88 -55 -294 -537 -442 -438 -261 83 0 -106 -73 -133 -246 -185 -90 32 163 285 348 371 301 67 -12 -333 -490 -570 -594 -399 -175 -60 20 105 169 257 267 294 170 186 76 -53 -174 -262 -307 -429 -355 -374 -260 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1.786177e-02 -6.000000e+00 3.507227e-02 232.96 -2.00 3.57 -2.00 501.96 0.00e+00 2.337 0.000 489.00 513.00 1 2.6459e-01 1.5112e-04 3.7212e-03 -6.0000e+00 2.6892e-03 -8.3843e-04 3.9092e-05 4.5236e-04 -6.0000e+00 6.9904e-04 1.0605e+00 4.4536e-04 9.7591e-06 2.4501e-05 -6.0000e+00 1.7929e-04 1.1433e-02 -1.1113e-04 10 0 0 10 0 0 87.41 17.44 0.89 0.01143 0.01452 2011 395 1 4 0 2.600 22.80 15.00 17.44 25.33 26.0 979.09 -287 -249 -59 98 161 413 413 306 353 183 103 -31 -129 -124 -157 -126 -83 50 88 23 131 189 110 201 229 75 5 -12 -157 -291 -155 -256 -159 57 -60 -139 -16 -51 -141 -88 -12 33 112 202 218 252 209 87 34 -156 -223 -243 -329 -229 -113 -111 -79 3 71 133 142 126 31 78 6 -19 -101 -136 -136 -197 -162 -188 -179 -103 -69 -204 -232 -160 -153 -245 -246 -209 -206 -79 -80 -155 -66 6 -11 47 60 121 152 124 158 107 -80 -161 -143 -328 -307 -319 -262 -159 -302 -231 -107 -54 -38 30 -16 51 198 282 368 350 356 290 206 190 200 116 149 190 23 106 249 131 67 164 15 -55 15 -39 -26 95 22 -77 88 158 122 198 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20220623T194426.1Z 8209.822524 413 6 7.40 2 35.77 247.27 87.49 282.46 0.00 1 0.00 1 0 15 1.584e-03 1.588e-03 2.023e-04 2.017e-04 1.046877e+03 1.179317e+01 7.108729e+01 -6.000000e+00 8.902992e+01 285.09 -2.00 20.00 -2.00 505.32 0.00e+00 4.489283e-04 5.591773e-06 2.748901e-05 -6.000000e+00 4.468527e-05 285.09 -2.00 20.00 -2.00 500.54 0.00e+00 -5.526985e-03 3.986245e-03 9.781917e-03 -6.000000e+00 3.159609e-02 232.96 -2.00 3.57 -2.00 502.14 0.00e+00 1.232 0.000 489.00 513.00 1 -2.7734e-01 3.0520e-04 2.0200e-03 -6.0000e+00 2.4228e-03 -1.2855e-03 7.8811e-05 2.2538e-04 -6.0000e+00 6.2964e-04 2.1636e+00 5.0307e-04 2.0174e-05 1.2870e-05 -6.0000e+00 1.6153e-04 8.2179e-03 -7.9940e-05 10 0 0 10 0 0 -8.19 17.67 0.94 0.00822 0.01171 530 104 2 4 0 13.490 23.11 15.00 17.67 35.37 27.0 1036.70 -319 -251 -77 51 122 369 349 278 309 157 106 -49 -122 -118 -143 -124 -62 47 101 27 100 164 114 196 214 64 4 17 -113 -234 -109 -226 -144 66 -77 -117 -6 -42 -82 -53 50 64 132 193 208 245 204 116 27 -95 -190 -203 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119 181 187 69 -46 -94 -172 -167 -226 -209 SQ 20220623T194441.2Z 8209.822700 413 8 7.48 2 35.81 247.34 87.53 282.50 0.00 1 0.00 1 0 15 1.614e-03 1.617e-03 2.022e-04 2.017e-04 1.047695e+03 1.179158e+01 7.141599e+01 -6.000000e+00 9.069437e+01 285.09 -2.00 20.00 -2.00 505.32 0.00e+00 4.489394e-04 5.590784e-06 2.760396e-05 -6.000000e+00 4.552050e-05 285.09 -2.00 20.00 -2.00 500.54 0.00e+00 -3.674853e-03 3.985564e-03 9.750312e-03 -6.000000e+00 3.218622e-02 232.96 -2.00 3.57 -2.00 502.14 0.00e+00 1.232 0.000 489.00 513.00 1 -2.7775e-01 3.0515e-04 2.0207e-03 -6.0000e+00 2.4680e-03 -1.2888e-03 7.8797e-05 2.2506e-04 -6.0000e+00 6.4138e-04 2.1640e+00 4.7356e-04 2.0170e-05 1.2940e-05 -6.0000e+00 1.6455e-04 8.2650e-03 -7.9089e-05 10 0 0 10 0 0 -4.44 17.67 0.94 0.00826 0.01155 530 104 2 4 0 13.490 23.11 15.00 17.67 35.37 27.1 1036.70 -271 -263 -83 48 119 365 366 280 313 182 88 -47 -109 -128 -136 -103 -60 53 87 25 100 183 107 206 243 68 5 0 -102 -274 -105 -243 -136 67 -58 -114 -17 -54 -118 -59 43 49 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75 6 -94 95 134 129 176 188 44 -72 -90 -181 -190 -213 -215 SQ 20220623T194909.8Z 8209.825808 416 1 7.39 2 36.56 248.53 88.29 283.26 0.00 1 0.00 1 0 15 1.597e-03 1.597e-03 2.021e-04 2.015e-04 1.052441e+03 1.175042e+01 7.162605e+01 -6.000000e+00 8.973057e+01 285.09 -2.00 20.00 -2.00 505.31 0.00e+00 4.470788e-04 5.585437e-06 2.739891e-05 -6.000000e+00 4.503670e-05 285.09 -2.00 20.00 -2.00 500.54 0.00e+00 -1.417502e-02 3.981231e-03 9.764789e-03 -6.000000e+00 3.184399e-02 232.96 -2.00 3.57 -2.00 502.15 0.00e+00 1.244 0.000 489.00 513.00 1 -2.7809e-01 3.0480e-04 2.0345e-03 -6.0000e+00 2.4418e-03 -1.0783e-03 7.8907e-05 2.2541e-04 -6.0000e+00 6.3456e-04 2.1628e+00 4.5496e-04 2.0145e-05 1.2861e-05 -6.0000e+00 1.6280e-04 8.0949e-03 -7.7746e-05 10 0 0 10 0 0 2.77 17.67 0.94 0.00809 0.01125 528 104 2 4 0 13.550 23.11 15.00 17.67 35.37 27.0 1036.49 -262 -250 -65 52 124 387 382 266 324 139 122 -29 -125 -111 -132 -113 -77 39 106 27 110 186 89 206 212 60 15 15 -113 -266 -93 -207 -156 69 -53 -160 13 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20220623T210449.6Z 8209.878352 453 5 8.44 2 49.85 265.00 100.54 296.47 0.00 1 0.00 1 0 15 1.662e-03 1.660e-03 1.971e-04 1.966e-04 1.460153e+03 1.160702e+01 1.006536e+02 -6.000000e+00 9.340471e+01 285.09 -2.00 20.00 -2.00 505.30 0.00e+00 4.766661e-04 5.440180e-06 2.944378e-05 -6.000000e+00 4.688004e-05 285.09 -2.00 20.00 -2.00 500.55 0.00e+00 2.735173e-02 3.883908e-03 1.257307e-02 -6.000000e+00 3.314558e-02 232.96 -2.00 3.57 -2.00 502.15 0.00e+00 1.548 0.000 489.00 513.00 1 -2.4396e-01 2.9713e-04 2.5159e-03 -6.0000e+00 2.5416e-03 -1.5271e-03 7.7205e-05 2.9774e-04 -6.0000e+00 6.6047e-04 1.9944e+00 4.8970e-04 1.9616e-05 1.5588e-05 -6.0000e+00 1.6946e-04 7.8371e-03 -7.3008e-05 10 0 0 10 0 0 -0.74 17.71 0.93 0.00784 0.01123 552 108 2 4 0 14.770 23.11 15.00 17.71 34.66 27.0 1030.49 -311 -246 -71 87 132 361 369 281 323 151 65 -11 -109 -127 -130 -88 -60 58 116 11 123 193 83 185 217 61 27 18 -128 -294 -139 -224 -160 79 -51 -146 11 -24 -93 -87 24 48 138 243 226 250 209 109 74 -138 -209 -261 -312 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20220623T215842.5Z 8209.915770 480 1 8.47 2 59.58 274.37 108.41 306.85 0.00 1 0.00 1 0 15 1.687e-03 1.678e-03 2.029e-04 2.024e-04 1.754021e+03 1.195662e+01 1.233802e+02 -6.000000e+00 9.483922e+01 285.10 -2.00 20.00 -2.00 505.24 0.00e+00 5.564673e-04 5.555341e-06 3.388796e-05 -6.000000e+00 4.760000e-05 285.10 -2.00 20.00 -2.00 500.49 0.00e+00 7.140009e-02 3.994427e-03 1.394925e-02 -6.000000e+00 3.365484e-02 232.96 -2.00 3.57 -2.00 502.06 0.00e+00 1.967 0.000 489.00 513.00 1 -2.3509e-01 3.0522e-04 3.1131e-03 -6.0000e+00 2.5806e-03 -1.8191e-03 7.9931e-05 3.4464e-04 -6.0000e+00 6.7063e-04 1.8547e+00 5.3143e-04 2.0132e-05 1.9322e-05 -6.0000e+00 1.7206e-04 8.1676e-03 -7.6413e-05 10 0 0 10 0 0 -4.58 17.72 0.91 0.00817 0.01185 503 99 2 4 0 16.250 23.11 15.01 17.72 33.85 26.9 1025.22 -269 -243 -61 72 154 390 396 291 337 173 103 -25 -107 -94 -123 -130 -57 93 106 9 91 156 95 169 234 79 18 22 -140 -247 -138 -225 -157 59 -92 -143 -3 -73 -109 -74 0 44 111 213 211 244 215 96 31 -138 -247 -296 -358 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81 23 -70 91 147 106 164 190 39 -28 -114 -169 -159 -222 -166 SQ 20220623T215908.6Z 8209.916071 480 4 8.52 2 59.66 274.44 108.47 306.94 0.00 1 0.00 1 0 15 1.703e-03 1.694e-03 2.032e-04 2.027e-04 1.753472e+03 1.197095e+01 1.229066e+02 -6.000000e+00 9.572663e+01 285.10 -2.00 20.00 -2.00 505.24 0.00e+00 5.771878e-04 5.561734e-06 3.512272e-05 -6.000000e+00 4.804533e-05 285.10 -2.00 20.00 -2.00 500.49 0.00e+00 7.711028e-02 3.999151e-03 1.409956e-02 -6.000000e+00 3.396953e-02 232.96 -2.00 3.57 -2.00 502.06 0.00e+00 1.971 0.000 489.00 513.00 1 -2.3480e-01 3.0558e-04 3.1305e-03 -6.0000e+00 2.6048e-03 -1.9079e-03 8.0022e-05 3.4600e-04 -6.0000e+00 6.7689e-04 1.8516e+00 5.1894e-04 2.0156e-05 1.9544e-05 -6.0000e+00 1.7367e-04 8.0864e-03 -7.5497e-05 10 0 0 10 0 0 -3.96 17.72 0.93 0.00809 0.01169 503 99 2 4 0 16.250 23.11 15.01 17.72 33.85 26.9 1025.22 -280 -270 -67 73 175 385 421 273 359 153 100 -25 -98 -71 -152 -76 -77 106 72 26 97 170 91 163 222 61 17 17 -133 -288 -120 -240 -146 57 -88 -120 -46 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2 74.07 287.39 118.09 325.08 0.00 1 0.00 1 0 22 1.921e-03 1.914e-03 1.783e-04 1.777e-04 2.811380e+03 1.091147e+01 1.991835e+02 -6.000000e+00 1.079914e+02 285.10 -2.00 20.00 -2.00 505.26 0.00e+00 7.722782e-04 4.908854e-06 4.678803e-05 -6.000000e+00 5.419984e-05 285.10 -2.00 20.00 -2.00 500.45 0.00e+00 2.892079e-01 3.539578e-03 2.141824e-02 -6.000000e+00 3.831724e-02 232.96 -2.00 3.57 -2.00 502.03 0.00e+00 3.581 0.001 489.00 513.00 1 -1.6375e-01 2.7185e-04 5.4719e-03 -6.0000e+00 2.9382e-03 -2.9633e-03 6.9993e-05 5.6491e-04 -6.0000e+00 7.6345e-04 1.3480e+00 5.0766e-04 1.7682e-05 2.7287e-05 -6.0000e+00 1.9591e-04 7.2140e-03 -6.3777e-05 10 0 0 10 0 0 -14.04 17.76 0.83 0.00721 0.01074 602 118 2 4 0 23.430 23.11 15.00 17.76 32.37 27.0 1014.53 -294 -311 -40 111 205 424 397 335 313 226 48 -4 -154 -97 -137 -119 -33 72 155 -12 148 138 137 188 258 72 19 24 -191 -268 -212 -249 -219 110 -78 -119 -34 -56 -109 -121 47 19 154 196 244 281 258 101 52 -169 -286 -287 -445 -242 -190 -90 -71 44 80 135 165 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