File name: Pandora108s1_Toronto-West_20220722_L2Fit_fwvt1c6d20211104p1-8.txt File generation date: 20240820T120631.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v3d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20220722_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20220722 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1653 1802 Nominal wavelengths inside fitting window [nm]: 492.1141 492.2350 492.3559 492.4768 492.5976 492.7185 492.8393 492.9601 493.0809 493.2016 493.3224 493.4431 493.5638 493.6845 493.8052 493.9259 494.0466 494.1672 494.2878 494.4084 494.5290 494.6496 494.7701 494.8907 495.0112 495.1317 495.2522 495.3726 495.4931 495.6135 495.7339 495.8543 495.9747 496.0951 496.2154 496.3358 496.4561 496.5764 496.6967 496.8169 496.9372 497.0574 497.1776 497.2978 497.4180 497.5382 497.6583 497.7785 497.8986 498.0187 498.1388 498.2588 498.3789 498.4989 498.6189 498.7389 498.8589 498.9789 499.0988 499.2187 499.3387 499.4585 499.5784 499.6983 499.8181 499.9380 500.0578 500.1776 500.2973 500.4171 500.5368 500.6566 500.7763 500.8960 501.0156 501.1353 501.2549 501.3746 501.4942 501.6138 501.7333 501.8529 501.9724 502.0920 502.2115 502.3310 502.4504 502.5699 502.6893 502.8087 502.9281 503.0475 503.1669 503.2862 503.4056 503.5249 503.6442 503.7635 503.8827 504.0020 504.1212 504.2404 504.3596 504.4788 504.5980 504.7171 504.8363 504.9554 505.0745 505.1935 505.3126 505.4316 505.5507 505.6697 505.7887 505.9076 506.0266 506.1455 506.2645 506.3834 506.5023 506.6211 506.7400 506.8588 506.9776 507.0964 507.2152 507.3340 507.4527 507.5715 507.6902 507.8089 507.9276 508.0462 508.1649 508.2835 508.4021 508.5207 508.6393 508.7578 508.8764 508.9949 509.1134 509.2319 509.3504 509.4688 509.5873 509.7057 509.8241 509.9425 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220722T103040.6Z 8238.437970 200 1 50.00 2 85.38 66.26 36.50 126.16 0.00 1 0.00 1 0 22 3.439e-03 3.395e-03 6.108e-04 6.086e-04 1.315112e+04 4.362705e+01 8.601032e+02 -6.000000e+00 1.948362e+02 287.24 -2.00 20.00 -2.00 505.39 0.00e+00 2.309491e-03 1.702798e-05 1.404350e-04 -6.000000e+00 9.753653e-05 287.24 -2.00 20.00 -2.00 500.88 0.00e+00 8.925020e-01 1.184490e-02 8.787686e-02 -6.000000e+00 6.849875e-02 232.83 -2.00 3.57 -2.00 502.40 0.00e+00 10.371 0.022 489.00 513.00 1 4.6361e+00 9.0600e-04 1.7018e-02 -6.0000e+00 5.2567e-03 -4.1228e-02 2.2892e-04 2.2598e-03 -6.0000e+00 1.3654e-03 3.9281e-03 8.0734e-04 5.7068e-05 1.0256e-04 -6.0000e+00 3.5074e-04 1.3384e-02 -1.2100e-04 10 0 0 10 0 0 80.28 17.56 1.12 0.01338 0.01898 111 22 1 4 0 450.430 22.90 15.00 17.56 25.82 26.6 953.09 -549 -383 85 345 327 798 663 658 572 326 188 9 -201 -326 -227 -264 10 26 273 43 234 175 257 332 315 290 6 40 -318 -421 -495 -383 -288 69 85 -155 37 -207 -191 -223 25 22 207 313 306 414 230 265 -190 -225 -607 -489 -674 -400 -224 -103 -38 -29 270 125 362 224 304 247 127 17 -197 -236 -315 -389 -464 -360 -388 -168 -181 -288 -450 -479 -346 -543 -386 -461 -265 -284 -173 -350 -261 -143 -13 157 66 341 283 448 279 204 -113 -356 -500 -852 -745 -754 -361 -270 -199 -382 -191 -353 -185 -136 -44 235 257 657 603 749 668 588 424 353 335 183 340 316 350 158 325 164 102 170 -1 -139 -151 -166 -306 104 -55 82 163 266 188 211 283 262 209 -118 -90 -388 -445 -411 -482 -345 79 330 321 797 673 671 581 328 187 9 -195 -315 -219 -257 10 27 283 42 228 171 252 328 312 288 6 38 -302 -420 -491 -356 -276 68 86 -157 37 -206 -188 -220 25 22 210 321 316 428 236 268 -190 -220 -578 -457 -630 -380 -219 -104 -39 -30 278 128 374 233 317 257 131 18 -198 -235 -310 -379 -452 -352 -384 -168 -182 -286 -440 -461 -330 -519 -370 -445 -258 -280 -172 -352 -262 -143 -13 156 66 346 289 451 275 194 -105 -322 -445 -754 -664 -693 -345 -271 -205 -397 -198 -362 -190 -140 -47 249 275 701 647 757 685 608 437 359 334 193 357 334 347 158 324 164 102 169 -1 -136 -146 -160 -299 103 -56 84 171 282 202 229 307 285 227 -127 -95 -406 -462 -428 SQ 20220722T104409.8Z 8238.447336 203 1 7.47 2 83.13 68.50 34.59 130.47 0.00 1 0.00 1 0 22 2.683e-03 2.667e-03 2.060e-04 2.054e-04 9.716695e+03 1.432451e+01 6.420443e+02 -6.000000e+00 1.519976e+02 287.24 -2.00 20.00 -2.00 505.40 0.00e+00 1.741056e-03 5.748605e-06 1.077681e-04 -6.000000e+00 7.608724e-05 287.24 -2.00 20.00 -2.00 500.76 0.00e+00 6.970645e-01 4.041965e-03 6.732237e-02 -6.000000e+00 5.342538e-02 232.83 -2.00 3.57 -2.00 502.33 0.00e+00 7.640 0.009 489.00 513.00 1 1.1787e+00 3.0899e-04 1.2500e-02 -6.0000e+00 4.1002e-03 -3.0590e-02 7.8751e-05 1.6933e-03 -6.0000e+00 1.0647e-03 1.8809e-01 6.6715e-04 1.9736e-05 7.4801e-05 -6.0000e+00 2.7359e-04 1.0920e-02 -9.1105e-05 10 0 0 10 0 0 -3.40 17.54 0.85 0.01092 0.01555 539 106 1 4 0 13.330 22.90 15.00 17.54 26.23 26.5 955.80 -361 -280 23 214 340 573 609 527 527 273 139 -19 -169 -168 -225 -136 -72 103 174 53 140 234 138 271 299 154 67 12 -220 -423 -327 -364 -210 72 -50 -100 -23 -99 -162 -123 -13 20 132 262 260 325 219 71 -6 -248 -369 -431 -521 -315 -125 -108 -32 32 146 210 205 223 123 116 66 -35 -131 -193 -236 -322 -283 -287 -297 -167 -127 -327 -326 -338 -361 -426 -377 -332 -307 -161 -156 -255 -171 -104 -66 16 48 172 238 174 227 138 -97 -254 -399 -592 -582 -540 -405 -181 -299 -282 -201 -162 -131 -59 -34 105 291 442 598 600 599 457 325 274 287 187 240 289 116 142 272 168 130 213 -8 -148 -71 -178 -167 49 35 -24 172 185 173 215 226 140 65 -14 -169 -236 -326 -313 -322 -256 22 208 338 582 627 546 543 279 139 -19 -166 -164 -219 -134 -72 106 182 56 148 231 137 270 300 154 67 12 -226 -423 -325 -366 -217 71 -51 -102 -23 -99 -160 -121 -13 20 133 268 268 335 224 72 -6 -240 -348 -428 -517 -296 -121 -107 -32 33 148 214 210 229 127 119 68 -35 -130 -189 -229 -309 -270 -276 -289 -164 -126 -321 -313 -320 -339 -400 -356 -315 -295 -156 -153 -252 -169 -102 -65 16 48 173 241 175 223 132 -90 -230 -356 -523 -518 -494 -387 -180 -305 -288 -204 -162 -131 -59 -35 109 304 464 630 638 643 463 328 291 299 193 246 297 120 148 283 175 135 221 -9 -150 -72 -178 -168 51 34 -24 174 190 179 224 236 147 68 -15 -172 -236 -324 -311 SQ 20220722T104417.5Z 8238.447425 203 2 7.42 2 83.11 68.52 34.57 130.51 0.00 1 0.00 1 0 22 2.662e-03 2.641e-03 2.047e-04 2.041e-04 9.680883e+03 1.419835e+01 6.398218e+02 -6.000000e+00 1.508470e+02 287.24 -2.00 20.00 -2.00 505.40 0.00e+00 1.714758e-03 5.717240e-06 1.064883e-04 -6.000000e+00 7.551120e-05 287.24 -2.00 20.00 -2.00 500.78 0.00e+00 6.944974e-01 4.012157e-03 6.692513e-02 -6.000000e+00 5.302045e-02 232.83 -2.00 3.57 -2.00 502.34 0.00e+00 7.621 0.008 489.00 513.00 1 1.1726e+00 3.0670e-04 1.2456e-02 -6.0000e+00 4.0691e-03 -3.0487e-02 7.8144e-05 1.6852e-03 -6.0000e+00 1.0566e-03 1.8989e-01 6.3464e-04 1.9618e-05 7.4527e-05 -6.0000e+00 2.7152e-04 1.1730e-02 -9.5427e-05 10 0 0 10 0 0 1.97 17.54 0.85 0.01173 0.01613 539 106 1 4 0 13.330 22.90 15.00 17.54 26.23 26.5 955.80 -378 -272 -10 239 342 583 574 494 517 273 121 -15 -148 -177 -185 -156 -86 80 150 72 171 223 168 254 303 154 55 15 -224 -425 -308 -382 -194 46 -16 -125 -37 -103 -169 -124 -2 38 143 273 290 356 243 96 -7 -259 -387 -420 -491 -335 -155 -107 -43 33 110 167 231 170 103 119 54 -52 -127 -199 -225 -337 -310 -299 -231 -158 -105 -270 -315 -336 -334 -383 -368 -347 -307 -167 -177 -253 -192 -95 -81 40 69 171 197 190 227 141 -110 -246 -379 -614 -558 -537 -397 -191 -287 -257 -209 -154 -136 -40 -39 100 279 456 572 580 602 485 303 274 308 181 230 323 141 133 238 167 122 244 3 -132 -78 -199 -169 55 25 -12 191 213 144 195 240 139 80 -33 -176 -277 -333 -306 -338 -249 -10 233 342 594 592 513 533 278 122 -15 -146 -173 -181 -154 -86 82 157 71 169 221 167 254 304 155 55 15 -230 -426 -306 -384 -188 46 -16 -127 -37 -103 -168 -123 -2 38 145 280 299 368 249 97 -7 -251 -366 -418 -456 -316 -150 -107 -44 34 112 170 237 175 107 122 55 -52 -126 -195 -218 -324 -297 -289 -225 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20220722T232027.4Z 8238.972540 581 7 5.67 2 75.51 284.15 113.48 336.19 0.00 1 0.00 1 0 15 1.929e-03 1.923e-03 9.903e-05 9.877e-05 5.393583e+03 6.504249e+00 3.645845e+02 -6.000000e+00 1.092979e+02 287.25 -2.00 20.00 -2.00 505.34 0.00e+00 9.766102e-04 2.756615e-06 6.220138e-05 -6.000000e+00 5.470982e-05 287.25 -2.00 20.00 -2.00 500.59 0.00e+00 3.254598e-01 1.953610e-03 3.907589e-02 -6.000000e+00 3.840199e-02 232.81 -2.00 3.57 -2.00 502.18 0.00e+00 3.912 0.001 489.00 513.00 1 6.2765e-02 1.4958e-04 6.5878e-03 -6.0000e+00 2.9474e-03 -6.1415e-03 3.8341e-05 9.5497e-04 -6.0000e+00 7.6505e-04 1.0146e+00 5.5524e-04 9.6948e-06 4.2111e-05 -6.0000e+00 1.9669e-04 5.7603e-03 -3.7361e-05 10 0 0 10 0 0 -5.95 17.82 0.82 0.00576 0.00961 1919 376 1 4 0 2.820 23.22 15.00 17.82 37.16 27.3 1014.99 -266 -222 -9 139 233 481 451 351 384 198 100 -40 -123 -141 -154 -118 -65 58 95 35 116 182 121 223 242 92 -14 -20 -189 -304 -162 -266 -164 54 -72 -132 -5 -49 -121 -78 10 30 111 213 223 283 214 96 30 -158 -238 -251 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190 84 -11 -86 -173 -205 -211 -200 SQ 20220722T232033.5Z 8238.972610 581 8 5.63 2 75.53 284.16 113.49 336.22 0.00 1 0.00 1 0 15 1.943e-03 1.937e-03 9.905e-05 9.880e-05 5.379451e+03 6.504127e+00 3.636074e+02 -6.000000e+00 1.100970e+02 287.25 -2.00 20.00 -2.00 505.34 0.00e+00 9.703812e-04 2.757277e-06 6.193312e-05 -6.000000e+00 5.510984e-05 287.25 -2.00 20.00 -2.00 500.59 0.00e+00 3.290862e-01 1.954022e-03 3.899284e-02 -6.000000e+00 3.868291e-02 232.81 -2.00 3.57 -2.00 502.18 0.00e+00 3.916 0.001 489.00 513.00 1 6.1533e-02 1.4961e-04 6.5881e-03 -6.0000e+00 2.9689e-03 -6.1809e-03 3.8349e-05 9.5316e-04 -6.0000e+00 7.7065e-04 1.0151e+00 5.7303e-04 9.6976e-06 4.1990e-05 -6.0000e+00 1.9813e-04 5.7939e-03 -3.7894e-05 10 0 0 10 0 0 -9.50 17.82 0.82 0.00579 0.00977 1919 376 1 4 0 2.820 23.22 15.00 17.82 37.16 27.2 1014.99 -275 -219 8 157 216 477 460 359 390 188 102 -40 -129 -140 -158 -123 -69 59 97 32 112 189 124 237 244 89 3 -25 -178 -300 -163 -268 -155 42 -85 -126 -9 -54 -113 -91 8 40 111 224 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-27 79 -2 -90 88 160 130 190 178 78 -26 -96 -167 -190 -218 -203 SQ 20220722T232039.5Z 8238.972680 581 9 5.66 2 75.54 284.18 113.49 336.24 0.00 1 0.00 1 0 15 1.932e-03 1.926e-03 9.904e-05 9.878e-05 5.386419e+03 6.504188e+00 3.642367e+02 -6.000000e+00 1.094525e+02 287.25 -2.00 20.00 -2.00 505.34 0.00e+00 9.599924e-04 2.756928e-06 6.148155e-05 -6.000000e+00 5.478721e-05 287.25 -2.00 20.00 -2.00 500.59 0.00e+00 3.289149e-01 1.953762e-03 3.898588e-02 -6.000000e+00 3.845646e-02 232.81 -2.00 3.57 -2.00 502.18 0.00e+00 3.921 0.001 489.00 513.00 1 6.1611e-02 1.4959e-04 6.5910e-03 -6.0000e+00 2.9516e-03 -6.1695e-03 3.8344e-05 9.5384e-04 -6.0000e+00 7.6614e-04 1.0145e+00 5.6747e-04 9.6955e-06 4.1959e-05 -6.0000e+00 1.9697e-04 5.8475e-03 -3.8239e-05 10 0 0 10 0 0 -10.62 17.82 0.82 0.00585 0.00978 1919 376 1 4 0 2.820 23.22 15.00 17.82 37.16 27.2 1014.99 -272 -222 -10 162 222 489 463 358 381 191 101 -34 -126 -145 -158 -117 -62 56 105 27 118 194 131 220 248 90 -17 -27 -192 -304 -160 -270 -157 39 -80 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40 110 256 139 79 170 6 -30 36 -32 -33 73 3 -89 91 147 110 185 187 74 -14 -97 -173 -185 -197 -197 SQ 20220722T232045.6Z 8238.972750 581 10 5.65 2 75.56 284.20 113.50 336.26 0.00 1 0.00 1 0 15 1.916e-03 1.910e-03 9.915e-05 9.890e-05 5.389553e+03 6.511993e+00 3.644883e+02 -6.000000e+00 1.085369e+02 287.25 -2.00 20.00 -2.00 505.34 0.00e+00 9.598413e-04 2.760075e-06 6.141683e-05 -6.000000e+00 5.432887e-05 287.25 -2.00 20.00 -2.00 500.59 0.00e+00 3.279329e-01 1.956000e-03 3.899102e-02 -6.000000e+00 3.813464e-02 232.81 -2.00 3.57 -2.00 502.18 0.00e+00 3.925 0.001 489.00 513.00 1 6.2177e-02 1.4976e-04 6.5964e-03 -6.0000e+00 2.9269e-03 -6.1027e-03 3.8387e-05 9.5424e-04 -6.0000e+00 7.5972e-04 1.0134e+00 5.5787e-04 9.7063e-06 4.1966e-05 -6.0000e+00 1.9532e-04 5.7856e-03 -3.7621e-05 10 0 0 10 0 0 -2.22 17.82 0.81 0.00579 0.00966 1919 376 1 4 0 2.820 23.22 15.00 17.82 37.16 27.2 1014.99 -259 -213 -12 154 233 477 446 361 378 198 96 -45 -138 -146 -159 -101 -67 59 101 28 118 187 106 206 242 103 -5 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433 416 326 225 189 210 122 165 192 43 107 279 149 78 154 -4 -36 37 -25 -14 79 -10 -91 94 145 125 200 194 69 -20 -102 -178 -192 -207 -196 SQ 20220722T232521.9Z 8238.975948 584 1 5.65 2 76.37 284.94 113.80 337.35 0.00 1 0.00 1 0 15 1.966e-03 1.952e-03 1.009e-04 1.007e-04 5.635871e+03 6.620612e+00 3.815494e+02 -6.000000e+00 1.113815e+02 287.25 -2.00 20.00 -2.00 505.32 0.00e+00 1.001443e-03 2.801813e-06 6.339817e-05 -6.000000e+00 5.575265e-05 287.25 -2.00 20.00 -2.00 500.60 0.00e+00 3.492855e-01 1.989683e-03 3.988700e-02 -6.000000e+00 3.913354e-02 232.81 -2.00 3.57 -2.00 502.18 0.00e+00 4.141 0.001 489.00 513.00 1 7.9410e-02 1.5217e-04 6.9056e-03 -6.0000e+00 3.0035e-03 -6.0645e-03 3.9229e-05 9.8230e-04 -6.0000e+00 7.7961e-04 9.6373e-01 5.5358e-04 9.8919e-06 4.5154e-05 -6.0000e+00 2.0044e-04 6.0391e-03 -3.8156e-05 10 0 0 10 0 0 -4.50 17.82 0.81 0.00604 0.00988 1807 354 1 4 0 3.010 23.22 15.00 17.82 37.06 27.2 1013.66 -268 -222 -8 160 242 478 451 361 386 193 97 -51 -126 -163 -169 -124 -69 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20220722T234239.7Z 8238.987959 590 5 5.74 2 79.37 287.74 114.82 341.49 0.00 1 0.00 1 0 15 2.063e-03 2.050e-03 1.123e-04 1.120e-04 6.764409e+03 7.474417e+00 4.579879e+02 -6.000000e+00 1.168971e+02 287.25 -2.00 20.00 -2.00 505.27 0.00e+00 1.137534e-03 3.117592e-06 7.163441e-05 -6.000000e+00 5.851369e-05 287.25 -2.00 20.00 -2.00 500.51 0.00e+00 4.774438e-01 2.231344e-03 4.551823e-02 -6.000000e+00 4.107211e-02 232.81 -2.00 3.57 -2.00 502.07 0.00e+00 5.209 0.003 489.00 513.00 1 1.6131e-01 1.7144e-04 8.4739e-03 -6.0000e+00 3.1523e-03 -7.5761e-03 4.3701e-05 1.1566e-03 -6.0000e+00 8.1825e-04 7.5398e-01 6.2068e-04 1.0902e-05 5.5525e-05 -6.0000e+00 2.1037e-04 5.5292e-03 -3.6319e-05 10 0 0 10 0 0 -6.35 17.83 0.78 0.00553 0.00983 1429 280 1 4 0 3.870 23.22 15.00 17.83 36.57 27.3 1011.12 -277 -234 5 148 250 505 487 373 419 207 104 -45 -146 -152 -183 -134 -76 63 101 46 126 182 118 235 256 115 23 -23 -197 -330 -194 -294 -181 41 -73 -134 1 -69 -159 -98 -10 43 127 211 219 282 204 88 4 -182 -257 -286 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70 191 6 -38 24 -57 -45 86 22 -68 111 156 126 191 205 90 -12 -102 -178 -221 -227 -202 SQ 20220722T234251.8Z 8238.988099 590 7 5.75 2 79.40 287.77 114.83 341.54 0.00 1 0.00 1 0 15 2.054e-03 2.040e-03 1.124e-04 1.121e-04 6.780270e+03 7.482009e+00 4.591235e+02 -6.000000e+00 1.163781e+02 287.25 -2.00 20.00 -2.00 505.28 0.00e+00 1.121857e-03 3.120042e-06 7.068675e-05 -6.000000e+00 5.825366e-05 287.25 -2.00 20.00 -2.00 500.51 0.00e+00 4.740930e-01 2.233158e-03 4.556637e-02 -6.000000e+00 4.088883e-02 232.81 -2.00 3.57 -2.00 502.07 0.00e+00 5.225 0.003 489.00 513.00 1 1.6097e-01 1.7158e-04 8.4909e-03 -6.0000e+00 3.1383e-03 -7.4822e-03 4.3735e-05 1.1590e-03 -6.0000e+00 8.1458e-04 7.5292e-01 6.0491e-04 1.0911e-05 5.5485e-05 -6.0000e+00 2.0943e-04 5.3692e-03 -3.3731e-05 10 0 0 10 0 0 -0.79 17.83 0.78 0.00537 0.00957 1429 280 1 4 0 3.870 23.22 15.00 17.83 36.57 27.2 1011.12 -280 -236 1 151 253 512 468 367 394 197 104 -51 -161 -144 -173 -124 -86 62 109 40 119 177 147 236 264 107 17 -14 -187 -329 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223 254 150 172 219 68 115 269 141 77 190 19 -60 7 -83 -85 79 35 -39 148 151 90 174 190 103 32 -47 -141 -210 -229 -215 SQ 20220723T000018.5Z 8239.000214 595 9 5.80 2 82.38 290.61 115.64 345.80 0.00 1 0.00 1 0 22 2.190e-03 2.191e-03 1.398e-04 1.395e-04 8.784475e+03 9.602003e+00 5.897011e+02 -6.000000e+00 1.240850e+02 287.25 -2.00 20.00 -2.00 505.37 0.00e+00 1.592439e-03 3.898673e-06 9.850437e-05 -6.000000e+00 6.211190e-05 287.25 -2.00 20.00 -2.00 500.62 0.00e+00 6.898412e-01 2.761101e-03 6.047746e-02 -6.000000e+00 4.359878e-02 232.81 -2.00 3.57 -2.00 502.22 0.00e+00 7.000 0.007 489.00 513.00 1 3.0025e-01 2.1139e-04 1.1390e-02 -6.0000e+00 3.3462e-03 -1.0339e-02 5.3731e-05 1.5364e-03 -6.0000e+00 8.6861e-04 4.9728e-01 6.7167e-04 1.3406e-05 6.4039e-05 -6.0000e+00 2.2330e-04 5.5265e-03 -3.8367e-05 10 0 0 10 0 0 -6.31 17.81 0.74 0.00553 0.01019 1015 199 1 4 0 5.550 23.22 15.00 17.81 35.82 27.3 1006.39 -298 -238 21 173 257 514 507 410 427 224 114 -36 -142 -140 -186 -129 -78 71 97 38 121 178 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20220723T002231.0Z 8239.015637 601 4 7.47 2 86.09 294.30 116.35 351.32 0.00 1 0.00 1 0 22 2.776e-03 2.734e-03 2.211e-04 2.204e-04 1.464794e+04 1.628900e+01 9.560754e+02 -6.000000e+00 1.573136e+02 287.25 -2.00 20.00 -2.00 505.42 0.00e+00 2.342346e-03 6.175165e-06 1.443415e-04 -6.000000e+00 7.874491e-05 287.25 -2.00 20.00 -2.00 500.78 0.00e+00 1.087998e+00 4.341107e-03 9.407160e-02 -6.000000e+00 5.527463e-02 232.81 -2.00 3.57 -2.00 502.34 0.00e+00 11.593 0.030 489.00 513.00 1 6.7761e-01 3.3192e-04 1.8995e-02 -6.0000e+00 4.2423e-03 -1.6918e-02 8.3770e-05 2.4593e-03 -6.0000e+00 1.1012e-03 1.7013e-01 7.9885e-04 2.0496e-05 1.0273e-04 -6.0000e+00 2.8311e-04 4.6144e-03 -3.3601e-05 10 0 0 10 0 0 4.76 17.81 0.86 0.00461 0.01016 529 104 1 4 0 13.580 23.22 14.99 17.81 35.13 27.3 1001.68 -384 -187 58 277 378 646 604 510 545 289 182 -16 -117 -228 -191 -167 -57 106 132 108 145 210 122 284 280 150 57 1 -224 -427 -284 -395 -194 50 -45 -151 -48 -142 -213 -171 -62 42 118 280 251 318 207 72 -39 -294 -442 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-120 -153 82 46 22 216 192 172 185 267 192 118 1 -118 -265 -355 -253 SQ 20220723T002238.6Z 8239.015724 601 5 7.35 2 86.11 294.32 116.35 351.35 0.00 1 0.00 1 0 22 2.814e-03 2.774e-03 2.227e-04 2.219e-04 1.472722e+04 1.642431e+01 9.603806e+02 -6.000000e+00 1.594497e+02 287.25 -2.00 20.00 -2.00 505.43 0.00e+00 2.373732e-03 6.220035e-06 1.463139e-04 -6.000000e+00 7.981434e-05 287.25 -2.00 20.00 -2.00 500.79 0.00e+00 1.088759e+00 4.369475e-03 9.527471e-02 -6.000000e+00 5.602667e-02 232.81 -2.00 3.57 -2.00 502.35 0.00e+00 11.632 0.030 489.00 513.00 1 6.8109e-01 3.3409e-04 1.9099e-02 -6.0000e+00 4.3000e-03 -1.7031e-02 8.4343e-05 2.4835e-03 -6.0000e+00 1.1162e-03 1.6851e-01 8.0604e-04 2.0604e-05 1.0069e-04 -6.0000e+00 2.8695e-04 4.1429e-03 -3.2596e-05 10 0 0 10 0 0 -9.23 17.81 0.87 0.00414 0.00973 529 104 1 4 0 13.580 23.22 14.99 17.81 35.13 27.3 1001.68 -372 -189 39 304 354 671 602 536 551 315 190 -26 -123 -211 -160 -174 -16 98 173 83 156 217 136 266 271 178 44 26 -250 -413 -313 -392 -192 33 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