File name: Pandora108s1_Toronto-West_20220809_L2Fit_fout2c6d20211104p1-8.txt File generation date: 20240820T120212.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v3d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20220809_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20220809 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220809T135623.8Z 8256.580831 215 1 6.16 2 51.87 105.85 159.25 317.43 0.00 1 0.00 1 0 17 1.255e-02 7.107e-03 3.219e-03 1.273e-03 2.141628e-01 6.582769e-04 2.595466e-03 -6.000000e+00 7.397255e-03 232.15 -2.00 3.57 -2.00 316.89 0.00e+00 5.495060e-04 8.547843e-05 1.191055e-04 -6.000000e+00 3.285215e-04 287.60 -2.00 20.00 -2.00 316.07 0.00e+00 1.616 0.000 302.00 328.00 3 2.0844e+00 1.7412e-03 1.9645e-02 -6.0000e+00 1.8535e-02 1.2583e-02 1.9477e-03 1.1386e-02 -6.0000e+00 2.0027e-02 6.1260e-03 1.1356e-03 5.5050e-03 -6.0000e+00 1.1925e-02 -7.7756e-03 5.3720e-04 1.5226e-03 -6.0000e+00 5.0246e-03 1.0499e-02 2.2036e-05 3.8065e-05 1.7995e-05 -6.0000e+00 3.5474e-04 2.0936e-02 -8.7918e-05 12 9 1 12 1 1 95.50 17.12 0.23 0.02094 0.02110 54 90 1 5 0 108.770 22.50 15.00 17.12 25.33 26.6 966.83 -1909 266 -2555 -4604 -4537 -3967 -412 -1437 1816 -3950 -1394 -3036 620 -238 1402 607 -342 1614 -503 2154 -773 1465 45 1668 21 365 -748 -2101 146 -966 2119 -88 2186 -1714 -2657 -2318 -1802 143 -239 707 -1147 283 -899 190 -434 -19 -482 -716 -627 -528 1522 218 1900 763 1502 693 995 518 437 798 798 1871 1491 2195 -366 -70 -820 -477 409 562 613 239 604 -362 183 -1244 -648 -1931 -1019 -1263 -1516 -1306 -2239 -1161 -1297 -184 -464 755 308 481 328 36 -153 -283 172 -290 940 664 554 -185 -269 -864 -514 -108 -1508 -592 -935 -186 -117 818 603 667 558 45 37 -411 59 -533 289 -198 370 370 458 511 335 488 -108 1241 -104 420 -224 25 -228 7 80 -425 418 7 286 -450 31 -657 -493 -281 42 -414 -716 -637 -531 -56 -219 297 -707 -243 -547 119 -51 335 158 -93 447 -146 632 -236 439 14 529 7 126 -260 -701 45 -294 655 -29 763 -630 -940 -803 -667 60 -116 389 -689 175 -573 121 -278 -12 -304 -441 -378 -318 937 143 1286 540 1089 512 744 389 324 590 604 1488 1259 1934 -326 -59 -649 -368 327 491 576 233 591 -347 166 -1055 -507 -1450 -780 -1054 -1385 -1284 -2329 -1247 -1463 -217 -571 947 388 593 383 39 -156 -280 176 -318 1104 837 731 -243 -339 -1035 -593 -127 -1892 -773 -1261 -258 -168 1214 924 1031 842 64 50 -533 77 -709 402 -290 552 550 670 726 460 647 -138 1578 -138 585 -324 37 -339 11 127 -700 701 11 491 -765 52 -1071 -792 SS 20220809T142325.2Z 8256.599597 231 1 17.16 2 47.25 111.88 161.88 332.57 0.00 1 0.00 1 0 17 1.471e-02 8.471e-03 9.483e-03 3.924e-03 1.972321e-01 2.026371e-03 2.371280e-03 -6.000000e+00 8.677202e-03 232.15 -2.00 3.57 -2.00 316.80 0.00e+00 7.243978e-04 2.569284e-04 1.194489e-04 -6.000000e+00 3.851222e-04 287.60 -2.00 20.00 -2.00 315.97 0.00e+00 1.471 0.000 302.00 328.00 3 5.1301e+00 5.3538e-03 1.7928e-02 -6.0000e+00 2.1743e-02 2.9945e-02 5.9868e-03 1.0430e-02 -6.0000e+00 2.3489e-02 9.8296e-03 3.4763e-03 5.0405e-03 -6.0000e+00 1.3987e-02 -1.0592e-02 1.6325e-03 1.4319e-03 -6.0000e+00 5.8965e-03 5.8733e-04 5.8590e-04 1.1744e-04 1.6419e-05 -6.0000e+00 4.1575e-04 1.9572e-02 7.4774e-06 12 9 1 12 9 1 99.55 17.14 0.45 0.01957 0.02398 7 5 1 5 0 2122.820 22.50 15.00 17.14 25.49 26.7 968.18 -1964 853 -2496 -3176 -3572 -3007 1308 -3897 4680 -4640 59 -4187 1401 580 -329 1449 -774 2271 -264 3927 -1864 788 1015 1409 -1015 54 -1345 -1838 568 -3266 1827 -934 2769 -2871 -2697 -2439 -2093 -5 262 1583 -1315 676 -870 348 -619 323 -250 -403 -693 -462 2195 343 1778 592 1763 900 1051 -198 325 911 487 1852 1080 2284 -648 -90 -1061 -1472 399 527 965 27 1272 -216 397 -683 -1087 -1874 -1720 -1926 -2055 -904 -2707 -711 -761 272 -106 739 193 611 177 -395 -73 -635 -69 -802 797 622 731 -32 -278 -714 -1037 -18 -1392 -539 -1213 -360 321 1048 758 877 937 -299 -37 -1037 292 -1059 176 -177 531 284 692 983 104 240 -143 1283 -518 540 -589 -14 -106 -173 123 -369 676 18 689 -483 166 -845 -753 -313 143 -436 -525 -534 -426 187 -648 792 -888 11 -804 280 131 -84 392 -221 651 -80 1180 -598 247 321 464 -356 19 -486 -630 179 -1037 576 -319 975 -1081 -964 -853 -783 -2 129 882 -808 427 -567 227 -406 210 -160 -252 -423 -280 1352 226 1215 424 1286 669 792 -151 243 677 372 1488 926 2036 -585 -76 -840 -1138 317 460 907 26 1245 -208 362 -575 -844 -1385 -1302 -1595 -1871 -881 -2821 -760 -858 323 -132 939 246 759 207 -432 -74 -622 -69 -874 932 783 965 -42 -350 -847 -1188 -21 -1742 -705 -1647 -504 461 1567 1173 1366 1416 -431 -50 -1334 371 -1397 244 -259 793 424 1010 1389 142 316 -181 1604 -682 742 -844 -21 -155 -262 194 -605 1130 30 1181 -823 276 -1378 -1210 SS 20220809T142816.9Z 8256.602974 234 1 11.27 2 46.44 113.03 162.24 335.67 0.00 1 0.00 1 0 17 1.083e-02 6.543e-03 1.046e-03 4.615e-04 1.926980e-01 2.379879e-04 2.337369e-03 -6.000000e+00 6.388802e-03 232.15 -2.00 3.57 -2.00 316.69 0.00e+00 5.578455e-04 2.928513e-05 1.060123e-04 -6.000000e+00 2.836020e-04 287.60 -2.00 20.00 -2.00 315.88 0.00e+00 1.449 0.000 302.00 328.00 3 7.0281e-01 6.2631e-04 1.7628e-02 -6.0000e+00 1.6009e-02 7.2689e-03 6.9969e-04 1.0227e-02 -6.0000e+00 1.7295e-02 5.3519e-03 4.0433e-04 4.9437e-03 -6.0000e+00 1.0298e-02 -7.5126e-03 1.8971e-04 1.3741e-03 -6.0000e+00 4.3410e-03 5.1265e-02 5.0988e-04 1.3785e-05 1.5991e-05 -6.0000e+00 3.0617e-04 1.9955e-02 -1.2731e-05 12 9 1 12 1 1 99.76 17.15 0.17 0.01996 0.02379 495 444 1 5 0 21.670 22.50 15.00 17.15 25.61 26.8 969.21 99 -499 -1982 -4492 -4775 -3020 -554 457 600 -2156 -2647 -1863 200 111 956 265 -129 1148 452 1278 166 757 1043 1168 296 132 -693 -1514 -774 -344 1290 809 1429 -1569 -2955 -1917 -1553 -229 275 300 -684 0 -580 -100 -256 -158 -686 -613 -758 -163 1036 705 1501 1052 1304 895 835 445 476 713 942 1844 1661 1973 -89 -159 -760 -588 578 378 411 344 499 -12 -25 -958 -885 -1778 -1062 -1268 -1513 -1438 -2074 -1255 -1055 -264 -240 555 293 474 283 -40 -260 -145 92 -291 723 721 526 -153 -188 -848 -570 -198 -1133 -793 -812 -273 5 779 539 642 521 68 29 -268 24 -463 282 -31 260 358 488 520 458 282 45 1071 85 283 -160 -90 -195 -41 -39 -256 225 157 200 -307 -61 -649 -533 17 -94 -381 -824 -785 -463 -87 79 114 -438 -532 -376 43 27 259 78 -39 356 146 420 56 252 351 410 110 50 -264 -547 -258 -111 423 283 529 -608 -1096 -687 -598 -101 144 181 -413 0 -374 -64 -165 -101 -431 -372 -491 -104 681 449 998 733 932 653 618 329 346 516 701 1451 1409 1755 -80 -133 -583 -477 442 325 387 338 491 -12 -22 -785 -717 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