File name: Pandora108s1_Toronto-West_20220902_L2Fit_fout2c6d20211104p1-8.txt File generation date: 20240820T121546.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v3d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20220902_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20220902 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220902T112606.7Z 8280.476467 62 1 46.24 2 83.13 85.74 149.72 44.97 0.00 1 0.00 1 0 25 4.939e-01 5.347e-02 3.903e-01 3.818e-02 8.144374e-01 2.385431e-02 9.394136e-03 -6.000000e+00 3.071054e-01 230.29 -2.00 3.57 -2.00 322.13 0.00e+00 9.869671e-03 1.162807e-02 9.588828e-04 -6.000000e+00 1.623295e-02 286.27 -2.00 20.00 -2.00 321.60 0.00e+00 7.637 0.009 302.00 328.00 3 1.2636e+00 8.9294e-02 8.8340e-02 -6.0000e+00 7.6778e-01 1.3586e+00 1.0669e-01 5.0988e-02 -6.0000e+00 8.3717e-01 -1.7504e+00 6.6591e-02 2.1446e-02 -6.0000e+00 4.9408e-01 6.8311e-01 3.4754e-02 1.1794e-02 -6.0000e+00 2.1202e-01 3.1945e-05 -1.2996e-03 1.2075e-03 1.6455e-04 -6.0000e+00 1.5392e-02 7.6606e-03 -2.3948e-05 12 9 9 12 1 1 94.17 17.12 0.44 0.00766 -0.00211 41 9 1 5 0 1096.650 22.50 15.00 17.12 22.47 26.7 981.87 900000 72400 900000 -38377 900000 -44313 900000 -46084 900000 7507 110067 900000 -26107 900000 -29933 900000 -6068 900000 5773 900000 118115 151448 900000 -10549 900000 -49178 900000 -38062 900000 -7986 900000 111284 102536 900000 -22638 900000 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4831 6711 6558 3168 7345 -223 8185 164 9885 1309 8225 2349 3794 3524 -1719 3161 -3928 8832 -5133 10837 -363 8343 285 1308 1808 -2899 7328 -7901 8806 -5532 8139 -5994 3401 -3984 -3934 600 -6863 4004 -8017 4297 -9736 3484 -5532 766 -2761 -4091 1425 -6861 6910 -8157 8211 -9387 5803 -4744 2974 -3302 -2853 3112 -4640 10300 -1037 10012 -3710 10112 -1571 5041 715 -3217 7557 -2128 9083 -8189 7452 -4589 3928 -623 2595 -1568 -3397 3337 -9287 SS 20220902T113712.8Z 8280.484176 65 1 49.87 2 81.13 87.64 148.35 49.02 0.00 1 0.00 1 0 25 5.826e-01 2.285e-02 2.795e-01 9.801e-03 7.162381e-01 5.780652e-03 8.746101e-03 -6.000000e+00 3.503640e-01 230.29 -2.00 3.57 -2.00 321.90 0.00e+00 1.259332e-02 3.306334e-03 3.820561e-03 -6.000000e+00 1.800088e-02 286.26 -2.00 20.00 -2.00 321.37 0.00e+00 6.129 0.004 302.00 328.00 3 7.3017e-01 2.2618e-02 7.2837e-02 -6.0000e+00 8.7593e-01 4.6794e-01 3.0338e-02 4.1081e-02 -6.0000e+00 9.5151e-01 -6.7043e-01 2.7028e-02 2.4359e-02 -6.0000e+00 5.6227e-01 2.7545e-01 1.2512e-02 1.1889e-02 -6.0000e+00 2.3899e-01 2.8880e-04 -1.4744e-03 3.0338e-04 2.1411e-04 -6.0000e+00 1.7335e-02 7.0179e-03 -6.5751e-05 12 8 8 10 0 0 -14.80 17.12 0.22 0.00702 -0.00406 217 43 1 5 0 229.780 22.50 15.00 17.12 23.24 26.7 986.37 900000 -166159 900000 -192758 900000 -205660 900000 -150023 900000 2751 -95138 900000 -114371 900000 -111133 900000 -72272 900000 -11938 74818 74579 9391 303394 -59667 900000 -79953 900000 -69230 900000 7132 49157 81284 9742 107828 -28271 214050 -47055 152112 -1017 87697 29731 57860 42634 5063 56685 5288 73355 -594 63968 14327 54617 25637 34545 38818 15750 38344 1757 34386 -152 28781 3227 27729 14433 19972 21192 8480 23914 -339 20472 -428 13921 4651 7571 4179 1636 6854 -6729 6769 -9011 10517 -5722 6014 -4673 255 -1140 -2118 445 -3232 1720 -4078 3863 -5180 1076 -4941 -1701 -2348 -2925 491 -2458 874 -3572 1578 -4540 1046 -4058 -2269 -2155 -2234 539 -1645 1162 -1574 1247 -1006 616 -766 616 149 -204 1101 -419 2593 390 2439 -157 2043 1051 2072 796 158 1105 -123 1309 -1008 688 -1063 745 -292 135 -131 -418 -14 -1534 900000 -4497 900000 -6805 900000 -6828 900000 -3069 900000 26 -1273 900000 -2519 900000 -3854 900000 -2375 900000 -265 776 773 173 2893 -2061 900000 -3408 900000 -2622 900000 147 826 1215 321 1558 -1365 2041 -2723 1625 -51 2281 1432 2316 2041 354 2528 387 2976 -49 3063 1141 3301 2219 3005 3469 1832 3696 241 3461 -20 2925 427 3201 2123 3160 3533 1603 3856 -71 3785 -109 3429 1308 2065 1113 412 1479 -1546 1376 -2364 2714 -2030 2187 -2078 115 -556 -1115 240 -1874 953 -2337 1932 -2653 501 -2492 -929 -1497 -2200 412 -2358 830 -3396 1298 -3606 773 -3329 -1958 -1957 -2194 564 -1989 1528 -2294 1808 -1460 845 -1024 818 207 -303 1682 -653 3796 561 3336 -213 2630 1325 2679 1162 265 2038 -248 2743 -2298 1653 -2744 1948 -782 364 -341 -1033 -33 -3451 SS 20220902T114917.0Z 8280.492558 70 1 49.76 2 78.95 89.72 146.77 53.11 0.00 1 0.00 1 0 25 3.721e-01 7.705e-03 1.812e-01 4.191e-03 6.173252e-01 2.323857e-03 7.192462e-03 -6.000000e+00 2.182260e-01 230.29 -2.00 3.57 -2.00 321.37 0.00e+00 3.310868e-03 1.165295e-03 1.902995e-03 -6.000000e+00 9.681720e-03 286.26 -2.00 20.00 -2.00 320.78 0.00e+00 5.028 0.002 302.00 328.00 3 5.6170e-01 8.2549e-03 6.0318e-02 -6.0000e+00 5.4463e-01 7.8025e-02 1.1271e-02 3.5525e-02 -6.0000e+00 5.8900e-01 -1.0483e-01 1.0881e-02 1.9019e-02 -6.0000e+00 3.5099e-01 3.2319e-02 5.1407e-03 6.1966e-03 -6.0000e+00 1.4865e-01 1.1309e-03 -8.0561e-04 1.2718e-04 8.9336e-05 -6.0000e+00 1.0502e-02 6.4387e-03 -6.0173e-05 11 8 0 10 0 0 -19.99 17.12 0.22 0.00644 0.00039 470 92 1 5 0 105.850 22.50 15.00 17.12 24.12 26.7 991.80 -179623 -1528 -138643 -112947 -136083 -145725 -91442 -136417 -60795 -130104 -27175 -127811 -29528 -83334 -21868 -36800 -18746 -24442 -41836 16978 -33859 8427 -48134 2315 -23828 -5619 -19823 -21562 -7749 -10833 9147 -13914 18758 -11139 4558 -17225 -5866 -1091 6614 2730 -263 7468 -4859 9079 -2907 6911 1415 4826 3469 4159 7109 1309 8724 1364 4827 1367 4005 2578 1638 3034 2129 6008 1719 6088 1744 4187 902 2173 1301 1872 1190 826 1736 -1373 348 -3004 -1372 -3129 -1481 -1579 -1272 -613 -2271 -961 -1869 353 -970 904 -406 560 142 -244 -324 -1017 501 -655 1165 323 457 -783 -469 -769 -501 -150 -1728 -1114 -1524 -12 -282 1007 28 496 397 226 512 -68 788 -361 455 -589 131 178 274 323 -16 353 -78 1536 -130 89 -445 9 -131 4 -76 -401 78 57 295 -430 180 -259 184 -2336 -6 -1545 -965 -1365 -1570 -673 -1622 -422 -1789 -155 -2042 -241 -1362 -244 -574 -279 -427 -948 227 -780 128 -1341 42 -611 -127 -530 -577 -178 -274 221 -507 571 -497 171 -794 -262 -55 345 178 -20 572 -445 748 -275 607 134 457 347 440 806 176 1200 220 801 245 723 474 298 536 390 1154 390 1485 473 1097 239 580 381 624 445 327 683 -532 122 -985 -409 -943 -480 -601 -566 -310 -1290 -576 -1206 238 -701 664 -303 403 96 -155 -196 -626 333 -507 1023 327 507 -896 -508 -760 -452 -134 -1662 -1134 -1644 -14 -349 1367 42 796 644 356 761 -97 1109 -535 709 -973 215 285 422 481 -22 487 -105 2066 -197 151 -835 17 -275 8 -181 -1009 202 150 776 -1106 435 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