File name: Pandora108s1_Toronto-West_20220918_L2Fit_fwvt1c6d20211104p1-8.txt File generation date: 20240820T122628.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v3d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20220918_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20220918 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1653 1802 Nominal wavelengths inside fitting window [nm]: 492.1141 492.2350 492.3559 492.4768 492.5976 492.7185 492.8393 492.9601 493.0809 493.2016 493.3224 493.4431 493.5638 493.6845 493.8052 493.9259 494.0466 494.1672 494.2878 494.4084 494.5290 494.6496 494.7701 494.8907 495.0112 495.1317 495.2522 495.3726 495.4931 495.6135 495.7339 495.8543 495.9747 496.0951 496.2154 496.3358 496.4561 496.5764 496.6967 496.8169 496.9372 497.0574 497.1776 497.2978 497.4180 497.5382 497.6583 497.7785 497.8986 498.0187 498.1388 498.2588 498.3789 498.4989 498.6189 498.7389 498.8589 498.9789 499.0988 499.2187 499.3387 499.4585 499.5784 499.6983 499.8181 499.9380 500.0578 500.1776 500.2973 500.4171 500.5368 500.6566 500.7763 500.8960 501.0156 501.1353 501.2549 501.3746 501.4942 501.6138 501.7333 501.8529 501.9724 502.0920 502.2115 502.3310 502.4504 502.5699 502.6893 502.8087 502.9281 503.0475 503.1669 503.2862 503.4056 503.5249 503.6442 503.7635 503.8827 504.0020 504.1212 504.2404 504.3596 504.4788 504.5980 504.7171 504.8363 504.9554 505.0745 505.1935 505.3126 505.4316 505.5507 505.6697 505.7887 505.9076 506.0266 506.1455 506.2645 506.3834 506.5023 506.6211 506.7400 506.8588 506.9776 507.0964 507.2152 507.3340 507.4527 507.5715 507.6902 507.8089 507.9276 508.0462 508.1649 508.2835 508.4021 508.5207 508.6393 508.7578 508.8764 508.9949 509.1134 509.2319 509.3504 509.4688 509.5873 509.7057 509.8241 509.9425 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220918T131619.6Z 8296.553005 284 1 43.28 2 66.85 111.29 25.84 237.66 0.00 1 0.00 1 0 15 2.442e-03 2.445e-03 1.376e-03 1.372e-03 5.698109e+03 8.988538e+01 3.843496e+02 -6.000000e+00 1.370036e+02 284.79 -2.00 20.00 -2.00 505.30 0.00e+00 7.289132e-04 3.787047e-05 5.030919e-05 -6.000000e+00 6.887254e-05 284.79 -2.00 20.00 -2.00 500.53 0.00e+00 1.743905e-01 2.711099e-02 4.100454e-02 -6.000000e+00 4.843648e-02 228.72 -2.00 3.57 -2.00 502.11 0.00e+00 2.524 0.000 489.00 513.00 1 7.5024e+00 2.0734e-03 5.0898e-03 -6.0000e+00 3.7156e-03 9.8676e-04 5.3518e-04 9.7655e-04 -6.0000e+00 9.6422e-04 7.3493e-04 5.9702e-04 1.3442e-04 4.4056e-05 -6.0000e+00 2.4896e-04 1.6443e-03 -7.0398e-06 12 1 1 12 1 1 95.79 17.33 0.93 0.00164 0.00579 11 3 1 4 0 3591.460 22.71 15.00 17.33 27.83 27.3 1023.87 -384 -309 -182 140 349 232 569 199 521 31 326 -90 -236 -238 -374 -342 -37 141 139 137 31 279 -42 447 331 258 242 -169 -267 -365 -252 -385 -134 -54 -39 -136 -208 -13 -82 5 41 166 223 133 273 515 27 393 39 -306 -202 -402 -151 -279 -227 -364 9 73 41 192 117 398 61 340 76 38 -206 -293 -243 -328 -123 -360 -76 -51 52 -227 -335 -214 -226 -53 -359 -228 -486 27 -193 -244 -141 12 8 28 -161 116 272 -38 238 -48 140 -369 -259 -168 -286 -393 -306 118 -456 -113 -171 -60 74 179 -22 50 322 328 295 271 526 135 248 200 364 3 85 287 90 383 58 276 -37 -10 24 -240 -63 -300 166 -27 -26 45 248 16 107 72 391 117 -150 -58 -273 -133 -538 1 -377 -311 -174 138 351 239 592 209 541 32 329 -90 -232 -233 -365 -337 -37 144 145 144 33 294 -45 473 351 273 254 -175 -269 -359 -245 -380 -136 -57 -42 -145 -219 -14 -84 5 42 172 233 141 290 545 28 407 40 -304 -195 -381 -142 -267 -224 -370 9 76 42 198 121 412 64 351 78 39 -206 -289 -237 -316 -118 -348 -74 -50 51 -222 -323 -203 -212 -49 -340 -217 -469 26 -190 -241 -139 12 8 28 -162 117 277 -38 236 -47 132 -341 -234 -150 -257 -364 -293 117 -463 -114 -172 -60 73 177 -22 51 332 339 307 283 552 133 259 205 367 3 85 286 90 384 58 276 -37 -10 23 -233 -60 -286 158 -27 -26 45 235 16 103 70 381 115 -147 -56 -258 -132 -532 1 SQ 20220918T133044.7Z 8296.563017 291 1 21.53 2 64.45 114.24 28.05 242.58 0.00 1 0.00 1 0 15 2.137e-03 2.132e-03 8.499e-04 8.475e-04 4.783813e+03 5.410789e+01 3.285435e+02 -6.000000e+00 1.198639e+02 284.79 -2.00 20.00 -2.00 505.27 0.00e+00 7.086240e-04 2.346492e-05 4.648980e-05 -6.000000e+00 6.025651e-05 284.79 -2.00 20.00 -2.00 500.47 0.00e+00 9.233828e-02 1.679895e-02 3.444957e-02 -6.000000e+00 4.237749e-02 228.72 -2.00 3.57 -2.00 502.05 0.00e+00 2.304 0.000 489.00 513.00 1 6.1920e+00 1.2905e-03 4.4892e-03 -6.0000e+00 3.2508e-03 -1.1443e-02 3.3057e-04 8.3107e-04 -6.0000e+00 8.4361e-04 2.8335e-03 5.3731e-04 8.3143e-05 4.0640e-05 -6.0000e+00 2.1781e-04 2.5375e-03 -1.3263e-05 12 1 1 12 1 1 99.37 17.33 0.84 0.00254 0.00626 21 10 1 4 0 970.480 22.71 15.00 17.33 28.30 27.3 1026.91 -431 -208 -151 100 109 421 520 381 292 159 161 -67 -165 -277 -113 -262 -75 119 28 94 43 270 112 288 240 117 -18 65 -211 -346 -276 -302 -57 105 53 -104 -10 -183 -94 -45 52 72 87 142 217 465 209 163 8 -204 -347 -278 -432 -397 -40 -81 51 96 236 172 222 180 83 22 26 -36 -139 -132 -153 -331 -141 -228 -241 -17 -87 -146 -145 -357 -128 -368 -302 -262 -220 -31 1 -169 -121 88 -38 38 48 171 158 31 161 -46 34 -216 -54 -364 -300 -433 -256 -144 -216 -173 -120 -92 -156 64 -67 -68 164 526 440 374 518 290 257 203 293 92 241 127 2 221 215 192 -39 112 -87 -92 -20 -53 -62 91 -96 -57 143 86 162 170 251 93 -5 -103 -262 -211 -326 -228 -420 -207 -145 99 110 434 542 399 305 164 163 -67 -163 -272 -110 -260 -75 122 30 100 46 287 120 308 257 125 -19 68 -214 -342 -271 -300 -58 110 57 -112 -11 -192 -98 -47 54 76 92 152 219 498 222 171 8 -205 -338 -267 -413 -386 -40 -83 53 100 247 179 232 178 82 22 27 -37 -141 -132 -152 -325 -138 -224 -239 -17 -88 -145 -142 -346 -122 -354 -292 -255 -216 -30 1 -171 -122 88 -38 39 46 166 155 30 154 -46 33 -206 -50 -336 -279 -413 -253 -138 -211 -169 -116 -87 -149 61 -65 -67 163 525 441 378 525 295 259 202 286 89 232 123 2 215 209 186 -38 108 -83 -87 -18 -49 -57 86 -93 -56 142 86 164 173 256 95 -5 -104 -259 -204 -311 -218 SQ 20220918T133457.2Z 8296.565940 294 1 6.64 2 63.76 115.12 28.71 243.91 0.00 1 0.00 1 0 22 1.820e-03 1.823e-03 2.627e-04 2.618e-04 4.522043e+03 1.692945e+01 3.090398e+02 -6.000000e+00 1.021084e+02 284.79 -2.00 20.00 -2.00 505.35 0.00e+00 5.989148e-04 7.288952e-06 4.096293e-05 -6.000000e+00 5.133270e-05 284.79 -2.00 20.00 -2.00 500.54 0.00e+00 1.061674e-01 5.172108e-03 3.398655e-02 -6.000000e+00 3.611081e-02 228.72 -2.00 3.57 -2.00 502.15 0.00e+00 2.249 0.000 489.00 513.00 1 2.2387e+00 3.9611e-04 4.3672e-03 -6.0000e+00 2.7699e-03 -1.0900e-02 1.0093e-04 8.1257e-04 -6.0000e+00 7.1909e-04 1.4896e-01 5.3971e-04 2.5716e-05 3.4696e-05 -6.0000e+00 1.8558e-04 4.5956e-03 -4.6709e-05 10 0 0 10 0 0 95.18 17.33 0.84 0.00460 0.00834 531 104 1 4 0 12.100 22.71 15.00 17.33 28.57 27.2 1028.27 -383 -301 -98 77 134 376 382 268 324 163 40 -31 -107 -144 -136 -112 -93 83 116 42 105 175 80 211 248 126 48 41 -124 -317 -168 -276 -149 76 -17 -89 4 -41 -93 -86 15 49 124 218 254 278 255 139 58 -131 -295 -305 -356 -255 -83 -89 -35 18 84 139 175 98 55 66 12 -38 -114 -155 -142 -193 -157 -226 -151 -63 -50 -182 -227 -191 -184 -274 -228 -217 -188 -78 -71 -181 -91 -22 -27 40 15 118 148 122 170 62 -87 -199 -197 -377 -304 -330 -213 -98 -236 -267 -145 -73 -38 1 -41 45 166 313 378 401 384 316 209 176 202 96 161 215 17 45 204 113 46 191 -46 -89 -39 -129 -59 74 51 -56 94 155 103 170 175 91 -8 -85 -197 -224 -261 -236 -364 -293 -98 80 142 405 417 295 354 176 42 -33 -111 -148 -139 -116 -98 89 118 43 107 180 82 217 256 130 49 41 -131 -329 -173 -286 -146 77 -18 -92 4 -41 -93 -86 15 50 127 224 263 288 262 141 58 -126 -278 -305 -356 -239 -80 -88 -36 19 85 140 177 99 56 67 12 -38 -111 -149 -136 -182 -147 -213 -145 -61 -48 -175 -214 -178 -171 -254 -212 -203 -177 -74 -68 -176 -89 -21 -26 39 15 118 149 123 168 60 -82 -183 -178 -336 -273 -303 -203 -96 -237 -268 -144 -72 -37 1 -41 46 170 322 391 416 402 331 217 180 203 95 160 213 17 45 204 113 46 189 -45 -87 -37 -122 -56 72 50 -57 96 160 107 177 183 95 -9 -88 -200 -223 -257 -232 SQ 20220918T133504.1Z 8296.566020 294 2 6.61 2 63.74 115.14 28.73 243.94 0.00 1 0.00 1 0 15 1.652e-03 1.656e-03 6.212e-04 6.190e-04 4.615964e+03 4.005389e+01 3.144685e+02 -6.000000e+00 9.267221e+01 284.79 -2.00 20.00 -2.00 505.35 0.00e+00 5.676281e-04 1.725136e-05 3.975323e-05 -6.000000e+00 4.658763e-05 284.79 -2.00 20.00 -2.00 500.55 0.00e+00 9.874973e-02 1.222044e-02 3.473448e-02 -6.000000e+00 3.275335e-02 228.72 -2.00 3.57 -2.00 502.16 0.00e+00 2.247 0.000 489.00 513.00 1 3.2644e+00 9.3596e-04 4.4005e-03 -6.0000e+00 2.5127e-03 -8.2402e-03 2.3818e-04 8.2832e-04 -6.0000e+00 6.5177e-04 5.3462e-02 1.2458e-04 6.0978e-05 3.5333e-05 -6.0000e+00 1.6836e-04 3.1464e-03 9.6895e-06 10 0 0 10 0 0 55.17 17.33 0.76 0.00315 0.00401 531 104 1 4 0 12.100 22.71 15.00 17.33 28.60 27.2 1028.27 -376 -288 -65 38 199 393 388 238 289 84 71 -12 -78 -139 -88 -21 -78 137 77 -24 71 154 53 176 219 90 -14 19 -178 -309 -125 -261 -63 126 -12 -132 7 -74 -165 -101 -40 67 100 164 229 222 227 110 57 -126 -173 -231 -295 -224 -55 -87 -32 -2 74 114 122 85 37 -1 -64 -75 -101 -110 -132 -143 -76 -177 -160 -140 -64 -259 -176 -113 -101 -154 -212 -309 -242 -75 -52 -180 -101 -46 13 107 44 76 143 31 83 84 -66 -176 -114 -291 -268 -352 -231 -155 -238 -271 -117 75 -25 26 -35 18 209 275 301 381 369 269 184 117 219 126 141 189 5 47 156 122 19 92 -44 -62 80 -23 -20 43 -33 -67 112 102 58 187 205 87 -51 -115 -176 -133 -193 -223 -362 -284 -67 40 213 429 429 265 319 92 77 -12 -82 -144 -91 -22 -83 137 79 -25 73 159 54 183 227 93 -15 20 -175 -296 -119 -251 -62 129 -13 -137 7 -76 -167 -102 -40 67 103 170 238 230 234 111 56 -122 -163 -214 -272 -211 -53 -86 -32 -2 75 116 124 87 38 -1 -65 -74 -98 -107 -126 -135 -72 -168 -154 -136 -62 -250 -167 -105 -94 -143 -198 -290 -229 -72 -50 -175 -99 -45 13 105 43 77 145 31 82 81 -62 -162 -103 -260 -241 -325 -221 -153 -240 -273 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27 103 148 155 140 44 96 -1 -14 -122 -161 -161 -232 -177 -222 -188 -113 -81 -212 -239 -204 -191 -283 -271 -223 -226 -76 -109 -164 -85 -17 -41 39 66 145 152 116 146 109 -84 -161 -168 -354 -325 -355 -279 -159 -291 -213 -98 -46 -24 36 -14 96 236 336 410 392 394 311 224 187 191 114 148 180 42 109 223 126 84 171 7 -26 26 -34 -25 110 46 -55 111 161 129 214 202 77 -11 -96 -190 -211 -235 -224 SQ 20220918T200229.1Z 8296.835059 520 3 5.79 2 56.51 234.17 92.31 311.20 0.00 1 0.00 1 0 15 1.941e-03 1.935e-03 1.020e-04 1.017e-04 3.907358e+03 6.398504e+00 2.758247e+02 -6.000000e+00 1.088781e+02 284.76 -2.00 20.00 -2.00 505.26 0.00e+00 8.245097e-04 2.804858e-06 5.154295e-05 -6.000000e+00 5.473636e-05 284.76 -2.00 20.00 -2.00 500.42 0.00e+00 2.598852e-03 2.020141e-03 2.792139e-02 -6.000000e+00 3.849513e-02 228.69 -2.00 3.57 -2.00 502.00 0.00e+00 1.806 0.000 489.00 513.00 1 4.9125e-01 1.5518e-04 3.6734e-03 -6.0000e+00 2.9530e-03 -9.9469e-03 3.9898e-05 6.7492e-04 -6.0000e+00 7.6626e-04 9.1486e-01 5.1346e-04 1.0068e-05 3.4794e-05 -6.0000e+00 1.9787e-04 -3.1285e-04 9.6016e-06 10 0 0 10 0 0 42.06 17.51 0.88 -0.00031 0.00325 1858 364 1 4 0 2.970 22.90 15.00 17.51 31.30 27.1 1040.35 -296 -226 -29 156 226 468 448 350 388 185 126 -13 -117 -133 -152 -105 -79 53 68 33 114 163 105 212 238 60 1 12 -184 -345 -198 -300 -175 61 -42 -126 -8 -64 -145 -90 -14 13 90 209 234 295 225 102 49 -186 -262 -301 -362 -263 -136 -117 -43 19 97 148 131 129 50 79 19 -25 -112 -160 -155 -228 -193 -212 -188 -113 -98 -228 -244 -198 -196 -278 -278 -226 -225 -71 -113 -190 -107 -13 -25 30 53 139 171 121 157 108 -88 -182 -183 -389 -355 -364 -289 -171 -302 -215 -106 -60 -39 41 -3 105 249 329 391 399 393 321 236 178 208 110 160 194 48 120 256 141 88 183 17 -36 34 -46 -31 101 39 -55 115 176 120 207 202 83 -14 -97 -193 -211 -251 -241 -271 -212 -28 155 230 485 471 369 407 191 129 -13 -117 -131 -150 -104 -80 55 72 35 121 174 112 227 256 64 2 13 -187 -343 -195 -298 -180 64 -45 -136 -8 -67 -151 -94 -15 14 96 224 253 318 240 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6.7533e-04 -6.0000e+00 7.6438e-04 9.1994e-01 5.2632e-04 1.0011e-05 3.4813e-05 -6.0000e+00 1.9738e-04 -2.5664e-04 8.9073e-06 10 0 0 10 0 0 38.61 17.51 0.88 -0.00026 0.00339 1858 364 1 4 0 2.970 22.90 15.00 17.51 31.30 27.1 1040.35 -298 -220 -10 155 230 464 447 346 390 189 119 -30 -126 -157 -155 -114 -72 66 89 36 119 177 103 192 224 64 -3 2 -178 -338 -198 -308 -183 52 -52 -105 -11 -69 -138 -97 -2 32 97 218 222 299 239 112 35 -181 -261 -310 -375 -260 -126 -114 -32 12 102 154 131 99 33 91 5 -22 -107 -154 -169 -228 -184 -210 -189 -111 -91 -217 -233 -190 -169 -286 -279 -230 -234 -73 -115 -172 -99 -14 -46 44 60 137 162 125 163 103 -84 -169 -183 -396 -360 -369 -282 -172 -307 -236 -108 -55 -32 44 13 97 242 322 394 395 390 305 227 183 208 128 157 207 41 117 243 149 82 200 30 -27 30 -50 -39 95 29 -70 116 173 135 190 196 84 -13 -84 -189 -216 -254 -227 -273 -206 -10 154 234 482 470 366 409 196 122 -30 -125 -155 -153 -113 -73 68 94 38 127 189 110 206 241 68 -4 2 -181 -337 -195 -308 -188 55 -56 -113 -11 -73 -144 -101 -2 33 104 234 240 322 255 119 36 -182 -256 -299 -360 -253 -127 -118 -33 13 107 162 138 98 32 90 5 -23 -109 -155 -167 -224 -180 -207 -188 -112 -92 -217 -230 -184 -163 -276 -271 -225 -231 -73 -116 -174 -101 -15 -44 41 58 132 158 122 157 97 -83 -163 -173 -371 -339 -356 -261 -164 -299 -229 -104 -53 -30 42 12 96 240 321 394 398 395 309 227 180 202 123 151 199 40 114 234 144 79 192 28 -26 28 -46 -36 89 28 -68 114 172 135 191 197 85 -13 -84 -185 -207 -240 -215 SQ 20220918T200241.2Z 8296.835199 520 5 5.74 2 56.54 234.22 92.34 311.24 0.00 1 0.00 1 0 15 1.917e-03 1.914e-03 1.011e-04 1.008e-04 3.902162e+03 6.338869e+00 2.750937e+02 -6.000000e+00 1.075409e+02 284.76 -2.00 20.00 -2.00 505.26 0.00e+00 8.281789e-04 2.786215e-06 5.181641e-05 -6.000000e+00 5.406413e-05 284.76 -2.00 20.00 -2.00 500.41 0.00e+00 3.616746e-03 2.004323e-03 2.809657e-02 -6.000000e+00 3.802234e-02 228.69 -2.00 3.57 -2.00 502.00 0.00e+00 1.808 0.000 489.00 513.00 1 4.7963e-01 1.5404e-04 3.6857e-03 -6.0000e+00 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224 501 492 372 405 184 125 -12 -121 -130 -169 -137 -83 64 95 24 121 192 127 244 264 74 12 -5 -195 -341 -195 -318 -199 57 -66 -115 10 -54 -148 -90 -29 35 110 236 224 281 227 119 29 -172 -262 -299 -343 -275 -130 -106 -47 23 95 148 159 133 55 107 23 -32 -110 -138 -168 -229 -190 -222 -174 -96 -78 -224 -233 -183 -186 -279 -277 -224 -244 -94 -125 -159 -80 -18 -34 54 70 129 141 93 166 102 -62 -185 -173 -359 -330 -376 -278 -159 -300 -235 -108 -62 -32 42 9 93 240 323 400 384 400 316 222 165 193 103 148 215 62 123 245 146 87 184 2 -29 44 -29 -22 89 23 -61 133 167 118 198 211 97 -12 -91 -194 -204 -238 -216 SQ 20220918T200305.4Z 8296.835479 520 9 5.80 2 56.60 234.32 92.39 311.30 0.00 1 0.00 1 0 15 1.964e-03 1.963e-03 1.002e-04 9.984e-05 3.903738e+03 6.302803e+00 2.768239e+02 -6.000000e+00 1.101679e+02 284.76 -2.00 20.00 -2.00 505.28 0.00e+00 8.323806e-04 2.765454e-06 5.230173e-05 -6.000000e+00 5.538486e-05 284.76 -2.00 20.00 -2.00 500.42 0.00e+00 5.444682e-03 1.986388e-03 2.827364e-02 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0.00 1 0 15 1.958e-03 1.945e-03 1.962e-04 1.956e-04 4.147980e+03 1.229538e+01 2.893309e+02 -6.000000e+00 1.097910e+02 284.76 -2.00 20.00 -2.00 505.22 0.00e+00 5.800492e-04 5.388094e-06 3.947070e-05 -6.000000e+00 5.519545e-05 284.76 -2.00 20.00 -2.00 500.45 0.00e+00 2.446263e-02 3.868900e-03 2.868374e-02 -6.000000e+00 3.881801e-02 228.69 -2.00 3.57 -2.00 502.02 0.00e+00 1.982 0.000 489.00 513.00 1 7.1950e-02 2.9665e-04 3.8162e-03 -6.0000e+00 2.9778e-03 -9.3664e-03 7.6546e-05 7.0022e-04 -6.0000e+00 7.7268e-04 1.3595e+00 5.5227e-04 1.9294e-05 3.7785e-05 -6.0000e+00 1.9953e-04 -2.0195e-04 9.1703e-06 10 0 0 10 0 0 1.79 17.53 0.88 -0.00020 0.00363 509 100 2 4 0 22.480 22.90 15.00 17.53 32.91 27.4 1048.93 -301 -253 0 153 211 461 442 341 349 185 71 -29 -125 -111 -159 -125 -56 87 107 42 116 166 144 196 239 81 17 1 -196 -344 -206 -275 -201 84 -71 -95 -6 -52 -132 -105 11 17 112 221 244 291 239 63 33 -149 -283 -339 -411 -258 -162 -74 -71 31 86 130 153 140 56 88 60 -16 -100 -179 -169 -242 -197 -217 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20220918T203428.9Z 8296.857279 535 2 5.83 2 61.41 241.55 96.32 316.78 0.00 1 0.00 1 0 15 2.046e-03 2.054e-03 8.937e-05 8.912e-05 4.412194e+03 5.733765e+00 3.054942e+02 -6.000000e+00 1.147498e+02 284.76 -2.00 20.00 -2.00 505.34 0.00e+00 6.000128e-04 2.472764e-06 4.191803e-05 -6.000000e+00 5.768833e-05 284.76 -2.00 20.00 -2.00 500.53 0.00e+00 3.264921e-02 1.761146e-03 3.260534e-02 -6.000000e+00 4.056985e-02 228.69 -2.00 3.57 -2.00 502.14 0.00e+00 2.080 0.000 489.00 513.00 1 1.8283e-01 1.3500e-04 4.1304e-03 -6.0000e+00 3.1122e-03 -1.2198e-02 3.4430e-05 7.8564e-04 -6.0000e+00 8.0752e-04 1.1986e+00 4.9848e-04 8.7431e-06 3.3878e-05 -6.0000e+00 2.0853e-04 -2.9775e-04 1.2667e-05 10 0 0 10 0 0 39.09 17.53 0.87 -0.00030 0.00316 2266 445 1 4 0 2.400 22.90 15.00 17.53 33.14 27.5 1050.04 -326 -266 -25 179 230 494 454 351 399 185 97 -40 -129 -131 -157 -120 -64 74 122 48 136 184 103 238 266 87 13 1 -177 -330 -197 -308 -167 74 -60 -145 -10 -37 -126 -79 2 47 117 222 211 281 235 106 23 -186 -287 -352 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202 193 82 0 -67 -183 -223 -252 -235 SQ 20220918T203434.9Z 8296.857349 535 3 5.83 2 61.43 241.58 96.33 316.79 0.00 1 0.00 1 0 15 2.047e-03 2.054e-03 8.897e-05 8.873e-05 4.408796e+03 5.697253e+00 3.047262e+02 -6.000000e+00 1.148280e+02 284.76 -2.00 20.00 -2.00 505.34 0.00e+00 5.979432e-04 2.467683e-06 4.177013e-05 -6.000000e+00 5.772765e-05 284.76 -2.00 20.00 -2.00 500.55 0.00e+00 3.173087e-02 1.750821e-03 3.275668e-02 -6.000000e+00 4.059763e-02 228.69 -2.00 3.57 -2.00 502.15 0.00e+00 2.081 0.000 489.00 513.00 1 1.7582e-01 1.3421e-04 4.1377e-03 -6.0000e+00 3.1143e-03 -1.1987e-02 3.4221e-05 7.8785e-04 -6.0000e+00 8.0807e-04 1.2069e+00 4.7800e-04 8.7002e-06 3.3817e-05 -6.0000e+00 2.0868e-04 -2.7119e-04 1.2260e-05 10 0 0 10 0 0 34.54 17.53 0.87 -0.00027 0.00304 2266 445 1 4 0 2.400 22.90 15.00 17.53 33.14 27.5 1050.04 -326 -282 -29 157 218 473 450 345 383 180 105 -34 -111 -137 -152 -116 -59 89 121 48 138 192 117 226 243 87 25 0 -189 -339 -203 -307 -165 70 -64 -128 -4 -40 -111 -69 3 42 123 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11 -34 19 -66 -55 81 21 -65 137 177 148 204 199 83 -14 -81 -200 -233 -255 -244 SQ 20220918T203441.0Z 8296.857419 535 4 5.83 2 61.45 241.60 96.35 316.81 0.00 1 0.00 1 0 15 2.047e-03 2.056e-03 8.935e-05 8.911e-05 4.408956e+03 5.729813e+00 3.045950e+02 -6.000000e+00 1.148289e+02 284.76 -2.00 20.00 -2.00 505.33 0.00e+00 6.006068e-04 2.473852e-06 4.182313e-05 -6.000000e+00 5.772812e-05 284.76 -2.00 20.00 -2.00 500.54 0.00e+00 2.926678e-02 1.760181e-03 3.270675e-02 -6.000000e+00 4.059787e-02 228.69 -2.00 3.57 -2.00 502.14 0.00e+00 2.082 0.000 489.00 513.00 1 1.8203e-01 1.3493e-04 4.1368e-03 -6.0000e+00 3.1143e-03 -1.1680e-02 3.4412e-05 7.8648e-04 -6.0000e+00 8.0808e-04 1.1995e+00 4.9746e-04 8.7362e-06 3.3686e-05 -6.0000e+00 2.0868e-04 4.8632e-05 1.0470e-05 10 0 0 10 0 0 96.92 17.53 0.87 0.00005 0.00350 2266 445 1 4 0 2.400 22.90 15.00 17.53 33.14 27.5 1050.04 -322 -283 -41 140 208 463 450 351 392 193 115 -8 -116 -119 -149 -105 -68 79 119 53 136 190 121 246 241 88 30 -2 -200 -355 -212 -308 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188 204 121 195 227 63 124 248 140 96 185 16 -41 22 -57 -52 88 19 -54 134 174 144 219 208 67 -15 -87 -192 -241 -260 -253 SQ 20220918T203447.1Z 8296.857489 535 5 5.76 2 61.46 241.62 96.36 316.83 0.00 1 0.00 1 0 15 1.808e-03 1.794e-03 1.185e-04 1.182e-04 4.412668e+03 7.550850e+00 3.043294e+02 -6.000000e+00 1.014295e+02 284.76 -2.00 20.00 -2.00 505.34 0.00e+00 5.599002e-04 3.278929e-06 3.960504e-05 -6.000000e+00 5.099303e-05 284.76 -2.00 20.00 -2.00 500.61 0.00e+00 5.063809e-02 2.324766e-03 3.249309e-02 -6.000000e+00 3.586788e-02 228.69 -2.00 3.57 -2.00 502.20 0.00e+00 2.083 0.000 489.00 513.00 1 5.6349e-01 1.7782e-04 4.1164e-03 -6.0000e+00 2.7514e-03 -1.1552e-02 4.5655e-05 7.7952e-04 -6.0000e+00 7.1409e-04 8.1811e-01 6.4866e-04 1.1655e-05 3.5468e-05 -6.0000e+00 1.8435e-04 8.0829e-04 -9.5555e-06 10 0 0 10 0 0 99.51 17.53 0.87 0.00081 0.00531 2266 445 1 4 0 2.400 22.90 15.00 17.53 33.14 27.5 1050.04 -252 -192 -1 151 199 440 412 319 357 175 118 4 -60 -69 -104 -93 -65 83 99 20 114 172 83 189 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385 377 375 298 210 173 216 135 171 220 48 98 220 116 59 166 34 -27 26 -33 -19 111 54 -41 144 169 119 181 178 49 -17 -76 -179 -214 -245 -212 SQ 20220918T203453.1Z 8296.857559 535 6 5.82 2 61.48 241.64 96.37 316.85 0.00 1 0.00 1 0 15 1.957e-03 1.942e-03 9.818e-05 9.787e-05 4.405858e+03 6.175412e+00 3.067990e+02 -6.000000e+00 1.097444e+02 284.76 -2.00 20.00 -2.00 505.22 0.00e+00 5.961260e-04 2.695684e-06 4.090422e-05 -6.000000e+00 5.517219e-05 284.76 -2.00 20.00 -2.00 500.46 0.00e+00 3.144998e-02 1.935453e-03 3.021601e-02 -6.000000e+00 3.880222e-02 228.69 -2.00 3.57 -2.00 502.02 0.00e+00 2.084 0.000 489.00 513.00 1 3.1838e-01 1.4840e-04 4.0135e-03 -6.0000e+00 2.9766e-03 -1.1725e-02 3.8299e-05 7.3988e-04 -6.0000e+00 7.7238e-04 1.0461e+00 5.6344e-04 9.6524e-06 4.0561e-05 -6.0000e+00 1.9944e-04 1.7919e-04 5.7540e-06 10 0 0 10 0 0 97.86 17.53 0.87 0.00018 0.00409 2266 445 1 4 0 2.400 22.90 15.00 17.53 33.14 27.5 1050.04 -284 -225 -5 166 220 462 442 329 381 188 110 -29 -111 -107 -132 -111 -65 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-6.0000e+00 2.0101e-04 -6.3492e-04 1.6371e-05 10 0 0 10 0 0 13.30 17.55 0.88 -0.00063 0.00316 616 121 2 4 0 23.010 22.90 15.00 17.55 33.18 27.7 1049.72 -347 -269 -29 122 203 454 439 344 364 187 108 -27 -137 -146 -173 -129 -76 87 109 30 130 189 131 229 254 93 19 -9 -189 -359 -194 -302 -154 61 -44 -112 -9 -74 -144 -89 -13 35 118 235 244 291 223 85 41 -173 -277 -330 -385 -282 -115 -113 -41 33 104 150 139 136 59 114 25 -33 -99 -156 -178 -249 -189 -187 -163 -51 -61 -224 -244 -199 -207 -280 -301 -221 -232 -87 -117 -197 -117 -13 -33 36 73 154 177 129 177 103 -84 -176 -219 -374 -361 -363 -276 -167 -280 -196 -104 -66 -60 11 -7 95 229 323 417 430 408 334 224 171 206 92 155 233 48 115 248 126 69 172 7 -47 24 -51 -11 98 16 -56 139 148 135 178 182 84 -27 -102 -203 -229 -277 -229 -340 -251 -28 121 205 468 458 361 380 193 110 -27 -136 -143 -170 -128 -77 89 115 32 138 201 139 245 272 100 20 -9 -192 -356 -190 -300 -157 65 -47 -121 -9 -78 -150 -92 -14 36 124 251 262 313 237 89 42 -173 -270 -316 -368 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