File name: Pandora108s1_Toronto-West_20220929_L2Fit_fout2c6d20211104p1-8.txt File generation date: 20240820T134403.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v3d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20220929_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20220929 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220929T115505.2Z 8307.496588 61 1 10.54 2 83.37 99.92 125.54 82.72 0.00 1 0.00 1 0 25 6.168e-01 3.746e-02 5.845e-01 4.583e-02 9.361776e-01 2.696127e-02 1.069870e-02 -6.000000e+00 3.629797e-01 227.40 -2.00 3.57 -2.00 322.21 0.00e+00 -1.801881e-02 1.412724e-02 2.760207e-03 -6.000000e+00 1.697278e-02 283.43 -2.00 20.00 -2.00 321.73 0.00e+00 7.876 0.009 302.00 328.00 3 8.5516e-01 1.0295e-01 9.8217e-02 -6.0000e+00 9.0357e-01 1.0368e+00 1.3125e-01 7.3279e-02 -6.0000e+00 9.8133e-01 -1.4249e+00 9.5229e-02 2.6743e-02 -6.0000e+00 5.8733e-01 5.8437e-01 4.5926e-02 1.8086e-02 -6.0000e+00 2.5223e-01 4.0482e-05 -1.2316e-03 1.2914e-03 2.3927e-04 -6.0000e+00 1.8148e-02 3.6871e-04 1.0813e-04 12 9 9 12 1 1 47.38 17.02 0.45 0.00037 -0.00889 10 10 1 5 0 941.780 22.40 15.00 17.02 14.21 26.5 986.90 -72472 900000 900000 900000 -127011 -167197 -106278 84355 -111568 -16688 -97887 -178761 900000 -84932 -4945 25949 900000 900000 145934 -19884 423857 2790 -51604 97228 74238 190722 -9058 41831 49598 8488 -20326 82217 18156 -10035 82608 -48426 117244 26165 900000 -20056 28872 65413 57148 1803 -8706 42094 -32107 161763 55119 36352 -230 51538 19161 49010 49082 4784 57053 12475 64014 40365 12024 19874 17870 11531 -11089 48829 23774 37028 -309 28415 23026 29768 7309 371 -6676 -23438 970 5084 37423 -10711 7736 4981 -239 -4207 4387 4779 -3690 9943 8583 11447 -2919 6567 -3517 -628 -1446 -6832 -3841 -3902 -7308 -5668 -4946 1956 -5009 -4061 -5968 -3210 -3425 -309 -2610 2292 -1370 -958 -1593 1624 1337 346 1606 473 125 -376 1204 1237 4498 983 2778 -993 1911 502 71 2161 -917 1573 -287 1757 -852 -939 423 557 698 -1514 205 -1439 -689 -3235 900000 900000 900000 -5670 -7463 -4744 3765 -4980 -745 -4369 -14002 900000 -3791 -221 1158 900000 900000 6514 -888 18920 125 -2303 4340 3314 8513 -404 1867 2214 379 -907 3670 810 -448 3687 -2718 5234 1168 900000 -1541 1589 2920 2580 133 -667 1926 -2868 7221 2460 1914 -19 2910 1618 3413 3703 577 4433 1467 4418 3228 1199 1922 1939 1499 -1909 4899 3017 4371 -57 4567 4326 5508 1664 85 -1481 -5393 165 838 5059 -2678 1924 1478 -84 -1656 1691 1954 -1702 4154 3606 4541 -1249 2442 -1423 -259 -685 -3975 -2551 -2994 -6485 -5111 -4270 1436 -3547 -2758 -4326 -2424 -2729 -259 -2476 2391 -1692 -1308 -2297 2279 1842 466 2144 659 184 -577 1803 1769 5950 1308 3534 -1278 2333 648 105 3631 -1793 3299 -657 4234 -2268 -2643 1209 1604 2006 -4257 531 -3485 -1572 SS 20220929T120554.6Z 8307.504104 64 1 50.02 2 81.45 101.84 123.71 84.70 0.00 1 0.00 1 0 17 5.829e-01 1.326e-02 3.627e-01 9.304e-03 7.841643e-01 5.274142e-03 8.938741e-03 -6.000000e+00 3.384404e-01 227.40 -2.00 3.57 -2.00 322.01 0.00e+00 6.666452e-03 3.146188e-03 1.775826e-03 -6.000000e+00 1.498945e-02 283.43 -2.00 20.00 -2.00 321.53 0.00e+00 6.340 0.005 302.00 328.00 3 3.7609e-01 2.1173e-02 7.6287e-02 -6.0000e+00 8.3969e-01 3.7401e-01 3.0262e-02 4.5634e-02 -6.0000e+00 9.1019e-01 -4.9736e-01 2.9958e-02 2.5231e-02 -6.0000e+00 5.4275e-01 1.9917e-01 1.3639e-02 1.0073e-02 -6.0000e+00 2.3085e-01 3.2413e-04 -1.0998e-03 2.6856e-04 1.5534e-04 -6.0000e+00 1.6433e-02 1.7883e-03 -4.2730e-06 12 8 8 10 0 0 -8.63 17.02 0.21 0.00179 -0.00648 250 49 1 5 0 200.050 22.40 15.00 17.02 15.33 26.5 993.74 -234815 -186311 -154026 -205028 -144739 -235033 -88728 -241063 -89323 -217486 -93430 -169484 -117899 -72563 -111150 -5533 -60119 -23884 -46008 4683 -88681 -3083 -66894 -48214 10501 -17942 -4812 -58969 21934 -57723 9142 -33259 36458 -7557 13 497 -11657 21486 -12470 32099 5241 28248 7540 17244 14196 9147 35076 12729 23031 8866 23319 15814 23193 14410 17045 14506 14304 -4012 3459 9041 5404 8966 5177 11592 4533 13699 9336 6953 10916 6974 10227 4181 5379 1718 4548 1229 -3052 -3522 -313 -838 67 1384 -2599 1586 -1781 636 -802 -728 -635 -296 1368 -2109 591 -2175 -677 -2538 -201 -432 -597 -1241 -1566 -1175 -1664 -442 -2781 -1885 -1864 -1191 -1020 213 -142 179 483 -270 359 -258 545 -319 138 -364 181 1078 704 1372 376 1298 323 2317 -184 239 181 176 563 -45 -20 -433 338 -122 42 -235 -62 -188 -773 -3680 -2151 -1397 -3044 -1313 -4071 -805 -4971 -810 -4126 -848 -2377 -1264 -658 -1925 -50 -893 -276 -721 51 -2268 -36 -1379 -875 124 -266 -70 -1313 239 -1381 149 -933 601 -212 0 12 -346 532 -525 1033 251 1165 371 868 749 477 1591 693 1311 577 1463 1208 1824 1351 1663 1514 1536 -516 400 964 609 1064 732 1762 806 2248 1595 1262 2088 1593 2521 1065 1460 457 1073 269 -646 -759 -73 -236 22 527 -1063 668 -825 306 -412 -387 -338 -153 708 -1060 280 -1092 -376 -1685 -153 -354 -547 -1178 -1424 -1042 -1335 -340 -2309 -1652 -1728 -1180 -1115 261 -198 270 747 -416 527 -367 766 -471 215 -591 291 1650 1035 1938 518 1713 419 3038 -279 415 352 371 1263 -107 -52 -1186 945 -347 120 -646 -160 -452 -1780 SS 20220929T121957.0Z 8307.513855 69 1 49.88 2 78.99 104.37 121.32 87.19 0.00 1 0.00 1 0 25 3.960e-01 8.061e-03 2.117e-01 3.506e-03 6.562950e-01 1.935225e-03 7.449144e-03 -6.000000e+00 2.299245e-01 227.40 -2.00 3.57 -2.00 321.53 0.00e+00 3.372567e-03 1.005322e-03 8.676966e-04 -6.000000e+00 1.018370e-02 283.42 -2.00 20.00 -2.00 320.96 0.00e+00 5.046 0.002 302.00 328.00 3 2.3816e-01 6.9387e-03 6.1160e-02 -6.0000e+00 5.7045e-01 1.0685e-01 9.7323e-03 3.6906e-02 -6.0000e+00 6.1838e-01 -1.0807e-01 9.8315e-03 2.0095e-02 -6.0000e+00 3.6874e-01 3.1531e-02 4.5963e-03 7.2666e-03 -6.0000e+00 1.5682e-01 1.4479e-03 -8.5330e-04 1.0526e-04 8.9734e-05 -6.0000e+00 1.1166e-02 2.0922e-03 -2.8854e-05 11 8 0 10 0 0 -1.38 17.02 0.18 0.00209 -0.00432 582 114 1 5 0 85.690 22.40 15.00 17.02 16.47 26.5 1001.23 -52539 -184682 -43254 -195633 -21428 -195545 -81229 -172427 -36537 -89454 -100585 -49488 -123141 9373 -89289 26085 -65557 -583 -30400 -12163 -13870 -9408 5743 -37996 24365 -48463 19953 -45237 1278 -19764 -1125 8882 -8904 13243 -18505 17070 -16152 13445 -8405 13123 -1596 4825 7125 -1237 10892 -5572 8259 -2911 8834 940 10585 4627 5953 7187 2428 7839 -344 5175 -1546 4129 47 6118 3628 3856 3334 1402 3491 -834 4424 99 2978 84 1567 -114 -1231 -194 -2810 -220 -3156 252 -2256 -405 -2558 -822 -1371 -752 -149 -168 994 -632 1057 -680 261 -475 277 -96 630 907 -223 49 -798 -244 -830 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