File name: Pandora108s1_Toronto-West_20221012_L2Fit_fout2c6d20211104p1-8.txt File generation date: 20240820T134250.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v3d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20221012_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20221012 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221012T123938.1Z 8320.527525 267 1 50.24 2 78.57 112.19 72.85 279.06 0.00 1 0.00 1 0 25 5.815e-01 1.830e-02 3.489e-01 1.510e-02 6.134904e-01 8.564219e-03 7.122785e-03 -6.000000e+00 3.427487e-01 225.83 -2.00 3.57 -2.00 321.35 0.00e+00 2.732879e-03 4.187643e-03 1.520755e-03 -6.000000e+00 1.735208e-02 281.80 -2.00 20.00 -2.00 320.80 0.00e+00 4.877 0.002 302.00 328.00 3 3.2420e+00 2.9530e-02 5.8411e-02 -6.0000e+00 8.5101e-01 1.0150e-01 4.0180e-02 3.4529e-02 -6.0000e+00 9.2772e-01 -1.3156e-01 3.9495e-02 1.8579e-02 -6.0000e+00 5.4547e-01 4.7755e-02 1.8778e-02 6.0060e-03 -6.0000e+00 2.3470e-01 8.9042e-05 -8.6387e-04 4.7553e-04 8.4592e-05 -6.0000e+00 1.7032e-02 -6.3720e-04 7.8741e-06 12 9 8 11 8 0 99.92 17.12 0.20 -0.00064 -0.00713 40 8 1 5 0 1255.540 22.50 14.99 17.12 19.97 27.0 1016.76 900000 -180820 900000 -89815 900000 900000 -173986 900000 -179890 900000 -182071 900000 -121371 900000 -45677 301279 176697 -37622 900000 -57010 900000 -94493 900000 -36121 223471 1555 13597 75917 -46044 115748 -49983 128373 -25208 158563 -21787 70207 12128 -15058 28969 -8932 40450 -14017 42470 -17002 35177 -5949 14409 11862 16571 32848 -4551 30272 -2760 15025 -3163 19586 -2013 13642 -2851 -398 6348 -2799 15233 -1304 9535 -1585 5927 -1785 4030 2513 2524 6202 -1562 6967 -4771 3996 -8383 5976 -3477 -2384 -42 -2584 2011 -2755 10 -3545 2635 -1729 1331 422 -474 -420 -1544 4651 -3658 2686 -1811 2214 -1774 -388 -931 -519 -920 -690 280 -4563 -64 -3065 2055 -599 261 247 476 168 -359 2214 -1220 981 -1434 678 -467 542 948 901 1023 -666 1681 429 892 -105 539 -257 422 -269 -174 518 -614 799 -940 220 -1022 946 -576 900000 -3234 900000 -1320 900000 900000 -3033 900000 -4148 900000 -4879 900000 -2509 900000 -734 4427 2597 -828 900000 -1702 900000 -4119 900000 -1029 3284 36 290 1116 -1630 1701 -2199 1886 -1192 2330 -1071 1484 461 -848 1310 -681 2204 -1373 2584 -1863 2405 -609 1246 1080 1502 2705 -583 3095 -424 2108 -564 2926 -382 2248 -538 -72 1102 -576 2951 -333 2329 -431 1464 -484 1114 802 899 2250 -616 2417 -1727 1199 -2631 1610 -1113 -880 -18 -1277 1049 -1612 6 -2384 1754 -1250 937 293 -313 -258 -918 2614 -2443 1921 -1564 2092 -1924 -423 -978 -495 -807 -594 253 -4623 -65 -3437 2370 -789 375 380 740 255 -521 2977 -1690 1374 -2184 1059 -746 836 1403 1293 1411 -903 2148 567 1285 -173 962 -495 843 -573 -394 1232 -1526 1988 -2403 541 -2418 2070 -1234 SS 20221012T124503.4Z 8320.531289 270 1 50.10 2 77.67 113.21 73.78 279.93 0.00 1 0.00 1 0 25 2.259e-01 5.879e-03 2.898e-01 7.377e-03 5.843430e-01 3.994496e-03 6.752682e-03 -6.000000e+00 1.303996e-01 225.83 -2.00 3.57 -2.00 321.19 0.00e+00 2.314215e-03 1.857620e-03 5.135851e-04 -6.000000e+00 5.769493e-03 281.80 -2.00 20.00 -2.00 320.63 0.00e+00 4.547 0.002 302.00 328.00 3 2.2579e+00 1.3418e-02 5.4557e-02 -6.0000e+00 3.2254e-01 5.2846e-02 1.8002e-02 3.2155e-02 -6.0000e+00 3.5007e-01 -5.4758e-02 1.7811e-02 1.6952e-02 -6.0000e+00 2.0880e-01 1.2268e-02 8.5905e-03 5.8632e-03 -6.0000e+00 8.8999e-02 3.3677e-04 -8.8261e-04 2.2483e-04 7.1836e-05 -6.0000e+00 6.3640e-03 -5.6414e-04 -6.8892e-06 10 0 0 10 0 0 99.23 17.11 0.17 -0.00056 -0.00720 128 25 1 5 0 391.320 22.50 14.99 17.11 20.29 27.1 1019.30 -17492 -108289 -48775 -52308 -108979 -82728 -85770 -34337 -76418 -57672 -86797 -20584 -45554 -5625 -32637 -19464 -22567 -25741 -5645 -3299 9675 -14326 70 -7682 -6555 -17141 -27688 -5706 -25409 -9924 -20314 2125 3375 4077 -4621 -8861 -515 -3386 1227 976 6003 -79 3013 -2612 7658 201 3632 -868 1353 2017 1225 -1291 503 1925 1038 2517 438 -210 898 -707 4484 4566 4862 2402 2871 1128 2208 823 1714 236 -671 648 154 -586 -1281 -1032 -2488 -963 -2354 -2943 -1959 -652 -886 -831 -1047 -62 -1 812 571 593 512 -716 -490 997 140 35 586 973 254 -542 -262 -397 541 -500 -1630 -1500 -1120 -513 97 848 361 243 366 6 62 521 328 -315 -307 -526 34 168 418 -104 58 -65 274 1524 241 -247 -357 -176 49 -9 -129 -267 165 426 -8 -227 -254 -5 111 -126 -1113 -351 -376 -1148 -670 -760 -247 -789 -544 -1127 -162 -540 -58 -524 -329 -440 -569 -112 -68 184 -342 2 -192 -175 -535 -976 -162 -853 -301 -774 77 139 180 -219 -430 -25 -194 81 77 512 -8 301 -286 772 22 397 -101 161 251 168 -201 85 346 201 500 92 -45 186 -146 901 997 1181 671 844 336 634 243 541 86 -275 277 66 -245 -502 -364 -826 -309 -828 -1207 -928 -348 -522 -523 -703 -44 -1 629 445 451 367 -484 -315 632 98 28 532 997 289 -632 -292 -403 500 -462 -1609 -1582 -1233 -600 121 1170 549 394 598 10 94 743 466 -465 -482 -866 57 272 651 -157 84 -92 370 2077 363 -418 -662 -348 100 -20 -299 -654 415 1086 -21 -573 -612 -11 242 SS 20221012T132046.8Z 8320.556097 286 1 50.16 2 71.91 120.19 79.81 285.65 0.00 1 0.00 1 0 17 2.242e-01 8.830e-03 1.903e-01 9.229e-03 4.202086e-01 4.805752e-03 4.978679e-03 -6.000000e+00 1.294884e-01 225.83 -2.00 3.57 -2.00 320.17 0.00e+00 4.886721e-04 1.595631e-03 2.427038e-04 -6.000000e+00 5.728687e-03 281.80 -2.00 20.00 -2.00 319.52 0.00e+00 3.177 0.001 302.00 328.00 3 3.7025e+00 1.4252e-02 3.8232e-02 -6.0000e+00 3.2028e-01 -1.3843e-02 1.7268e-02 2.2257e-02 -6.0000e+00 3.4760e-01 3.6580e-02 1.4405e-02 1.1243e-02 -6.0000e+00 2.0733e-01 -2.4458e-02 7.3784e-03 3.3551e-03 -6.0000e+00 8.8392e-02 3.4867e-04 -8.1401e-05 2.8900e-04 4.0817e-05 -6.0000e+00 6.3177e-03 -8.6482e-04 4.6099e-05 11 8 0 10 0 0 99.92 17.11 0.13 -0.00086 -0.00148 189 37 1 5 0 265.320 22.50 14.99 17.11 21.64 27.0 1026.60 21693 -10565 -16474 -40240 135675 -25982 192073 -64644 872 -2508 1657 -3349 298 16727 -33600 17969 -21212 33026 -5386 14335 -1309 -4649 5447 -13128 15532 -12574 16057 -19275 9605 235 6055 4103 1440 9440 -8398 13648 -7890 6596 -7860 7330 -4591 402 -2310 -698 1980 -3230 -191 -5421 3810 -2662 4032 -819 3022 2352 -119 2246 -1688 248 -862 4744 -232 3224 1357 2964 -1074 11 2341 -932 2975 180 3024 -786 105 -995 -960 -544 -962 347 -1570 1528 -2559 243 -3320 -636 -481 -254 -109 -547 635 -698 1547 -212 2003 350 1929 -44 27 854 163 -78 -1069 -46 -494 502 -1347 -752 -1019 -547 -176 126 739 -379 804 -711 980 -84 419 -518 175 -365 -635 407 -208 657 -344 730 259 1866 182 -219 -119 -491 408 -382 344 -538 609 -176 343 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