File name: Pandora108s1_Toronto-West_20221027_L2Fit_fout2c6d20211104p1-8.txt File generation date: 20240820T142007.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v3d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20221027_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20221027 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221027T122108.0Z 8335.514676 60 1 50.34 2 85.16 112.97 110.62 101.88 0.00 1 0.00 1 0 25 6.710e-01 1.121e-01 6.092e-01 1.167e-01 8.832200e-01 6.914568e-02 1.038158e-02 -6.000000e+00 3.943031e-01 224.35 -2.00 3.57 -2.00 321.45 0.00e+00 -1.754827e-02 2.027008e-02 1.955421e-03 -6.000000e+00 1.947839e-02 279.90 -2.00 20.00 -2.00 320.78 0.00e+00 10.067 0.020 302.00 328.00 3 8.8131e-02 2.1206e-01 1.1211e-01 -6.0000e+00 9.7720e-01 1.9615e+00 2.4727e-01 5.9917e-02 -6.0000e+00 1.0686e+00 -1.9274e+00 1.4348e-01 2.2196e-02 -6.0000e+00 6.3253e-01 6.4420e-01 7.7422e-02 1.4474e-02 -6.0000e+00 2.7255e-01 8.8471e-06 -1.4126e-03 3.4134e-03 1.8233e-04 -6.0000e+00 2.0109e-02 3.4017e-03 1.0096e-04 12 8 8 10 0 0 74.58 18.10 1.36 0.00340 -0.00721 28 5 1 5 0 1797.310 23.53 15.00 18.10 9.18 26.3 962.09 17911 900000 35708 900000 49131 -73400 79007 -76484 167955 11204 900000 -41552 900000 900000 102485 38893 76011 61507 10143 900000 -29461 900000 84512 144181 23617 196958 12227 26892 36005 -132298 900000 -55255 900000 958 900000 13712 235119 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-11115 900000 3018 10558 3644 6330 10017 -3209 10293 -5578 8382 -7610 18487 -4211 2119 -14905 1603 8217 432 6745 -5919 15831 -3517 16023 931 11218 617 -9131 -2264 -18636 8902 -5907 2660 -10568 13488 -3465 2758 -2221 435 162 -10643 12507 -9341 19918 -2416 1553 -1054 4812 -691 -806 5243 -6497 5485 -17357 14549 -10587 8627 682 6810 6192 -6730 10155 -18143 8066 -333 11894 -9444 10616 463 -13837 3094 -2438 5642 -4713 19109 -16656 13758 -9459 993 SS 20221027T123355.0Z 8335.523554 63 1 50.10 2 83.06 115.28 108.49 103.87 0.00 1 0.00 1 0 25 5.508e-01 2.111e-02 4.361e-01 1.710e-02 7.655854e-01 9.769504e-03 9.060823e-03 -6.000000e+00 3.171985e-01 224.35 -2.00 3.57 -2.00 322.06 0.00e+00 1.464066e-02 5.569471e-03 1.635796e-03 -6.000000e+00 1.517703e-02 279.90 -2.00 20.00 -2.00 321.60 0.00e+00 7.583 0.008 302.00 328.00 3 9.9567e-02 3.7454e-02 8.5831e-02 -6.0000e+00 7.8488e-01 6.5917e-01 5.0623e-02 4.6349e-02 -6.0000e+00 8.5430e-01 -8.4558e-01 4.6961e-02 2.4141e-02 -6.0000e+00 5.0742e-01 3.4200e-01 2.1790e-02 1.4668e-02 -6.0000e+00 2.1835e-01 1.3259e-04 -1.7588e-03 5.1006e-04 2.2270e-04 -6.0000e+00 1.5880e-02 5.1258e-03 1.0052e-05 12 8 8 10 0 0 1.94 18.11 0.31 0.00513 -0.00809 150 29 1 5 0 333.940 23.53 14.99 18.11 9.73 26.2 966.51 -178380 900000 -174744 900000 -182329 42065 -123151 -111688 900000 -153626 900000 -188005 76849 -145824 92766 -66048 42015 -48237 -3692 47377 -9697 70358 -75438 -2055 -30602 67201 -63739 243053 -12925 58448 32927 16477 60980 3580 134552 -13149 151285 -28549 56561 8013 43144 34963 36599 80695 -10791 45044 7856 67040 26829 64789 36053 19218 39116 11142 43816 12814 50307 4472 26540 -1414 34708 20282 24054 26335 10305 21709 8589 27284 8745 23984 2364 8122 4441 4513 5862 -7182 7603 -12136 -3715 -4347 3716 -857 473 -795 -701 709 -1088 2029 -3894 3185 -2807 -1174 -2976 -3363 -2136 -3698 -18 -2443 913 -3555 79 -1272 -280 -2105 -4036 -2841 -2475 -1100 -2798 -98 -1076 2109 -252 375 -647 -50 1028 -924 728 -1272 1452 548 2330 1086 1195 579 2238 2161 114 845 116 1093 -398 569 -608 16 7 422 -86 -952 567 -1417 -216 -4706 900000 -5581 900000 -5317 701 -2052 -1861 900000 -3258 900000 -5744 1281 -5062 1546 -1801 700 -1388 -73 789 -206 1172 -2619 -37 -742 1120 -2124 4050 -255 974 549 399 1109 125 2242 -498 2521 -1470 1457 388 1634 1536 1663 2445 -764 2047 491 2641 1666 2944 2403 1548 2825 1145 3407 1388 4115 522 2396 -165 2892 2140 2806 3438 1717 3256 1455 3940 1652 4430 601 2041 1147 1097 1278 -1596 1351 -2663 -841 -1189 1120 -313 190 -346 -323 342 -563 1054 -2157 1601 -1411 -544 -1356 -1583 -1115 -2311 -13 -2080 840 -3534 72 -1069 -209 -1555 -3206 -2379 -2189 -1035 -2965 -116 -1443 2984 -377 549 -919 -68 1385 -1325 1089 -2028 2246 825 3301 1509 1605 758 2807 2806 171 1449 224 2278 -897 1353 -1567 43 19 1188 -244 -2636 1451 -3450 -495 SS 20221027T124451.2Z 8335.531149 66 1 50.07 2 81.29 117.29 106.68 105.57 0.00 1 0.00 1 0 17 4.778e-01 9.329e-03 2.844e-01 6.628e-03 6.707468e-01 3.661540e-03 7.671183e-03 -6.000000e+00 2.741374e-01 224.35 -2.00 3.57 -2.00 321.65 0.00e+00 4.006805e-03 1.930767e-03 1.323551e-03 -6.000000e+00 1.210579e-02 279.90 -2.00 20.00 -2.00 321.15 0.00e+00 6.235 0.005 302.00 328.00 3 1.3636e-01 1.3192e-02 7.1149e-02 -6.0000e+00 6.7621e-01 1.7246e-01 1.8729e-02 3.7897e-02 -6.0000e+00 7.3516e-01 -1.9560e-01 1.9451e-02 2.1061e-02 -6.0000e+00 4.3848e-01 7.0012e-02 9.0763e-03 7.7027e-03 -6.0000e+00 1.8696e-01 5.3885e-04 -1.1601e-03 2.0090e-04 1.0610e-04 -6.0000e+00 1.3461e-02 5.1734e-03 -1.0414e-06 11 8 0 10 0 0 98.44 18.10 0.22 0.00517 -0.00354 320 63 1 5 0 156.420 23.53 15.00 18.10 10.71 26.2 972.95 -160678 -169495 -38268 -187054 -105055 -235234 -21664 -180413 -115953 -160240 -144630 -110138 -104328 -47153 -80549 53318 -64723 -39450 -44885 -16722 -54173 -21207 8361 -21117 24027 -61819 6037 -45737 -3576 -58574 -18051 -26258 -4709 -3285 -13160 11689 -18565 10187 -6270 20802 662 7357 2865 3999 12503 -2809 5109 988 11722 1332 9793 9626 11024 7349 7755 7169 2941 5820 592 6504 4310 7592 2402 8752 4034 4559 4582 2864 4507 2654 4084 760 2730 -654 -1073 -554 -2244 -1538 -2369 -257 -2293 -26 -2261 -290 -1593 -457 -365 -1082 893 530 1158 -1330 -426 -1246 -384 -929 182 532 -201 -281 -1041 -430 -1145 128 -2477 -1409 -1133 -676 51 246 457 11 473 -253 335 3 685 -304 381 -273 17 596 553 727 -261 415 302 1554 19 248 -249 -95 184 16 22 -488 244 -94 177 -205 -11 -66 -311 -1227 -1693 -247 -2418 -679 -4423 -140 -2332 -974 -2072 -1700 -1036 -1165 -427 -1183 345 -1141 -603 -791 -236 -1146 -324 108 -360 311 -1816 92 -1156 -59 -1790 -435 -833 -141 -106 -464 316 -731 353 -313 953 39 440 190 271 795 -213 369 77 865 117 876 970 1211 915 1028 1000 442 853 89 907 629 1170 444 1721 895 1007 997 651 1100 756 1280 260 918 -217 -328 -152 -579 -394 -675 -85 -912 -12 -1150 -155 -919 -279 -235 -725 590 342 698 -769 -234 -702 -237 -668 151 505 -212 -305 -1082 -403 -983 106 -2243 -1345 -1140 -726 60 320 663 17 750 -395 495 5 960 -448 589 -445 28 935 835 1060 -370 565 399 2079 29 425 -476 -195 397 36 53 -1274 651 -256 481 -545 -27 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