File name: Pandora108s1_Toronto-West_20221122_L2Fit_fout2c6d20211104p1-8.txt File generation date: 20240820T142214.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v3d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20221122_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20221122 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221122T154904.3Z 8361.659078 193 1 50.23 2 66.22 160.68 60.32 178.57 0.00 1 0.00 1 0 17 5.714e-02 8.228e-03 1.493e-01 2.084e-02 3.307480e-01 1.051674e-02 4.027230e-03 -6.000000e+00 3.256896e-02 222.50 -2.00 3.57 -2.00 319.02 0.00e+00 5.410283e-04 2.377645e-03 3.403261e-04 -6.000000e+00 1.428985e-03 276.67 -2.00 20.00 -2.00 318.41 0.00e+00 2.462 0.000 302.00 328.00 3 5.4643e+00 2.8674e-02 2.9480e-02 -6.0000e+00 8.0101e-02 6.7884e-02 3.3005e-02 1.7027e-02 -6.0000e+00 8.7221e-02 1.9322e-02 2.3223e-02 8.6251e-03 -6.0000e+00 5.1994e-02 -1.6561e-02 1.2154e-02 2.5807e-03 -6.0000e+00 2.2205e-02 1.2840e-04 1.7894e-05 6.4398e-04 3.0812e-05 -6.0000e+00 1.6083e-03 4.0990e-03 1.4509e-04 11 8 0 10 0 0 99.90 18.21 0.29 0.00410 0.00423 120 24 1 5 0 418.550 23.64 14.98 18.21 9.80 26.4 1033.72 37970 1219 21081 12480 -16539 -6573 -14662 7439 -20121 -7618 1198 6174 -2887 -16231 7938 -1883 7889 531 -2198 -6382 13719 -12793 -2134 -1313 -10056 -1183 -4299 -6945 -346 7816 -2386 6212 -586 1370 225 -4679 -2002 -801 1179 -774 5058 -669 6056 -1593 -332 988 -1223 -102 -2722 -620 -247 3324 -942 2395 3524 2311 778 -1236 -388 -2132 3676 2653 4044 -340 -599 -1378 1581 -1841 -274 393 -1623 1548 -694 1105 -767 -54 -1521 8 323 -1418 210 -1434 -815 -871 1059 -710 -195 -481 392 155 136 -386 -281 -581 -1819 11 99 1129 259 -68 -99 -1081 1030 -813 -577 -1244 -664 80 805 520 -10 558 250 925 -434 -9 468 -28 -192 -423 171 -210 116 55 349 -177 1124 557 36 66 -390 31 -480 562 -621 17 -175 480 -11 -434 92 -155 76 1187 58 874 541 -847 -297 -740 343 -1306 -469 70 356 -201 -1456 663 -191 784 59 -262 -826 1514 -1803 -278 -179 -1574 -179 -677 -1077 -48 1000 -357 936 -103 247 40 -843 -374 -170 291 -228 1558 -232 2028 -587 -121 358 -449 -37 -997 -225 -95 1318 -417 1083 1651 1120 392 -637 -195 -1077 1793 1400 2284 -217 -390 -866 904 -1065 -163 261 -1212 1178 -546 823 -548 -35 -906 5 185 -925 152 -1176 -716 -809 1023 -749 -215 -554 449 174 143 -374 -253 -504 -1679 11 110 1378 344 -90 -125 -1276 1113 -901 -681 -1579 -873 110 1158 807 -17 949 418 1452 -642 -12 634 -39 -288 -672 279 -339 182 83 503 -246 1466 730 50 100 -629 52 -824 993 -1174 33 -358 994 -23 -899 183 -295 141 SS 20221122T164008.0Z 8361.694537 225 1 50.00 2 64.18 173.68 61.37 192.22 0.00 1 0.00 1 0 17 1.192e-01 1.841e-02 1.239e-01 1.832e-02 3.084056e-01 9.207682e-03 3.760147e-03 -6.000000e+00 6.793717e-02 222.50 -2.00 3.57 -2.00 318.55 0.00e+00 2.174274e-03 1.850450e-03 3.127901e-04 -6.000000e+00 2.980597e-03 276.67 -2.00 20.00 -2.00 317.94 0.00e+00 2.282 0.000 302.00 328.00 3 6.4213e+00 2.4707e-02 2.7341e-02 -6.0000e+00 1.6709e-01 1.4283e-01 2.8249e-02 1.5820e-02 -6.0000e+00 1.8193e-01 6.6215e-03 1.9198e-02 8.1499e-03 -6.0000e+00 1.0845e-01 -1.3244e-02 1.0038e-02 3.0784e-03 -6.0000e+00 4.6323e-02 5.8108e-05 3.3446e-04 5.5718e-04 3.2137e-05 -6.0000e+00 3.3544e-03 3.0742e-03 1.4276e-04 12 9 8 11 8 0 99.74 18.21 0.37 0.00307 0.00559 14 3 1 5 0 3568.260 23.64 14.99 18.21 10.64 26.5 1038.01 50120 -26399 39449 -5755 22854 22624 -9221 50949 -19180 49935 -36169 17635 -3919 29684 14420 34925 16293 -6993 35107 -13200 16883 -16268 8917 -14040 1697 -5935 2760 2462 -11576 9048 -1803 11651 -5875 18950 -7138 6695 -2143 1790 1038 -5271 6055 -4885 6988 -3194 4661 -5954 856 -2625 -2048 3611 -3011 3960 -3504 5478 -1723 4905 -1695 1401 -1112 -641 1807 -2111 2354 608 1544 -1427 -1117 88 1668 1055 -1510 2716 -479 3601 -1451 -36 -5414 -2877 394 -3713 1487 -1331 -311 -1778 674 -2181 1919 -103 2311 317 -418 65 -1100 749 -845 1692 -1097 3122 -1179 425 -1029 -1499 418 -827 -550 -1822 1165 -1639 1632 -376 648 1384 1330 1455 -1167 686 -2162 1001 -2595 90 -235 1764 511 -371 56 -722 2017 -1751 3199 -2095 -654 -2453 -183 -58 -119 1494 347 871 -1054 1275 -1678 765 47 1707 -2028 1711 -366 1019 959 -543 1897 -1511 2181 -3561 1082 -331 2123 1379 3086 1831 -1035 3626 -2253 2201 -2921 1268 -2613 285 -1118 482 413 -2122 1341 -317 1962 -1284 3402 -1588 1265 -468 433 300 -1900 2153 -2057 2696 -1394 1887 -2692 359 -1123 -863 1450 -1358 1783 -1815 2733 -961 2610 -981 787 -628 -357 1005 -1309 1515 430 1096 -995 -722 55 1067 759 -1228 2223 -407 2838 -1130 -25 -3604 -1764 241 -2646 1137 -1159 -289 -1762 690 -2465 2190 -124 2733 372 -462 66 -1037 666 -799 1709 -1271 3838 -1624 576 -1345 -1810 463 -936 -662 -2367 1530 -2327 2356 -593 1069 2329 2191 2255 -1720 927 -2967 1371 -3919 140 -379 2762 788 -556 80 -989 2559 -2298 4224 -3147 -1025 -4053 -301 -98 -214 2781 674 1714 -2136 2472 -3232 1380 83 SS 20221122T171903.4Z 8361.721568 247 1 44.10 2 64.03 183.83 63.54 202.19 0.00 1 0.00 1 0 17 6.025e-02 1.931e-02 5.785e-02 1.032e-02 3.050137e-01 5.180398e-03 3.773155e-03 -6.000000e+00 3.435554e-02 222.50 -2.00 3.57 -2.00 318.55 0.00e+00 -3.489916e-03 1.023804e-03 4.564603e-04 -6.000000e+00 1.507189e-03 276.66 -2.00 20.00 -2.00 317.92 0.00e+00 2.270 0.000 302.00 328.00 3 5.7214e+00 1.3948e-02 2.7431e-02 -6.0000e+00 8.4495e-02 9.1279e-02 1.5911e-02 1.6943e-02 -6.0000e+00 9.1992e-02 6.0255e-03 1.0633e-02 7.9949e-03 -6.0000e+00 5.4839e-02 -1.4474e-02 5.5246e-03 3.8495e-03 -6.0000e+00 2.3429e-02 1.2533e-04 2.7186e-04 3.1718e-04 3.7786e-05 -6.0000e+00 1.6958e-03 2.1371e-03 1.7976e-04 12 9 9 12 1 1 99.97 18.21 0.57 0.00214 0.00418 16 4 1 5 0 2583.670 23.64 15.00 18.21 11.66 26.5 1044.34 -11907 7405 -486 -4321 7627 -31978 5355 -27993 19128 -12645 18736 -4865 2563 761 -2319 9114 -10427 1142 -10288 5176 -10512 2992 -3465 5624 9591 5565 10309 609 2938 -6376 10005 -3451 2697 -2924 -4814 -3394 -4246 5440 1050 7941 224 7364 779 4959 -857 2314 95 -2777 303 -4656 2560 -1652 4488 -1727 4375 2336 3511 -22329 2170 4769 -466 4847 -517 3259 -1903 535 -153 216 2488 -916 2843 511 3043 -726 2115 -2178 -160 -1420 -2245 -547 -2266 -173 -3445 1452 -1481 634 -771 1721 758 460 1630 -820 1238 -1287 2430 -1571 1488 143 784 -327 -767 263 -1387 841 -3105 -410 -1763 -61 285 593 1401 863 605 -345 1521 -507 328 -1492 352 -1131 -197 -52 -337 663 -353 460 -1171 2427 -822 452 -974 -145 -250 91 280 -473 737 162 490 -847 515 -331 -65 -708 406 -30 -262 377 -2198 275 -2233 1115 -1071 1206 -400 216 74 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