File name: Pandora108s1_Toronto-West_20221210_L2Fit_fout2c6d20211104p1-8.txt
File generation date: 20240820T143130.5Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c6p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 108
Spectrometer number: 1
Processing software version used: BlickP v1.8.59
Instrument operation file used: Pandora108_OF_v3d20210713.txt
Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt
Level 1 file used: Pandora108s1_Toronto-West_20221210_L1_smca1c6d20211104p1-8.txt
Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke)
Short location name: Toronto-West
Country of location: Canada
Location latitude [deg]: 43.7094
Location longitude [deg]: -79.5435
Location altitude [m]: 141
Local noon date: 20221210
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 231 373
Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20221210T200127.4Z 8379.834345 515 1 50.27 2 77.26 219.70 109.68 9.49 0.00 1 0.00 1 0 25 4.231e-01 1.305e-02 3.025e-01 1.158e-02 5.330676e-01 6.187565e-03 6.224775e-03 -6.000000e+00 2.439189e-01 222.27 -2.00 3.57 -2.00 320.86 0.00e+00 2.554936e-03 2.489880e-03 5.003816e-04 -6.000000e+00 1.100166e-02 274.61 -2.00 20.00 -2.00 320.36 0.00e+00 4.415 0.002 302.00 328.00 3 3.4158e+00 1.9183e-02 5.1466e-02 -6.0000e+00 6.0098e-01 9.7632e-02 2.4680e-02 2.8870e-02 -6.0000e+00 6.5590e-01 -4.4755e-02 2.4507e-02 1.5042e-02 -6.0000e+00 3.8719e-01 5.7401e-03 1.2237e-02 5.4073e-03 -6.0000e+00 1.6474e-01 1.2450e-04 -8.2744e-04 3.6352e-04 6.4044e-05 -6.0000e+00 1.2223e-02 6.0824e-03 -4.8353e-05 12 8 8 10 0 0 99.49 18.16 0.24 0.00608 -0.00014 38 7 1 5 0 1322.630 23.53 15.01 18.16 3.62 25.9 1018.86 111151 -103220 900000 -65304 900000 -121386 900000 -124230 900000 -84642 291899 11287 -72147 169463 -11872 41226 -32193 103987 -51062 121705 -1620 27211 9282 35011 10762 -18913 64709 -38511 71635 -38653 50991 -21681 12280 1678 -17326 12496 -16653 20009 -10848 25971 -8227 6819 -7572 5709 4372 2554 8469 -6410 12577 -6489 14772 -8207 8074 2888 4079 5855 -2130 4202 -5923 6325 -6757 6613 1801 4182 1458 1959 603 -319 3925 -393 3891 -1874 1770 -1507 1483 -2811 -2930 -168 -2880 2498 -3167 1374 -3073 605 -2408 1071 -608 35 -342 -399 928 -390 2614 -1554 2294 -782 1167 -697 -385 -506 -553 1035 -1020 2084 -2472 -575 -2018 176 425 228 664 -671 1280 -550 1425 -843 1379 -666 -21 -841 -680 658 -375 1200 -946 448 -283 2733 -309 503 41 -613 641 -259 467 -904 530 -281 494 -750 16 222 -193 1254 -1652 900000 -785 900000 -2201 900000 -2737 900000 -1572 3294 127 -1643 1912 -234 589 -994 1173 -2191 1373 -48 629 259 832 341 -833 1359 -2029 1361 -2079 1370 -1307 616 99 -1204 649 -1216 1208 -1050 2115 -1037 807 -1073 738 579 352 1118 -995 1678 -1089 2204 -1679 1546 625 928 1354 -549 1023 -1558 1460 -1811 1695 538 1361 510 673 202 -109 1387 -164 1733 -928 851 -715 637 -1134 -1096 -60 -1137 1082 -1679 790 -2020 409 -1779 821 -497 29 -290 -330 711 -281 1738 -1073 1659 -658 1104 -758 -456 -606 -631 1062 -983 1940 -2554 -623 -2320 211 546 324 1022 -1105 2072 -872 2095 -1200 1915 -974 -32 -1372 -1122 1047 -583 1779 -1376 620 -379 3627 -459 827 73 -1171 1257 -538 1025 -2119 1262 -685 1208 -1803 36 480 -405
SS 20221210T200810.8Z 8379.839013 519 1 49.11 2 78.05 221.07 109.47 11.00 0.00 1 0.00 1 0 17 5.270e-01 2.155e-02 3.603e-01 2.026e-02 5.597166e-01 1.107037e-02 6.523608e-03 -6.000000e+00 3.061256e-01 222.27 -2.00 3.57 -2.00 320.88 0.00e+00 3.120026e-03 4.463719e-03 6.589161e-04 -6.000000e+00 1.515410e-02 274.61 -2.00 20.00 -2.00 320.38 0.00e+00 4.684 0.002 302.00 328.00 3 4.0389e+00 3.4293e-02 5.4299e-02 -6.0000e+00 7.5645e-01 2.0059e-01 4.4098e-02 2.9851e-02 -6.0000e+00 8.2849e-01 -1.0561e-01 4.3253e-02 1.6262e-02 -6.0000e+00 4.8691e-01 3.1417e-02 2.1565e-02 6.2697e-03 -6.0000e+00 2.0863e-01 4.7884e-05 -5.8223e-04 6.3944e-04 7.5809e-05 -6.0000e+00 1.5431e-02 5.1801e-03 4.4536e-05 12 8 8 10 0 0 99.64 18.15 0.21 0.00518 0.00080 16 3 1 5 0 3068.660 23.53 14.99 18.15 3.49 26.0 1017.95 900000 -140518 900000 -41348 212611 900000 -103598 900000 -83258 900000 -112157 900000 -100975 44928 -11456 35389 900000 -53324 168915 -36826 900000 -18456 295732 -32001 105189 -26985 -15697 900000 -40187 277568 -47555 900000 -47262 102512 -53 10734 51548 19511 39144 -25232 25019 -10556 21135 -8873 26680 1196 7183 5734 -7101 39483 -5689 29247 -3797 27922 -15639 8920 333 -3097 10270 -56 18093 -4140 14186 -4652 8467 -3157 3833 -1977 -541 2710 -476 6494 -3360 5533 -5721 5547 -9423 4082 -943 537 -1598 -3355 4718 -4091 2671 -3131 2166 -1303 2075 -1183 -1575 5613 -1250 1693 -3063 1922 -896 741 -1037 -738 -700 -187 614 -1173 -35 -4783 1884 -1179 1125 -1302 816 769 -1059 877 100 1422 -1762 1151 -547 212 -9 869 -198 87 1646 -2068 2586 -834 1999 -287 575 -184 -111 -211 -580 938 -33 958 -1187 89 -843 509 -330 900000 -3260 900000 -816 4193 900000 -2043 900000 -1642 900000 -2802 900000 -2988 886 -228 698 900000 -2210 3332 -1480 900000 -648 5833 -1390 2075 -1260 -674 900000 -2080 5475 -3119 900000 -4095 2418 -3 562 1983 1164 2328 -3255 2248 -1436 2221 -1283 2783 162 934 772 -1115 4181 -1009 4086 -796 4641 -4201 1953 82 -786 2240 -13 3681 -1135 3625 -1595 2682 -1108 1216 -672 -195 1072 -216 2887 -1651 2375 -2548 1993 -3623 1351 -354 230 -811 -1968 2803 -2821 1829 -2430 1674 -1082 1666 -955 -1197 3698 -836 1100 -2272 1537 -846 778 -1213 -871 -786 -190 569 -1097 -34 -5238 2023 -1391 1397 -1829 1228 1225 -1723 1349 147 1953 -2484 1627 -834 335 -15 1347 -299 127 2270 -2851 3275 -1115 2835 -465 1005 -344 -215 -432 -1266 2125 -78 2267 -2892 207 -1891 1064 -673