File name: Pandora108s1_Toronto-West_20230225_L2Fit_fout2c6d20211104p1-8.txt File generation date: 20240820T140722.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v3d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20230225_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20230225 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230225T154541.0Z 8456.656724 158 1 49.53 2 57.92 148.80 80.28 75.27 0.00 1 0.00 1 0 17 3.586e-02 7.203e-03 3.093e-02 4.703e-03 3.223720e-01 2.383612e-03 3.919236e-03 -6.000000e+00 2.063313e-02 225.07 -2.00 3.57 -2.00 318.77 0.00e+00 1.478408e-03 4.943161e-04 2.341997e-04 -6.000000e+00 8.831487e-04 272.91 -2.00 20.00 -2.00 318.21 0.00e+00 1.876 0.000 302.00 328.00 3 5.0239e+00 6.4491e-03 2.4943e-02 -6.0000e+00 5.1099e-02 5.9332e-02 7.3532e-03 1.6695e-02 -6.0000e+00 5.5582e-02 -2.3127e-03 5.1011e-03 8.4909e-03 -6.0000e+00 3.2997e-02 -8.3884e-03 2.6706e-03 2.8183e-03 -6.0000e+00 1.3969e-02 3.5083e-04 1.6975e-05 1.4400e-04 3.1426e-05 -6.0000e+00 1.0099e-03 3.4466e-03 1.0129e-04 11 8 0 10 0 0 99.94 18.27 0.34 0.00345 0.00357 31 6 1 5 0 1597.310 23.64 15.01 18.27 3.65 26.3 1008.92 -5873 6977 -12649 3304 -17139 15351 -21081 -559 -788 -1017 -4352 -2566 5580 -8129 7786 -5195 2465 -3637 3567 -421 2277 844 -1376 3353 -2797 1617 -7099 -266 -4714 1924 -1010 1106 3500 -4362 63 -4802 2410 -3431 1557 -1984 -579 -212 -334 -282 -1056 1537 -2637 1169 -1831 1530 413 2010 1475 1611 1579 102 1650 -760 1758 -40 1748 1758 1877 1868 -883 600 -537 982 313 1844 -990 874 -130 124 -224 -784 -29 -1456 -97 -1567 -623 -2075 -1179 -1186 -1117 -508 -688 663 -122 790 -438 268 27 1131 699 7 1085 246 409 -773 320 -1657 306 -221 -840 -1269 -1214 -73 109 1267 -227 472 -201 282 147 467 435 -132 429 -500 72 -141 669 -68 551 -12 310 1252 -181 93 -520 289 -76 509 -315 -217 -52 -170 242 -475 257 -464 90 -277 327 -744 161 -926 578 -1171 -28 -45 -61 -274 -164 374 -723 691 -589 278 -460 439 -56 303 114 -193 473 -443 256 -1237 -41 -733 276 -160 188 638 -897 12 -931 463 -806 415 -644 -205 -80 -129 -112 -422 604 -1070 451 -722 590 170 872 689 791 811 54 882 -417 924 -21 930 1003 1159 1247 -614 394 -333 585 196 1274 -775 705 -107 98 -167 -534 -18 -862 -59 -1072 -476 -1783 -1080 -1145 -1140 -552 -786 777 -144 906 -476 267 25 996 648 7 1221 307 549 -1049 410 -1997 340 -249 -1010 -1632 -1623 -101 159 1950 -375 795 -334 443 215 640 589 -185 635 -789 116 -226 1037 -102 790 -17 407 1631 -252 139 -828 474 -127 878 -577 -416 -103 -343 490 -950 494 -862 163 SS 20230225T181234.5Z 8456.758733 248 1 1.02 2 53.53 192.74 54.34 99.30 0.00 1 0.00 1 0 17 2.024e-02 6.753e-03 1.983e-02 4.857e-03 3.112744e-01 2.456510e-03 3.816282e-03 -6.000000e+00 1.164491e-02 225.07 -2.00 3.57 -2.00 317.73 0.00e+00 5.845330e-04 3.878752e-04 1.425595e-04 -6.000000e+00 4.984597e-04 272.92 -2.00 20.00 -2.00 317.18 0.00e+00 1.678 0.000 302.00 328.00 3 2.5370e+00 6.4884e-03 2.3128e-02 -6.0000e+00 2.8840e-02 4.5004e-02 7.3102e-03 1.6032e-02 -6.0000e+00 3.1371e-02 -1.1364e-02 4.6031e-03 8.0354e-03 -6.0000e+00 1.8624e-02 -3.7616e-03 2.3416e-03 2.3547e-03 -6.0000e+00 7.8829e-03 5.2390e-03 -1.5016e-04 1.4408e-04 2.7089e-05 -6.0000e+00 5.7008e-04 3.5562e-03 6.6903e-05 12 9 1 12 1 1 96.29 18.20 0.15 0.00356 0.00243 4 58 1 5 0 169.330 23.64 15.01 18.20 6.95 26.8 1019.87 6066 -9913 -3671 -3400 -9394 -2078 -9002 2008 -4451 1970 -5679 -5875 -1843 -1952 2217 -3457 -195 -289 856 -1239 1326 -2417 1808 527 -324 -1366 -2053 49 -1664 812 -204 889 387 -1465 -2761 -2144 1118 -360 1339 -724 -248 -547 464 -1126 544 214 -781 294 -730 398 1723 1725 1014 1246 1480 1636 730 -302 1205 131 720 1433 1687 1803 -885 147 838 -117 1407 988 -164 -287 -255 -786 -210 24 -500 -580 310 -854 -441 -2063 -2381 -1070 -630 -906 -429 -326 -247 -220 -230 472 117 1112 811 411 577 766 -85 -1179 35 -385 1131 48 -993 -1067 -859 -596 53 340 309 -106 19 220 318 520 486 312 413 -103 -285 49 416 407 720 136 509 1628 408 212 -316 -96 -314 259 138 -250 -438 -40 -117 -87 -282 -436 -44 426 -902 -326 -290 -773 -152 -733 163 -430 189 -596 -635 -215 -262 329 -602 -35 -54 166 -255 271 -515 375 116 -76 -338 -515 11 -379 177 -48 222 106 -424 -782 -588 315 -117 504 -320 -119 -278 240 -600 286 113 -412 152 -377 205 916 972 609 780 959 1076 493 -206 799 87 483 1012 1268 1440 -729 116 620 -86 1052 811 -147 -267 -239 -720 -182 19 -374 -414 225 -683 -387 -1987 -2431 -1127 -691 -1049 -513 -402 -304 -267 -265 509 119 1090 826 449 683 973 -114 -1600 46 -473 1311 56 -1234 -1390 -1150 -826 76 509 480 -169 30 331 453 707 654 430 595 -155 -438 75 622 593 1014 186 672 2129 559 307 -479 -149 -493 415 230 -434 -775 -71 -211 -154 -491 -739 -74 SS 20230225T181746.1Z 8456.762340 251 1 49.48 2 53.74 194.31 53.43 100.26 0.00 1 0.00 1 0 17 6.520e-02 1.489e-02 7.487e-02 1.209e-02 3.174978e-01 6.119165e-03 3.818792e-03 -6.000000e+00 3.752018e-02 225.07 -2.00 3.57 -2.00 318.67 0.00e+00 2.234090e-03 1.242221e-03 1.601687e-04 -6.000000e+00 1.605913e-03 272.92 -2.00 20.00 -2.00 318.13 0.00e+00 1.687 0.000 302.00 328.00 3 6.1239e+00 1.6479e-02 2.3464e-02 -6.0000e+00 9.2923e-02 7.8243e-02 1.8783e-02 1.6672e-02 -6.0000e+00 1.0107e-01 2.9532e-03 1.2814e-02 8.2974e-03 -6.0000e+00 5.9999e-02 -8.2652e-03 6.6815e-03 3.2488e-03 -6.0000e+00 2.5404e-02 1.3794e-04 5.1952e-04 3.6762e-04 3.3563e-05 -6.0000e+00 1.8360e-03 3.6351e-03 1.6182e-04 12 8 8 10 0 0 99.85 18.19 0.60 0.00364 0.00754 33 6 1 5 0 1498.050 23.64 14.99 18.19 7.43 26.8 1023.75 -6465 -505 9327 -7120 30740 -33829 18110 -10345 22860 -19452 -10320 -11286 -8705 2254 -3306 9799 -7707 8795 -6267 5104 -3946 5423 -5226 -251 3260 -7361 5409 -12352 10635 -9496 9804 -3431 4601 -742 -645 5143 -4841 7864 -3958 680 -2648 1648 -3561 1893 -1592 -2519 981 -2464 2952 -4112 6224 -1564 4118 -342 2243 93 208 22519 -1261 59 -1679 3438 27 1996 -1039 -1507 859 -688 2431 -980 2523 -1524 1461 -1698 791 -2170 -708 -2192 -1871 618 -2629 695 -3344 721 -2433 -447 -874 -75 1183 378 1502 -1416 1018 -1293 1321 -1453 962 927 359 86 -281 379 -845 1279 -1986 -407 -1864 533 213 376 654 -66 825 -1440 156 -1265 579 -1167 490 -598 197 1503 246 967 -530 803 -224 2355 -975 824 -168 -413 1098 -575 626 -800 824 -512 585 -498 -137 -134 -819 -343 -28 496 -426 1186 -2249 773 -630 1136 -1505 -743 -848 -721 196 -352 1033 -1025 1056 -906 691 -594 748 -805 -39 511 -1331 872 -2265 1494 -1598 1469 -638 869 -154 -129 944 -1039 1721 -1153 222 -984 625 -1463 756 -659 -1060 396 -1015 1144 -1721 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