File name: Pandora108s1_Toronto-West_20230610_L2Fit_fout2c6d20211104p1-8.txt File generation date: 20240820T151741.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v3d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20230610_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20230610 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230610T110206.0Z 8561.459792 190 1 28.22 2 76.99 70.48 54.16 176.47 0.00 1 0.00 1 0 25 5.025e-01 1.655e-02 3.674e-01 1.553e-02 6.529436e-01 8.912674e-03 7.528069e-03 -6.000000e+00 3.009638e-01 232.59 -2.00 3.57 -2.00 321.36 0.00e+00 4.863150e-03 4.354560e-03 1.305171e-03 -6.000000e+00 1.444895e-02 283.81 -2.00 20.00 -2.00 320.79 0.00e+00 4.327 0.001 302.00 328.00 3 3.6138e+00 3.1030e-02 5.6168e-02 -6.0000e+00 7.6059e-01 1.7630e-01 4.1574e-02 3.6669e-02 -6.0000e+00 8.2461e-01 -2.1030e-01 3.9766e-02 1.9698e-02 -6.0000e+00 4.8491e-01 7.5422e-02 1.8858e-02 7.4946e-03 -6.0000e+00 2.0545e-01 9.2270e-05 -8.1753e-04 4.7893e-04 1.0025e-04 -6.0000e+00 1.4609e-02 5.7545e-03 -9.1474e-06 12 9 9 12 9 1 99.76 17.98 0.28 0.00575 -0.00039 17 6 1 5 0 1555.740 23.32 15.00 17.98 20.18 28.1 985.97 900000 -185436 900000 -175050 -61778 -105391 -207187 900000 -181535 900000 -166294 900000 -10957 900000 -111152 20704 -6044 -7541 900000 -79292 900000 -81946 900000 -43164 242682 -7712 -11121 26890 -34287 117001 -644 91075 -3378 100397 -16613 90309 -22678 -14866 -10251 15967 37997 1235 29799 6788 33399 341 13870 16333 -4728 18740 5086 15471 3331 29755 -2007 14953 4286 10833 -1954 846 7746 1846 12386 -181 11808 -3241 10551 -4555 9288 2992 1523 2989 -3772 3498 -4691 7571 -4634 3493 296 -1143 -2709 -3168 -605 -3271 -489 -3415 1454 -645 4281 -2012 813 186 -3112 282 -3095 1592 -1664 2570 -622 -271 -1032 205 -1072 -2028 -179 -3817 -157 -2338 1275 -894 1474 268 -118 -209 10 1051 -541 493 -855 782 -521 1692 -91 144 1024 -162 1689 442 1054 -76 913 78 495 -344 -350 -427 -190 375 -135 34 -168 178 -876 900000 -3462 900000 -3184 -934 -1594 -4804 900000 -4091 900000 -3666 900000 -166 900000 -3187 313 -91 -125 900000 -2901 900000 -3171 900000 -1281 3670 -185 -281 472 -1049 1769 -18 1377 -131 1627 -775 1559 -1180 -835 -662 959 2083 103 1999 586 2284 33 1195 1419 -523 1765 600 1833 487 3656 -356 2336 764 1821 -363 151 1322 364 2473 -46 2831 -898 2507 -1283 2479 966 555 1129 -1525 1254 -1687 2178 -1396 966 92 -424 -1194 -1603 -329 -1950 -301 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17.98 0.38 0.00563 0.00193 21 17 1 5 0 566.810 23.43 15.00 17.98 21.17 28.0 992.33 -127777 17851 -159477 900000 -145744 20145 -136881 70620 -78722 -90144 900000 -101100 94192 -69772 89364 -50902 61546 -42738 12434 12299 16490 12919 -48117 71768 -25041 50198 -17606 29518 -22460 -8339 8087 -10990 22198 -16413 23319 -20459 22662 -13804 18149 2215 8934 12333 6531 19909 -3683 15797 -5010 9893 -2704 8722 1971 6362 5690 1520 8407 12 7691 -21769 9324 -2216 2482 2390 2100 4859 1246 5362 -2854 5092 -872 2045 1571 2001 908 1903 1596 -2127 1562 -4574 2299 -3832 81 -1708 -754 -1821 -1913 114 -379 1516 -647 2702 -513 939 -953 119 326 -1403 1201 -729 753 -1647 291 -1597 205 -1447 -778 -1126 -1529 -80 -1116 978 -411 1274 -137 807 81 171 232 121 689 -689 233 -552 842 -224 1190 125 176 1221 -252 879 -342 129 -1031 179 -177 145 267 340 -86 -715 731 -1108 291 -1694 141 -3524 900000 -2620 159 -2405 559 -1051 -1458 900000 -2107 745 -1589 707 -1387 655 -1320 246 259 344 283 -1935 1036 -970 1031 -695 731 -880 -295 280 -525 889 -1013 978 -1280 1022 -1030 1217 207 883 1280 746 2064 -480 1740 -681 1189 -379 1156 306 1047 1037 312 1725 3 1719 -6508 2023 -528 575 601 589 1479 412 1687 -944 1590 -312 809 693 926 428 849 665 -829 546 -1665 847 -1733 41 -995 -477 -1242 -1388 87 -304 1240 -541 2133 -392 663 -653 81 241 -1193 1139 -792 879 -1989 331 -1691 197 -1406 -795 -1230 -1751 -96 -1455 1376 -638 2057 -226 1273 123 246 334 179 1077 -1139 386 -899 1308 -341 1723 177 241 1684 -383 1469 -625 248 -2086 376 -395 339 641 828 -211 -1722 1666 -2438 613 SS 20230610T112313.9Z 8561.474466 196 1 15.41 2 73.36 73.82 54.04 182.76 0.00 1 0.00 1 0 17 2.085e-01 8.996e-03 2.201e-01 7.770e-03 5.358640e-01 4.220935e-03 6.293201e-03 -6.000000e+00 1.243527e-01 232.59 -2.00 3.57 -2.00 320.64 0.00e+00 1.871461e-03 1.654105e-03 1.665144e-03 -6.000000e+00 5.487949e-03 283.81 -2.00 20.00 -2.00 320.00 0.00e+00 3.437 0.001 302.00 328.00 3 3.4333e+00 1.3225e-02 4.5396e-02 -6.0000e+00 3.1219e-01 4.9300e-02 1.6726e-02 3.0532e-02 -6.0000e+00 3.3729e-01 -4.9210e-02 1.5187e-02 1.5589e-02 -6.0000e+00 1.9953e-01 9.4838e-03 7.5430e-03 4.5906e-03 -6.0000e+00 8.3649e-02 2.9878e-04 -5.0007e-04 2.3559e-04 6.2769e-05 -6.0000e+00 5.9956e-03 6.1412e-03 -1.5092e-05 12 9 1 12 1 1 70.70 17.98 0.21 0.00614 0.00238 15 10 1 5 0 951.980 23.32 15.00 17.98 22.28 27.9 998.51 -74688 -15803 15890 -94295 900000 -102233 900000 -96706 41815 -67772 -31200 -68607 35205 -13917 -27577 13316 -38250 46005 -28676 13808 -14487 18768 -9433 -6918 53 -18991 18336 -22913 14810 -29222 16607 -12151 11806 4065 -9621 17586 -5576 -2719 -6756 8445 -3207 5404 -2288 3115 4467 -965 489 -2517 3381 -1636 7917 -924 3020 547 6013 2574 1772 2902 -966 -1917 -3437 4521 -119 4671 365 2241 -16 -45 2591 -558 3175 -775 1540 -845 763 -1607 -290 -2168 -1520 -958 -2119 -1470 -2906 -807 -1004 868 -134 905 915 140 676 -863 667 -2661 424 -739 1430 534 313 -374 7 -821 -1784 396 -2283 -96 -1648 -69 -179 995 784 164 433 11 420 -314 100 -400 893 -219 125 383 256 631 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