File name: Pandora108s1_Toronto-West_20230701_L2Fit_fout2c6d20211104p1-8.txt File generation date: 20240820T153354.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v3d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20230701_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20230701 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230701T111650.9Z 8582.470033 157 1 50.16 2 75.16 72.04 128.64 269.40 0.00 1 0.00 1 0 25 1.961e-01 6.784e-03 1.483e-01 3.933e-03 5.151781e-01 2.135534e-03 6.000962e-03 -6.000000e+00 1.161605e-01 233.00 -2.00 3.57 -2.00 320.81 0.00e+00 6.607720e-04 8.783017e-04 1.278130e-03 -6.000000e+00 5.092167e-03 285.79 -2.00 20.00 -2.00 320.14 0.00e+00 3.827 0.001 302.00 328.00 3 2.1708e+00 6.8932e-03 4.7540e-02 -6.0000e+00 2.9191e-01 1.8999e-02 8.7943e-03 2.9407e-02 -6.0000e+00 3.1505e-01 -2.2610e-02 7.9173e-03 1.4480e-02 -6.0000e+00 1.8726e-01 -2.6688e-04 3.8968e-03 4.0102e-03 -6.0000e+00 7.8838e-02 7.7067e-04 -4.7668e-04 1.2172e-04 5.2585e-05 -6.0000e+00 5.5380e-03 5.5235e-03 -5.5737e-05 11 8 0 10 0 0 52.77 17.74 0.17 0.00552 0.00194 161 32 1 5 0 311.490 23.11 15.00 17.74 26.64 28.5 990.52 -82619 32544 -77659 39265 -106358 20699 -109466 -3817 -67061 -26440 -38189 -43274 -5032 -29448 20262 -27823 3212 -26609 3670 -7539 3788 -6046 -9641 3383 -13845 11008 -19214 5754 -18671 135 -3524 231 2662 -4803 3215 -10968 5540 -6558 6383 -2903 2458 -1296 639 2221 -322 3919 -436 3900 -3076 2033 -1548 2925 1981 850 2051 574 2440 -1879 2367 -1032 2997 693 3293 2801 1297 1108 -29 1378 -67 3327 -203 1550 311 -12 -237 -1378 -247 -3702 560 -2640 -136 -2077 -1165 -1687 -685 -34 -273 1309 -96 1218 32 704 -812 172 -35 -174 538 172 933 -761 -82 -1344 -270 -866 -1017 -1674 -1217 -469 54 828 319 870 183 421 -171 210 -88 -105 137 -412 234 -112 929 -104 296 81 -63 892 74 215 -319 86 -503 175 -254 -90 -110 294 199 -162 134 -407 0 -998 159 -1100 191 -1807 109 -2013 -31 -1078 -318 -536 -689 -67 -592 312 -770 74 -878 98 -237 111 -197 -336 113 -587 394 -930 215 -856 5 -162 12 150 -310 189 -731 342 -532 554 -329 297 -176 89 314 -47 560 -66 572 -495 326 -280 557 417 195 495 146 630 -510 606 -270 772 199 1018 965 472 396 -10 478 -25 1387 -98 770 158 -6 -109 -576 -94 -1426 222 -1243 -72 -1271 -772 -1200 -513 -27 -231 1131 -85 1030 26 522 -579 121 -27 -149 522 189 1107 -926 -94 -1438 -265 -856 -1072 -1895 -1435 -585 71 1196 501 1432 303 668 -258 299 -126 -154 214 -680 390 -185 1464 -160 436 115 -86 1231 112 359 -578 163 -999 362 -563 -209 -265 716 489 -389 309 -895 1 SS 20230701T112741.9Z 8582.477569 160 1 50.24 2 73.29 73.75 130.51 271.19 0.00 1 0.00 1 0 17 3.076e-01 8.962e-03 1.864e-01 5.288e-03 4.761484e-01 2.847163e-03 5.609681e-03 -6.000000e+00 1.822426e-01 233.00 -2.00 3.57 -2.00 320.55 0.00e+00 1.420257e-03 1.069644e-03 1.299166e-03 -6.000000e+00 7.987147e-03 285.79 -2.00 20.00 -2.00 319.86 0.00e+00 3.423 0.001 302.00 328.00 3 2.7579e+00 8.8851e-03 4.3018e-02 -6.0000e+00 4.5798e-01 1.7568e-02 1.1050e-02 2.6941e-02 -6.0000e+00 4.9422e-01 -3.2357e-03 9.5500e-03 1.3447e-02 -6.0000e+00 2.9376e-01 -8.5358e-03 4.7782e-03 3.8159e-03 -6.0000e+00 1.2372e-01 6.4644e-04 -3.2314e-04 1.6430e-04 5.0758e-05 -6.0000e+00 8.6849e-03 5.2716e-03 1.5788e-05 11 8 0 10 0 0 99.90 17.74 0.26 0.00527 0.00284 204 40 1 5 0 246.230 23.11 15.00 17.74 27.52 28.4 996.43 -76307 277082 -84851 69103 -84477 53198 -43263 -8956 11871 -39933 67286 -53410 68556 -41933 36665 -22561 20385 251 -3525 -2123 -6485 26440 -19725 30138 -21661 16691 -14145 9617 -7422 790 8052 -5980 12242 -2871 15781 -13224 7560 -7397 3711 -1398 -1324 2019 -1323 4819 -2692 7848 -4726 2018 -3908 1875 1518 669 5246 -883 4579 -1377 3277 -2405 1799 -1715 421 1480 1743 4179 9 3615 -2081 2412 -1196 1874 -588 680 352 158 1369 -1988 1229 -4666 562 -3303 -644 -2426 -1472 -738 -958 654 -453 1496 -571 1935 -847 907 -526 -80 375 -808 912 161 1587 -1193 -10 -1643 -13 -978 -1151 -1193 -1303 199 -446 1661 -189 1008 66 467 -58 -121 379 -405 634 -605 470 -244 558 -145 389 -175 -168 1122 -425 570 -550 249 -642 49 -279 -110 -23 137 505 -395 487 -664 117 -1281 1429 -1873 377 -1715 305 -631 -108 134 -765 515 -1293 654 -1289 666 -804 542 9 -134 -84 -276 850 -992 1035 -1279 734 -842 448 -394 40 422 -404 789 -226 1027 -1112 564 -740 402 -189 -200 319 -225 797 -483 1296 -888 359 -750 354 311 151 1236 -237 1234 -407 955 -746 527 -515 127 478 620 1602 4 1411 -821 914 -502 865 -309 372 195 84 675 -916 506 -1970 240 -1677 -366 -1584 -1039 -550 -761 550 -406 1368 -533 1723 -727 710 -393 -58 295 -719 908 181 1916 -1491 -12 -1805 -13 -993 -1247 -1382 -1579 253 -608 2423 -304 1674 110 743 -87 -172 534 -595 982 -999 783 -402 884 -223 573 -250 -229 1533 -635 931 -979 464 -1246 99 -601 -249 -54 326 1211 -931 1093 -1434 243 SS 20230701T113420.5Z 8582.482182 164 1 50.23 2 72.14 74.80 131.66 272.31 0.00 1 0.00 1 0 17 1.639e-01 6.794e-03 1.313e-01 4.096e-03 4.444726e-01 2.185759e-03 5.181216e-03 -6.000000e+00 9.710786e-02 233.00 -2.00 3.57 -2.00 320.34 0.00e+00 -4.419818e-04 7.666015e-04 5.215889e-04 -6.000000e+00 4.256298e-03 285.79 -2.00 20.00 -2.00 319.63 0.00e+00 3.215 0.001 302.00 328.00 3 2.7289e+00 6.6769e-03 4.0054e-02 -6.0000e+00 2.4403e-01 -1.0100e-02 8.1721e-03 2.4488e-02 -6.0000e+00 2.6336e-01 1.8931e-02 6.8746e-03 1.1942e-02 -6.0000e+00 1.5654e-01 -1.6685e-02 3.4791e-03 3.3594e-03 -6.0000e+00 6.5917e-02 8.5495e-04 -2.0399e-04 1.2776e-04 3.9677e-05 -6.0000e+00 4.6285e-03 5.4281e-03 -1.0091e-05 11 8 0 10 0 0 98.85 17.75 0.16 0.00543 0.00390 203 40 1 5 0 247.390 23.11 15.00 17.75 28.00 28.5 998.85 114135 -58338 64062 -48416 25041 -22523 -16669 26017 -31981 25088 -43498 58589 -29914 38951 -12269 10310 -4190 270 5872 -15652 3599 -19301 16240 -8100 10343 238 11051 -1275 -1548 4891 -11117 10602 -5862 7028 -9100 3123 -4231 2420 318 -17 2483 -1972 2764 -3101 4150 -2678 2301 -1707 -1447 145 64 2522 -1086 3309 -1096 4327 -573 -6770 287 1512 1179 1124 2758 999 2529 -1002 1675 -1364 1866 684 911 1085 -53 1085 -1212 618 -2153 -145 -2212 -236 -1414 -1471 -1639 -1806 -261 -652 826 207 1378 561 938 231 -29 341 -392 529 -72 1454 -87 -37 -906 -773 -821 -297 -825 -1254 -519 -938 431 180 897 243 636 108 39 -112 -188 -180 -514 296 -368 404 133 317 -122 179 -92 501 223 -249 246 -403 22 -203 72 -173 46 469 124 -12 -56 5 -487 456 -1187 466 -936 236 -316 -238 288 -669 340 -1131 656 -849 706 -415 325 -164 11 240 -825 164 -1104 691 -467 542 15 623 -78 -92 276 -802 702 -508 572 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