File name: Pandora108s1_Toronto-West_20231122_L2Fit_fwvt1c6d20211104p1-8.txt File generation date: 20240820T165236.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v3d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20231122_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20231122 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1653 1802 Nominal wavelengths inside fitting window [nm]: 492.1141 492.2350 492.3559 492.4768 492.5976 492.7185 492.8393 492.9601 493.0809 493.2016 493.3224 493.4431 493.5638 493.6845 493.8052 493.9259 494.0466 494.1672 494.2878 494.4084 494.5290 494.6496 494.7701 494.8907 495.0112 495.1317 495.2522 495.3726 495.4931 495.6135 495.7339 495.8543 495.9747 496.0951 496.2154 496.3358 496.4561 496.5764 496.6967 496.8169 496.9372 497.0574 497.1776 497.2978 497.4180 497.5382 497.6583 497.7785 497.8986 498.0187 498.1388 498.2588 498.3789 498.4989 498.6189 498.7389 498.8589 498.9789 499.0988 499.2187 499.3387 499.4585 499.5784 499.6983 499.8181 499.9380 500.0578 500.1776 500.2973 500.4171 500.5368 500.6566 500.7763 500.8960 501.0156 501.1353 501.2549 501.3746 501.4942 501.6138 501.7333 501.8529 501.9724 502.0920 502.2115 502.3310 502.4504 502.5699 502.6893 502.8087 502.9281 503.0475 503.1669 503.2862 503.4056 503.5249 503.6442 503.7635 503.8827 504.0020 504.1212 504.2404 504.3596 504.4788 504.5980 504.7171 504.8363 504.9554 505.0745 505.1935 505.3126 505.4316 505.5507 505.6697 505.7887 505.9076 506.0266 506.1455 506.2645 506.3834 506.5023 506.6211 506.7400 506.8588 506.9776 507.0964 507.2152 507.3340 507.4527 507.5715 507.6902 507.8089 507.9276 508.0462 508.1649 508.2835 508.4021 508.5207 508.6393 508.7578 508.8764 508.9949 509.1134 509.2319 509.3504 509.4688 509.5873 509.7057 509.8241 509.9425 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231122T155845.2Z 8726.665801 196 1 50.63 2 65.62 163.10 125.58 53.54 0.00 1 0.00 1 0 15 2.622e-03 2.613e-03 1.341e-03 1.336e-03 2.256359e+03 7.907240e+01 1.622654e+02 -6.000000e+00 1.423380e+02 276.67 -2.00 20.00 -2.00 505.26 0.00e+00 6.556078e-04 3.617288e-05 3.843920e-05 -6.000000e+00 7.249872e-05 276.67 -2.00 20.00 -2.00 500.37 0.00e+00 1.908970e-01 2.647715e-02 1.880884e-02 -6.000000e+00 5.186519e-02 222.50 -2.00 3.57 -2.00 501.98 0.00e+00 2.406 0.000 489.00 513.00 1 7.5753e+00 2.0254e-03 3.8446e-03 -6.0000e+00 3.9692e-03 1.1687e-02 5.2414e-04 4.6710e-04 -6.0000e+00 1.0319e-03 6.9939e-04 1.1863e-03 1.3241e-04 2.4632e-05 -6.0000e+00 2.6710e-04 1.4621e-03 -5.1336e-05 10 0 0 10 0 0 99.82 18.23 0.88 0.00146 0.00969 15 3 1 4 0 3374.380 23.64 15.00 18.23 11.55 28.7 1013.92 -185 -627 44 -194 208 464 344 346 328 287 -26 158 -437 -27 -386 -232 -64 289 260 -106 218 1 250 101 400 -47 176 -96 -310 -250 -476 -127 -287 378 -148 9 -53 80 -138 -142 -84 -29 424 -115 392 413 291 302 19 58 -450 -95 -658 -167 -316 198 -131 100 267 -52 273 160 175 -93 199 -146 67 -241 54 -380 -142 -240 -265 140 -51 -68 -585 8 -452 -233 -390 -188 -397 -183 13 -420 22 -154 75 -171 210 199 288 306 83 135 -189 -28 -222 -339 -432 -388 -257 -5 -272 -129 43 -460 -59 -52 220 103 272 230 379 449 333 489 107 558 92 253 192 70 47 268 180 63 43 -276 156 -267 -107 -316 125 40 -186 165 80 352 107 283 117 140 -101 53 -101 -446 -289 -411 -178 -617 44 -200 217 491 368 371 349 302 -28 163 -447 -28 -391 -236 -66 302 277 -114 233 1 267 108 429 -51 187 -101 -319 -251 -476 -128 -295 396 -158 9 -56 84 -143 -147 -87 -30 443 -121 415 436 305 313 20 58 -441 -91 -633 -162 -314 200 -135 103 274 -53 280 165 180 -96 203 -147 67 -238 53 -368 -136 -232 -259 138 -51 -66 -565 7 -429 -221 -371 -180 -382 -177 12 -412 22 -151 74 -168 208 199 289 306 83 132 -181 -27 -206 -311 -397 -363 -247 -5 -270 -128 43 -447 -57 -50 215 102 272 231 382 455 338 494 107 552 90 245 186 68 46 261 175 61 42 -267 149 -253 -100 -293 116 37 -178 159 79 345 105 280 116 140 -101 52 -98 -425 -272 -387 SQ 20231122T160320.0Z 8726.668982 199 1 13.46 2 65.39 164.25 124.92 54.61 0.00 1 0.00 1 0 15 2.579e-03 2.570e-03 1.394e-03 1.390e-03 2.119242e+03 8.158820e+01 1.505619e+02 -6.000000e+00 1.400503e+02 276.67 -2.00 20.00 -2.00 505.28 0.00e+00 6.195146e-04 3.755952e-05 3.678792e-05 -6.000000e+00 7.132713e-05 276.67 -2.00 20.00 -2.00 500.47 0.00e+00 1.914107e-01 2.738594e-02 1.823372e-02 -6.000000e+00 5.100958e-02 222.50 -2.00 3.57 -2.00 502.07 0.00e+00 2.385 0.000 489.00 513.00 1 6.7482e+00 2.0904e-03 3.7882e-03 -6.0000e+00 3.9040e-03 1.0784e-02 5.4249e-04 4.4940e-04 -6.0000e+00 1.0144e-03 1.6052e-03 3.7520e-04 1.3788e-04 2.3585e-05 -6.0000e+00 2.6275e-04 -1.0100e-04 -1.3113e-05 12 1 1 12 1 1 94.08 18.22 0.90 -0.00010 0.00250 7 6 1 4 0 1681.370 23.64 15.00 18.22 11.72 28.6 1014.63 -687 -359 -405 210 62 410 646 318 604 78 111 -100 9 -371 -91 -298 -165 -28 90 136 -203 374 -110 319 192 297 30 54 -225 -416 -208 -556 21 237 229 -213 19 -38 -25 -149 21 292 139 452 88 455 69 227 166 -225 -287 -321 -529 -391 6 -66 -10 181 158 -50 310 306 31 143 -54 104 -351 -15 -220 -201 -120 -195 -172 -123 175 -167 -137 -247 10 -537 -462 -380 -219 -136 45 -119 -305 283 -102 80 -52 162 336 40 239 -9 189 -412 -191 -333 -435 -540 -79 34 -117 -77 -16 -72 -214 111 -172 310 108 322 469 347 546 269 170 -20 124 -207 283 58 62 217 65 327 27 360 -72 21 -175 -25 -118 175 134 -211 29 32 92 -12 402 -69 92 -233 -4 -294 -506 -135 -668 -356 -415 220 63 423 674 334 629 80 113 -100 9 -387 -94 -295 -166 -29 94 143 -216 395 -116 338 205 315 32 56 -227 -410 -202 -548 22 246 242 -227 19 -39 -26 -152 22 301 145 476 94 481 73 235 168 -222 -276 -322 -529 -373 6 -67 -10 186 162 -52 318 316 32 147 -56 105 -349 -14 -212 -193 -114 -187 -167 -121 171 -162 -131 -233 9 -504 -435 -361 -209 -131 44 -117 -301 277 -100 79 -51 164 342 40 241 -9 183 -390 -176 -304 -398 -506 -76 34 -118 -78 -16 -71 -210 109 -172 315 111 333 460 342 540 266 167 -21 124 -206 281 57 62 217 65 325 27 356 -71 21 -167 -24 -112 168 132 -212 28 31 89 -12 393 -68 90 -226 -4 -289 -492 -131 SQ 20231122T160720.5Z 8726.671766 202 1 5.29 2 65.20 165.27 124.33 55.54 0.00 1 0.00 1 0 15 2.778e-03 2.766e-03 2.449e-03 2.445e-03 2.144163e+03 1.425170e+02 1.567542e+02 -6.000000e+00 1.508261e+02 276.67 -2.00 20.00 -2.00 505.27 0.00e+00 5.757902e-04 6.625168e-05 3.564004e-05 -6.000000e+00 7.681627e-05 276.67 -2.00 20.00 -2.00 500.47 0.00e+00 1.739769e-01 4.815067e-02 1.767631e-02 -6.000000e+00 5.494033e-02 222.50 -2.00 3.57 -2.00 502.06 0.00e+00 2.369 0.000 489.00 513.00 1 6.7916e+00 3.6836e-03 3.7458e-03 -6.0000e+00 4.2047e-03 7.6387e-03 9.5324e-04 4.4681e-04 -6.0000e+00 1.0927e-03 1.5436e-03 3.1071e-04 2.4212e-04 2.4154e-05 -6.0000e+00 2.8298e-04 1.4280e-04 -2.2129e-05 12 1 1 12 1 1 999.00 18.23 0.76 0.00014 0.00230 2 5 1 4 0 1760.370 23.64 15.01 18.23 11.93 28.7 1016.23 -271 -465 -11 257 224 281 160 464 531 -18 -183 210 -318 -98 -222 -318 76 340 96 -174 448 328 304 44 -78 318 -100 98 -554 -228 -538 -42 -163 311 37 -208 88 -144 4 -91 81 -294 504 -25 186 258 135 320 -79 -160 -336 73 -733 243 -466 -88 -102 273 -121 66 418 33 478 -168 184 137 -264 -228 -27 -293 -148 171 -590 -58 196 -12 -356 -263 -119 143 -378 -380 -105 -588 214 -287 -30 -402 29 21 -131 18 144 165 -153 431 -67 153 -125 -533 -674 -122 27 -204 -154 -94 348 -164 -10 181 36 -204 245 292 11 308 277 574 380 411 -179 -50 136 -254 -106 68 427 121 259 60 425 -37 239 -361 -36 309 -425 58 -147 123 161 355 335 140 150 -166 -137 -608 -322 -183 -263 -458 -11 261 231 292 169 488 556 -19 -189 214 -323 -99 -224 -321 78 351 100 -183 470 345 319 47 -82 335 -105 102 -566 -229 -538 -42 -166 322 39 -218 92 -149 4 -93 83 -303 520 -26 194 269 140 328 -80 -160 -330 71 -712 237 -464 -89 -104 279 -124 67 425 33 487 -172 187 137 -264 -225 -27 -286 -144 166 -580 -57 193 -12 -347 -253 -114 137 -364 -367 -102 -575 209 -282 -29 -396 29 20 -130 18 145 166 -152 423 -65 146 -118 -500 -634 -116 26 -202 -153 -93 343 -161 -10 178 36 -203 246 294 11 312 281 580 382 409 -177 -49 133 -250 -104 67 419 118 253 58 411 -36 227 -343 -34 295 -413 56 -145 121 160 354 334 140 150 -165 -134 -588 -308 -175 SQ 20231122T161630.9Z 8726.678135 208 1 49.20 2 64.81 167.60 122.97 57.61 0.00 1 0.00 1 0 15 3.233e-03 3.205e-03 2.044e-03 2.036e-03 2.274027e+03 1.210997e+02 1.659824e+02 -6.000000e+00 1.755438e+02 276.67 -2.00 20.00 -2.00 505.26 0.00e+00 6.353292e-04 5.509845e-05 3.667180e-05 -6.000000e+00 8.941048e-05 276.67 -2.00 20.00 -2.00 500.34 0.00e+00 2.000953e-01 4.043175e-02 1.834418e-02 -6.000000e+00 6.396105e-02 222.50 -2.00 3.57 -2.00 501.95 0.00e+00 2.335 0.000 489.00 513.00 1 8.0356e+00 3.0924e-03 3.7332e-03 -6.0000e+00 4.8949e-03 1.1971e-02 8.0062e-04 4.6138e-04 -6.0000e+00 1.2725e-03 4.4563e-04 6.3259e-04 2.0170e-04 2.4517e-05 -6.0000e+00 3.2940e-04 -9.1300e-05 -3.7706e-05 10 0 0 10 0 0 99.22 18.24 0.79 -0.00009 0.00430 16 3 1 4 0 3074.190 23.64 15.00 18.24 12.48 28.7 1019.53 -53 -767 -28 -255 304 279 435 411 96 251 -138 298 -457 164 -456 89 13 182 247 -253 332 21 311 63 405 -20 150 -75 -391 45 -665 7 -349 379 -282 -56 -121 -105 -200 29 210 -147 339 -110 646 335 303 439 -236 155 -824 65 -932 243 -516 55 -28 238 188 -168 217 -48 375 -156 237 -363 137 -277 122 -392 3 -129 -256 316 -30 191 -459 50 -388 -379 -550 -482 -15 -406 81 -509 146 -78 -10 -214 302 358 422 359 -178 437 -474 243 -395 -175 -656 -553 -231 56 -164 -213 429 -693 -134 -294 220 134 408 98 372 484 361 552 -179 363 40 -68 321 126 240 439 33 13 172 -178 269 -320 271 -423 -146 249 -350 482 -311 342 -77 388 -121 201 -55 -93 83 -311 -204 -437 -51 -755 -29 -264 319 298 468 444 103 267 -145 308 -469 166 -463 90 13 192 265 -273 357 23 335 68 437 -22 161 -80 -404 45 -667 7 -361 399 -303 -61 -129 -111 -209 30 218 -153 356 -117 686 356 319 456 -242 155 -810 62 -896 234 -514 55 -29 245 194 -173 223 -50 387 -161 242 -367 136 -273 118 -379 3 -124 -249 310 -29 186 -442 48 -366 -357 -521 -459 -15 -392 78 -499 142 -76 -10 -210 298 356 423 359 -177 424 -455 227 -363 -159 -598 -514 -220 55 -162 -211 417 -673 -129 -286 215 133 407 99 376 489 366 558 -180 359 39 -66 309 122 232 425 32 13 165 -172 256 -301 251 -390 -134 232 -333 463 -304 335 -76 383 -120 200 -54 -91 80 -294 -191 -408