File name: Pandora108s1_Toronto-West_20231123_L2Fit_fwvt1c6d20211104p1-8.txt File generation date: 20240820T165240.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v3d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20231123_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20231123 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1653 1802 Nominal wavelengths inside fitting window [nm]: 492.1141 492.2350 492.3559 492.4768 492.5976 492.7185 492.8393 492.9601 493.0809 493.2016 493.3224 493.4431 493.5638 493.6845 493.8052 493.9259 494.0466 494.1672 494.2878 494.4084 494.5290 494.6496 494.7701 494.8907 495.0112 495.1317 495.2522 495.3726 495.4931 495.6135 495.7339 495.8543 495.9747 496.0951 496.2154 496.3358 496.4561 496.5764 496.6967 496.8169 496.9372 497.0574 497.1776 497.2978 497.4180 497.5382 497.6583 497.7785 497.8986 498.0187 498.1388 498.2588 498.3789 498.4989 498.6189 498.7389 498.8589 498.9789 499.0988 499.2187 499.3387 499.4585 499.5784 499.6983 499.8181 499.9380 500.0578 500.1776 500.2973 500.4171 500.5368 500.6566 500.7763 500.8960 501.0156 501.1353 501.2549 501.3746 501.4942 501.6138 501.7333 501.8529 501.9724 502.0920 502.2115 502.3310 502.4504 502.5699 502.6893 502.8087 502.9281 503.0475 503.1669 503.2862 503.4056 503.5249 503.6442 503.7635 503.8827 504.0020 504.1212 504.2404 504.3596 504.4788 504.5980 504.7171 504.8363 504.9554 505.0745 505.1935 505.3126 505.4316 505.5507 505.6697 505.7887 505.9076 506.0266 506.1455 506.2645 506.3834 506.5023 506.6211 506.7400 506.8588 506.9776 507.0964 507.2152 507.3340 507.4527 507.5715 507.6902 507.8089 507.9276 508.0462 508.1649 508.2835 508.4021 508.5207 508.6393 508.7578 508.8764 508.9949 509.1134 509.2319 509.3504 509.4688 509.5873 509.7057 509.8241 509.9425 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231123T141048.5Z 8727.590839 190 1 51.79 2 75.42 138.24 133.07 5.07 0.00 1 0.00 1 0 22 2.772e-03 2.767e-03 1.282e-03 1.278e-03 2.945360e+03 7.737247e+01 2.035620e+02 -6.000000e+00 1.504488e+02 276.56 -2.00 20.00 -2.00 505.34 0.00e+00 1.254355e-03 3.484690e-05 7.229851e-05 -6.000000e+00 7.663550e-05 276.56 -2.00 20.00 -2.00 500.53 0.00e+00 3.528260e-01 2.518055e-02 2.760080e-02 -6.000000e+00 5.482663e-02 222.49 -2.00 3.57 -2.00 502.14 0.00e+00 3.893 0.001 489.00 513.00 1 7.3045e+00 1.9253e-03 6.1799e-03 -6.0000e+00 4.1959e-03 5.5339e-03 4.9215e-04 6.6647e-04 -6.0000e+00 1.0904e-03 7.2850e-04 6.3249e-04 1.2677e-04 3.6387e-05 -6.0000e+00 2.8238e-04 -1.5247e-03 -1.0224e-05 10 0 0 10 0 0 97.25 18.25 0.87 -0.00152 0.00286 15 3 1 4 0 3451.870 23.64 15.00 18.25 10.55 28.6 1005.83 -547 -429 -67 141 251 265 475 360 625 8 228 -70 -193 -158 -416 -291 19 175 -13 -103 163 254 40 322 335 291 263 -167 11 -495 -337 -486 -141 94 36 -105 24 50 -304 -8 -118 293 209 411 252 637 20 226 190 -295 -371 -439 -538 -425 -192 -52 14 203 345 265 34 326 72 252 -28 -56 -166 -154 -266 -403 166 -537 -197 -210 98 -306 -165 -343 -198 -404 -308 -302 -471 -74 -184 -38 -109 -136 -203 -197 283 -54 463 18 272 -84 66 -365 -190 -427 -478 -379 -360 164 -334 110 -62 -121 -350 -99 117 175 312 389 617 289 537 328 146 292 313 -25 317 237 -31 583 -63 372 -68 58 -59 -189 -127 -209 -83 9 -2 -35 86 55 218 82 209 -24 15 -49 -228 -177 -538 0 -526 -422 -68 147 268 289 523 368 686 8 244 -74 -202 -163 -430 -303 20 175 -13 -107 168 261 41 333 348 301 270 -169 11 -517 -347 -508 -140 96 37 -109 24 50 -307 -8 -119 297 215 425 263 661 21 230 189 -287 -352 -409 -500 -401 -186 -52 14 206 350 268 34 333 74 257 -28 -56 -163 -149 -255 -383 156 -512 -190 -204 96 -296 -156 -321 -184 -375 -288 -284 -447 -71 -177 -37 -106 -132 -197 -192 278 -54 466 18 270 -82 63 -340 -173 -385 -432 -350 -345 161 -335 110 -61 -118 -341 -97 116 177 319 399 636 300 559 341 151 296 313 -25 313 236 -31 580 -63 370 -68 58 -58 -183 -121 -198 -79 9 -2 -35 88 57 224 85 217 -25 16 -50 -231 -175 -526 0 SQ 20231123T143541.7Z 8727.608122 200 1 49.69 2 72.59 143.54 132.28 13.08 0.00 1 0.00 1 0 15 2.495e-03 2.494e-03 1.488e-03 1.481e-03 2.967457e+03 9.014472e+01 2.177332e+02 -6.000000e+00 1.354036e+02 276.56 -2.00 20.00 -2.00 505.28 0.00e+00 1.269651e-03 4.025588e-05 7.170914e-05 -6.000000e+00 6.897217e-05 276.56 -2.00 20.00 -2.00 500.30 0.00e+00 3.150239e-01 2.958916e-02 2.475390e-02 -6.000000e+00 4.934512e-02 222.49 -2.00 3.57 -2.00 501.93 0.00e+00 3.295 0.001 489.00 513.00 1 7.6392e+00 2.2709e-03 5.3563e-03 -6.0000e+00 3.7764e-03 8.1908e-03 5.8165e-04 6.1296e-04 -6.0000e+00 9.8141e-04 5.6820e-04 8.5340e-04 1.4620e-04 3.4951e-05 -6.0000e+00 2.5414e-04 -1.3348e-03 -1.2596e-05 10 0 0 10 0 0 72.93 18.21 0.88 -0.00133 0.00458 13 3 1 4 0 3821.760 23.64 15.00 18.21 10.87 28.6 1007.21 -359 -424 92 -166 253 264 568 137 584 20 -98 155 -471 -18 -588 -191 -43 175 74 -2 265 282 -5 89 427 77 318 28 -246 -306 -340 -212 -127 188 -21 37 -98 69 -84 -345 -165 185 186 83 354 475 77 223 345 -188 -224 -335 -679 -213 -255 46 -156 121 257 164 168 373 -25 75 -140 -141 -44 -222 32 -270 129 -258 -143 -10 -20 -376 -138 -99 -253 -123 -289 -284 -319 -182 275 -191 -217 -51 -31 -257 259 -17 350 229 218 113 -22 -151 -235 -329 -499 -341 -328 190 -363 14 8 -416 -75 -111 105 19 292 344 445 247 380 309 113 414 122 195 24 62 118 375 -45 426 34 -34 116 -380 135 -392 65 48 131 16 -31 130 194 179 172 87 -92 -68 -215 -214 -439 -152 -339 -410 92 -170 265 282 614 149 629 21 -103 160 -484 -18 -597 -195 -45 186 80 -2 290 308 -5 98 470 85 347 30 -257 -311 -343 -216 -133 203 -23 41 -108 74 -90 -368 -176 199 202 84 360 483 78 222 363 -194 -224 -330 -669 -212 -262 49 -154 120 254 162 167 371 -25 74 -138 -137 -42 -228 32 -270 128 -259 -145 -9 -19 -353 -137 -97 -247 -120 -285 -281 -319 -170 257 -181 -205 -49 -29 -244 248 -16 342 224 210 107 -20 -136 -225 -312 -474 -305 -305 181 -353 13 8 -395 -71 -105 102 19 289 343 445 250 385 312 113 407 119 187 23 60 114 362 -43 410 32 -32 110 -357 124 -360 59 45 125 16 -30 128 194 179 173 88 -93 -67 -209 -204 -414 -143 SQ 20231123T144435.2Z 8727.614296 206 1 49.52 2 71.66 145.50 131.86 15.88 0.00 1 0.00 1 0 15 2.683e-03 2.676e-03 1.376e-03 1.370e-03 3.026239e+03 8.326639e+01 2.238638e+02 -6.000000e+00 1.456125e+02 276.56 -2.00 20.00 -2.00 505.28 0.00e+00 1.117083e-03 3.727811e-05 6.349049e-05 -6.000000e+00 7.417174e-05 276.56 -2.00 20.00 -2.00 500.31 0.00e+00 2.480252e-01 2.734823e-02 2.432953e-02 -6.000000e+00 5.306154e-02 222.49 -2.00 3.57 -2.00 501.94 0.00e+00 3.138 0.001 489.00 513.00 1 7.5607e+00 2.0978e-03 5.0945e-03 -6.0000e+00 4.0608e-03 9.6304e-03 5.3747e-04 6.1207e-04 -6.0000e+00 1.0552e-03 6.3274e-04 6.0112e-04 1.3487e-04 3.3787e-05 -6.0000e+00 2.7330e-04 -6.7436e-04 -1.1147e-05 10 0 0 10 0 0 78.80 18.22 0.93 -0.00067 0.00350 13 3 1 4 0 3808.410 23.64 15.00 18.22 10.83 28.5 1006.52 -733 -351 98 59 188 236 403 220 537 57 218 -108 -220 -163 -437 -355 -43 367 -10 72 -156 337 -4 376 156 263 346 -126 -55 -616 -245 -351 -122 18 180 -136 121 -45 -106 -114 89 224 106 282 211 727 3 322 54 -221 -54 -449 -583 -343 6 -89 -52 166 261 -37 96 80 -3 217 1 84 -23 -117 -186 -450 95 -276 -181 -79 159 -225 -232 -386 -168 -180 -358 -307 -475 39 -68 -2 -69 31 -22 97 74 47 396 173 361 36 32 -69 -223 -414 -527 -542 -236 67 -413 -25 -212 -183 -187 -30 -73 109 310 280 447 148 641 182 335 193 271 30 324 134 144 649 -104 281 -28 60 -262 -110 -241 -95 -59 114 -33 40 90 39 405 107 260 189 21 -32 -389 -185 -724 -208 -698 -341 98 61 198 254 439 241 583 61 230 -113 -227 -166 -445 -365 -45 392 -11 79 -172 370 -5 414 172 291 378 -136 -58 -633 -249 -360 -129 20 183 -139 122 -49 -114 -122 96 241 107 287 216 740 3 321 57 -229 -55 -444 -576 -343 6 -87 -51 165 260 -37 95 80 -3 216 1 82 -22 -111 -189 -453 95 -277 -170 -75 151 -212 -233 -383 -165 -176 -354 -305 -441 37 -64 -2 -65 29 -21 93 72 46 389 170 349 34 30 -63 -214 -393 -503 -489 -220 64 -404 -24 -204 -174 -177 -28 -71 107 308 281 450 150 650 184 336 191 264 29 311 129 140 626 -101 271 -27 58 -251 -103 -223 -87 -54 107 -31 39 88 39 403 107 261 191 21 -32 -381 -177 -686 -197 SQ 20231123T144926.6Z 8727.617669 209 1 50.27 2 71.17 146.59 131.60 17.39 0.00 1 0.00 1 0 15 2.578e-03 2.572e-03 1.313e-03 1.307e-03 2.949222e+03 7.885188e+01 2.207499e+02 -6.000000e+00 1.399235e+02 276.56 -2.00 20.00 -2.00 505.25 0.00e+00 1.066992e-03 3.552780e-05 6.014040e-05 -6.000000e+00 7.127387e-05 276.56 -2.00 20.00 -2.00 500.30 0.00e+00 2.538207e-01 2.610227e-02 2.299822e-02 -6.000000e+00 5.098859e-02 222.49 -2.00 3.57 -2.00 501.91 0.00e+00 3.061 0.001 489.00 513.00 1 7.4453e+00 2.0042e-03 4.9360e-03 -6.0000e+00 3.9022e-03 6.6334e-03 5.1481e-04 5.8816e-04 -6.0000e+00 1.0140e-03 7.1812e-04 8.6179e-04 1.2907e-04 3.3528e-05 -6.0000e+00 2.6262e-04 -2.2474e-03 -1.6091e-06 10 0 0 10 0 0 78.08 18.22 0.92 -0.00225 0.00373 15 3 1 4 0 3350.260 23.64 15.01 18.22 10.80 28.6 1006.72 -597 -468 -254 93 299 284 382 308 560 -39 258 -78 -181 -176 -292 -196 -200 93 44 210 123 399 -28 395 373 268 225 48 -242 -446 -434 -227 -215 63 122 -236 -123 -215 -112 -101 63 217 182 208 298 520 146 250 4 -51 -464 -470 -559 -300 -37 -55 43 41 158 -28 157 238 -28 225 -44 -24 -143 -126 -239 -413 163 -74 3 65 47 -268 -234 -342 -117 -279 -408 -269 -147 -27 -30 -51 -315 103 -258 -6 11 210 469 309 196 96 27 -128 -151 -518 -433 -508 -284 127 -484 42 -23 -272 -236 -183 43 211 86 325 567 288 546 191 340 208 267 -48 135 192 90 383 281 358 -24 119 -133 -137 -146 -233 -125 35 -89 55 49 171 174 30 338 113 43 -142 -205 -279 -368 -241 -559 -448 -251 94 311 301 410 332 597 -41 268 -81 -184 -177 -293 -199 -206 98 47 227 134 432 -30 429 407 292 243 51 -251 -451 -435 -230 -224 68 133 -258 -133 -230 -118 -107 67 231 196 226 300 567 158 267 5 -52 -461 -459 -545 -296 -38 -57 46 44 156 -27 155 235 -28 221 -43 -26 -147 -127 -239 -410 160 -73 3 66 48 -270 -232 -335 -113 -270 -398 -264 -145 -27 -31 -48 -297 96 -243 -6 10 202 455 299 188 90 25 -124 -144 -487 -408 -491 -262 121 -469 41 -22 -256 -222 -173 41 205 84 322 564 289 547 192 338 203 257 -46 129 184 87 367 269 342 -23 113 -126 -127 -134 -212 -114 32 -84 53 48 168 172 30 337 113 43 -141 -199 -265 -344 -226 SQ 20231123T145428.7Z 8727.621166 212 1 49.87 2 70.68 147.72 131.30 18.95 0.00 1 0.00 1 0 15 2.438e-03 2.431e-03 1.134e-03 1.132e-03 2.640973e+03 6.745127e+01 1.860650e+02 -6.000000e+00 1.323121e+02 276.56 -2.00 20.00 -2.00 505.28 0.00e+00 1.029249e-03 3.064260e-05 5.959074e-05 -6.000000e+00 6.739569e-05 276.56 -2.00 20.00 -2.00 500.45 0.00e+00 2.443765e-01 2.235684e-02 2.345890e-02 -6.000000e+00 4.820865e-02 222.49 -2.00 3.57 -2.00 502.04 0.00e+00 2.988 0.000 489.00 513.00 1 7.2322e+00 1.7098e-03 4.8460e-03 -6.0000e+00 3.6895e-03 5.2874e-03 4.4146e-04 5.6457e-04 -6.0000e+00 9.5859e-04 8.9954e-04 5.7449e-04 1.1224e-04 3.1728e-05 -6.0000e+00 2.4832e-04 -3.7749e-03 1.7184e-05 10 0 0 10 0 0 84.34 18.23 0.86 -0.00377 0.00021 18 4 1 4 0 2769.590 23.64 15.01 18.23 10.80 28.6 1006.61 -367 -487 76 -8 130 310 375 307 505 37 -16 54 -267 -75 -453 -103 -164 186 217 -58 209 111 138 217 383 155 234 -271 -220 -454 -415 -211 -256 257 15 -101 -62 -82 -19 36 8 148 381 135 482 486 269 72 165 -94 -354 -335 -574 -340 -81 43 -149 55 108 85 144 110 272 0 147 -70 17 -281 -54 -441 -154 -159 -250 -44 53 -68 -242 -212 -329 -200 -348 -339 -239 -221 -40 -125 -90 -183 66 -240 73 196 300 176 53 132 -157 -125 -226 -335 -409 -489 -181 51 -248 -149 192 -322 -48 -200 91 -17 263 309 397 404 477 419 234 457 212 8 172 70 106 364 255 21 102 140 103 -244 31 -312 -157 162 -50 118 76 363 -138 119 -60 177 -35 -85 -83 -288 -280 -424 -351 -475 76 -9 135 325 397 326 533 39 -17 55 -271 -75 -455 -104 -168 194 229 -62 221 118 147 231 407 165 247 -283 -224 -455 -413 -211 -262 268 16 -107 -66 -85 -20 37 8 154 397 142 508 511 281 74 168 -94 -347 -323 -553 -330 -81 43 -153 56 111 87 148 113 280 0 149 -70 17 -277 -53 -428 -149 -154 -245 -44 53 -67 -234 -203 -313 -190 -332 -325 -230 -215 -39 -122 -88 -179 65 -237 72 196 301 177 53 129 -151 -118 -210 -308 -378 -459 -174 50 -246 -148 189 -314 -47 -195 90 -17 264 312 403 410 485 426 236 455 208 8 168 69 104 356 249 20 99 137 99 -233 29 -292 -147 154 -48 115 75 360 -137 119 -60 177 -35 -84 -82 -277 -266 -404 SQ 20231123T150435.8Z 8727.628192 215 1 50.39 2 69.73 150.03 130.64 22.03 0.00 1 0.00 1 0 15 2.298e-03 2.274e-03 5.303e-04 5.290e-04 2.096847e+03 3.054134e+01 1.508711e+02 -6.000000e+00 1.247071e+02 276.56 -2.00 20.00 -2.00 505.23 0.00e+00 9.532277e-04 1.421745e-05 5.472138e-05 -6.000000e+00 6.352212e-05 276.56 -2.00 20.00 -2.00 500.51 0.00e+00 1.818891e-01 1.034340e-02 1.855524e-02 -6.000000e+00 4.543773e-02 222.49 -2.00 3.57 -2.00 502.07 0.00e+00 2.857 0.000 489.00 513.00 1 5.8032e+00 7.8881e-04 4.5021e-03 -6.0000e+00 3.4775e-03 -1.7205e-03 2.0632e-04 4.5877e-04 -6.0000e+00 9.0349e-04 3.8509e-03 4.2331e-04 5.2650e-05 2.9088e-05 -6.0000e+00 2.3405e-04 1.3903e-03 -1.4203e-05 10 0 0 10 0 0 97.75 18.26 0.86 0.00139 0.00433 72 14 1 4 0 699.720 23.64 15.00 18.26 10.90 28.5 1006.62 -540 -299 -96 158 159 437 494 324 480 110 201 -173 -159 -263 -231 -211 -115 105 123 86 -17 195 68 297 197 147 131 68 -177 -445 -251 -390 -122 28 103 -89 49 -11 -131 5 1 150 57 335 224 451 234 120 123 -235 -294 -474 -495 -434 -47 -100 54 34 101 189 136 200 84 188 25 56 -210 -60 -200 -301 -219 -258 -132 -106 62 -297 -177 -274 -209 -274 -289 -219 -223 -77 -162 -148 -151 74 -69 -38 62 170 282 119 158 72 -19 -296 -123 -407 -416 -432 -224 23 -241 -76 -161 -94 -179 49 1 109 226 307 443 320 577 302 353 149 231 -22 226 187 108 249 121 194 68 239 20 -76 -29 -207 -145 27 43 -116 141 99 202 122 245 124 74 -75 -239 -271 -464 -284 -530 -300 -92 155 160 447 513 338 497 113 203 -173 -156 -256 -224 -207 -115 108 128 90 -18 205 72 314 209 155 138 70 -178 -437 -244 -384 -123 29 109 -95 51 -11 -135 5 1 156 60 354 238 479 247 125 125 -234 -284 -451 -469 -418 -47 -102 56 35 104 195 141 209 88 196 26 57 -210 -59 -196 -291 -211 -250 -130 -105 61 -293 -171 -262 -198 -261 -276 -210 -217 -75 -161 -148 -151 74 -69 -38 63 175 292 124 162 73 -19 -285 -115 -378 -389 -413 -221 23 -249 -78 -164 -95 -179 49 1 113 221 302 438 318 575 301 348 145 221 -23 230 178 103 238 115 185 64 227 19 -76 -29 -201 -142 26 40 -111 136 97 198 120 244 124 74 -73 -231 -255 -432 -265 SQ 20231123T151553.5Z 8727.636036 219 1 45.62 2 68.76 152.66 129.81 25.39 0.00 1 0.00 1 0 15 2.296e-03 2.280e-03 8.910e-04 8.885e-04 2.085705e+03 5.219228e+01 1.473436e+02 -6.000000e+00 1.246236e+02 276.56 -2.00 20.00 -2.00 505.27 0.00e+00 8.242311e-04 2.404996e-05 4.848282e-05 -6.000000e+00 6.348705e-05 276.56 -2.00 20.00 -2.00 500.43 0.00e+00 1.967316e-01 1.755367e-02 1.892664e-02 -6.000000e+00 4.543416e-02 222.49 -2.00 3.57 -2.00 502.03 0.00e+00 2.734 0.000 489.00 513.00 1 6.4751e+00 1.3423e-03 4.3121e-03 -6.0000e+00 3.4768e-03 4.5657e-03 3.4732e-04 4.6323e-04 -6.0000e+00 9.0398e-04 2.0023e-03 8.0526e-04 8.8203e-05 2.5537e-05 -6.0000e+00 2.3397e-04 2.9890e-03 -6.3310e-05 12 1 1 12 1 1 99.93 18.26 0.87 0.00299 0.00857 60 13 1 4 0 747.720 23.64 15.00 18.26 11.62 28.5 1012.24 -426 -391 125 14 291 75 445 247 427 110 174 55 -275 -74 -331 -17 -274 215 84 88 -3 113 179 132 407 -33 251 -93 61 -485 -245 -331 -211 217 -86 19 -35 101 -231 47 -86 -20 189 250 240 354 322 71 221 -219 -146 -361 -523 -324 18 45 -92 172 -60 185 9 149 -36 76 -37 -94 -43 -203 82 -455 -55 -429 -95 30 -26 -74 -292 -22 -385 -180 -401 -84 -301 -7 -48 -118 -10 -55 12 -257 119 -151 380 -80 247 5 -35 -231 -325 -280 -517 -169 -231 79 -329 35 -213 -201 -70 7 156 -74 346 155 436 203 483 322 242 272 72 173 58 221 38 379 150 226 77 162 307 -210 136 -305 80 -123 109 -102 179 196 18 213 71 242 -215 100 -295 -278 -464 -290 -407 -380 124 14 302 79 473 263 453 116 181 56 -279 -75 -332 -17 -281 225 89 94 -3 120 191 141 435 -35 266 -97 62 -486 -243 -331 -216 227 -91 21 -37 106 -240 48 -88 -21 197 263 254 373 337 74 225 -219 -142 -346 -501 -313 18 45 -94 177 -61 190 9 153 -37 78 -38 -95 -43 -200 80 -440 -53 -415 -93 30 -25 -73 -281 -21 -365 -170 -381 -80 -290 -7 -47 -116 -10 -54 11 -253 118 -152 382 -81 246 5 -33 -218 -302 -256 -476 -158 -222 77 -328 34 -210 -195 -68 7 154 -74 348 157 442 207 493 328 245 271 71 169 57 216 37 371 147 221 75 157 296 -200 127 -285 75 -116 105 -100 176 195 18 213 71 242 -216 99 -289 -267 -440 -274 SQ 20231123T175204.3Z 8727.744494 312 1 1.97 2 65.02 192.28 110.25 62.69 0.00 1 0.00 1 0 15 2.533e-03 2.512e-03 1.606e-03 1.602e-03 1.495957e+03 9.141670e+01 1.045988e+02 -6.000000e+00 1.374466e+02 276.55 -2.00 20.00 -2.00 505.27 0.00e+00 8.540765e-04 4.325211e-05 4.844402e-05 -6.000000e+00 7.001046e-05 276.55 -2.00 20.00 -2.00 500.48 0.00e+00 1.083917e-01 3.146851e-02 1.502974e-02 -6.000000e+00 5.006924e-02 222.49 -2.00 3.57 -2.00 502.07 0.00e+00 2.353 0.000 489.00 513.00 1 5.2163e+00 2.4040e-03 3.7183e-03 -6.0000e+00 3.8321e-03 5.7813e-03 6.2407e-04 3.5838e-04 -6.0000e+00 9.9529e-04 7.4927e-03 -2.8601e-05 1.5978e-04 2.2415e-05 -6.0000e+00 2.5792e-04 -3.4428e-03 3.5393e-05 12 1 1 12 1 1 25.34 18.27 0.88 -0.00344 -0.00364 4 25 1 4 0 393.250 23.64 15.00 18.27 11.75 28.5 1010.30 -634 -208 -113 36 35 457 441 482 410 114 52 40 -105 -201 -166 -220 19 176 -62 70 70 79 13 194 224 44 400 331 -139 -498 -37 -340 70 272 199 -301 193 -82 -201 -166 6 115 -116 200 395 132 -88 -58 262 -429 119 -510 -347 -554 -231 5 282 184 -237 123 403 61 134 184 161 -125 -70 -31 -91 -345 -154 -362 -260 -64 -2 -364 -172 -269 -115 -354 -592 -188 -219 99 177 -125 -168 171 -309 -247 211 133 244 -1 245 -85 -75 -333 -51 -364 -392 -392 -126 -242 -266 -174 -242 -218 -72 72 78 193 348 396 290 307 518 198 326 320 338 -20 102 233 101 399 78 71 109 107 182 35 244 -290 65 118 -143 -84 191 250 139 -12 334 -93 14 63 -278 -183 -673 -322 -604 -202 -113 37 36 470 459 504 426 117 52 40 -108 -205 -169 -227 19 180 -65 74 74 83 14 205 238 46 419 341 -139 -489 -38 -334 71 282 210 -320 203 -85 -206 -170 6 118 -122 211 419 140 -93 -60 265 -425 119 -504 -341 -531 -227 5 289 190 -245 126 415 63 139 190 165 -127 -70 -31 -88 -332 -147 -349 -254 -63 -2 -356 -165 -255 -108 -334 -563 -180 -211 96 174 -123 -167 169 -307 -247 212 136 241 -1 249 -85 -74 -319 -48 -337 -364 -371 -123 -245 -261 -170 -243 -217 -71 72 75 190 346 397 293 312 526 201 327 316 329 -19 98 225 98 387 76 69 105 103 181 34 234 -278 62 115 -137 -82 187 247 138 -12 336 -94 14 63 -271 -175 -635 -316