File name: Pandora108s1_Toronto-West_20240612_L2Fit_fout2c6d20211104p1-8.txt File generation date: 20240820T174832.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v4d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20240612_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20240612 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240612T104914.5Z 8929.450862 71 1 49.58 2 79.14 68.20 122.98 9.49 0.00 1 0.00 1 0 25 5.881e-01 1.469e-02 3.909e-01 1.169e-02 7.441004e-01 6.695051e-03 8.473328e-03 -6.000000e+00 3.480207e-01 232.78 -2.00 3.57 -2.00 321.75 0.00e+00 2.864242e-03 3.658680e-03 2.445704e-03 -6.000000e+00 1.562167e-02 284.12 -2.00 20.00 -2.00 321.23 0.00e+00 5.110 0.003 302.00 328.00 3 2.3368e+00 2.5133e-02 6.6419e-02 -6.0000e+00 8.7452e-01 2.7339e-01 3.5151e-02 4.4511e-02 -6.0000e+00 9.4443e-01 -3.7378e-01 3.4240e-02 2.3272e-02 -6.0000e+00 5.6119e-01 1.5038e-01 1.5765e-02 6.9832e-03 -6.0000e+00 2.3663e-01 1.4636e-04 -1.2424e-03 3.4549e-04 1.0857e-04 -6.0000e+00 1.6849e-02 7.8208e-03 -8.9170e-05 12 9 9 12 1 1 37.60 17.46 0.34 0.00782 -0.00152 60 12 1 5 0 812.730 22.80 15.00 17.46 18.59 30.0 992.49 -195805 155880 -217840 900000 -215801 -222203 -166627 -219998 105971 -220251 146615 -166883 900000 -4429 -6119 -83452 -87906 -25794 -64006 26373 -58023 105159 -34613 74848 -33723 8648 -22450 -1005 26868 -62084 20979 -36020 79518 4969 84421 -11974 31163 5489 -10801 3342 2877 32546 -10841 44267 1809 42615 12033 21054 13125 4026 11935 -87 12951 -1870 21202 7198 23571 5509 6023 6711 9201 5658 1359 10969 4574 14260 -361 6677 2784 7279 4539 337 6156 -1687 3162 -5333 5007 -2729 2100 -3221 -1556 -1429 -111 514 -3429 755 -1237 2415 -1069 1235 -918 -402 -1890 -2952 754 -3083 54 -1584 861 -1180 -337 -1227 -675 -1251 -2999 -1920 -2340 410 -908 1053 63 487 197 451 188 -539 740 -1049 1172 -575 738 692 1400 365 94 243 -149 2144 -600 1282 -490 557 -78 3 28 -526 192 -3 282 -806 553 -692 -154 -2335 1777 -4021 900000 -3575 -3787 -1899 -4325 1208 -5208 1671 -2868 900000 -50 -70 -1574 -1962 -359 -1368 301 -1261 1199 -626 853 -703 128 -453 -16 332 -1873 347 -1206 1061 143 1145 -391 733 191 -526 170 165 1540 -802 2027 124 2045 786 1311 928 332 1017 -9 1348 -243 2374 958 2780 773 818 886 1209 839 236 1976 935 2680 -77 1388 657 1882 1341 109 1882 -526 868 -1428 1136 -670 547 -1045 -585 -618 -53 259 -1912 433 -757 1480 -677 744 -532 -218 -1005 -1626 448 -2200 43 -1493 877 -1249 -339 -1127 -562 -1028 -2647 -1792 -2302 423 -1038 1332 89 744 309 689 277 -766 1043 -1558 1807 -937 1188 1075 2071 529 132 329 -196 2856 -914 2189 -941 1142 -169 8 68 -1380 514 -8 767 -2139 1368 -1621 -344 SS 20240612T105538.5Z 8929.455307 74 1 50.05 2 78.06 69.22 122.80 11.26 0.00 1 0.00 1 0 25 6.141e-01 2.950e-02 4.281e-01 1.841e-02 7.022358e-01 1.052157e-02 8.132724e-03 -6.000000e+00 3.706747e-01 232.78 -2.00 3.57 -2.00 321.47 0.00e+00 -2.325110e-02 4.997495e-03 2.533112e-03 -6.000000e+00 1.672364e-02 284.12 -2.00 20.00 -2.00 320.88 0.00e+00 4.684 0.002 302.00 328.00 3 3.7282e+00 3.7231e-02 6.9466e-02 -6.0000e+00 9.3494e-01 1.7887e-01 5.0879e-02 6.5139e-02 -6.0000e+00 1.0130e+00 -2.9966e-01 4.8359e-02 2.4632e-02 -6.0000e+00 5.9702e-01 1.2190e-01 2.2688e-02 2.8434e-02 -6.0000e+00 2.4884e-01 6.1848e-05 -2.8371e-04 5.6387e-04 2.6831e-04 -6.0000e+00 1.7879e-02 8.4551e-03 -1.2569e-04 12 8 8 10 0 0 97.10 17.47 0.37 0.00846 0.00632 25 5 1 5 0 2001.610 22.80 15.00 17.47 18.96 29.9 994.52 -91429 -27176 900000 -129478 900000 -184577 900000 -147013 900000 -123551 218522 -96180 -29945 900000 -46004 900000 -64296 900000 -84998 33048 -89100 83944 -17543 43552 404193 42899 203567 7694 70401 -28824 99130 -28478 39340 -19823 5738 75115 30825 197975 24849 72794 19128 60989 29419 63045 15637 19810 48424 -12567 17791 -4082 42535 -2130 26768 18663 19906 24248 15013 -61046 8057 31885 8353 23743 -2472 16553 2418 6488 -1576 3534 9424 4542 10867 3187 13823 1898 11401 2721 7574 271 -2355 4716 -2499 4964 -4587 1026 -3050 4313 -2135 445 -222 -767 3703 1475 4906 -1881 2685 -1809 1347 -3296 -2297 -1175 -4333 -1444 -3464 785 -2748 321 -2695 893 -730 435 43 620 2025 1878 1594 688 1354 -795 122 -1266 -766 208 -542 1149 -1115 2041 -524 2145 -46 31 -804 -92 -248 -1265 341 -313 1630 117 841 -957 -224 105 -814 -1639 -487 900000 -2321 900000 -3309 900000 -2818 900000 -2754 3918 -1974 -537 900000 -835 900000 -1656 900000 -2974 592 -3489 1505 -410 781 7246 921 3650 215 1262 -997 1777 -1198 1000 -922 208 1448 988 3549 1295 3019 1494 3494 2292 3547 1316 1568 2889 -1332 1468 -441 3306 -282 3002 2486 2879 3626 2613 -22477 1470 4410 1420 3690 -542 3360 588 1506 -390 870 2426 1410 3545 1183 4661 683 3462 806 1989 76 -731 1584 -1049 2223 -2501 571 -1889 2670 -1474 310 -154 -519 2248 862 2689 -1130 1709 -1368 1133 -3275 -2470 -1260 -4565 -1349 -3042 661 -2548 308 -2791 956 -862 569 63 959 3140 2846 2315 963 1883 -1164 187 -2047 -1234 321 -811 1639 -1566 2690 -684 2819 -68 51 -1490 -182 -516 -2821 803 -781 4114 303 2171 -2417 -530 234 -1759 SS 20240612T110122.0Z 8929.459282 77 1 49.41 2 77.09 70.13 122.62 12.84 0.00 1 0.00 1 0 17 4.694e-01 2.769e-02 3.767e-01 2.229e-02 6.521403e-01 1.283246e-02 7.798366e-03 -6.000000e+00 2.803517e-01 232.78 -2.00 3.57 -2.00 321.27 0.00e+00 3.082026e-03 6.043285e-03 3.793391e-03 -6.000000e+00 1.426450e-02 284.12 -2.00 20.00 -2.00 320.69 0.00e+00 4.357 0.002 302.00 328.00 3 4.0785e+00 4.3602e-02 5.8834e-02 -6.0000e+00 7.0509e-01 3.7481e-01 5.5497e-02 4.2195e-02 -6.0000e+00 7.6276e-01 -4.5935e-01 4.7759e-02 1.9759e-02 -6.0000e+00 4.5124e-01 1.9040e-01 2.2993e-02 5.1535e-03 -6.0000e+00 1.9138e-01 5.3609e-05 -1.4342e-03 6.7872e-04 9.6874e-05 -6.0000e+00 1.3645e-02 9.1893e-03 -1.3148e-04 12 9 8 11 8 0 98.10 17.47 0.78 0.00919 -0.00159 26 5 1 5 0 1900.260 22.80 15.00 17.47 19.06 30.0 995.03 -171517 900000 -130269 900000 -153103 110395 -70025 -26985 900000 -139205 900000 -128150 900000 -95544 900000 -68436 211474 -64290 36166 21293 31317 900000 -18435 900000 -46005 900000 -11027 55064 -44184 -39762 61026 86453 64287 2597 121426 -18951 134452 -9473 70780 8282 28316 60905 21520 55285 -9968 93386 1904 37563 -13824 21528 19585 1003 35329 4695 39170 -1053 29952 900000 28013 -2796 9700 4205 4625 11095 -618 21072 -5131 19793 -4232 5299 1433 5901 780 204 7986 -7578 6737 -7909 12027 -8867 1244 -2956 -4904 -4118 -4824 2954 -3104 5840 -4085 5888 -7056 2554 -6395 -2030 -2605 -4918 1036 -2640 3391 -2914 2454 -3883 -46 -1718 -914 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