File name: Pandora108s1_Toronto-West_20240623_L2Fit_fout2c6d20211104p1-8.txt File generation date: 20240820T175235.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v4d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20240623_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20240623 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240623T141752.1Z 8940.595742 312 1 50.00 2 42.44 103.35 124.20 263.84 0.00 1 0.00 1 0 17 2.077e-02 9.367e-03 1.430e-02 5.083e-03 1.948768e-01 2.631151e-03 2.351325e-03 -6.000000e+00 1.231144e-02 232.96 -2.00 3.57 -2.00 317.32 0.00e+00 4.831469e-04 3.687621e-04 1.886297e-04 -6.000000e+00 5.380757e-04 285.16 -2.00 20.00 -2.00 316.51 0.00e+00 1.353 0.000 302.00 328.00 3 5.4050e+00 7.0187e-03 1.7001e-02 -6.0000e+00 3.0943e-02 1.8809e-02 7.8561e-03 1.0353e-02 -6.0000e+00 3.3387e-02 1.1561e-02 4.6203e-03 5.0120e-03 -6.0000e+00 1.9839e-02 -1.1813e-02 2.2076e-03 1.3865e-03 -6.0000e+00 8.3583e-03 5.0222e-04 6.5133e-04 1.5478e-04 1.6127e-05 -6.0000e+00 5.8621e-04 2.2599e-03 1.2034e-04 12 8 8 10 0 0 99.91 17.48 0.31 0.00226 0.00715 69 14 1 5 0 724.540 22.90 15.00 17.48 30.18 30.8 1006.40 -1986 -2730 2719 -8462 812 -7990 8105 -2674 5551 -3165 -910 1178 -2839 3854 -2931 4238 -2553 3658 -987 2251 -1292 -1312 1697 -1104 2724 -2365 3420 -4703 1498 -3129 2398 635 1402 -92 -4171 341 -4574 2239 -2246 2435 -841 1288 -865 -85 -399 -978 157 -2028 332 -1510 2687 -229 1282 561 1139 1506 500 -1430 -630 2255 -119 2606 1195 2840 -115 199 -359 -1555 1283 -633 1443 -314 1398 -261 444 -1503 -1373 -1539 -2233 -312 -2041 -360 -2897 -528 -1516 295 29 399 989 282 650 -516 375 -1067 596 -1442 856 931 522 289 -496 -287 -1611 456 -1922 -420 -1219 -33 -158 477 952 482 1073 -347 146 -1072 53 -607 153 -101 280 642 224 1005 -173 841 -772 1104 -320 211 -466 -351 190 -387 573 -810 641 59 536 -261 254 -405 -854 -266 -401 386 -1272 100 -1013 914 -369 788 -511 -144 183 -497 707 -646 950 -636 885 -257 589 -356 -362 457 -320 796 -754 1032 -1455 409 -856 642 183 429 -29 -1320 100 -1495 788 -978 1182 -460 729 -510 -51 -237 -585 91 -1165 181 -830 1470 -136 795 365 764 1019 348 -1018 -438 1518 -84 1908 949 2359 -98 159 -263 -1109 921 -515 1266 -294 1306 -241 386 -1207 -999 -1042 -1543 -232 -1722 -328 -2890 -541 -1662 343 36 507 1257 353 758 -556 367 -1001 567 -1510 968 1150 691 382 -629 -337 -1820 515 -2381 -547 -1666 -47 -233 737 1528 790 1694 -519 200 -1388 67 -796 212 -151 434 990 339 1460 -241 1114 -984 1370 -419 292 -680 -526 285 -605 934 -1408 1136 107 987 -477 451 -698 -1450 SS 20240623T142239.7Z 8940.599070 315 1 50.17 2 41.60 104.41 125.02 264.59 0.00 1 0.00 1 0 17 1.043e-02 6.468e-03 4.731e-03 1.720e-03 1.881842e-01 8.866985e-04 2.278662e-03 -6.000000e+00 6.185768e-03 232.96 -2.00 3.57 -2.00 317.32 0.00e+00 5.550764e-04 1.239911e-04 1.494150e-04 -6.000000e+00 2.703515e-04 285.16 -2.00 20.00 -2.00 316.51 0.00e+00 1.336 0.000 302.00 328.00 3 2.9114e+00 2.3640e-03 1.6648e-02 -6.0000e+00 1.5547e-02 2.4284e-03 2.6435e-03 1.0026e-02 -6.0000e+00 1.6775e-02 1.2843e-02 1.5559e-03 4.8581e-03 -6.0000e+00 9.9678e-03 -1.1613e-02 7.4204e-04 1.3648e-03 -6.0000e+00 4.1996e-03 6.3081e-03 6.5119e-04 5.2304e-05 1.6158e-05 -6.0000e+00 2.9454e-04 2.1008e-03 1.1142e-04 11 8 0 10 0 0 99.98 17.48 0.15 0.00210 0.00699 1423 279 1 5 0 35.250 22.90 15.00 17.48 30.39 30.7 1007.75 786 981 -1456 -3645 -4909 -1390 222 -131 1912 -1651 -1375 -1992 670 -383 1291 -541 -458 1006 -65 1238 -235 277 391 1172 -127 50 -458 -1698 -724 -694 1459 726 2070 -1120 -2567 -2295 -1651 -798 283 210 -929 52 -800 -199 -446 -249 -814 -779 -904 -622 976 408 1403 774 1292 644 991 334 402 768 887 1848 1259 2201 98 -72 -826 -457 264 726 336 466 541 35 -13 -1064 -756 -1840 -1027 -1309 -1528 -1365 -2215 -1279 -1196 -167 -225 722 347 739 337 51 -275 -291 133 -426 603 815 714 -164 -59 -906 -626 -265 -1175 -836 -971 -336 -115 904 624 751 443 109 -75 -521 -105 -683 181 -57 212 196 481 442 360 233 -310 949 36 264 -380 -46 -275 -65 -44 -143 252 266 365 -303 109 -549 -495 104 141 -218 -527 -642 -174 28 -18 293 -276 -227 -331 117 -76 283 -131 -115 256 -17 334 -66 77 109 336 -39 16 -144 -513 -201 -185 389 207 620 -356 -786 -675 -513 -283 118 102 -501 29 -464 -116 -260 -144 -463 -428 -512 -347 552 246 884 513 877 447 697 236 279 529 625 1368 1010 1849 84 -58 -608 -319 190 579 296 432 506 32 -11 -841 -534 -1222 -683 -958 -1253 -1229 -2153 -1291 -1284 -191 -272 898 437 903 385 53 -261 -261 129 -426 702 976 912 -210 -76 -1097 -715 -306 -1480 -1119 -1362 -488 -174 1425 1034 1259 720 165 -105 -677 -134 -903 253 -85 331 306 733 649 502 308 -391 1165 46 362 -551 -68 -413 -101 -72 -246 446 483 670 -551 192 -941 -828 SS 20240623T142641.3Z 8940.601867 318 1 4.83 2 40.89 105.32 125.70 265.22 0.00 1 0.00 1 0 17 1.039e-02 6.495e-03 2.473e-03 1.194e-03 1.875366e-01 6.215645e-04 2.265685e-03 -6.000000e+00 6.155789e-03 232.96 -2.00 3.57 -2.00 316.34 0.00e+00 6.047880e-04 6.993985e-05 7.354784e-05 -6.000000e+00 2.690613e-04 285.16 -2.00 20.00 -2.00 315.59 0.00e+00 1.321 0.000 302.00 328.00 3 2.1191e+00 1.6329e-03 1.6492e-02 -6.0000e+00 1.5472e-02 7.3775e-03 1.8164e-03 9.9600e-03 -6.0000e+00 1.6695e-02 2.7561e-03 1.0489e-03 4.8057e-03 -6.0000e+00 9.9201e-03 -6.1012e-03 4.8099e-04 1.3498e-03 -6.0000e+00 4.1785e-03 1.4152e-02 2.3598e-04 3.5461e-05 1.5952e-05 -6.0000e+00 2.9320e-04 2.2326e-03 5.5420e-05 12 9 1 12 1 1 99.26 17.48 0.16 0.00223 0.00401 54 112 1 5 0 87.700 22.90 15.00 17.48 30.70 30.6 1009.22 1207 -931 -1225 -3479 -5070 -2565 -1408 1560 98 -568 -2800 -1653 -58 246 873 341 17 555 778 1047 716 247 1147 1265 565 360 -711 -1044 -1418 -87 811 1254 1735 -754 -2884 -2142 -1632 -642 39 43 -431 -251 -380 -222 -271 -291 -734 -633 -839 -16 974 853 1178 1179 1024 1077 906 450 483 421 1024 1382 1586 1975 213 -113 -651 -583 386 467 171 354 442 209 -61 -804 -904 -1742 -1177 -1272 -1406 -1589 -1973 -1564 -897 -340 -194 476 286 599 233 239 -38 42 61 -301 390 828 595 -158 -195 -644 -440 -247 -967 -920 -882 -383 -109 642 523 641 358 266 -13 -264 -19 -278 209 123 179 341 415 531 444 318 -71 1073 301 302 -154 -190 -223 -154 63 -177 90 326 173 -249 -181 -562 -535 222 -191 -256 -700 -925 -466 -260 310 22 -123 -667 -389 -15 63 250 107 6 184 265 366 256 88 409 468 220 145 -289 -403 -510 -32 305 457 669 -306 -1135 -879 -648 -290 21 27 -295 -166 -259 -152 -185 -198 -532 -443 -569 -10 660 613 889 859 768 821 703 350 370 321 793 1132 1397 1831 201 -99 -526 -486 329 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