File name: Pandora108s1_Toronto-West_20240710_L2Fit_fout2c6d20211104p1-8.txt File generation date: 20240820T180058.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v4d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20240710_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20240710 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240710T182846.1Z 8957.769978 320 1 2.18 2 25.46 217.13 50.24 123.90 0.00 1 0.00 1 0 17 1.890e-02 1.061e-02 1.595e-02 9.216e-03 1.580381e-01 4.839575e-03 1.903903e-03 -6.000000e+00 1.122067e-02 233.05 -2.00 3.57 -2.00 315.65 0.00e+00 4.717578e-04 4.707783e-04 3.576782e-05 -6.000000e+00 4.932700e-04 286.73 -2.00 20.00 -2.00 314.93 0.00e+00 1.107 0.000 302.00 328.00 3 5.0001e+00 1.2626e-02 1.3839e-02 -6.0000e+00 2.8193e-02 1.4387e-02 1.3984e-02 8.3515e-03 -6.0000e+00 3.0399e-02 4.6430e-03 7.9938e-03 4.0285e-03 -6.0000e+00 1.8079e-02 -5.0484e-03 3.5782e-03 1.1251e-03 -6.0000e+00 7.6372e-03 1.0318e-03 -3.5159e-04 2.7190e-04 1.4093e-05 -6.0000e+00 5.3354e-04 -8.0226e-03 -8.0004e-07 12 9 9 12 1 1 999.00 17.58 0.23 -0.00802 -0.01066 1 9 1 5 0 1086.100 22.90 14.99 17.58 23.41 30.7 956.83 3151 -2538 1504 -6364 200 -2168 7536 -2156 8412 -829 -4342 417 -2537 4550 -3132 3800 -925 1704 -1545 492 555 615 3260 -137 2389 -3047 963 -3361 1984 -692 2722 -475 1757 -270 -5076 50 -2696 1247 -2656 377 -836 1925 -865 -582 380 -1138 -489 -2828 169 -1675 4050 -273 1382 715 -890 275 -420 2910 -1130 929 -501 1590 953 3033 813 -1326 365 -1431 -193 382 1495 -555 992 -224 1038 -135 -1813 -1906 -276 -57 -2385 -949 -1945 -416 -1019 321 886 297 517 -425 839 770 1088 -913 302 -842 679 730 666 158 -597 -236 -838 324 -1688 -821 -934 -269 -83 -294 167 -84 1112 -195 -213 -855 569 92 435 -330 -333 1192 -34 1195 -5 748 -879 1023 71 -481 -60 802 800 -1171 130 -794 544 111 996 -658 242 -220 -1027 776 -712 413 -1793 48 -495 1610 -548 2147 -240 -1292 118 -781 1440 -1171 1437 -376 691 -657 212 242 268 1388 -62 1099 -1514 463 -1602 849 -289 1119 -209 798 -128 -2405 22 -1259 632 -1601 252 -608 1431 -668 -455 293 -888 -373 -2135 121 -1197 2824 -205 1070 574 -743 229 -357 2421 -959 772 -428 1401 887 2910 793 -1252 316 -1203 -163 348 1460 -574 1027 -230 1017 -124 -1559 -1535 -219 -48 -2232 -944 -2048 -450 -1154 380 1089 378 662 -541 1009 867 1139 -921 306 -906 776 891 854 204 -749 -280 -959 371 -2064 -1050 -1231 -364 -115 -423 246 -125 1617 -273 -280 -1069 694 114 567 -455 -475 1693 -48 1633 -6 957 -1093 1238 88 -628 -81 1091 1095 -1656 188 -1204 839 174 1576 -1043 375 -335 -1547 SS 20240710T184057.1Z 8957.778438 330 1 7.11 2 26.88 222.67 48.52 127.08 0.00 1 0.00 1 0 17 1.052e-02 6.695e-03 3.464e-03 1.916e-03 1.575239e-01 1.004080e-03 1.914330e-03 -6.000000e+00 6.248780e-03 233.05 -2.00 3.57 -2.00 315.86 0.00e+00 5.190896e-04 1.019543e-04 4.027209e-05 -6.000000e+00 2.746491e-04 286.73 -2.00 20.00 -2.00 315.11 0.00e+00 1.121 0.000 302.00 328.00 3 3.5599e+00 2.6263e-03 1.3956e-02 -6.0000e+00 1.5701e-02 6.0732e-03 2.9118e-03 8.3852e-03 -6.0000e+00 1.6924e-02 3.7775e-03 1.6661e-03 4.0448e-03 -6.0000e+00 1.0066e-02 -7.0744e-03 7.5019e-04 1.1440e-03 -6.0000e+00 4.2553e-03 4.3241e-03 4.7579e-04 5.6869e-05 1.4124e-05 -6.0000e+00 2.9680e-04 -8.9215e-03 1.8023e-04 12 9 1 12 1 1 99.98 17.58 0.25 -0.00892 -0.00535 25 36 1 5 0 273.210 22.90 15.00 17.58 24.33 30.7 963.62 1549 -381 -1275 -2849 -5125 -850 -2377 2860 -1322 417 -2968 -283 754 -232 1478 72 717 -275 1555 72 1416 -278 1147 830 572 521 -1267 -73 -1680 492 384 1367 969 45 -2679 -2072 -1291 -1729 733 -576 -70 -637 -38 -611 -234 479 -864 -282 -1042 -136 495 1093 697 1615 1064 987 1150 446 503 12 1290 1041 1801 1647 521 -358 -584 -659 132 535 -377 688 -111 290 -137 -521 -986 -1352 -1151 -1428 -1463 -1822 -1698 -1627 -810 -661 -303 520 364 516 222 347 -685 419 -190 141 473 927 471 48 278 -789 -341 -279 -520 -1075 -789 -584 -117 667 330 567 461 329 -215 -101 -244 -133 63 274 202 73 696 271 584 259 137 701 747 -5 -87 -191 -47 154 -212 -120 -35 268 -35 -281 -53 -408 -583 360 -98 -336 -729 -1205 -179 -518 647 -344 112 -818 -75 211 -72 500 26 272 -107 610 29 581 -116 472 355 254 239 -593 -32 -706 193 153 561 422 20 -1187 -879 -568 -859 413 -375 -49 -470 -28 -465 -177 359 -644 -203 -732 -93 345 789 529 1256 856 801 946 370 412 10 1063 904 1638 1573 502 -330 -500 -539 109 479 -369 697 -114 293 -134 -473 -827 -1062 -900 -1199 -1340 -1803 -1770 -1763 -912 -788 -376 662 467 653 268 391 -721 415 -192 150 540 1131 607 62 347 -939 -388 -321 -631 -1383 -1044 -799 -164 965 492 856 681 463 -285 -127 -301 -167 83 381 291 106 991 378 781 335 171 856 933 -6 -118 -265 -65 219 -314 -184 -56 429 -57 -454 -84 -634 -893 SS 20240710T184808.2Z 8957.783428 336 1 50.13 2 27.78 225.71 47.54 129.03 0.00 1 0.00 1 0 17 9.429e-03 5.876e-03 1.969e-03 9.149e-04 1.585350e-01 4.788258e-04 1.923611e-03 -6.000000e+00 5.602497e-03 233.05 -2.00 3.57 -2.00 316.56 0.00e+00 5.116303e-04 5.542246e-05 7.293134e-05 -6.000000e+00 2.462490e-04 286.73 -2.00 20.00 -2.00 315.72 0.00e+00 1.130 0.000 302.00 328.00 3 2.9739e+00 1.2660e-03 1.4061e-02 -6.0000e+00 1.4077e-02 9.1416e-03 1.4093e-03 8.4388e-03 -6.0000e+00 1.5174e-02 3.1972e-03 8.0974e-04 4.0695e-03 -6.0000e+00 9.0250e-03 -7.4719e-03 3.7149e-04 1.1435e-03 -6.0000e+00 3.8151e-03 7.6812e-03 5.6151e-04 2.7930e-05 1.4363e-05 -6.0000e+00 2.6611e-04 -8.5109e-03 1.8567e-04 10 0 0 10 0 0 99.98 17.58 0.11 -0.00851 -0.00429 478 94 1 5 0 104.860 22.90 15.00 17.58 25.76 30.5 972.12 951 -724 -915 -3748 -3863 -2727 -473 892 526 -1024 -2307 -1285 85 314 382 405 -577 834 377 1216 585 355 1207 1115 637 33 -303 -1483 -827 -491 1120 1140 1319 -352 -2923 -1438 -1561 -225 23 431 -692 -170 -585 -336 -298 -180 -716 -755 -560 -422 811 753 1177 1120 1051 955 797 615 352 674 749 1497 1368 1800 146 -276 -424 -653 510 311 240 220 456 13 -5 -840 -773 -1333 -1130 -955 -1509 -1255 -2013 -1391 -1059 -342 -326 382 286 483 300 35 29 67 306 -189 397 709 479 -222 -197 -556 -596 -84 -991 -946 -958 -419 -117 641 457 458 428 60 72 -220 193 -327 186 42 95 265 307 522 352 466 -112 1086 298 256 -163 -164 -78 -54 43 -259 111 163 223 -247 -22 -452 -575 180 -152 -196 -780 -717 -462 -80 163 107 -222 -502 -273 19 78 105 120 -180 260 121 431 197 129 434 415 249 13 -123 -579 -296 -166 375 402 490 -137 -1110 -514 -586 -95 11 250 -447 -114 -406 -235 -208 -125 -486 -493 -351 -259 502 491 804 799 771 712 603 466 264 500 566 1186 1165 1613 134 -236 -329 -479 378 256 218 211 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