File name: Pandora108s1_Toronto-West_20240711_L2Fit_fout2c6d20211104p1-8.txt File generation date: 20240820T180220.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v4d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20240711_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20240711 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240711T125033.3Z 8958.535108 137 1 1.68 2 59.58 87.75 116.37 55.85 0.00 1 0.00 1 0 17 3.188e-02 1.055e-02 2.390e-02 6.164e-03 2.771022e-01 3.203867e-03 3.330374e-03 -6.000000e+00 1.892815e-02 233.06 -2.00 3.57 -2.00 317.72 0.00e+00 4.509076e-04 5.136953e-04 2.205956e-04 -6.000000e+00 8.323736e-04 286.80 -2.00 20.00 -2.00 316.91 0.00e+00 1.967 0.000 302.00 328.00 3 3.2716e+00 8.6041e-03 2.4554e-02 -6.0000e+00 4.7558e-02 2.5354e-02 9.6726e-03 1.4829e-02 -6.0000e+00 5.1278e-02 1.6787e-03 5.9113e-03 7.1702e-03 -6.0000e+00 3.0498e-02 -7.8840e-03 2.9429e-03 1.9643e-03 -6.0000e+00 1.2883e-02 2.0228e-03 4.4795e-05 1.8392e-04 2.2154e-05 -6.0000e+00 8.9998e-04 -6.2495e-03 6.4932e-05 12 9 9 12 9 1 98.30 17.54 0.36 -0.00625 -0.00591 3 24 1 5 0 418.150 22.90 15.00 17.54 25.73 30.6 973.35 -12291 8028 -704 -3653 -1759 -5335 4769 -8398 8234 -12513 6754 -13926 5743 -1843 176 1601 -4671 5066 -3565 6062 -6357 3500 -3809 7091 -291 -406 2323 -4720 2305 -5541 4198 -1834 5869 -2334 -1219 -2458 -2543 449 -2003 2074 -2610 1866 -2585 1616 -1313 942 320 -1341 -722 -2827 2582 -1116 4108 -225 3503 -311 2358 359 1239 653 429 2031 -310 2804 -644 477 -1011 -316 1450 1010 897 -755 1826 -955 1368 -1738 881 -2885 157 -1476 -879 -582 -2443 -1584 -2570 493 -791 803 -217 732 398 -114 5 -1240 645 -1362 1661 63 1278 -238 418 -635 -934 80 -1798 -586 -1296 -71 -193 1131 95 360 420 30 -141 -677 317 -754 749 -30 672 -17 675 755 130 752 -107 1781 -566 1282 -824 -307 66 -157 66 -475 667 -112 561 -805 -219 -869 68 -1117 670 -66 -341 -147 -436 368 -813 764 -1496 683 -1741 659 -259 28 276 -904 937 -742 1203 -1445 732 -860 1524 -71 -103 580 -1205 523 -1313 953 -473 1529 -683 -342 -676 -739 145 -775 899 -1287 937 -1381 850 -708 500 169 -706 -373 -1489 1352 -638 2381 -141 2214 -206 1561 243 821 432 289 1428 -237 2219 -529 374 -753 -227 1061 813 785 -698 1677 -875 1179 -1419 651 -2079 112 -1163 -760 -545 -2461 -1654 -2828 562 -947 982 -268 886 460 -124 5 -1226 647 -1482 1920 79 1688 -319 539 -779 -1095 93 -2242 -762 -1748 -99 -277 1684 148 573 658 45 -202 -922 424 -1036 1069 -45 1032 -26 1017 1109 185 1035 -143 2329 -778 1838 -1247 -475 103 -252 110 -824 1177 -202 1016 -1453 -386 -1497 114 SS 20240711T125550.2Z 8958.538776 140 1 33.85 2 58.63 88.64 115.62 57.00 0.00 1 0.00 1 0 17 3.007e-02 7.617e-03 2.379e-02 5.051e-03 2.690700e-01 2.625577e-03 3.238233e-03 -6.000000e+00 1.786742e-02 233.06 -2.00 3.57 -2.00 318.27 0.00e+00 7.189581e-04 4.820493e-04 3.320560e-04 -6.000000e+00 7.855905e-04 286.80 -2.00 20.00 -2.00 317.44 0.00e+00 1.913 0.000 302.00 328.00 3 5.0074e+00 7.1453e-03 2.3900e-02 -6.0000e+00 4.4893e-02 4.2756e-02 8.0842e-03 1.4451e-02 -6.0000e+00 4.8393e-02 1.1398e-02 5.0825e-03 7.0215e-03 -6.0000e+00 2.8784e-02 -1.3628e-02 2.5682e-03 1.9702e-03 -6.0000e+00 1.2167e-02 3.7566e-04 7.1260e-04 1.5472e-04 2.2200e-05 -6.0000e+00 8.4877e-04 -7.3845e-03 2.0079e-04 12 9 1 12 9 1 99.97 17.55 0.19 -0.00738 -0.00203 20 6 1 5 0 1611.440 22.90 15.00 17.55 25.85 30.5 974.02 11404 -13066 2490 -16097 -5505 -1610 -8152 1592 -9259 8406 -8295 5591 -4695 7185 -1008 4285 105 -3138 -827 -2420 4725 -1570 3663 -897 1235 405 -1989 355 -2979 463 -4019 2702 -1512 2738 -4687 -396 -1093 -399 264 -256 -27 -760 527 -965 770 123 -127 -1606 -931 134 -19 1295 203 2785 -223 2438 564 133 466 101 817 1783 2611 966 1459 -475 202 -1448 1096 -133 647 855 -193 828 -680 -246 -2112 -1444 -2457 -830 -1507 -983 -2179 -1873 -453 -703 350 313 983 667 710 0 -919 -59 -777 -319 -47 1567 602 12 -423 -564 -730 -669 -902 -1478 -549 -836 514 863 924 622 499 243 -89 -184 -422 -50 -498 329 -375 801 272 490 335 -124 -333 323 393 -41 441 -396 -262 -417 216 -101 -325 667 9 181 -216 -8 -654 673 -1089 185 -1387 -389 -103 -578 114 -825 669 -787 471 -483 752 -131 590 16 -516 -138 -429 799 -284 636 -171 244 84 -428 72 -586 85 -811 551 -349 634 -1127 -88 -260 -108 85 -97 -11 -340 239 -455 357 58 -59 -740 -419 60 -9 634 107 1507 -130 1406 338 81 277 60 490 1130 1767 713 1085 -344 134 -946 723 -99 526 731 -169 698 -552 -181 -1441 -916 -1602 -587 -1203 -862 -2074 -1871 -472 -787 408 380 1194 797 797 0 -891 -54 -741 -328 -53 1925 800 16 -545 -678 -827 -763 -1098 -1929 -738 -1180 748 1327 1490 1033 813 375 -129 -249 -564 -68 -726 504 -600 1265 422 736 482 -172 -441 421 534 -60 674 -631 -423 -695 377 -186 -616 1279 17 349 -406 -14 -1164 SS 20240711T142613.2Z 8958.601541 199 1 9.13 2 42.48 106.10 101.47 74.63 0.00 1 0.00 1 0 17 2.016e-02 1.055e-02 1.318e-02 6.114e-03 1.962383e-01 3.196855e-03 2.387971e-03 -6.000000e+00 1.196311e-02 233.06 -2.00 3.57 -2.00 316.38 0.00e+00 8.851452e-04 3.648242e-04 1.328247e-04 -6.000000e+00 5.260960e-04 286.81 -2.00 20.00 -2.00 315.61 0.00e+00 1.354 0.000 302.00 328.00 3 5.4511e+00 8.4066e-03 1.7067e-02 -6.0000e+00 3.0058e-02 5.0773e-02 9.3506e-03 1.0439e-02 -6.0000e+00 3.2414e-02 5.3511e-03 5.3935e-03 5.0438e-03 -6.0000e+00 1.9278e-02 -7.7200e-03 2.4959e-03 1.4280e-03 -6.0000e+00 8.1409e-03 4.7020e-04 -7.2589e-04 1.8123e-04 1.6914e-05 -6.0000e+00 5.6909e-04 -6.3403e-03 -3.5950e-05 12 9 9 12 1 1 999.00 17.57 0.27 -0.00634 -0.01179 2 3 1 5 0 3042.000 22.90 15.00 17.57 26.87 30.7 980.37 3209 -1951 1464 -6369 -371 -9574 6748 -4487 5955 -4035 -882 -768 -184 2134 -3247 2819 -3339 3760 -433 3018 -36 736 1264 2011 1683 -2287 1243 -4208 -248 -3180 2881 1307 2114 -931 -3739 -608 -4812 2679 -1859 1656 -1362 644 -401 735 1119 -538 -289 -1920 1311 -3223 796 -347 2132 1455 775 1245 390 906 -1192 1418 116 2013 832 2702 331 63 -302 -2242 1279 -647 1263 -427 1491 -554 -483 -1479 16 -1304 -1947 -742 -2018 -1368 -2747 -512 -938 1056 -580 755 1049 1098 1007 -957 557 -1686 145 -850 740 143 527 672 -255 -959 -1633 -418 -1842 -1160 -1099 -54 647 977 1062 401 833 -277 744 -492 -284 -958 -52 222 48 846 851 633 -40 1017 -1089 1073 -692 227 -425 -321 245 118 340 -428 1305 -758 498 -346 80 -441 -928 557 -389 289 -1297 -65 -1695 1051 -850 1135 -885 -188 -163 -42 529 -947 847 -1103 1200 -147 1028 -13 261 446 732 639 -932 492 -1672 -90 -1130 994 481 823 -383 -1520 -232 -1993 1173 -983 975 -891 435 -278 514 777 -379 -200 -1312 850 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