File name: Pandora108s1_Toronto-West_20240808_L2Fit_fout2c6d20211104p1-8.txt File generation date: 20240820T181356.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v4d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20240808_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20240808 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240808T110137.4Z 8986.459461 56 1 49.89 2 82.97 74.67 122.81 52.70 0.00 1 0.00 1 0 25 7.685e-01 4.244e-02 4.077e-01 2.852e-02 8.749796e-01 1.768228e-02 9.926740e-03 -6.000000e+00 4.705320e-01 232.15 -2.00 3.57 -2.00 322.19 0.00e+00 -3.946035e-03 9.573714e-03 7.985119e-04 -6.000000e+00 2.423822e-02 287.60 -2.00 20.00 -2.00 321.68 0.00e+00 7.495 0.008 302.00 328.00 3 8.4947e-01 6.9534e-02 8.8274e-02 -6.0000e+00 1.1805e+00 1.2127e+00 8.5513e-02 4.8363e-02 -6.0000e+00 1.2793e+00 -1.6382e+00 5.7046e-02 2.3973e-02 -6.0000e+00 7.5710e-01 6.6428e-01 2.8222e-02 7.2783e-03 -6.0000e+00 3.2091e-01 5.5277e-05 -1.7313e-03 8.5694e-04 1.0802e-04 -6.0000e+00 2.3608e-02 -3.9798e-03 4.8408e-05 12 8 8 10 0 0 28.84 17.53 0.55 -0.00398 -0.01699 72 14 1 5 0 692.920 22.90 14.99 17.53 23.51 30.8 977.86 495250 -13842 -22338 900000 -83592 900000 -81477 900000 -107070 900000 -17076 18807 900000 -40637 900000 -45528 900000 -34856 900000 -18182 900000 35885 133752 152571 -35815 900000 -23811 900000 -57307 900000 -20967 208938 44573 83261 131921 -19926 900000 -44012 900000 3935 900000 39641 261492 82560 30713 186721 23606 900000 -9997 900000 -6097 319578 14774 99314 47938 20803 128079 22160 138258 -7655 124767 600 67282 8026 58755 27214 15817 67455 -417 53539 7765 56088 1515 42735 3297 14684 3354 3440 17517 -9510 31164 -13268 16089 -13849 15183 -5325 5179 37 -1405 9695 -8805 17465 -11523 10696 -14525 5148 -4953 -1379 857 -5792 2256 -7883 4284 -8992 2248 -9574 1410 -6465 -2329 -1956 -1974 2889 -2703 2964 -2906 3950 -3804 1364 -2651 1233 1587 1234 4746 16 7833 -1779 4261 -936 3172 -358 -94 1749 -1017 2688 -2115 1995 -1335 2349 -1530 -70 -865 -947 -1012 13725 -583 -992 900000 -4988 900000 -4122 900000 -7601 900000 -522 521 900000 -2128 900000 -3231 900000 -2460 900000 -1084 900000 1149 3707 4228 -2392 900000 -1393 900000 -3853 900000 -1108 5790 1634 2307 3656 -1247 900000 -3919 900000 306 900000 2556 7247 3516 2045 5175 1612 900000 -967 900000 -651 8857 1550 5044 4180 2409 5548 2558 5088 -1043 4784 78 5143 1201 5850 3680 2352 6399 -81 7084 1745 8372 376 6750 688 2444 575 587 2887 -2381 6281 -4703 4819 -5940 5229 -2373 2177 17 -649 3923 -4007 5843 -4960 3850 -7490 2562 -3200 -997 681 -5091 1773 -6226 2715 -6255 1469 -7519 1049 -5617 -2145 -2057 -2366 3651 -3772 3913 -3961 4867 -5075 1793 -3847 1794 2302 1726 6133 22 9259 -2251 4947 -1184 4340 -590 -175 3495 -2229 6104 -5423 5209 -3715 6381 -4331 -187 -2195 -2222 -2252 SS 20240808T111234.5Z 8986.467066 59 1 50.22 2 81.06 76.49 121.30 55.26 0.00 1 0.00 1 0 17 5.347e-01 1.535e-02 3.685e-01 1.025e-02 7.400446e-01 5.905548e-03 8.636032e-03 -6.000000e+00 3.198507e-01 232.15 -2.00 3.57 -2.00 321.86 0.00e+00 3.827968e-03 3.408204e-03 4.331113e-03 -6.000000e+00 1.417435e-02 287.60 -2.00 20.00 -2.00 321.32 0.00e+00 6.087 0.004 302.00 328.00 3 8.6380e-01 2.3300e-02 7.5676e-02 -6.0000e+00 8.0346e-01 3.1703e-01 3.3015e-02 4.9847e-02 -6.0000e+00 8.6785e-01 -4.5278e-01 3.0916e-02 2.5648e-02 -6.0000e+00 5.1296e-01 1.8328e-01 1.4022e-02 7.2499e-03 -6.0000e+00 2.1571e-01 2.6555e-04 -5.6525e-04 3.0378e-04 1.2997e-04 -6.0000e+00 1.5311e-02 -3.7120e-03 4.9499e-05 12 8 8 10 0 0 22.75 17.53 0.26 -0.00371 -0.00796 187 37 1 5 0 268.530 22.90 15.00 17.53 24.38 30.6 983.19 -251554 -62088 -192909 -4927 -192954 -88170 900000 -199261 900000 -206671 18137 -204347 -109634 -117223 32124 -8996 -19402 24616 -70155 129391 -66607 49762 -89396 14635 -105411 -8884 -29617 -31981 57979 -38627 116854 -30018 21129 -5229 14264 8319 5420 26801 3823 24130 14947 49666 822 21774 149 23456 14700 29612 22172 25443 21708 15517 23897 10911 23668 6233 15726 3547 8685 13291 7664 22328 5291 20188 3569 10755 2767 7348 1672 7128 7738 4860 7338 -611 6612 -1967 1483 -5811 32 -1112 894 751 -2611 101 -1870 651 -2202 1701 -804 -758 -427 -595 -1545 -2382 -865 -2422 938 -2134 238 -1969 -658 -1666 -1968 -574 -2795 -893 -2374 -239 -1516 272 -174 443 158 -52 869 220 647 -661 453 -576 1156 180 1468 852 466 1356 154 1968 -233 750 -425 619 -203 358 -29 -559 226 173 369 -866 275 -936 -113 -5413 -620 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20.00 -2.00 321.00 0.00e+00 5.118 0.003 302.00 328.00 3 8.8780e-01 1.1508e-02 6.3014e-02 -6.0000e+00 6.2985e-01 7.7263e-02 1.5964e-02 3.9575e-02 -6.0000e+00 6.7959e-01 -8.7383e-02 1.5412e-02 2.1028e-02 -6.0000e+00 4.0470e-01 2.3950e-02 7.1801e-03 6.4812e-03 -6.0000e+00 1.7134e-01 7.1834e-04 -2.5173e-04 1.6693e-04 1.0492e-04 -6.0000e+00 1.1992e-02 -3.7521e-03 4.3195e-05 11 8 0 10 0 0 99.94 17.51 0.16 -0.00375 -0.00564 352 69 1 5 0 142.520 22.80 14.99 17.51 25.25 30.6 988.58 -145980 -144495 -70615 -173175 -129761 -178635 18777 -151702 113832 -147736 -95614 -122803 -85345 -71210 -75784 25124 -70526 23309 -43493 -17274 -47241 -3454 -23101 -39589 -17404 -38224 15319 -29874 -1541 -35959 1824 -23002 -3538 -2717 -15458 7479 -20953 9179 -6971 9760 -1161 4786 -2527 6084 4252 698 7075 -663 11363 1316 10946 1049 9036 5643 3551 4010 3614 5960 -847 4050 957 4193 1248 7120 1756 2363 1258 634 3113 175 3203 182 2062 -891 558 -1575 -1081 -1952 -1772 189 -1935 51 -2260 -1308 -1545 362 184 65 634 -189 837 -750 -89 -1179 202 -882 538 527 77 -504 -591 -610 -1294 412 -1946 -1217 -1433 -517 -336 430 739 238 557 -42 459 -274 659 -342 353 -39 -128 418 422 755 -464 204 -401 1479 24 194 -173 -101 -135 -186 -80 -542 318 49 446 -415 212 -205 -121 -1039 -1221 -377 -1991 -981 -1981 100 -1687 608 -1820 -808 -1530 -911 -855 -1120 179 -1390 218 -804 -262 -1009 -52 -408 -894 -343 -989 259 -724 -28 -975 40 -775 -115 -96 -572 233 -871 358 -364 521 -79 336 -202 464 337 59 575 -60 958 131 1094 121 1144 753 518 611 572 929 -139 621 155 715 248 1508 421 562 296 153 799 53 1054 65 731 -311 178 -462 -291 -525 -519 64 -785 23 -1172 -719 -909 224 120 44 431 -126 521 -442 -50 -670 124 -630 439 493 80 -539 -603 -566 -1104 364 -1739 -1234 -1434 -586 -386 585 1037 359 851 -63 695 -399 942 -513 557 -66 -215 677 657 1133 -677 285 -544 2005 36 332 -327 -206 -289 -422 -193 -1396 839 131 1201 -1096 525 -481 -273 SS 20240808T124955.9Z 8986.534675 113 1 20.56 2 63.61 92.94 106.16 75.09 0.00 1 0.00 1 0 17 3.004e-02 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