File name: Pandora108s1_Toronto-West_20240828_L2Fit_fout2c6d20211104p1-8.txt File generation date: 20240829T052401.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v4d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20240828_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20240828 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240828T124131.2Z 9006.528834 263 1 49.88 2 68.69 97.47 15.73 165.57 0.00 1 0.00 1 0 25 2.761e-01 2.564e-02 2.283e-01 2.053e-02 3.542260e-01 1.083864e-02 4.326721e-03 -6.000000e+00 1.628252e-01 230.66 -2.00 3.57 -2.00 319.38 0.00e+00 6.354972e-04 2.835960e-03 7.142103e-04 -6.000000e+00 7.864280e-03 286.60 -2.00 20.00 -2.00 318.60 0.00e+00 2.725 0.000 302.00 328.00 3 5.9216e+00 3.0746e-02 3.3085e-02 -6.0000e+00 4.0761e-01 7.6221e-02 3.5886e-02 1.9462e-02 -6.0000e+00 4.4091e-01 4.1403e-02 2.6412e-02 9.4936e-03 -6.0000e+00 2.6180e-01 -2.9838e-02 1.3791e-02 2.6235e-03 -6.0000e+00 1.1269e-01 5.9336e-05 1.6482e-04 6.4533e-04 3.2317e-05 -6.0000e+00 7.8628e-03 -4.8682e-03 2.3126e-04 12 8 8 10 0 0 99.78 17.51 0.55 -0.00487 -0.00363 17 3 1 5 0 2934.100 22.90 15.00 17.51 31.19 30.7 1005.46 900000 6337 900000 -63562 161963 -18357 52015 142393 -8123 900000 -30109 900000 -36814 167107 346 40245 -5875 5889 30173 -1078 53200 -18301 37668 -9826 24075 -17428 31466 1546 299 23662 -16197 32292 -20581 43514 -17330 27705 -21801 6626 2093 9137 6270 -3755 12957 -12185 7174 -10229 4330 -11549 4380 -3318 -4778 5480 -3340 10588 -3421 9641 -7083 5012 -2564 3396 -907 -1065 7608 1127 6330 -2747 7058 -4692 5658 -2863 5483 566 -114 3894 -3056 2478 -8029 6643 -5002 1620 -3903 -1495 -2726 -1189 2779 -2241 3406 -2204 3562 -1155 2990 -2284 1548 -1017 -2728 1050 -2215 3369 -1302 2234 -2491 865 -2853 -1730 -1646 -2375 333 -2691 2747 -476 3777 -781 2248 -1072 225 414 -1141 -720 -3169 1909 -1585 2074 -1219 2310 114 -171 -1523 1462 2382 -773 2289 -1287 1710 -649 42 -1451 612 568 -838 2035 -1142 1167 -2229 900000 180 900000 -3541 3241 -597 1041 2849 -316 900000 -1579 900000 -2403 3344 22 1986 -480 459 1973 -99 3038 -2064 2557 -1107 2101 -2375 2753 173 32 2031 -2171 3013 -3510 4275 -2965 3004 -4014 1073 423 2050 1613 -1144 3472 -4287 2098 -3576 1311 -4044 1311 -1086 -1679 1878 -1345 3950 -1540 3921 -3487 2209 -1197 1480 -420 -529 3778 649 3556 -1629 3560 -2595 2956 -1823 3575 409 -84 2674 -2120 1474 -4827 3267 -2843 966 -2789 -1166 -2332 -1061 2529 -2304 3493 -2489 3823 -1270 2962 -2194 1326 -859 -2455 1000 -2445 3913 -1716 2869 -3200 990 -3155 -1892 -1915 -2979 424 -3725 3796 -730 5924 -1329 3664 -1710 330 567 -1563 -1010 -4845 2949 -2613 3272 -1931 3415 165 -237 -2035 1890 3225 -1174 3595 -2185 2885 -1163 79 -2928 1253 1185 -1799 4163 -2327 2224 -4268 SS 20240828T125206.6Z 9006.536187 266 1 50.16 2 66.80 99.42 15.40 173.94 0.00 1 0.00 1 0 17 2.207e-02 5.484e-03 1.931e-02 2.249e-03 3.264505e-01 1.169521e-03 3.917449e-03 -6.000000e+00 1.298974e-02 230.66 -2.00 3.57 -2.00 319.35 0.00e+00 6.581578e-04 2.952941e-04 3.688422e-04 -6.000000e+00 5.757712e-04 286.60 -2.00 20.00 -2.00 318.55 0.00e+00 2.518 0.000 302.00 328.00 3 2.0584e+00 3.3039e-03 3.0392e-02 -6.0000e+00 3.2445e-02 -1.7135e-03 3.8369e-03 1.7538e-02 -6.0000e+00 3.5048e-02 2.1237e-02 2.7102e-03 8.6227e-03 -6.0000e+00 2.0885e-02 -1.8028e-02 1.4042e-03 2.4552e-03 -6.0000e+00 8.8648e-03 3.7916e-03 1.6499e-04 7.0254e-05 2.8990e-05 -6.0000e+00 6.2261e-04 -4.9026e-03 1.2757e-04 10 0 0 10 0 0 99.98 17.52 0.11 -0.00490 -0.00366 1141 224 1 5 0 43.960 22.90 14.99 17.52 31.63 30.9 1008.01 3953 -5256 4186 -11266 -311 -14620 1504 -5775 412 -4657 -2193 247 -1670 3836 -2072 2870 -2253 1906 -1986 1127 -822 -348 977 -1164 1540 -2644 208 -4322 419 -2802 1532 684 550 -392 -5221 -1220 -4133 668 -1523 849 -1720 -374 -328 -799 -36 -606 -289 -1485 -360 -1090 1492 335 1521 1106 1387 1231 464 1137 -542 890 283 2475 1406 2125 325 -61 204 -337 1051 451 703 139 447 -338 -120 -1168 -825 -1008 -1077 -620 -1685 -787 -2189 -1019 -913 -82 -176 464 635 590 735 54 351 -125 786 -283 646 770 338 -242 -416 -552 -881 18 -1318 -1096 -1076 -215 -45 686 555 371 448 -73 249 -211 404 -357 75 -264 -207 144 95 448 -48 193 -257 1270 139 190 -306 -196 -64 -7 64 -384 227 152 258 -346 107 -227 -150 126 -204 156 -471 -11 -554 52 -234 18 -223 -105 12 -92 232 -153 227 -201 173 -196 113 -86 -37 104 -133 183 -344 27 -559 49 -335 187 92 82 -62 -840 -184 -679 121 -337 217 -501 -115 -104 -262 -12 -201 -95 -488 -116 -359 506 123 596 460 605 551 215 528 -252 405 132 1212 756 1231 196 -36 110 -179 576 278 481 101 328 -243 -81 -725 -466 -538 -593 -379 -1181 -609 -1860 -906 -861 -82 -187 512 704 642 748 51 306 -105 686 -274 693 917 437 -317 -522 -640 -959 20 -1547 -1376 -1410 -295 -64 1053 906 628 747 -116 367 -291 549 -503 112 -421 -342 236 151 690 -70 273 -347 1688 197 292 -502 -335 -111 -12 122 -779 475 325 559 -740 220 -451 -290 SS 20240828T125813.8Z 9006.540438 270 1 3.06 2 65.71 100.56 15.33 178.89 0.00 1 0.00 1 0 17 4.886e-02 1.014e-02 3.950e-02 6.986e-03 3.079751e-01 3.607825e-03 3.683155e-03 -6.000000e+00 2.877417e-02 230.66 -2.00 3.57 -2.00 318.39 0.00e+00 2.433563e-04 7.033199e-04 1.248723e-04 -6.000000e+00 1.275222e-03 286.59 -2.00 20.00 -2.00 317.58 0.00e+00 2.413 0.000 302.00 328.00 3 3.5800e+00 9.8134e-03 2.8893e-02 -6.0000e+00 7.1870e-02 1.7680e-03 1.1162e-02 1.6374e-02 -6.0000e+00 7.7619e-02 1.8426e-02 7.2628e-03 7.9703e-03 -6.0000e+00 4.6256e-02 -1.4331e-02 3.7323e-03 2.2327e-03 -6.0000e+00 1.9644e-02 9.4038e-04 7.1403e-04 2.1104e-04 2.4917e-05 -6.0000e+00 1.3781e-03 -5.6760e-03 2.5315e-04 12 9 9 12 1 1 -832.44 17.52 0.39 -0.00568 -0.00031 3 13 1 5 0 764.360 22.90 15.00 17.52 31.90 30.9 1009.09 -22631 9802 -17646 -859 -16150 -7054 3864 -12222 9539 -23152 10744 -14337 12234 -4705 5167 4419 -2140 6052 -7382 6166 -9214 4849 -6390 6177 -388 1799 -4012 -2207 -921 -4165 7477 -4415 6299 -5147 2082 -2889 2102 -949 1344 674 -1640 1977 -1736 888 -2017 1797 -1663 370 -8 -97 2467 -627 5216 229 2719 -777 2029 227 611 97 75 2956 709 3345 -836 -483 -650 143 1684 168 -216 485 729 -2044 1347 -1932 632 -3340 -696 -930 -1397 -480 -2267 -1547 -1942 683 -1180 1399 -147 1709 346 591 125 -359 130 -1299 1039 -179 1171 -755 -403 -1395 257 -58 -930 -524 -1109 693 -545 1126 -273 96 477 171 787 -137 902 -1136 745 -1050 401 -414 84 875 446 19 -232 1516 -56 884 -1168 422 -22 730 96 -12 -77 215 343 -825 -64 -711 -161 -1402 502 -1226 -50 -986 -375 194 -794 569 -2010 691 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