File name: Pandora108s1_Toronto-West_20250101_L2Fit_fout2c6d20211104p1-8.txt File generation date: 20250102T052818.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora108_OF_v4d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20250101_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20250101 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250101T164251.2Z 9132.696426 165 1 50.25 2 67.25 170.23 75.02 147.83 0.00 1 0.00 1 0 17 1.845e-01 1.293e-02 1.004e-01 5.312e-03 4.069512e-01 2.707562e-03 4.905855e-03 -6.000000e+00 1.053018e-01 222.87 -2.00 3.57 -2.00 319.71 0.00e+00 1.092435e-03 7.592060e-04 2.427352e-04 -6.000000e+00 4.544652e-03 272.99 -2.00 20.00 -2.00 319.19 0.00e+00 2.565 0.000 302.00 328.00 3 4.4587e+00 7.5947e-03 3.2798e-02 -6.0000e+00 2.5952e-01 4.4720e-02 8.9399e-03 2.1118e-02 -6.0000e+00 2.8265e-01 -1.1283e-02 7.3343e-03 1.0872e-02 -6.0000e+00 1.6808e-01 -2.9590e-03 3.8609e-03 3.4296e-03 -6.0000e+00 7.1539e-02 2.8931e-04 -4.6579e-04 1.6264e-04 4.0926e-05 -6.0000e+00 5.1915e-03 -3.0829e-03 -9.9448e-06 12 8 8 10 0 0 89.18 17.67 0.61 -0.00308 -0.00658 32 6 1 5 0 1570.150 23.01 15.00 17.67 7.08 29.8 985.50 -70873 90522 -48684 33363 -23542 -11494 34501 -28960 93419 -44738 96889 -40376 23957 -22844 -182 -7648 -6161 17699 -7826 21547 -16032 16404 -10536 18850 -12222 -730 -2771 -4812 5879 -10066 24229 -9452 17899 -10240 7900 -7959 892 923 -296 4348 -3914 6865 -4770 7317 -4307 4528 -2699 1705 1936 -2041 4705 -2028 6800 -1788 5589 -1528 2751 -1078 982 1380 -197 5311 -196 5500 -2485 3066 -1656 2247 411 474 166 -1055 1506 -2081 1707 -3447 1670 -4144 597 -2079 -1305 -780 -3110 107 -1875 1347 -1820 1486 -1073 890 -287 174 799 -423 1993 -1511 2463 -127 854 -1193 420 -629 -378 713 -2182 409 -2134 484 -695 1320 -402 272 93 -202 1299 -574 1656 -884 821 -1281 235 -172 168 382 -36 886 -869 3040 -588 1000 -831 486 -220 538 -218 -872 474 -348 459 -977 641 -794 418 -2583 817 -1733 534 -594 -248 506 -863 986 -1870 1094 -1763 654 -1157 -9 -457 -395 969 -578 1262 -1381 1044 -885 1274 -1191 -67 -265 -453 479 -956 1805 -1091 1773 -1415 893 -1022 112 134 -52 873 -950 1614 -1302 1827 -1209 1179 -755 456 520 -584 1346 -671 2234 -680 2086 -628 1114 -456 399 551 -82 2236 -95 2773 -1395 1585 -847 1093 214 277 108 -732 1029 -1417 1053 -2021 853 -2140 308 -1243 -883 -588 -2600 92 -1737 1297 -1897 1560 -1158 922 -282 158 672 -350 1708 -1480 2613 -153 1108 -1590 528 -734 -409 762 -2543 497 -2764 646 -991 1996 -661 462 157 -327 1942 -822 2294 -1288 1249 -2095 387 -282 266 584 -53 1243 -1185 4009 -853 1562 -1409 851 -398 1005 -434 -1830 1013 -763 1010 -2127 1326 -1589 804 SS 20250101T165221.0Z 9132.703021 172 1 51.43 2 66.99 172.59 74.14 149.81 0.00 1 0.00 1 0 17 2.023e-01 1.123e-02 1.820e-01 1.232e-02 4.040790e-01 6.274605e-03 4.880078e-03 -6.000000e+00 1.154454e-01 222.87 -2.00 3.57 -2.00 319.64 0.00e+00 2.061544e-03 1.709977e-03 4.353850e-04 -6.000000e+00 4.983351e-03 272.99 -2.00 20.00 -2.00 319.11 0.00e+00 2.539 0.000 302.00 328.00 3 5.6256e+00 1.7509e-02 3.2481e-02 -6.0000e+00 2.8451e-01 8.4072e-02 2.0542e-02 2.0903e-02 -6.0000e+00 3.0994e-01 -6.5649e-03 1.6543e-02 1.0932e-02 -6.0000e+00 1.8430e-01 -7.3400e-03 8.7164e-03 3.8175e-03 -6.0000e+00 7.8397e-02 9.0224e-05 -7.7363e-04 3.7744e-04 4.4390e-05 -6.0000e+00 5.6957e-03 -1.8671e-03 -1.2289e-04 12 8 8 10 0 0 99.99 17.67 0.49 -0.00187 -0.00768 19 4 1 5 0 2706.750 23.01 15.00 17.67 7.38 29.8 987.29 -45777 98877 -34378 158029 -56995 32327 -57661 -11208 -46039 -21844 22139 -40821 20124 -13624 37726 -6836 24091 -5278 5793 901 -7967 -2657 -7672 30484 -6511 15205 -13344 1776 -11484 2996 11565 5616 4766 -6773 7918 -11825 4062 -2950 69 -2402 -931 649 -1254 2392 -3009 4883 -593 3390 -1416 5305 -1108 118 2277 184 7483 1523 3660 -3637 3884 -822 2223 2210 818 3497 -714 -246 -1165 1156 -1123 3782 -187 1482 501 -1607 236 -4141 -503 -3520 -1083 -3758 148 -2186 -1406 -1495 -1244 -605 -444 1777 -425 1377 26 358 -801 425 614 -534 471 129 -31 -1355 828 -335 1573 -821 -1400 -1160 -864 146 -440 2000 292 1311 173 552 -322 -253 -49 -716 482 -805 372 -628 922 452 374 -255 -522 1324 -314 73 -699 -313 -864 831 -195 415 486 -9 74 -898 278 -381 241 -1457 1188 -1179 1898 -2172 519 -2216 -311 -1969 -793 552 -1919 621 -683 1389 -436 1252 -387 404 69 -680 -217 -668 1964 -632 1262 -1475 164 -1163 265 1033 593 567 -952 941 -1656 520 -467 13 -535 -227 168 -342 648 -863 1313 -168 925 -408 1464 -347 39 808 71 2819 623 1505 -1610 1565 -343 918 984 404 1844 -404 -134 -605 580 -607 2189 -125 1021 351 -1105 149 -2472 -265 -1827 -575 -2315 100 -1694 -1172 -1320 -1160 -601 -463 1884 -462 1432 26 325 -686 350 535 -520 513 157 -41 -1822 1040 -391 1670 -891 -1623 -1432 -1108 196 -629 3019 479 2219 293 887 -488 -360 -68 -1038 734 -1308 612 -1028 1443 687 544 -357 -702 1753 -450 114 -1175 -548 -1561 1539 -385 859 1037 -19 163 -1946 574 -754 461 SS 20250101T171022.1Z 9132.715534 181 1 49.24 2 66.70 177.09 72.60 153.66 0.00 1 0.00 1 0 17 4.101e-02 9.012e-03 7.972e-02 5.821e-03 4.055401e-01 2.963160e-03 4.890369e-03 -6.000000e+00 2.341077e-02 222.87 -2.00 3.57 -2.00 319.63 0.00e+00 -2.219622e-03 8.042617e-04 5.667841e-04 -6.000000e+00 1.010373e-03 272.99 -2.00 20.00 -2.00 319.10 0.00e+00 2.509 0.000 302.00 328.00 3 4.6920e+00 8.2837e-03 3.2520e-02 -6.0000e+00 5.7696e-02 4.1874e-02 9.7246e-03 2.1766e-02 -6.0000e+00 6.2840e-02 8.8694e-04 7.9120e-03 1.0760e-02 -6.0000e+00 3.7368e-02 -1.1476e-02 4.1753e-03 3.9369e-03 -6.0000e+00 1.5904e-02 2.4438e-04 -4.8372e-04 1.7851e-04 4.1519e-05 -6.0000e+00 1.1542e-03 -2.7715e-03 -1.7058e-06 11 8 0 10 0 0 98.33 17.66 0.16 -0.00277 -0.00641 26 5 1 5 0 1893.830 23.01 15.00 17.66 7.52 29.9 988.18 18415 -4998 1434 -5709 13745 -20469 5240 2461 -13233 -7676 -7156 8492 -7188 -264 -13175 -548 -6185 -10101 3407 -1314 -4950 -3674 2510 290 2571 -3077 -675 -521 1467 -1725 -1293 -3784 -33 1277 -6298 -2297 -3034 2986 -154 1843 2560 2517 1947 182 3368 -602 -988 -2747 -786 840 1726 1009 1240 1599 1305 2398 2208 -15401 2556 2952 1042 2318 2203 2264 728 -935 762 -757 1920 141 737 687 483 711 -20 237 -379 -1174 -1124 -637 -780 -1281 -1408 -1104 -163 277 59 393 245 -25 331 557 890 1119 212 437 280 767 -431 -716 -573 -643 -324 367 -1330 -1206 -923 -454 -26 698 84 -11 368 68 747 595 659 426 228 -460 -564 9 -11 191 -271 133 157 1515 268 -256 -187 -217 -130 261 -7 -580 347 5 -108 -198 160 -228 193 303 -115 33 -136 252 -497 107 58 -416 -247 -239 256 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