File name: Pandora108s1_Toronto-West_20250125_L2Fit_fsus1c6d20211104p1-8.txt File generation date: 20250126T053745.3Z Data description: Level 2 spectral fitting results file Data file version: fsus1c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora108_OF_v4d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20250125_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20250125 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 238 383 Nominal wavelengths inside fitting window [nm]: 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 325.0558 325.1951 325.3343 325.4735 325.6128 325.7520 325.8912 326.0303 326.1695 326.3087 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Bromine oxide slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of bromine oxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of bromine oxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of bromine oxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of bromine oxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Bromine oxide effective temperature [K] Column 28: Independent uncertainty of bromine oxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of bromine oxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of bromine oxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective bromine oxide fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for bromine oxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Formaldehyde slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of formaldehyde slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Formaldehyde effective temperature [K] Column 39: Independent uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective formaldehyde fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for formaldehyde [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrous acid slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrous acid slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrous acid slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrous acid slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrous acid slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrous acid effective temperature [K] Column 50: Independent uncertainty of nitrous acid effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrous acid effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrous acid effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrous acid fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrous acid [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 56: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Nitrogen dioxide effective temperature [K] Column 61: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: rms-based uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 76: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 77: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 78: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 79: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 80: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 82: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 83: Sulfur dioxide effective temperature [K] Column 84: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 85: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 86: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 87: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 88: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 89: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 90: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 91: Lower limit used for wavelength scaling [nm] Column 92: Upper limit used for wavelength scaling [nm] Column 93: Order of smoothing polynomial Column 94: Smoothing polynomial coefficient, order 0 Column 95: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 99: Smoothing polynomial coefficient, order 1 Column 100: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 104: Smoothing polynomial coefficient, order 2 Column 105: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 109: Smoothing polynomial coefficient, order 3 Column 110: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 114: Smoothing polynomial coefficient, order 4 Column 115: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 119: Mean value of measured data inside fitting window [same units as measurements] Column 120: Offset polynomial coefficient, order 0 Column 121: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 125: Wavelength change polynomial coefficient, order 0 Column 126: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 130: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 131: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 132: Resolution change polynomial coefficient, order 0 Column 133: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 134: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 135: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 136: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 137: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 138: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 139: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 140: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 141: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 142: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 143: Atmospheric variability [%], 999=no atmospheric variability was determined Column 144: Wavelength effective temperature [°C], 999=no effective temperature given Column 145: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 146: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 147: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 148: Number of bright count cycles Column 149: Number of dark count cycles Column 150: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 151: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 152: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 153: Integration time [ms] Column 154: Temperature at electronics board [°C], 999=no temperature signal Column 155: Spectrometer control temperature [°C], 999=no temperature signal Column 156: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 157: Temperature in head sensor [°C], 999=no temperature signal Column 158: Humidity in head sensor [%], -9=no humidity signal Column 159: Pressure in head sensor [hPa], -9=no pressure signal Columns 160-305: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 306-451: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250125T174946.4Z 9156.742899 289 1 2.69 2 62.63 185.11 88.67 226.52 0.00 1 0.00 1 0 87 3.682e-02 6.678e-03 5.507e-02 8.766e-03 1.884956e-08 3.214455e-06 8.573752e-08 4.995889e-07 1.671997e-05 223.83 -2.00 3.57 -2.00 322.58 0.00e+00 -4.373289e-04 1.260967e-03 6.066140e-05 6.419264e-05 4.329647e-03 272.10 -2.00 20.00 -2.00 322.75 0.00e+00 1.171161e-03 1.642320e-03 1.397994e-05 3.431112e-05 7.973645e-03 272.10 -2.00 20.00 -2.00 322.23 0.00e+00 -1.067228e-04 2.969357e-03 4.930316e-05 2.961716e-05 8.007226e-03 272.10 -2.00 20.00 -2.00 322.42 0.00e+00 3.853574e-01 1.508919e-02 1.847910e-04 7.398657e-03 4.690354e-02 222.06 8.97 0.00 0.58 81.25 319.75 0.00e+00 -5.831899e-04 1.157154e-03 3.569424e-05 3.317067e-05 1.142139e-03 272.10 -2.00 20.00 -2.00 318.84 0.00e+00 2.164 0.000 303.00 329.40 4 4.0888e+00 3.2681e-02 2.0589e-02 2.5882e-03 1.4531e-01 4.1412e-02 5.5027e-02 2.4986e-03 4.4750e-04 1.5663e-01 -2.6752e-02 3.0080e-02 4.9622e-04 1.8167e-04 8.4753e-02 1.8502e-02 1.8867e-02 6.7283e-04 1.3410e-04 3.5015e-02 -8.9633e-04 1.0492e-02 9.7364e-05 1.1493e-04 2.5594e-02 7.4311e-04 6.4832e-03 6.1597e-03 1.2232e-04 2.7669e-05 4.0894e-03 -3.8799e-04 2.7622e-04 3.0548e-06 1.2515e-06 1.1431e-03 -1.8480e-03 -7.6456e-05 -9.1349e-01 7.9197e-01 4.9338e-03 6.4027e-04 2.6434e+00 12 9 9 12 1 1 999.00 17.97 0.35 -0.00185 -0.00481 2 11 1 5 0 896.320 23.32 15.00 17.97 2.30 29.8 1000.73 -19295 -8315 -14787 -9616 -14711 -1324 -9400 -4064 -2044 -2526 9195 -7051 11325 2357 7249 -3489 4657 665 2767 1869 -3300 6928 -7941 3537 -3603 6536 -589 854 -459 107 3044 -2139 3454 -2203 2778 -1976 2317 186 -110 668 -2205 601 -2022 2838 -2196 2494 -1414 1209 -142 -359 1273 -566 -499 -581 1395 -1398 1241 -1500 1373 173 -36 -36 -68 14 120 1172 -3008 1278 -1234 505 562 1 -706 -1356 598 -21 -33 36 -95 -691 1234 -633 -658 195 -559 2222 -1228 498 -271 593 -188 394 220 -203 126 -1500 879 -911 1201 50 331 447 274 128 -1201 492 -521 279 269 120 376 -303 685 -305 -226 -310 265 173 -113 -146 285 -110 415 -19 -688 266 -147 -282 54 481 -45 -473 -311 303 583 -63 -330 416 1 -792 300 -475 471 48 69 8 -737 -323 -680 -435 -726 -64 -590 -285 -161 -218 744 -710 984 231 678 -368 485 78 337 234 -421 752 -981 415 -507 922 -96 136 -71 17 548 -483 875 -660 844 -649 746 61 -36 219 -737 196 -684 962 -841 977 -608 532 -65 -169 593 -263 -228 -268 670 -747 701 -904 784 95 -19 -20 -42 9 85 832 -2146 832 -754 280 299 1 -436 -947 453 -17 -28 32 -90 -683 1233 -644 -655 183 -494 1805 -997 417 -249 593 -206 461 260 -232 133 -1514 868 -970 1327 57 395 556 361 178 -1737 698 -716 361 331 146 468 -397 932 -426 -312 -418 347 219 -138 -173 332 -136 549 -26 -999 391 -223 -447 89 804 -76 -813 -527 496 921 -98 -520 682 2 -1472 583 -976 993 103 149 17 SS 20250125T175518.8Z 9156.746745 293 1 50.21 2 62.73 186.58 89.38 227.46 0.00 1 0.00 1 0 87 8.494e-02 1.353e-02 1.489e-01 1.218e-02 3.440522e-06 4.575914e-06 1.239046e-07 4.997291e-07 3.629033e-05 223.83 -2.00 3.57 -2.00 323.23 0.00e+00 1.197936e-03 1.886913e-03 1.212658e-04 6.409220e-05 9.875315e-03 272.10 -2.00 20.00 -2.00 323.73 0.00e+00 2.458734e-03 2.490660e-03 6.488248e-05 3.435303e-05 1.809290e-02 272.10 -2.00 20.00 -2.00 322.73 0.00e+00 5.487450e-03 4.835315e-03 4.761884e-04 2.986622e-05 1.847386e-02 272.10 -2.00 20.00 -2.00 323.05 0.00e+00 3.799396e-01 2.380690e-02 1.677114e-03 7.394759e-03 1.072037e-01 220.71 14.29 0.00 0.59 181.99 320.71 0.00e+00 3.785887e-04 2.079838e-03 5.707751e-04 3.301502e-05 2.634458e-03 272.10 -2.00 20.00 -2.00 319.75 0.00e+00 2.171 0.000 303.00 329.40 4 4.8330e+00 4.7653e-02 2.1131e-02 2.5855e-03 3.2883e-01 6.2022e-02 8.7232e-02 1.1235e-02 4.5896e-04 3.5623e-01 -9.2446e-02 4.8114e-02 5.1713e-03 1.8580e-04 1.9373e-01 1.2122e-01 2.5666e-02 1.5077e-03 1.3132e-04 6.6585e-02 -4.9792e-02 1.4229e-02 4.7039e-04 1.1532e-04 5.1310e-02 3.0368e-04 7.5254e-02 1.6215e-02 8.5115e-05 1.6175e-05 1.5692e-03 6.4593e-04 4.2862e-04 1.3799e-05 1.2786e-06 2.6661e-03 -1.6777e-03 7.6761e-05 1.6125e+00 1.2251e+00 2.2578e-02 1.4221e-03 5.9119e+00 12 8 8 10 0 0 99.92 17.98 0.67 -0.00168 0.00325 241 47 1 5 0 208.310 23.32 15.00 17.98 2.62 29.9 1000.59 -25048 -23848 -25013 -4987 -46237 3908 -28714 20185 -12021 17473 -176 4795 5504 -2235 17641 -9951 18213 -10664 22149 -5138 16433 -7696 -4894 -2272 -10951 11100 -13669 9346 -14660 16007 -5730 12817 -62 5986 6442 791 9040 -4592 10166 -3265 8444 -667 3796 961 -1457 2200 -1875 4940 -3349 5902 -4855 5367 -1957 2965 -725 -780 2342 -3020 3507 -4217 2015 -3805 2529 -2581 1837 -1318 -2051 983 -4583 2141 -5049 3202 -4173 1294 -1103 1069 150 342 2015 -1592 2063 -2127 1049 -2063 1125 -2734 -1613 -995 -1983 916 -1008 2655 -1117 2029 -1156 1360 16 345 -48 -1590 1487 -142 1792 -31 1775 -633 808 -650 39 -24 -807 1113 -1511 1727 -726 1300 -532 616 -1649 94 746 -1151 519 -1433 1146 -1313 765 -956 -65 126 -43 -17 -505 273 -668 2047 -1192 581 -705 39 270 -266 654 -532 720 -353 -426 -551 -736 -74 -2350 64 -1647 520 -802 763 -11 304 357 -169 928 -830 1025 -1040 1373 -494 1055 -653 -384 -185 -1163 973 -1856 901 -1848 1412 -813 1779 -12 1264 1444 196 2075 -1227 2298 -857 1907 -166 909 250 -425 663 -630 1618 -1234 2014 -1872 1803 -700 1022 -279 -330 1045 -1490 1552 -1898 830 -1735 1220 -1468 1053 -787 -1191 518 -2317 911 -2214 1335 -2147 725 -713 738 110 265 1636 -1410 1813 -1958 909 -1723 835 -1959 -1104 -717 -1615 815 -1024 2830 -1251 2088 -1131 1200 15 330 -49 -1729 1651 -170 2244 -42 2479 -895 1066 -810 45 -28 -962 1380 -2045 2322 -988 1679 -672 731 -1917 103 801 -1355 657 -1987 1620 -1952 1157 -1563 -112 221 -78 -31 -902 463 -1096 3168 -1934 984 -1315 79 585 -624 1595 -1350 1817 -891