File name: Pandora108s1_Toronto-West_20250214_L2Fit_fout2c6d20211104p1-8.txt File generation date: 20250215T053559.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora108_OF_v4d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20250214_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20250214 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250214T142508.9Z 9176.600797 317 1 50.19 2 70.76 131.16 102.49 288.53 0.00 1 0.00 1 0 25 2.364e-01 1.424e-02 1.367e-01 7.455e-03 4.064619e-01 3.865978e-03 4.844495e-03 -6.000000e+00 1.357944e-01 224.62 -2.00 3.57 -2.00 319.94 0.00e+00 1.546140e-03 1.134944e-03 2.119489e-04 -6.000000e+00 5.956863e-03 272.11 -2.00 20.00 -2.00 319.42 0.00e+00 3.000 0.000 302.00 328.00 3 3.7677e+00 1.0999e-02 3.6229e-02 -6.0000e+00 3.3605e-01 4.1134e-02 1.3002e-02 2.1407e-02 -6.0000e+00 3.6572e-01 -1.3079e-03 1.0937e-02 1.0949e-02 -6.0000e+00 2.1738e-01 -6.6851e-03 5.7209e-03 3.6745e-03 -6.0000e+00 9.2934e-02 3.8679e-04 -2.1625e-04 2.3489e-04 4.2569e-05 -6.0000e+00 6.7397e-03 3.3212e-03 4.7242e-05 12 8 8 10 0 0 99.97 18.01 0.46 0.00332 0.00170 149 29 1 5 0 336.780 23.43 15.00 18.01 -1.07 30.1 1018.50 -38084 900000 -63293 900000 -49562 192982 -45072 80551 -37239 -3953 23591 -25817 64481 -34056 62769 -30553 34781 -10307 21572 2697 4154 17528 -9995 40551 -17407 34210 -15548 25737 -6414 12336 5277 3950 11826 -10571 13700 -14734 19030 -9165 10112 -5208 1518 1839 -4326 5425 -3370 7786 -5111 9884 -4780 6243 30 3775 1853 345 4359 -3632 6306 -4902 4034 -3781 5090 846 1987 2771 -1977 2545 -5086 5120 -2750 4354 -1619 2028 -757 -1130 226 -2988 2555 -3124 3137 -3063 1107 -3584 -1021 -1961 -1369 17 -1142 1767 -1638 2028 -1006 1664 -930 1978 639 167 1711 -441 1007 -1487 1405 -1586 1789 -533 -623 -1462 -1195 157 -680 1283 -793 1348 -876 860 -111 1111 518 -353 990 -1394 374 -896 1065 -720 876 -537 482 1451 43 654 -1391 917 -865 1192 -626 -52 -295 143 52 -832 406 -846 1123 -963 900000 -2394 900000 -1501 1403 -1328 852 -1271 -106 511 -920 1176 -1782 1615 -2087 1421 -681 1122 175 273 1028 -770 2091 -1629 2090 -1529 1672 -542 881 440 372 1153 -1344 1352 -1859 1868 -1358 1491 -1051 319 414 -1071 1259 -856 1801 -1340 2246 -1260 1519 8 1091 590 119 1518 -1403 2275 -1980 1467 -1469 1855 347 882 1338 -1028 1228 -2501 2260 -1387 2307 -1007 1281 -496 -715 132 -1632 1213 -1504 1495 -1755 696 -2643 -797 -1638 -1206 16 -1135 1776 -1706 1989 -952 1417 -759 1533 534 156 1774 -521 1271 -1934 1694 -1806 1834 -561 -699 -1767 -1504 206 -956 1920 -1298 2251 -1479 1358 -166 1540 715 -507 1496 -2277 615 -1470 1664 -1107 1268 -758 643 1931 62 1028 -2387 1613 -1590 2241 -1270 -110 -649 318 118 -1851 859 -1726 2188 SS 20250214T144338.9Z 9176.613645 323 1 6.88 2 68.32 135.21 105.59 291.85 0.00 1 0.00 1 0 17 5.503e-02 8.198e-03 3.764e-02 4.160e-03 3.665119e-01 2.109888e-03 4.433585e-03 -6.000000e+00 3.160868e-02 224.62 -2.00 3.57 -2.00 319.15 0.00e+00 1.156901e-03 4.952147e-04 1.813803e-04 -6.000000e+00 1.350852e-03 272.12 -2.00 20.00 -2.00 318.62 0.00e+00 2.683 0.000 302.00 328.00 3 2.9553e+00 5.7810e-03 3.2430e-02 -6.0000e+00 7.8224e-02 3.5369e-02 6.6518e-03 1.9097e-02 -6.0000e+00 8.5125e-02 -4.2824e-03 4.9783e-03 9.6757e-03 -6.0000e+00 5.0529e-02 -7.4836e-03 2.6322e-03 3.0581e-03 -6.0000e+00 2.1396e-02 1.2515e-03 -1.9500e-04 1.2671e-04 3.4820e-05 -6.0000e+00 1.5498e-03 2.2390e-03 4.0277e-05 12 9 1 12 1 1 99.82 18.02 0.29 0.00224 0.00077 18 27 1 5 0 361.880 23.43 15.00 18.02 -0.37 30.1 1018.85 -31221 9877 -20009 6922 -21302 -8022 1189 -12252 3621 -20519 11555 -19568 8776 -9640 11770 -5967 -1290 4641 -3591 7566 -7428 4370 -6289 8224 -5218 1510 -5764 -3650 -1222 -2554 5162 -4120 6707 -5698 664 -4111 -285 -1356 -1276 405 -640 1528 -2736 2829 -1654 1205 -1803 478 191 1177 2215 644 2846 -36 2531 -824 2045 -861 226 895 881 3002 1502 3057 -1375 1396 -413 1317 1289 -2 90 -608 505 -1527 397 -1734 439 -2456 544 -1737 -969 -1290 -2156 -678 -1219 531 -1004 861 -326 189 175 87 519 622 1770 169 1481 1 203 -1037 -196 -190 -236 546 -1239 -710 -1509 347 -517 808 -237 232 254 186 473 190 1142 -302 575 -1013 -185 -392 625 -76 193 396 233 2125 -472 467 -687 283 -158 439 -114 -317 -7 -226 196 -582 211 -572 420 -1228 299 -838 219 -808 -257 37 -477 137 -1032 441 -1047 411 -631 738 -503 -112 407 -358 711 -824 437 -709 858 -658 188 -778 -465 -146 -307 625 -603 981 -987 105 -665 -47 -264 -296 109 -192 481 -926 933 -570 409 -627 162 65 404 799 253 1179 -16 1166 -401 993 -431 110 429 431 1546 851 1850 -885 847 -240 744 764 -1 66 -470 390 -1161 280 -1139 260 -1429 320 -1166 -727 -1073 -1939 -633 -1207 552 -1106 967 -371 210 184 85 474 552 1633 172 1658 2 269 -1394 -251 -227 -265 613 -1492 -902 -2001 475 -746 1230 -384 385 418 293 702 268 1583 -434 867 -1622 -301 -633 979 -116 283 561 319 2866 -685 723 -1131 479 -274 782 -214 -620 -13 -462 402 -1180 414 -1088 777 SS 20250214T144903.9Z 9176.617406 327 1 7.14 2 67.64 136.43 106.48 292.84 0.00 1 0.00 1 0 17 4.404e-02 8.451e-03 7.183e-02 8.636e-03 3.563707e-01 4.369659e-03 4.287694e-03 -6.000000e+00 2.529679e-02 224.62 -2.00 3.57 -2.00 318.92 0.00e+00 3.000370e-04 9.632881e-04 3.154183e-04 -6.000000e+00 1.081027e-03 272.12 -2.00 20.00 -2.00 318.39 0.00e+00 2.607 0.000 302.00 328.00 3 4.3815e+00 1.1875e-02 3.1467e-02 -6.0000e+00 6.2604e-02 4.4881e-02 1.3605e-02 1.8461e-02 -6.0000e+00 6.8123e-02 4.7775e-04 9.8943e-03 9.3262e-03 -6.0000e+00 4.0437e-02 -7.1985e-03 5.2315e-03 2.7661e-03 -6.0000e+00 1.7126e-02 3.2597e-04 2.7525e-04 2.6107e-04 3.1606e-05 -6.0000e+00 1.2400e-03 1.1067e-03 4.3901e-05 12 9 1 12 1 1 97.53 18.03 0.34 0.00111 0.00318 3 5 1 5 0 1783.720 23.43 15.00 18.03 -0.24 30.2 1018.94 -17975 -9991 -5018 8384 6073 10784 11458 -17021 9237 -17053 7049 -16372 7890 -7555 3850 -812 -815 7818 -6406 -1530 -6675 13459 -2618 2818 -6328 3144 -328 -6568 -329 -8037 -2144 -3398 4216 -3598 1794 -5799 2840 -1140 958 461 -3107 204 -2126 714 -420 1091 0 57 -985 50 2764 -275 2806 -197 1722 512 1999 -820 2512 1017 1233 1858 414 1225 -493 -30 -233 1511 1493 1202 86 1314 425 -329 -875 -2394 1333 -2637 -475 456 -999 -1352 -1990 -1459 -2291 670 -737 576 267 1609 -517 -726 158 784 -27 -93 1035 620 399 -855 -580 -201 200 432 -1674 -1506 -1018 85 573 1185 -249 -73 399 145 791 -160 421 -614 300 -235 58 -437 796 191 459 179 -153 1981 141 -269 -699 -64 -339 217 165 -246 11 -167 829 -914 543 -575 -112 -721 -418 -209 298 203 330 368 -799 381 -961 324 -981 427 -553 295 -74 -79 745 -734 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