File name: Pandora108s1_Toronto-West_20250419_L2Fit_fnvs5c6d20211104p1-8.txt
File generation date: 20250420T052132.0Z
Data description: Level 2 spectral fitting results file
Data file version: fnvs5c6p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 108
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora108_OF_v4d20210713.txt
Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt
Level 1 file used: Pandora108s1_Toronto-West_20250419_L1_smca1c6d20211104p1-8.txt
Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke)
Short location name: Toronto-West
Country of location: Canada
Location latitude [deg]: 43.7094
Location longitude [deg]: -79.5435
Location altitude [m]: 141
Local noon date: 20250419
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 926 1472
Nominal wavelengths inside fitting window [nm]: 400.0348 400.1669 400.2990 400.4311 400.5632 400.6953 400.8273 400.9594 401.0914 401.2234 401.3554 401.4874 401.6194 401.7514 401.8833 402.0152 402.1472 402.2791 402.4109 402.5428 402.6747 402.8065 402.9384 403.0702 403.2020 403.3338 403.4655 403.5973 403.7290 403.8608 403.9925 404.1242 404.2559 404.3875 404.5192 404.6509 404.7825 404.9141 405.0457 405.1773 405.3089 405.4404 405.5720 405.7035 405.8350 405.9665 406.0980 406.2295 406.3609 406.4924 406.6238 406.7552 406.8866 407.0180 407.1494 407.2807 407.4121 407.5434 407.6747 407.8060 407.9373 408.0685 408.1998 408.3310 408.4623 408.5935 408.7247 408.8559 408.9870 409.1182 409.2493 409.3804 409.5115 409.6426 409.7737 409.9048 410.0358 410.1669 410.2979 410.4289 410.5599 410.6909 410.8218 410.9528 411.0837 411.2146 411.3456 411.4764 411.6073 411.7382 411.8690 411.9999 412.1307 412.2615 412.3923 412.5230 412.6538 412.7846 412.9153 413.0460 413.1767 413.3074 413.4381 413.5687 413.6994 413.8300 413.9606 414.0912 414.2218 414.3523 414.4829 414.6134 414.7440 414.8745 415.0050 415.1355 415.2659 415.3964 415.5268 415.6572 415.7876 415.9180 416.0484 416.1788 416.3091 416.4395 416.5698 416.7001 416.8304 416.9606 417.0909 417.2211 417.3514 417.4816 417.6118 417.7420 417.8722 418.0023 418.1325 418.2626 418.3927 418.5228 418.6529 418.7829 418.9130 419.0430 419.1731 419.3031 419.4331 419.5630 419.6930 419.8229 419.9529 420.0828 420.2127 420.3426 420.4725 420.6023 420.7322 420.8620 420.9918 421.1216 421.2514 421.3812 421.5109 421.6407 421.7704 421.9001 422.0298 422.1595 422.2892 422.4188 422.5484 422.6781 422.8077 422.9373 423.0668 423.1964 423.3260 423.4555 423.5850 423.7145 423.8440 423.9735 424.1029 424.2324 424.3618 424.4912 424.6206 424.7500 424.8794 425.0087 425.1380 425.2674 425.3967 425.5260 425.6552 425.7845 425.9138 426.0430 426.1722 426.3014 426.4306 426.5598 426.6889 426.8181 426.9472 427.0763 427.2054 427.3345 427.4636 427.5926 427.7217 427.8507 427.9797 428.1087 428.2377 428.3666 428.4956 428.6245 428.7534 428.8823 429.0112 429.1401 429.2689 429.3978 429.5266 429.6554 429.7842 429.9130 430.0418 430.1705 430.2992 430.4280 430.5567 430.6854 430.8140 430.9427 431.0713 431.2000 431.3286 431.4572 431.5858 431.7143 431.8429 431.9714 432.1000 432.2285 432.3570 432.4854 432.6139 432.7423 432.8708 432.9992 433.1276 433.2560 433.3844 433.5127 433.6411 433.7694 433.8977 434.0260 434.1543 434.2825 434.4108 434.5390 434.6673 434.7955 434.9236 435.0518 435.1800 435.3081 435.4363 435.5644 435.6925 435.8206 435.9486 436.0767 436.2047 436.3327 436.4607 436.5887 436.7167 436.8447 436.9726 437.1006 437.2285 437.3564 437.4843 437.6121 437.7400 437.8678 437.9956 438.1234 438.2512 438.3790 438.5068 438.6345 438.7623 438.8900 439.0177 439.1454 439.2730 439.4007 439.5283 439.6560 439.7836 439.9112 440.0387 440.1663 440.2939 440.4214 440.5489 440.6764 440.8039 440.9314 441.0588 441.1863 441.3137 441.4411 441.5685 441.6959 441.8232 441.9506 442.0779 442.2052 442.3326 442.4598 442.5871 442.7144 442.8416 442.9688 443.0960 443.2232 443.3504 443.4776 443.6047 443.7319 443.8590 443.9861 444.1132 444.2403 444.3673 444.4944 444.6214 444.7484 444.8754 445.0024 445.1293 445.2563 445.3832 445.5101 445.6370 445.7639 445.8908 446.0176 446.1445 446.2713 446.3981 446.5249 446.6517 446.7785 446.9052 447.0319 447.1587 447.2854 447.4120 447.5387 447.6654 447.7920 447.9186 448.0452 448.1718 448.2984 448.4250 448.5515 448.6781 448.8046 448.9311 449.0576 449.1840 449.3105 449.4369 449.5633 449.6897 449.8161 449.9425 450.0689 450.1952 450.3215 450.4479 450.5742 450.7004 450.8267 450.9530 451.0792 451.2054 451.3316 451.4578 451.5840 451.7101 451.8363 451.9624 452.0885 452.2146 452.3407 452.4668 452.5928 452.7189 452.8449 452.9709 453.0969 453.2228 453.3488 453.4747 453.6007 453.7266 453.8525 453.9783 454.1042 454.2301 454.3559 454.4817 454.6075 454.7333 454.8591 454.9848 455.1105 455.2363 455.3620 455.4877 455.6133 455.7390 455.8646 455.9903 456.1159 456.2415 456.3671 456.4926 456.6182 456.7437 456.8692 456.9947 457.1202 457.2457 457.3712 457.4966 457.6220 457.7474 457.8728 457.9982 458.1236 458.2489 458.3742 458.4996 458.6249 458.7501 458.8754 459.0007 459.1259 459.2511 459.3763 459.5015 459.6267 459.7518 459.8770 460.0021 460.1272 460.2523 460.3774 460.5025 460.6275 460.7525 460.8776 461.0026 461.1275 461.2525 461.3775 461.5024 461.6273 461.7522 461.8771 462.0020 462.1269 462.2517 462.3765 462.5013 462.6261 462.7509 462.8757 463.0004 463.1252 463.2499 463.3746 463.4993 463.6239 463.7486 463.8732 463.9979 464.1225 464.2471 464.3716 464.4962 464.6207 464.7453 464.8698 464.9943 465.1187 465.2432 465.3677 465.4921 465.6165 465.7409 465.8653 465.9897 466.1140 466.2384 466.3627 466.4870 466.6113 466.7356 466.8598 466.9841 467.1083 467.2325 467.3567 467.4809 467.6050 467.7292 467.8533 467.9774 468.1015 468.2256 468.3497 468.4737 468.5978 468.7218 468.8458 468.9698 469.0937 469.2177 469.3416 469.4656 469.5895 469.7134 469.8372 469.9611
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Molecular iodine slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of molecular iodine slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Molecular iodine effective temperature [K]
Column 39: Independent uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective molecular iodine fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for molecular iodine [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Nitrogen dioxide effective temperature [K]
Column 50: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful
Column 56: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 57: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 58: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 59: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 60: Oxygen dimer effective temperature [K]
Column 61: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 62: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 63: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 64: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful
Column 65: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 71: Ozone effective temperature [K]
Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 75: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 76: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 77: Iodine dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 78: Independent uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 79: Structured uncertainty of iodine dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 80: Common uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 81: rms-based uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 82: Iodine dioxide effective temperature [K]
Column 83: Independent uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 84: Structured uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 85: Common uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 86: Effective iodine dioxide fitting wavelength [nm], -9=fitting not successful
Column 87: Diffuse correction applied before fitting at effective fitting wavelength for iodine dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 88: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 89: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 90: Lower limit used for wavelength scaling [nm]
Column 91: Upper limit used for wavelength scaling [nm]
Column 92: Order of smoothing polynomial
Column 93: Smoothing polynomial coefficient, order 0
Column 94: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 95: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 96: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 97: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 98: Smoothing polynomial coefficient, order 1
Column 99: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 100: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 101: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 102: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 103: Smoothing polynomial coefficient, order 2
Column 104: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 105: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 106: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 107: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 108: Smoothing polynomial coefficient, order 3
Column 109: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 110: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 111: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 112: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 113: Smoothing polynomial coefficient, order 4
Column 114: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful
Column 115: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful
Column 116: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful
Column 117: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful
Column 118: Mean value of measured data inside fitting window [same units as measurements]
Column 119: Offset polynomial coefficient, order 0
Column 120: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful
Column 121: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful
Column 122: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful
Column 123: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful
Column 124: Wavelength change polynomial coefficient, order 0
Column 125: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 126: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 127: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 128: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 129: Wavelength change polynomial coefficient, order 1
Column 130: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful
Column 131: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful
Column 132: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful
Column 133: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful
Column 134: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 135: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 136: Resolution change polynomial coefficient, order 0
Column 137: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful
Column 138: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful
Column 139: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful
Column 140: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful
Column 141: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 142: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 143: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 144: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 145: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 146: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 147: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 148: Wavelength effective temperature [°C], 999=no effective temperature given
Column 149: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 150: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 151: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 152: Number of bright count cycles
Column 153: Number of dark count cycles
Column 154: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 155: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 156: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 157: Integration time [ms]
Column 158: Temperature at electronics board [°C], 999=no temperature signal
Column 159: Spectrometer control temperature [°C], 999=no temperature signal
Column 160: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 161: Temperature in head sensor [°C], 999=no temperature signal
Column 162: Humidity in head sensor [%], -9=no humidity signal
Column 163: Pressure in head sensor [hPa], -9=no pressure signal
Columns 164-710: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 711-1257: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
---------------------------------------------------------------------------------------
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SQ 20250419T213250.5Z 9240.897806 558 5 5.96 2 63.31 260.10 159.30 315.67 0.00 1 0.00 1 0 33 2.747e-04 2.535e-04 1.545e-04 1.453e-04 -3.600102e+01 2.700042e+01 4.183151e+00 4.252391e+02 5.460239e+01 278.19 -2.00 20.00 -2.00 447.12 0.00e+00 2.115577e-04 1.662802e-05 1.441042e-06 2.454180e-05 2.985067e-05 278.19 -2.00 20.00 -2.00 456.33 0.00e+00 2.065353e-04 1.300676e-06 1.391964e-06 2.015329e-05 2.484823e-06 225.66 -2.00 2.20 -2.00 438.70 0.00e+00 1.023845e+05 1.968509e+04 2.859127e+03 2.641785e+05 3.943647e+04 260.35 -2.00 11.30 -2.00 458.53 0.00e+00 2.946335e-01 3.842929e-03 1.108815e-03 1.268066e-02 8.582291e-03 228.58 -2.00 3.57 -2.00 455.61 0.00e+00 -9.646353e-07 4.880326e-07 1.082439e-07 1.322310e-06 1.049043e-06 278.19 -2.00 20.00 -2.00 456.56 0.00e+00 2.214 0.000 397.00 473.00 4 8.3520e-01 1.6092e-04 5.5554e-03 5.1585e-04 2.7945e-04 -6.1869e-03 1.9473e-04 1.1601e-03 3.5803e-04 3.5039e-04 -1.6585e-03 1.0957e-04 1.5241e-04 2.2726e-04 1.9649e-04 -6.5610e-05 3.6806e-05 1.6615e-05 5.4086e-05 6.6412e-05 4.1936e-04 1.9020e-05 2.0807e-06 2.3892e-05 3.3298e-05 5.0599e-01 -1.7015e-03 1.0764e-04 5.9713e-06 1.6230e-04 1.6557e-04 -2.2780e-05 1.5558e-06 1.2807e-07 8.6604e-07 2.8711e-06 2.0630e-05 2.1514e-06 4.6418e-08 8.7491e-07 3.8968e-06 -1.3776e-03 -2.2209e-05 5.6646e-02 1.5664e-02 4.0779e-04 1.3264e-02 2.6124e-02 10 0 0 10 0 0 -4.60 18.27 0.87 -0.00138 -0.00363 1720 337 1 4 0 3.420 23.64 15.00 18.27 19.29 31.9 998.47 30 -11 38 -16 -16 -5 -9 -82 -18 5 30 42 9 29 -4 2 -36 39 19 9 6 -10 -41 -51 -12 -13 -10 -36 -21 -11 32 13 -1 30 -4 79 0 6 0 61 27 28 -22 -12 -14 -33 11 -2 38 41 17 -30 10 16 -45 14 -47 -52 -20 43 6 14 14 48 47 28 25 -9 47 47 47 27 14 -17 -65 -51 -82 -48 -4 28 -16 6 13 29 8 7 27 13 5 22 19 10 13 6 30 -14 -26 -16 -30 -6 -2 46 19 6 -75 -69 -70 -32 -39 -55 -32 -103 -98 -81 -51 -75 5 -16 3 -11 -34 -15 -19 5 -17 7 14 25 12 -26 -33 -36 3 -41 -30 -19 12 -2 19 2 18 -3 -20 34 14 -3 -4 52 45 41 30 7 15 -15 9 -7 27 14 41 34 52 53 35 34 24 30 3 14 -17 12 -10 -18 -34 -29 1 -45 -33 -11 54 8 14 -2 -2 -1 -9 6 3 -7 -19 -1 -3 -9 -19 -22 -28 -6 21 -12 -13 6 49 -7 -1 17 40 45 -7 -5 -15 -18 -19 -19 -48 -9 -20 6 11 -17 -8 10 23 4 26 28 22 30 44 41 7 14 -23 33 41 69 -7 12 25 72 69 93 103 60 58 20 25 51 78 36 25 -10 11 -13 -35 -21 5 35 31 27 -3 -33 -66 -50 -25 -62 3 -21 17 14 8 -19 1 -6 14 -10 -26 7 -5 14 -22 -19 -20 -11 -2 -9 -14 -27 -24 -55 -29 -25 -27 -31 3 -23 -53 -13 -36 -25 -25 1 17 30 -15 12 19 4 10 -49 -2 -23 -56 -18 7 -42 -1 -18 -30 -10 -29 17 -4 12 5 -14 -13 16 17 1 -1 3 -4 -3 28 -14 -9 1 -1 4 -9 13 -12 -6 -7 -5 -26 7 0 0 21 -13 28 -9 -15 -15 9 -5 32 50 12 38 17 5 -3 9 20 35 16 21 37 -8 16 -19 21 -7 -9 -20 -5 -20 -21 -18 -21 -20 -36 11 -16 7 -23 -32 -4 -30 -3 -14 3 3 13 2 15 5 2 -30 -21 -3 -19 6 -6 14 -8 8 -6 -6 -12 0 -14 -12 30 31 36 33 38 26 19 9 2 9 1 20 -1 -21 -48 -48 -58 -32 -39 -30 13 12 18 9 35 8 -6 0 -14 -14 12 -2 18 17 3 15 14 14 -1 -7 4 -5 9 2 7 10 39 1 31 20 7 -1 24 44 22 23 -12 -22 -36 -34 -34 -11 -13 7 10 5 17 -13 19 3 26 26 7 22 16 17 11 -14 -11 -3 -32 -49 -42 -49 -35 -25 -10 -5 0 2 23 2 21 29 15 -1 25 23 14 16 -22 -5 -12 10 13 13 1 -6 -5 -9 -12 0 2 12 7 25 4 6 0 3 -11 2 -11 9 9 7 -6 3 18 -12 -26 -19 -31 22 -8 27 -11 -11 -4 -6 -61 -14 4 23 32 7 22 -3 2 -28 30 15 7 5 -8 -31 -36 -8 -9 -7 -28 -17 -9 26 11 -1 21 -3 58 0 4 0 48 21 21 -16 -9 -10 -25 8 -1 29 31 13 -23 8 12 -34 11 -38 -42 -16 35 5 11 12 39 38 23 21 -8 42 41 40 22 11 -14 -53 -39 -60 -35 -3 22 -13 5 11 24 6 6 24 12 4 20 16 9 12 5 27 -12 -23 -14 -26 -6 -2 41 17 5 -68 -64 -64 -28 -33 -46 -27 -88 -87 -72 -45 -65 5 -14 3 -10 -30 -13 -18 4 -16 7 13 23 11 -23 -28 -30 3 -34 -25 -17 10 -1 16 2 16 -2 -17 29 12 -3 -4 48 41 37 25 6 12 -12 8 -6 25 13 39 33 50 51 33 32 22 27 3 13 -17 11 -9 -15 -26 -22 1 -39 -30 -10 50 7 13 -2 -1 -1 -8 6 2 -7 -17 -1 -3 -7 -16 -19 -26 -6 19 -11 -11 5 44 -6 -1 16 39 41 -6 -4 -11 -14 -16 -16 -45 -8 -18 5 10 -15 -7 9 19 4 22 24 19 26 38 33 5 10 -15 21 27 46 -5 8 16 46 46 68 85 55 54 19 26 51 73 34 22 -9 10 -12 -35 -20 5 34 30 25 -3 -28 -53 -39 -20 -53 3 -19 16 14 7 -18 1 -5 13 -9 -25 6 -5 14 -22 -20 -21 -11 -2 -9 -14 -26 -22 -51 -27 -23 -25 -30 3 -20 -48 -11 -31 -21 -22 1 16 28 -14 12 18 4 10 -48 -2 -22 -51 -16 7 -38 -1 -18 -31 -11 -30 17 -4 12 6 -15 -14 17 18 2 -1 3 -5 -3 29 -15 -9 1 -1 5 -9 13 -12 -6 -7 -5 -26 7 0 0 21 -13 29 -9 -15 -14 9 -5 33 48 12 38 17 5 -3 9 21 37 17 23 40 -9 16 -19 21 -7 -9 -22 -5 -21 -22 -19 -22 -21 -38 11 -18 8 -26 -35 -4 -34 -4 -16 3 3 15 2 17 6 3 -33 -23 -3 -21 6 -7 15 -9 8 -6 -6 -12 0 -15 -13 31 33 39 37 43 29 21 10 2 10 2 23 -1 -24 -55 -55 -68 -38 -44 -35 15 14 21 11 43 10 -8 0 -17 -18 15 -2 22 21 4 18 16 17 -1 -8 4 -6 11 2 9 13 48 1 37 24 8 -1 29 53 27 28 -15 -28 -46 -44 -44 -14 -17 8 12 6 21 -16 25 4 33 34 9 28 20 22 15 -18 -15 -4 -40 -62 -53 -61 -44 -31 -13 -6 -1 2 28 2 26 36 19 -2 31 29 18 21 -29 -7 -16 13 16 17 1 -8 -7 -11 -15 0 2 15 9 32 5 8 0 4 -14 3 -14 12 11 8 -8 4 23 -16 -34 -27 -42
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SQ 20250419T220414.4Z 9240.919611 577 2 5.96 2 68.93 265.84 162.40 333.62 0.00 1 0.00 1 0 33 2.721e-04 2.379e-04 1.349e-04 1.251e-04 9.288761e+01 2.392840e+01 7.036970e+00 4.254950e+02 5.409653e+01 278.19 -2.00 20.00 -2.00 447.58 0.00e+00 8.295692e-05 1.437527e-05 2.049082e-06 2.464011e-05 2.948622e-05 278.19 -2.00 20.00 -2.00 456.66 0.00e+00 3.052186e-04 1.116385e-06 2.101967e-06 2.013269e-05 2.461796e-06 225.65 -2.00 2.20 -2.00 439.54 0.00e+00 4.347057e+05 1.705510e+04 3.299186e+03 2.643037e+05 3.906649e+04 260.36 -2.00 11.30 -2.00 458.77 0.00e+00 3.719950e-01 3.261549e-03 1.581780e-03 1.244597e-02 8.497003e-03 228.58 -2.00 3.57 -2.00 455.95 0.00e+00 1.619249e-06 4.127541e-07 1.592650e-07 1.322957e-06 1.039107e-06 278.19 -2.00 20.00 -2.00 456.85 0.00e+00 2.756 0.000 397.00 473.00 4 4.2931e-01 1.3833e-04 6.9157e-03 5.1451e-04 2.7676e-04 -9.2472e-03 1.6973e-04 1.4441e-03 3.6124e-04 3.4847e-04 1.2994e-03 9.4110e-05 1.8978e-04 2.2720e-04 1.9282e-04 1.6330e-04 3.1980e-05 2.1484e-05 5.4955e-05 6.5840e-05 -3.4128e-05 1.6628e-05 5.8917e-06 2.4658e-05 3.2971e-05 6.6520e-01 -5.0858e-03 9.1521e-05 9.5714e-06 1.6326e-04 1.6176e-04 -1.5365e-05 1.3431e-06 1.7281e-07 8.8632e-07 2.8441e-06 1.1264e-05 1.8706e-06 9.9067e-08 8.2745e-07 3.8600e-06 -1.7980e-03 -1.6785e-05 2.3173e-02 1.3606e-02 6.4695e-04 1.4095e-02 2.5873e-02 10 0 0 10 0 0 -4.28 18.28 0.86 -0.00180 -0.00309 2124 417 1 4 0 2.770 23.64 15.00 18.28 17.86 32.1 989.86 23 -8 2 -36 -40 5 -61 -75 -52 1 2 36 41 8 32 18 0 42 51 55 50 36 2 18 37 48 -17 0 -37 -17 0 -15 -23 -38 -13 61 5 -42 2 32 49 5 -5 -19 -17 -47 -51 -18 -48 -15 -44 -91 -43 -25 -33 8 -53 -72 -9 21 19 -6 -2 6 40 -5 -23 -11 8 32 54 62 31 -1 -1 1 -11 4 75 59 25 16 5 -21 -32 -16 49 39 35 36 -19 15 -17 -9 35 3 7 -7 -9 -6 18 23 29 13 -35 -63 -69 -39 -23 -48 -57 -42 -59 -17 -27 9 27 25 57 40 40 43 12 -3 -6 -23 -10 16 8 7 9 18 12 5 -8 14 30 43 2 0 -7 14 16 14 2 -24 -25 19 45 44 66 43 6 -28 -19 9 13 36 50 70 51 57 12 -12 -26 -21 -1 -9 -9 -13 -37 -57 -53 -50 -45 -63 -45 -12 36 13 8 13 28 26 -4 -11 -11 -54 -49 -30 -31 -18 -40 -50 -12 11 33 23 7 12 14 -31 -35 -20 3 -11 -17 -30 -31 -25 -54 -63 -49 -67 -32 -29 -27 -64 -87 -47 -72 -24 -9 22 22 26 16 8 18 -19 29 37 49 49 53 45 67 82 57 68 15 31 24 37 20 49 40 20 11 4 28 2 22 15 56 55 42 34 31 -20 -45 -30 -31 1 18 15 17 13 -16 -4 11 5 -9 -19 -31 -9 13 20 -5 -20 -12 -17 -4 -16 -39 -21 -23 9 15 43 35 31 30 6 -20 -16 -43 -63 -21 -23 35 38 9 30 27 1 -23 -36 7 19 9 22 8 -20 2 7 5 2 -42 -28 -23 -31 -35 -35 -36 -1 -29 -7 -25 6 2 5 12 4 15 20 9 29 12 3 27 9 28 18 0 9 23 23 24 -9 16 23 21 17 3 2 7 8 -28 6 -10 -16 4 2 1 0 -19 9 12 -1 -19 -22 -19 10 -21 14 18 12 21 21 -5 -11 -9 0 12 12 -5 -12 -8 2 -5 2 -18 14 -5 6 4 11 -3 9 4 12 9 -5 -12 2 -13 -5 6 -5 15 3 -11 -19 -24 -4 -5 18 1 11 29 13 15 -6 -13 -19 -14 -31 -11 -22 -8 11 0 19 3 5 -4 -26 -11 3 -16 -9 -28 -15 -16 -20 -16 -26 -2 -11 -7 5 -4 -11 -8 -5 -2 19 8 -8 17 2 5 18 5 -5 5 6 5 -19 -23 -14 -10 -19 -18 -4 -10 8 -7 -1 7 11 9 -4 16 6 2 12 7 9 16 13 9 11 5 8 2 17 22 1 -4 19 -22 -14 -10 19 14 19 17 -5 21 13 7 23 15 -4 -1 9 -5 -13 -37 -25 -25 -17 -19 -3 1 10 6 18 9 9 16 -2 23 8 -1 -4 1 -24 -27 0 5 -8 -18 -8 -2 16 -5 1 -24 -26 3 -41 -53 -37 1 1 26 30 6 23 13 0 31 38 41 37 27 1 12 24 32 -11 0 -28 -13 0 -11 -16 -25 -9 39 4 -32 2 24 36 4 -4 -13 -12 -34 -36 -13 -35 -11 -33 -66 -32 -18 -24 6 -42 -57 -7 17 15 -4 -1 5 31 -4 -19 -10 7 27 45 50 24 -1 -1 1 -8 3 53 45 21 12 4 -17 -26 -14 41 34 31 31 -16 12 -15 -8 30 3 6 -6 -7 -5 16 19 23 11 -31 -57 -62 -33 -19 -39 -46 -35 -50 -15 -24 8 22 21 47 33 34 38 11 -3 -5 -21 -9 14 7 6 8 15 10 4 -7 12 25 37 2 0 -6 12 14 12 2 -21 -23 17 40 38 55 34 5 -23 -16 8 12 33 47 66 49 54 12 -11 -23 -19 -1 -8 -9 -13 -33 -46 -39 -37 -36 -54 -42 -11 33 12 7 11 24 23 -4 -11 -10 -50 -45 -27 -27 -16 -35 -44 -10 10 30 20 6 10 12 -29 -34 -19 3 -10 -15 -24 -24 -20 -45 -56 -45 -62 -30 -27 -24 -58 -78 -41 -61 -20 -8 19 19 23 14 6 14 -14 20 24 33 33 35 29 42 52 38 50 12 29 22 36 20 49 37 17 9 4 24 2 20 15 54 54 41 32 28 -17 -37 -24 -25 1 16 13 16 13 -15 -4 10 4 -8 -18 -30 -8 13 20 -5 -21 -13 -17 -4 -16 -39 -20 -22 8 14 41 34 30 29 5 -17 -12 -35 -53 -19 -22 33 36 8 29 27 1 -23 -36 7 19 8 20 8 -19 2 7 6 3 -45 -29 -24 -32 -37 -35 -37 -1 -29 -7 -25 6 2 5 12 4 15 20 9 29 12 3 27 9 28 18 0 10 24 24 24 -9 16 22 20 16 3 1 7 7 -28 6 -10 -16 4 2 1 0 -21 9 14 -1 -20 -23 -19 10 -22 15 20 13 22 22 -6 -12 -9 0 13 14 -6 -14 -9 3 -6 2 -21 17 -6 8 4 12 -3 10 4 14 10 -6 -13 2 -14 -5 6 -5 15 3 -11 -20 -25 -4 -6 21 1 12 33 14 17 -6 -15 -20 -15 -34 -13 -24 -9 13 0 22 4 5 -4 -30 -13 4 -19 -10 -34 -18 -19 -24 -20 -32 -2 -12 -9 6 -5 -14 -10 -6 -2 24 11 -10 21 3 6 23 7 -6 7 8 7 -24 -30 -18 -14 -25 -23 -5 -14 10 -9 -2 9 14 12 -5 22 8 3 16 9 12 21 17 12 15 7 10 3 22 29 2 -5 25 -28 -18 -12 24 18 25 22 -7 28 18 9 31 20 -5 -1 12 -6 -16 -45 -31 -31 -21 -25 -4 1 13 8 23 11 12 20 -3 31 10 -1 -6 1 -32 -36 0 6 -11 -24 -10 -3
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