File name: Pandora108s1_Toronto-West_20250430_L2Fit_fout2c6d20211104p1-8.txt
File generation date: 20250501T052451.5Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c6p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 108
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora108_OF_v4d20210713.txt
Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt
Level 1 file used: Pandora108s1_Toronto-West_20250430_L1_smca1c6d20211104p1-8.txt
Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke)
Short location name: Toronto-West
Country of location: Canada
Location latitude [deg]: 43.7094
Location longitude [deg]: -79.5435
Location altitude [m]: 141
Local noon date: 20250430
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 231 373
Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250430T124208.7Z 9251.529267 114 1 30.34 2 64.13 93.84 83.36 58.12 0.00 1 0.00 1 0 17 3.420e-02 6.766e-03 3.615e-02 5.050e-03 3.309924e-01 2.601083e-03 3.976222e-03 -6.000000e+00 2.001704e-02 229.54 -2.00 3.57 -2.00 318.86 0.00e+00 9.602537e-04 5.646177e-04 2.754496e-04 -6.000000e+00 8.650745e-04 279.40 -2.00 20.00 -2.00 318.19 0.00e+00 2.278 0.000 302.00 328.00 3 4.7068e+00 7.1382e-03 2.8591e-02 -6.0000e+00 4.9986e-02 5.9086e-02 8.1598e-03 1.7543e-02 -6.0000e+00 5.4132e-02 4.1728e-03 5.6503e-03 8.7148e-03 -6.0000e+00 3.2146e-02 -1.1533e-02 2.9368e-03 2.6125e-03 -6.0000e+00 1.3563e-02 3.2297e-04 8.8385e-05 1.5456e-04 2.9467e-05 -6.0000e+00 9.6451e-04 2.3216e-03 8.0824e-05 12 9 1 12 9 1 99.61 17.98 0.22 0.00232 0.00299 12 4 1 5 0 2333.100 23.32 15.01 17.98 8.26 31.0 970.27 -18023 -2613 -13693 13899 -15322 2370 -7758 -2584 -1564 -5890 -2014 -10342 387 -7448 2623 -4718 2561 -944 1548 -3231 585 5025 -491 4306 -4417 3044 -4823 -500 -5188 -1639 1720 2986 3292 -3482 -1007 -7190 261 -2429 1832 -1808 -86 1168 -533 707 398 1065 -1806 1560 -1685 746 437 1170 1113 1270 2254 716 1927 -2392 953 -811 2143 1730 1799 1584 152 609 -2011 533 196 1115 384 872 -236 -347 -255 -1617 1039 -2579 -906 -2294 -710 -2045 -1209 -1191 -490 31 -181 411 -5 553 -124 639 -868 395 372 218 1136 453 771 -646 109 -1026 -195 7 -615 -1265 -865 -215 155 809 -36 365 167 445 568 120 -40 26 11 -681 191 -197 693 -139 294 155 222 1079 282 185 -708 19 -534 274 -78 -252 -83 269 151 -391 110 -254 66 -837 -118 -715 540 -719 90 -339 -120 -81 -335 -113 -650 25 -600 224 -487 264 -107 179 -410 73 606 -63 563 -667 449 -775 -74 -765 -230 251 472 571 -675 -184 -1362 49 -543 469 -565 -29 418 -200 268 152 406 -703 581 -644 282 175 499 509 611 1125 371 1009 -1310 497 -427 1120 972 1093 1042 103 394 -1248 316 122 770 294 696 -192 -274 -189 -1107 635 -1548 -554 -1583 -543 -1752 -1104 -1145 -494 33 -205 479 -6 632 -134 634 -812 353 348 223 1280 564 1025 -871 140 -1233 -219 8 -742 -1629 -1154 -299 224 1244 -58 610 276 696 831 166 -56 37 16 -1080 309 -317 1078 -211 427 216 297 1431 396 279 -1138 32 -903 477 -144 -483 -163 537 306 -781 212 -473 120
SS 20250430T124720.6Z 9251.532877 117 1 5.39 2 63.19 94.77 82.59 58.91 0.00 1 0.00 1 0 17 2.309e-02 7.624e-03 4.174e-02 7.821e-03 3.173430e-01 4.013267e-03 3.836120e-03 -6.000000e+00 1.350663e-02 229.54 -2.00 3.57 -2.00 318.27 0.00e+00 1.481118e-03 7.409823e-04 2.284013e-04 -6.000000e+00 5.838305e-04 279.40 -2.00 20.00 -2.00 317.59 0.00e+00 2.205 0.000 302.00 328.00 3 4.3934e+00 1.0826e-02 2.7547e-02 -6.0000e+00 3.3728e-02 5.2238e-02 1.2251e-02 1.6783e-02 -6.0000e+00 3.6533e-02 1.5439e-04 7.9869e-03 8.3073e-03 -6.0000e+00 2.1694e-02 -7.9936e-03 4.1062e-03 2.5820e-03 -6.0000e+00 9.1474e-03 4.8525e-04 -5.4864e-04 2.3465e-04 2.8005e-05 -6.0000e+00 6.5129e-04 2.8915e-03 -5.4930e-05 12 9 1 12 1 1 999.00 18.01 0.24 0.00289 -0.00123 2 5 1 5 0 1795.510 23.43 15.01 18.01 8.46 31.1 971.75 -6216 -2269 -12294 -7153 -4299 -8529 6251 -5491 1554 -4092 -1879 -4574 1390 -1856 1763 -4449 -5693 838 2857 1781 -779 3039 -530 -1406 1503 1713 -4244 -4618 -1454 -2329 -50 3493 908 1176 -4782 1664 -69 1143 1347 -183 -2975 -1077 15 -1120 -615 -485 -1599 -383 140 751 1153 -764 865 1077 3331 2140 1558 1363 -740 2144 170 2245 1278 2105 -149 727 -1055 373 425 390 256 -335 515 -1396 670 -604 -982 -1144 11 -613 -84 -1477 -2498 -1730 -835 563 -290 849 88 851 -647 -172 -427 961 558 -576 341 169 493 -12 -684 -705 -1323 527 -899 -716 -1597 -284 -112 1022 202 171 485 537 306 -233 247 -2 -5 -535 210 -78 890 641 553 -120 411 1280 -23 227 -192 -184 -50 -156 -492 90 570 217 55 -863 629 -447 -696 -360 -142 -878 -470 -251 -493 329 -358 106 -310 -142 -366 119 -190 202 -607 -840 123 428 282 -129 489 -89 -252 276 328 -868 -909 -265 -423 -10 699 204 275 -1142 365 -16 308 428 -69 -1253 -473 7 -517 -283 -225 -743 -174 63 338 544 -390 464 604 1907 1260 941 827 -450 1264 104 1437 885 1549 -113 527 -731 250 297 300 215 -295 453 -1213 544 -455 -687 -763 7 -461 -69 -1356 -2459 -1770 -889 629 -340 1017 107 1004 -732 -181 -423 912 553 -620 398 215 660 -16 -893 -863 -1546 612 -1111 -930 -2158 -396 -162 1543 320 278 774 820 443 -321 337 -3 -7 -826 330 -123 1356 953 794 -167 551 1702 -32 337 -298 -294 -80 -261 -857 161 1049 406 103 -1615 1137 -791 -1211
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