File name: Pandora108s1_Toronto-West_20250615_L2Fit_fout2c6d20211104p1-8.txt File generation date: 20250616T053450.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora108_OF_v4d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20250615_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20250615 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250615T113756.9Z 9297.484686 221 1 1.54 2 70.79 75.70 75.36 221.04 0.00 1 0.00 1 0 17 1.295e-01 9.580e-03 1.821e-01 1.103e-02 4.179542e-01 5.783422e-03 4.940850e-03 -6.000000e+00 7.676949e-02 232.91 -2.00 3.57 -2.00 319.50 0.00e+00 8.451664e-04 1.583153e-03 1.818818e-04 -6.000000e+00 3.344241e-03 284.33 -2.00 20.00 -2.00 318.78 0.00e+00 3.003 0.000 302.00 328.00 3 2.8697e+00 1.6498e-02 3.7385e-02 -6.0000e+00 1.9298e-01 2.3155e-02 1.9344e-02 2.2677e-02 -6.0000e+00 2.0828e-01 3.6701e-03 1.4902e-02 1.1085e-02 -6.0000e+00 1.2370e-01 -1.3359e-02 7.7534e-03 3.2083e-03 -6.0000e+00 5.2075e-02 9.2314e-04 -5.1250e-04 3.3201e-04 3.5672e-05 -6.0000e+00 3.6570e-03 -6.5474e-04 -2.8778e-05 12 9 9 12 1 1 999.00 18.01 0.29 -0.00065 -0.00451 2 19 1 5 0 511.080 23.32 15.00 18.01 22.95 31.8 1000.59 -7179 50589 -31974 48932 -61665 43860 -47636 55065 -43007 7300 -27304 5870 -3022 -7448 16911 -7819 20102 -18406 11350 -15676 5892 -5811 -1724 5898 1664 20406 -13392 7173 -10176 8637 -1647 10532 110 485 1347 -4976 8140 -6863 10237 -6311 4243 -4212 1232 -1584 -1084 1239 -4254 3840 -391 2298 -2349 3860 -917 3531 1134 -391 2289 -487 2623 -2156 2746 666 2825 -48 449 125 1503 1187 -1831 1406 -939 2570 -476 951 -447 235 -1477 -2868 -1259 60 -885 -3527 -704 -2444 822 -790 458 197 511 1029 -152 345 -1114 1055 -864 382 497 1056 216 352 -353 -1165 338 -39 -611 -1186 -346 -911 -608 994 455 1024 -459 661 -375 780 -987 -394 -980 47 183 76 391 -220 1189 393 -437 640 441 -12 419 -693 -15 751 -259 -569 125 793 228 -348 -418 -594 126 -137 644 -925 658 -2142 553 -1486 743 -1631 186 -995 166 -107 -327 700 -468 1010 -1430 706 -1329 419 -469 -137 468 147 1598 -1471 628 -1013 722 -166 1061 14 64 172 -661 1022 -1153 1755 -1497 1015 -1171 337 -459 -314 356 -1289 1080 -115 679 -774 1301 -348 1369 473 -170 1001 -220 1134 -964 1199 317 1437 -27 261 71 802 630 -1051 875 -655 1825 -351 670 -302 144 -851 -1608 -727 38 -642 -2896 -607 -2250 775 -804 482 215 558 1098 -155 329 -1013 922 -808 386 556 1288 283 465 -451 -1402 378 -44 -728 -1499 -450 -1247 -868 1497 726 1683 -757 1043 -567 1115 -1420 -577 -1517 75 300 123 617 -341 1758 567 -612 892 649 -20 699 -1210 -27 1370 -497 -1141 255 1636 477 -718 -841 -1155 239 SS 20250615T122026.5Z 9297.514195 242 1 35.31 2 63.25 82.43 80.54 229.43 0.00 1 0.00 1 0 17 2.139e-02 5.437e-03 9.577e-03 1.443e-03 3.111320e-01 7.509884e-04 3.723339e-03 -6.000000e+00 1.267903e-02 232.91 -2.00 3.57 -2.00 318.87 0.00e+00 7.123524e-04 1.626770e-04 1.953439e-04 -6.000000e+00 5.522725e-04 284.33 -2.00 20.00 -2.00 318.09 0.00e+00 2.209 0.000 302.00 328.00 3 2.3967e+00 2.0798e-03 2.7600e-02 -6.0000e+00 3.1872e-02 2.1356e-02 2.3758e-03 1.6760e-02 -6.0000e+00 3.4394e-02 1.5662e-03 1.5973e-03 8.1760e-03 -6.0000e+00 2.0427e-02 -8.4828e-03 8.2209e-04 2.3417e-03 -6.0000e+00 8.6027e-03 3.6631e-03 1.3872e-04 4.4591e-05 2.6527e-05 -6.0000e+00 6.0368e-04 -6.2672e-04 7.0880e-05 12 1 1 12 1 1 99.88 18.02 0.09 -0.00063 0.00042 212 59 1 5 0 165.760 23.43 15.00 18.02 25.38 31.8 1014.94 -362 -6566 1876 -10522 -2048 -13255 -235 -7481 -245 -4624 -5697 -1699 -3781 1621 -3236 1529 -3971 1944 -2413 734 -705 -638 1228 -905 1076 -2148 -390 -4322 -642 -1929 1700 831 1247 -916 -3969 -1099 -2442 579 -862 357 -1401 -287 -286 -270 339 -569 116 -1205 -85 -669 1517 523 1612 1099 1284 1211 640 1063 -11 1118 869 1992 1585 1900 293 -285 -57 -294 1193 479 694 39 298 -155 -120 -819 -827 -946 -909 -393 -1370 -959 -2104 -1321 -1204 -269 -227 245 304 388 440 -70 185 137 643 -53 613 800 256 -308 -399 -413 -578 415 -1088 -885 -926 -440 -98 523 353 281 267 -19 311 -68 368 -280 54 -213 -231 184 74 441 99 548 -62 1404 223 171 -158 -75 118 -50 152 -450 197 -1 199 -367 73 -294 -266 -16 -339 93 -568 -93 -638 -10 -397 -14 -285 -361 -107 -272 128 -310 157 -458 224 -303 94 -93 -85 163 -130 161 -347 -63 -691 -94 -281 254 137 224 -176 -760 -199 -478 127 -229 111 -488 -105 -108 -105 131 -223 45 -464 -32 -256 600 224 731 528 644 621 338 562 -6 577 459 1115 964 1242 197 -185 -35 -174 726 328 523 31 240 -122 -89 -555 -513 -555 -549 -263 -1040 -802 -1911 -1257 -1211 -287 -254 284 355 443 472 -70 171 122 593 -53 685 982 339 -410 -509 -489 -647 464 -1314 -1136 -1236 -614 -142 806 574 470 439 -29 454 -94 500 -393 80 -335 -376 296 116 671 144 767 -83 1860 313 258 -253 -124 198 -87 278 -868 389 -1 406 -740 142 -555 -492 SS 20250615T122522.6Z 9297.517622 245 1 7.15 2 62.37 83.23 81.19 230.36 0.00 1 0.00 1 0 17 2.212e-02 5.904e-03 1.303e-02 2.531e-03 3.007633e-01 1.313819e-03 3.621200e-03 -6.000000e+00 1.310748e-02 232.91 -2.00 3.57 -2.00 318.32 0.00e+00 7.705716e-04 2.456270e-04 2.120806e-04 -6.000000e+00 5.709771e-04 284.33 -2.00 20.00 -2.00 317.54 0.00e+00 2.145 0.000 302.00 328.00 3 2.7636e+00 3.5762e-03 2.6737e-02 -6.0000e+00 3.2949e-02 1.9296e-02 4.0464e-03 1.6174e-02 -6.0000e+00 3.5559e-02 7.4453e-05 2.5958e-03 7.8676e-03 -6.0000e+00 2.1119e-02 -6.4555e-03 1.3216e-03 2.2253e-03 -6.0000e+00 8.8920e-03 2.7464e-03 -1.1043e-04 7.6597e-05 2.4989e-05 -6.0000e+00 6.2426e-04 -3.2779e-05 3.0896e-05 12 1 1 12 1 1 97.47 18.03 0.24 -0.00003 -0.00086 25 36 1 5 0 274.900 23.43 15.00 18.03 25.60 31.9 1016.27 -6730 2395 -9441 434 -14347 -285 -6369 -2969 -2909 -5119 -2622 -6949 2692 -5649 2189 -3193 1378 -796 730 455 -812 1519 -494 1981 -2464 941 -2864 -869 -2907 -1700 1068 713 2478 -1767 -1021 -4198 989 -1519 883 391 -443 375 -911 -53 -560 836 -1364 424 -1133 670 949 587 1259 876 1697 437 1476 -54 956 292 1050 1831 1385 2143 -23 -160 -594 672 456 1206 -258 120 157 -196 33 -726 -89 -1830 -252 -1241 -836 -1366 -1711 -1428 -982 -355 -509 394 -109 560 -19 426 -293 558 533 -54 556 412 310 -418 -73 -725 -20 -405 -850 -1014 -857 -350 118 803 290 606 186 274 -17 166 417 -389 212 -447 -29 -30 374 279 424 182 68 1134 385 292 -300 -30 -355 219 -121 -26 41 147 214 -505 162 -676 -102 -410 150 -685 28 -961 -16 -393 -197 -216 -412 -209 -594 235 -614 255 -437 192 -119 112 73 -136 250 -84 347 -476 184 -587 -167 -543 -307 199 145 541 -419 -232 -958 229 -414 278 145 -181 162 -409 -24 -256 380 -627 189 -507 296 440 291 660 483 968 257 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