File name: Pandora108s1_Toronto-West_20250722_L2Fit_fnvh3c6d20211104p1-8.txt File generation date: 20250723T053709.4Z Data description: Level 2 spectral fitting results file Data file version: fnvh3c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora108_OF_v4d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20250722_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20250722 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1195 1635 Nominal wavelengths inside fitting window [nm]: 435.0518 435.1800 435.3081 435.4363 435.5644 435.6925 435.8206 435.9486 436.0767 436.2047 436.3327 436.4607 436.5887 436.7167 436.8447 436.9726 437.1006 437.2285 437.3564 437.4843 437.6121 437.7400 437.8678 437.9956 438.1234 438.2512 438.3790 438.5068 438.6345 438.7623 438.8900 439.0177 439.1454 439.2730 439.4007 439.5283 439.6560 439.7836 439.9112 440.0387 440.1663 440.2939 440.4214 440.5489 440.6764 440.8039 440.9314 441.0588 441.1863 441.3137 441.4411 441.5685 441.6959 441.8232 441.9506 442.0779 442.2052 442.3326 442.4598 442.5871 442.7144 442.8416 442.9688 443.0960 443.2232 443.3504 443.4776 443.6047 443.7319 443.8590 443.9861 444.1132 444.2403 444.3673 444.4944 444.6214 444.7484 444.8754 445.0024 445.1293 445.2563 445.3832 445.5101 445.6370 445.7639 445.8908 446.0176 446.1445 446.2713 446.3981 446.5249 446.6517 446.7785 446.9052 447.0319 447.1587 447.2854 447.4120 447.5387 447.6654 447.7920 447.9186 448.0452 448.1718 448.2984 448.4250 448.5515 448.6781 448.8046 448.9311 449.0576 449.1840 449.3105 449.4369 449.5633 449.6897 449.8161 449.9425 450.0689 450.1952 450.3215 450.4479 450.5742 450.7004 450.8267 450.9530 451.0792 451.2054 451.3316 451.4578 451.5840 451.7101 451.8363 451.9624 452.0885 452.2146 452.3407 452.4668 452.5928 452.7189 452.8449 452.9709 453.0969 453.2228 453.3488 453.4747 453.6007 453.7266 453.8525 453.9783 454.1042 454.2301 454.3559 454.4817 454.6075 454.7333 454.8591 454.9848 455.1105 455.2363 455.3620 455.4877 455.6133 455.7390 455.8646 455.9903 456.1159 456.2415 456.3671 456.4926 456.6182 456.7437 456.8692 456.9947 457.1202 457.2457 457.3712 457.4966 457.6220 457.7474 457.8728 457.9982 458.1236 458.2489 458.3742 458.4996 458.6249 458.7501 458.8754 459.0007 459.1259 459.2511 459.3763 459.5015 459.6267 459.7518 459.8770 460.0021 460.1272 460.2523 460.3774 460.5025 460.6275 460.7525 460.8776 461.0026 461.1275 461.2525 461.3775 461.5024 461.6273 461.7522 461.8771 462.0020 462.1269 462.2517 462.3765 462.5013 462.6261 462.7509 462.8757 463.0004 463.1252 463.2499 463.3746 463.4993 463.6239 463.7486 463.8732 463.9979 464.1225 464.2471 464.3716 464.4962 464.6207 464.7453 464.8698 464.9943 465.1187 465.2432 465.3677 465.4921 465.6165 465.7409 465.8653 465.9897 466.1140 466.2384 466.3627 466.4870 466.6113 466.7356 466.8598 466.9841 467.1083 467.2325 467.3567 467.4809 467.6050 467.7292 467.8533 467.9774 468.1015 468.2256 468.3497 468.4737 468.5978 468.7218 468.8458 468.9698 469.0937 469.2177 469.3416 469.4656 469.5895 469.7134 469.8372 469.9611 470.0850 470.2088 470.3326 470.4564 470.5802 470.7039 470.8277 470.9514 471.0751 471.1988 471.3225 471.4462 471.5698 471.6935 471.8171 471.9407 472.0643 472.1879 472.3114 472.4350 472.5585 472.6820 472.8055 472.9290 473.0524 473.1759 473.2993 473.4227 473.5461 473.6695 473.7929 473.9162 474.0396 474.1629 474.2862 474.4095 474.5327 474.6560 474.7792 474.9024 475.0257 475.1488 475.2720 475.3952 475.5183 475.6414 475.7645 475.8876 476.0107 476.1338 476.2568 476.3798 476.5029 476.6259 476.7488 476.8718 476.9947 477.1177 477.2406 477.3635 477.4864 477.6092 477.7321 477.8549 477.9777 478.1005 478.2233 478.3461 478.4689 478.5916 478.7143 478.8370 478.9597 479.0824 479.2050 479.3277 479.4503 479.5729 479.6955 479.8181 479.9406 480.0632 480.1857 480.3082 480.4307 480.5532 480.6757 480.7981 480.9205 481.0430 481.1653 481.2877 481.4101 481.5324 481.6548 481.7771 481.8994 482.0217 482.1439 482.2662 482.3884 482.5106 482.6329 482.7550 482.8772 482.9994 483.1215 483.2436 483.3657 483.4878 483.6099 483.7319 483.8540 483.9760 484.0980 484.2200 484.3420 484.4639 484.5859 484.7078 484.8297 484.9516 485.0735 485.1953 485.3172 485.4390 485.5608 485.6826 485.8044 485.9261 486.0479 486.1696 486.2913 486.4130 486.5347 486.6564 486.7780 486.8996 487.0213 487.1429 487.2644 487.3860 487.5075 487.6291 487.7506 487.8721 487.9936 488.1150 488.2365 488.3579 488.4793 488.6007 488.7221 488.8435 488.9648 489.0862 489.2075 489.3288 489.4501 489.5713 489.6926 489.8138 489.9350 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 45: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Oxygen dimer effective temperature [K] Column 50: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 56: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Ozone effective temperature [K] Column 61: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Fitted Ring spectrum, -9e99=no fitting done or fitting not successful Column 67: Independent uncertainty of fitted Ring spectrum, -9=fitting not successful Column 68: Structured uncertainty of fitted Ring spectrum, -9=fitting not successful Column 69: Common uncertainty of fitted Ring spectrum, -9=fitting not successful Column 70: rms-based uncertainty of fitted Ring spectrum, -9=fitting not successful Column 71: Effective Ring fitting wavelength [nm], -9=fitting not done or not successful Column 72: Diffuse correction applied before fitting at effective Ring fitting wavelength [%], 0=no diffuse correction applied, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 73: Lower limit used for wavelength scaling [nm] Column 74: Upper limit used for wavelength scaling [nm] Column 75: Order of smoothing polynomial Column 76: Smoothing polynomial coefficient, order 0 Column 77: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 78: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 79: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 80: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 81: Smoothing polynomial coefficient, order 1 Column 82: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 83: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 84: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 85: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 86: Smoothing polynomial coefficient, order 2 Column 87: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 88: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 89: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 90: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 91: Smoothing polynomial coefficient, order 3 Column 92: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 93: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 94: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 95: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 96: Smoothing polynomial coefficient, order 4 Column 97: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 98: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 99: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 100: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 101: Mean value of measured data inside fitting window [same units as measurements] Column 102: Offset polynomial coefficient, order 0 Column 103: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 104: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 105: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 106: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 107: Offset polynomial coefficient, order 1 Column 108: Independent uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful Column 109: Structured uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful Column 110: Common uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful Column 111: rms-based uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful Column 112: Wavelength change polynomial coefficient, order 0 Column 113: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 114: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 115: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 116: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 117: Wavelength change polynomial coefficient, order 1 Column 118: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 119: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 120: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 121: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 122: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 123: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 124: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 125: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 126: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 127: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 128: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 129: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 130: Atmospheric variability [%], 999=no atmospheric variability was determined Column 131: Wavelength effective temperature [°C], 999=no effective temperature given Column 132: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 133: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 134: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 135: Number of bright count cycles Column 136: Number of dark count cycles Column 137: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 138: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 139: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 140: Integration time [ms] Column 141: Temperature at electronics board [°C], 999=no temperature signal Column 142: Spectrometer control temperature [°C], 999=no temperature signal Column 143: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 144: Temperature in head sensor [°C], 999=no temperature signal Column 145: Humidity in head sensor [%], -9=no humidity signal Column 146: Pressure in head sensor [hPa], -9=no pressure signal Columns 147-587: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 588-1028: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- EK 20250722T102151.3Z 9334.431843 139 1 12.94 6 86.88 64.81 59.29 79.22 0.00 0 59.60 0 0 91 2.414e-03 2.371e-03 1.827e-03 1.801e-03 -1.283058e+04 3.204701e+02 1.056657e+03 -6.000000e+00 4.070084e+02 287.24 -2.00 20.00 -2.00 461.87 0.00e+00 -2.505936e-03 2.231042e-05 1.943003e-04 -6.000000e+00 2.957728e-05 287.24 -2.00 20.00 -2.00 461.69 0.00e+00 -3.767013e+06 2.649845e+04 3.945695e+04 -6.000000e+00 3.760860e+04 287.24 -2.00 20.00 -2.00 474.78 0.00e+00 1.286597e-01 3.075749e-02 2.977260e-02 -6.000000e+00 4.323933e-02 287.24 -2.00 20.00 -2.00 472.33 0.00e+00 -1.5896e+01 1.2101e+01 1.3187e+01 -6.0000e+00 1.5295e+01 462.24 0.00e+00 432.10 492.96 4 1.6569e-01 2.2168e-03 5.0618e-03 -6.0000e+00 2.6713e-03 1.8174e-01 1.8701e-03 2.7914e-03 -6.0000e+00 2.2371e-03 -1.2235e-03 7.2779e-04 8.6593e-04 -6.0000e+00 1.0111e-03 9.1427e-04 2.5951e-04 5.9506e-04 -6.0000e+00 3.4355e-04 -3.1400e-04 2.9659e-04 4.0622e-04 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