File name: Pandora108s1_Toronto-West_20250803_L2Fit_fout2c6d20211104p1-8.txt
File generation date: 20250804T053626.5Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c6p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 108
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora108_OF_v4d20210713.txt
Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt
Level 1 file used: Pandora108s1_Toronto-West_20250803_L1_smca1c6d20211104p1-8.txt
Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke)
Short location name: Toronto-West
Country of location: Canada
Location latitude [deg]: 43.7094
Location longitude [deg]: -79.5435
Location altitude [m]: 141
Local noon date: 20250803
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 231 373
Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250803T124310.5Z 9346.529983 103 1 50.83 2 63.99 90.43 162.07 9.68 0.00 1 0.00 1 0 17 3.651e-02 7.349e-03 5.881e-02 7.447e-03 3.205723e-01 3.896236e-03 3.842776e-03 -6.000000e+00 2.162078e-02 232.38 -2.00 3.57 -2.00 319.14 0.00e+00 7.350592e-04 9.223899e-04 3.402371e-04 -6.000000e+00 9.591666e-04 287.48 -2.00 20.00 -2.00 318.32 0.00e+00 2.266 0.000 302.00 328.00 3 5.3712e+00 1.0925e-02 2.8373e-02 -6.0000e+00 5.4213e-02 1.3440e-02 1.2589e-02 1.7288e-02 -6.0000e+00 5.8480e-02 4.0719e-03 8.6986e-03 8.4407e-03 -6.0000e+00 3.4827e-02 -1.0477e-02 4.5142e-03 2.3757e-03 -6.0000e+00 1.4746e-02 1.7462e-04 -2.7823e-05 2.3187e-04 2.7818e-05 -6.0000e+00 1.0337e-03 -5.9506e-03 3.9061e-05 11 8 0 10 0 0 87.10 18.01 0.47 -0.00595 -0.00616 17 3 1 5 0 2989.620 23.32 15.00 18.01 26.94 31.7 1008.70 6548 13045 -12260 -430 -20219 4248 -16128 9107 -11981 2715 -7615 5791 3402 900000 5401 339 5263 -6638 -141 -6421 660 -4002 -2990 4893 447 2032 -1281 1621 -2768 445 -4244 3866 408 -309 -858 -7218 803 -1222 2936 -1080 132 -1714 44 752 620 608 545 338 -3290 1032 -1376 1130 327 1670 599 1183 2400 -4106 1084 835 1689 291 2537 2714 -598 -316 -319 -158 513 981 366 829 -353 -92 -626 -1160 -480 -1724 529 -1144 313 -930 -1459 -1871 -1242 -626 -279 839 980 1681 0 198 -864 637 -164 -131 1520 700 415 -1113 -3 -264 -128 -396 -1264 -1619 -1000 -416 -425 1128 522 775 9 54 320 341 76 -508 -242 -505 31 213 1072 7 319 -498 235 206 53 522 -669 24 -373 694 -133 -101 -201 487 -61 -420 181 -303 37 222 468 -585 -18 -926 147 -706 349 -632 132 -419 288 195 900000 409 30 481 -721 -15 -764 75 -482 -362 581 59 277 -183 216 -366 56 -595 547 66 -53 -143 -1243 136 -244 673 -305 41 -579 15 263 217 215 191 117 -1173 356 -513 441 138 736 280 562 1157 -2122 524 402 822 154 1422 1646 -382 -193 -182 -87 295 629 262 623 -272 -69 -444 -749 -281 -963 297 -728 222 -744 -1265 -1723 -1204 -649 -303 943 1106 1847 0 191 -779 543 -147 -129 1641 842 540 -1479 -3 -308 -140 -436 -1498 -2058 -1317 -574 -615 1720 849 1297 15 85 468 468 104 -713 -360 -801 51 345 1681 11 467 -704 315 275 74 790 -1084 41 -639 1222 -250 -198 -409 1007 -129 -872 363 -586 70
SS 20250803T124925.3Z 9346.534320 106 1 50.37 2 62.86 91.52 161.86 13.96 0.00 1 0.00 1 0 17 3.207e-02 7.436e-03 3.373e-02 4.793e-03 3.085899e-01 2.497345e-03 3.722048e-03 -6.000000e+00 1.898469e-02 232.38 -2.00 3.57 -2.00 318.99 0.00e+00 1.850035e-03 5.652023e-04 1.646214e-04 -6.000000e+00 8.393608e-04 287.48 -2.00 20.00 -2.00 318.16 0.00e+00 2.180 0.000 302.00 328.00 3 4.7959e+00 6.9514e-03 2.7313e-02 -6.0000e+00 4.7608e-02 1.4557e-02 7.9793e-03 1.6706e-02 -6.0000e+00 5.1358e-02 -3.2429e-04 5.3779e-03 8.2025e-03 -6.0000e+00 3.0576e-02 -7.3553e-03 2.7762e-03 2.7574e-03 -6.0000e+00 1.2939e-02 3.4219e-04 -4.2363e-04 1.4857e-04 3.0030e-05 -6.0000e+00 9.0514e-04 -4.8873e-03 2.1429e-05 11 8 0 10 0 0 93.52 18.01 0.42 -0.00489 -0.00807 30 6 1 5 0 1678.780 23.32 15.00 18.01 27.02 31.7 1008.75 -12358 7368 -17519 6578 -14723 10486 -3694 1016 139 -4912 2150 -7238 -462 -5663 4552 -1368 634 -533 -561 1566 -3416 3404 -3074 5951 -4393 386 -3178 -3259 -2197 -3996 3884 -1459 3804 -3781 -2257 -6135 3013 -1918 -271 129 -1335 -445 -2785 586 -943 75 -1420 -489 -865 1220 785 438 2371 -103 2296 251 1357 6272 9 -584 1072 2338 1816 2883 174 651 -755 1281 -502 1442 20 -117 -214 -875 24 -1638 300 -1539 221 -2083 -942 -1724 -2040 -1066 -1306 8 -527 883 -136 835 -35 523 70 163 571 -390 1083 651 572 -506 -193 -509 -484 -253 -1114 -914 -1165 -111 -319 877 96 744 36 21 160 63 -92 -653 405 -522 -46 -115 730 -160 535 209 112 1611 319 347 -675 325 -180 411 -108 -114 -43 111 450 -434 102 -733 -166 -577 321 -1011 293 -734 389 -163 47 7 -287 119 -452 -30 -454 385 -138 67 -60 -67 191 -448 421 -408 763 -657 58 -498 -492 -312 -567 544 -235 640 -720 -411 -1123 535 -412 -68 38 -444 -157 -1035 217 -355 28 -539 -181 -319 444 302 181 1031 -49 1103 126 687 3046 4 -296 547 1264 1069 1817 115 410 -448 726 -301 948 15 -91 -169 -676 17 -1097 180 -884 128 -1373 -694 -1419 -1816 -993 -1291 8 -585 1008 -158 942 -38 513 64 142 517 -389 1186 791 750 -674 -246 -602 -537 -282 -1332 -1166 -1551 -154 -463 1347 157 1247 60 34 234 87 -125 -918 599 -827 -74 -187 1150 -246 783 295 150 2126 447 524 -1088 539 -306 719 -200 -223 -86 227 932 -891 203 -1413 -311
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