File name: Pandora163s1_Tsukuba-NIES-West_20250504_L2Fit_fout2c12d20240101p1-8.txt File generation date: 20250504T144530.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Jinsoo Park Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 163 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora163_OF_v9d20190605.txt Instrument calibration file used: Pandora163s1_CF_v12d20240101.txt Level 1 file used: Pandora163s1_Tsukuba-NIES-West_20250504_L1_smca1c12d20240101p1-8.txt Full location name: National Institute for Environmental Studies (NIES), lidar building Short location name: Tsukuba-NIES-West Country of location: Japan Location latitude [deg]: 36.0506 Location longitude [deg]: 140.1202 Location altitude [m]: 30 Local noon date: 20250504 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 for fieldcal for VP from 20240101 First and last pixel inside fitting window: 225 366 Nominal wavelengths inside fitting window [nm]: 305.1227 305.2636 305.4045 305.5454 305.6863 305.8272 305.9680 306.1089 306.2497 306.3906 306.5314 306.6722 306.8130 306.9538 307.0946 307.2353 307.3761 307.5168 307.6575 307.7982 307.9390 308.0796 308.2203 308.3610 308.5017 308.6423 308.7829 308.9236 309.0642 309.2048 309.3454 309.4860 309.6265 309.7671 309.9076 310.0482 310.1887 310.3292 310.4697 310.6102 310.7506 310.8911 311.0316 311.1720 311.3124 311.4529 311.5933 311.7337 311.8740 312.0144 312.1548 312.2951 312.4355 312.5758 312.7161 312.8564 312.9967 313.1370 313.2772 313.4175 313.5577 313.6980 313.8382 313.9784 314.1186 314.2588 314.3990 314.5391 314.6793 314.8194 314.9596 315.0997 315.2398 315.3799 315.5200 315.6600 315.8001 315.9402 316.0802 316.2202 316.3602 316.5002 316.6402 316.7802 316.9202 317.0601 317.2001 317.3400 317.4799 317.6198 317.7597 317.8996 318.0395 318.1794 318.3192 318.4591 318.5989 318.7387 318.8785 319.0183 319.1581 319.2979 319.4376 319.5774 319.7171 319.8568 319.9965 320.1362 320.2759 320.4156 320.5553 320.6949 320.8346 320.9742 321.1138 321.2534 321.3930 321.5326 321.6722 321.8117 321.9513 322.0908 322.2304 322.3699 322.5094 322.6489 322.7883 322.9278 323.0673 323.2067 323.3461 323.4856 323.6250 323.7644 323.9038 324.0431 324.1825 324.3218 324.4612 324.6005 324.7398 324.8791 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250503T205817.0Z 9254.873808 106 1 50.90 2 76.36 80.04 121.42 8.61 0.00 1 0.00 1 0 17 2.375e-01 5.818e-03 2.327e-01 3.495e-03 6.274393e-01 1.890547e-03 6.854698e-03 -6.000000e+00 1.359450e-01 230.46 -2.00 3.41 -2.00 321.07 0.00e+00 3.378439e-03 8.765622e-04 8.778444e-04 -6.000000e+00 6.359361e-03 285.30 -2.00 20.00 -2.00 320.49 0.00e+00 4.140 0.001 302.00 328.00 3 2.4516e+00 6.3092e-03 5.3257e-02 -6.0000e+00 3.4003e-01 2.2632e-02 8.7728e-03 3.4694e-02 -6.0000e+00 3.6796e-01 -2.8060e-02 9.0296e-03 1.7710e-02 -6.0000e+00 2.1862e-01 -2.4891e-04 4.3434e-03 7.9633e-03 -6.0000e+00 9.4644e-02 3.5704e-04 -6.4781e-04 9.7112e-05 6.2922e-05 -6.0000e+00 6.3219e-03 1.2051e-02 0.0000e+00 10 0 0 10 0 0 93.52 21.57 0.39 0.01205 0.00718 87 16 1 5 0 584.900 25.39 20.01 21.57 24.01 13.2 1026.23 -138823 -69132 -65369 900000 -61853 43156 -88851 1393 -50389 900000 -88680 -60630 -76021 -61118 22725 -26137 10591 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-877 -1416 377 -154 1018 446 1128 118 154 236 694 5 506 1085 -184 104 -484 384 -118 -264 -608 -1473 -1176 -1217 -680 -32 -480 -919 -317 387 73 365 329 1368 -75 42 -950 194 414 432 451 -91 524 1154 1567 682 493 -488 -330 0 -665 -304 -297 552 87 129 -754 -533 237 SS 20250503T210853.9Z 9254.881179 109 1 1.61 2 74.24 81.51 121.09 11.33 0.00 1 0.00 1 0 17 3.321e-01 1.636e-02 2.928e-01 1.413e-02 5.548124e-01 7.368171e-03 6.267133e-03 -6.000000e+00 1.913586e-01 230.46 -2.00 3.41 -2.00 320.01 0.00e+00 2.697427e-03 2.439960e-03 8.363987e-04 -6.000000e+00 8.390828e-03 285.30 -2.00 20.00 -2.00 319.34 0.00e+00 3.617 0.001 302.00 328.00 3 2.8225e+00 2.1707e-02 4.6188e-02 -6.0000e+00 4.7905e-01 5.2368e-02 2.6483e-02 2.8571e-02 -6.0000e+00 5.1884e-01 -8.9257e-02 2.2820e-02 1.4680e-02 -6.0000e+00 3.0843e-01 3.9097e-02 1.1781e-02 4.9027e-03 -6.0000e+00 1.3224e-01 4.3489e-04 -9.0208e-04 3.7947e-04 5.0765e-05 -6.0000e+00 8.6526e-03 1.0836e-02 0.0000e+00 12 9 9 12 1 1 999.00 21.60 0.23 0.01084 0.00406 1 11 1 5 0 801.950 25.39 20.00 21.60 25.44 13.1 1038.08 -40400 -99074 -78696 -99451 -80661 -121506 -136315 24225 5466 -2131 -72347 -61195 82570 -19823 96163 -46295 900000 -28600 -17025 -15164 16789 -46161 -2063 -34964 -16265 22582 9517 205461 472 11081 -11358 -1058 2386 24041 -25365 -21772 18749 -10296 19810 -9450 -7577 -733 1539 -4749 7665 4153 4299 9455 -8749 16878 6101 8568 4361 9716 7113 -750 12075 -60 4332 -2958 4872 1574 1330 -3576 2155 2865 -4327 5730 -1881 -221 1259 2147 -2741 -127 -1077 132 3943 555 1303 -74 -1010 -1606 -350 -185 -226 294 -2614 505 -953 -52 2199 1171 -2538 -425 -341 -259 403 155 -946 -1581 -333 2200 -1136 -1783 -1464 -1774 -331 -145 -1445 16 -679 -710 -510 -554 503 367 2699 -209 2220 -787 685 1242 671 -290 2117 762 2393 848 -605 873 346 465 13 -529 -243 -23 623 -783 -968 -79 -906 64 -556 -2232 -1478 -2116 -1313 -3042 -4437 334 75 -29 -1893 -1685 1137 -573 1324 -2423 900000 -1497 -844 -773 624 -3242 -99 -2552 -1053 1026 485 2829 25 595 -907 -89 217 1755 -2864 -2458 1627 -1460 2537 -1704 -1461 -139 297 -987 1430 816 856 1835 -2114 3402 1528 2306 1327 2992 2342 -277 3976 -22 1470 -1085 1763 660 631 -1773 1002 1370 -2011 2769 -1029 -135 812 1395 -1805 -76 -586 70 1915 293 722 -49 -773 -1271 -292 -163 -213 294 -2607 495 -928 -51 1947 975 -2132 -373 -340 -275 487 196 -1255 -2024 -409 2372 -1223 -2060 -1815 -2310 -419 -196 -2183 24 -1132 -1200 -834 -850 764 545 4046 -320 3535 -1320 1105 1914 1006 -449 3075 1067 3249 1270 -972 1520 607 846 24 -1024 -500 -49 1335 -1719 -2090 -161 -1847 122 SS 20250503T211859.1Z 9254.888184 112 1 3.82 2 72.22 82.91 120.69 13.88 0.00 1 0.00 1 0 17 1.935e-01 1.008e-02 1.812e-01 7.727e-03 4.998360e-01 3.996604e-03 5.626791e-03 -6.000000e+00 1.107459e-01 230.46 -2.00 3.41 -2.00 319.72 0.00e+00 2.427148e-04 1.197560e-03 2.491162e-04 -6.000000e+00 4.882147e-03 285.31 -2.00 20.00 -2.00 319.02 0.00e+00 3.229 0.000 302.00 328.00 3 3.2662e+00 1.1516e-02 4.1331e-02 -6.0000e+00 2.7684e-01 6.8982e-03 1.3840e-02 2.5664e-02 -6.0000e+00 2.9945e-01 -1.5937e-02 1.1593e-02 1.2704e-02 -6.0000e+00 1.7812e-01 8.5247e-05 6.0561e-03 3.6569e-03 -6.0000e+00 7.6782e-02 4.3699e-04 -4.7306e-04 2.1061e-04 3.5823e-05 -6.0000e+00 5.0370e-03 1.2403e-02 0.0000e+00 12 9 9 12 9 1 76.25 21.61 0.27 0.01240 0.00885 3 10 1 5 0 952.610 25.39 19.99 21.61 26.05 13.0 1042.59 -102191 115443 -26623 -1435 67410 -33963 -67868 -55652 -12914 -16503 8879 -40857 12335 -39564 74130 -26642 -3338 -1735 -17752 -1196 -5798 19225 -15037 17936 -259 -4866 -4006 -20766 5283 3954 9095 -6752 12767 -2725 4795 -3996 -3780 1034 2384 3130 -2442 6589 -4458 -3443 -1419 -4339 2528 -6154 2031 7355 4883 -282 4796 -579 2995 -4003 1772 4905 2065 2039 630 1984 3275 1010 -769 -1119 -2017 2115 2923 874 8 1247 15 -1206 -1521 -511 -546 -1384 1056 85 -3041 -881 -1052 -1692 -2140 -1458 275 544 462 -918 1906 999 990 -190 21 -480 1232 1638 -628 454 -776 587 -476 381 -1364 -1049 -1126 -850 -170 24 217 -264 526 -505 295 459 -41 446 -313 -744 303 401 601 1232 232 179 892 1054 695 -212 -529 -327 173 -665 205 -53 16 399 43 -245 -255 -483 -3080 870 -421 -16 508 -512 -1636 -1384 -234 -323 140 -1231 270 -1789 1285 -1425 -153 -85 -1083 -65 -332 869 -1031 973 -18 -370 -296 -1721 334 277 706 -707 1222 -302 466 -443 -484 155 431 649 -582 1509 -1069 -823 -336 -1070 644 -1581 545 2006 1378 -92 1606 -218 1135 -1689 716 1885 795 789 263 912 1662 563 -429 -590 -1053 1114 1748 554 5 856 10 -767 -955 -286 -290 -772 659 57 -2413 -758 -963 -1525 -2081 -1497 290 578 482 -913 1842 902 865 -178 21 -536 1536 2098 -851 581 -984 664 -531 451 -1640 -1316 -1490 -1195 -260 37 361 -444 844 -765 444 674 -62 669 -504 -1235 488 621 900 1880 343 251 1224 1563 1079 -362 -963 -576 317 -1307 425 -107 34 827 88 -508 -500 -905 SS 20250503T214500.6Z 9254.906257 128 1 50.77 2 66.98 86.56 119.28 20.31 0.00 1 0.00 1 0 17 3.142e-02 4.786e-03 7.740e-03 7.381e-04 3.947769e-01 3.801290e-04 4.569815e-03 -6.000000e+00 1.798138e-02 230.47 -2.00 3.41 -2.00 319.25 0.00e+00 5.780229e-04 9.548789e-05 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