File name: Pandora176s1_Tsukuba-NIES_20240811_L2Fit_fout2c4d20240516p1-8.txt File generation date: 20250127T232832.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Tamaki Fujinawa Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 176 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora176_OF_v3d20200605.txt Instrument calibration file used: Pandora176s1_CF_v4d20240516.txt Level 1 file used: Pandora176s1_Tsukuba-NIES_20240811_L1_smca1c4d20240516p1-8.txt Full location name: National Institute for Environmental Studies (NIES) Short location name: Tsukuba-NIES Country of location: Japan Location latitude [deg]: 36.0513 Location longitude [deg]: 140.1210 Location altitude [m]: 45 Local noon date: 20240811 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 3, but MLE correction for HCHO. First and last pixel inside fitting window: 256 398 Nominal wavelengths inside fitting window [nm]: 305.0215 305.1624 305.3032 305.4440 305.5848 305.7256 305.8664 306.0072 306.1480 306.2888 306.4295 306.5702 306.7110 306.8517 306.9924 307.1331 307.2737 307.4144 307.5551 307.6957 307.8363 307.9770 308.1176 308.2582 308.3987 308.5393 308.6799 308.8204 308.9610 309.1015 309.2420 309.3825 309.5230 309.6635 309.8039 309.9444 310.0848 310.2253 310.3657 310.5061 310.6465 310.7869 310.9272 311.0676 311.2079 311.3483 311.4886 311.6289 311.7692 311.9095 312.0498 312.1901 312.3303 312.4706 312.6108 312.7510 312.8912 313.0314 313.1716 313.3118 313.4519 313.5921 313.7322 313.8723 314.0124 314.1526 314.2926 314.4327 314.5728 314.7128 314.8529 314.9929 315.1329 315.2729 315.4129 315.5529 315.6929 315.8329 315.9728 316.1127 316.2527 316.3926 316.5325 316.6724 316.8122 316.9521 317.0920 317.2318 317.3716 317.5115 317.6513 317.7911 317.9308 318.0706 318.2104 318.3501 318.4899 318.6296 318.7693 318.9090 319.0487 319.1884 319.3280 319.4677 319.6073 319.7469 319.8866 320.0262 320.1658 320.3053 320.4449 320.5845 320.7240 320.8635 321.0031 321.1426 321.2821 321.4216 321.5610 321.7005 321.8400 321.9794 322.1188 322.2582 322.3976 322.5370 322.6764 322.8158 322.9551 323.0945 323.2338 323.3731 323.5124 323.6517 323.7910 323.9303 324.0696 324.2088 324.3481 324.4873 324.6265 324.7657 324.9049 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240810T203655.8Z 8988.858980 52 1 48.66 2 82.66 76.49 149.48 47.39 0.00 1 0.00 1 0 17 4.510e-01 2.291e-02 3.473e-01 1.573e-02 8.078201e-01 9.420463e-03 9.143825e-03 -6.000000e+00 2.730737e-01 231.58 -2.00 3.41 -2.00 322.06 0.00e+00 4.625758e-03 5.734052e-03 5.652930e-03 -6.000000e+00 1.372604e-02 292.45 -2.00 20.00 -2.00 321.51 0.00e+00 7.223 0.006 302.00 328.00 3 1.6949e+00 3.9659e-02 8.7926e-02 -6.0000e+00 6.8725e-01 8.2110e-01 5.3967e-02 5.5374e-02 -6.0000e+00 7.4878e-01 -1.0085e+00 4.4484e-02 2.6814e-02 -6.0000e+00 4.4105e-01 3.9842e-01 2.0394e-02 7.0526e-03 -6.0000e+00 1.8534e-01 3.0961e-05 -6.9300e-04 4.6558e-04 1.4641e-04 -6.0000e+00 1.3023e-02 1.4273e-02 0.0000e+00 12 8 8 10 0 0 13.01 19.87 0.35 0.01427 0.00907 45 11 1 5 0 1081.100 26.41 20.00 19.87 33.70 16.8 985.96 42103 900000 -88220 900000 -151144 900000 -113320 900000 4448 -109351 -165162 900000 28508 -115863 900000 -100964 900000 49966 900000 -58720 81887 -84597 79345 -45359 900000 -15969 53401 900000 -61841 900000 -45074 900000 -19334 900000 -11644 900000 27126 40053 -29440 57175 63688 16293 84523 -16400 211607 42165 66223 46587 83436 18658 73410 2593 33226 40580 44104 19734 25188 72474 -7775 26091 21 24980 -6866 40669 -794 12753 6075 28744 5753 6420 8515 6449 13693 6117 20274 -6074 30511 3127 14771 -3631 11458 -2862 1345 -3932 1678 1018 -2020 -162 -1401 545 -7622 312 -6575 1256 -6826 2916 -4245 -155 -2848 -1490 594 -1440 -3476 -2246 -1344 -5349 1320 -3279 1962 -922 873 -2494 -193 -136 113 251 -365 886 225 1122 -515 3182 -894 2911 225 2848 1008 2294 57 14 41 149 769 -854 627 -710 673 -100 835 -1050 388 -1103 -873 644 900000 -1631 900000 -4200 900000 -2006 900000 68 -2173 -5623 900000 436 -4113 900000 -4523 900000 765 900000 -2263 1253 -3938 1214 -1514 900000 -431 817 900000 -2338 900000 -1795 900000 -832 900000 -479 900000 768 1146 -1915 1932 2251 952 2700 -1361 3238 2033 2584 2247 2983 1300 3375 257 2697 3314 3680 2136 2642 4832 -1055 2489 3 2617 -1096 4706 -146 2066 1037 4092 1113 1409 2022 1637 3210 1451 3835 -1320 4367 587 2778 -967 3131 -1031 517 -1700 729 473 -1015 -83 -723 268 -3827 136 -2986 548 -3627 1655 -3026 -123 -2583 -1371 512 -1144 -2548 -1590 -1002 -4419 1082 -3018 1898 -1043 1098 -3525 -275 -192 153 328 -481 1209 327 1686 -784 4492 -1260 3849 296 3548 1241 2891 84 24 77 302 1650 -1983 1540 -1866 1792 -272 2255 -2796 958 -2580 -1948 SS 20240810T204735.5Z 8988.866384 55 1 48.49 2 80.56 77.99 147.94 51.17 0.00 1 0.00 1 0 17 4.425e-01 1.117e-02 3.008e-01 7.944e-03 6.733549e-01 4.421034e-03 7.898323e-03 -6.000000e+00 2.583610e-01 231.58 -2.00 3.41 -2.00 321.60 0.00e+00 6.949138e-03 2.424338e-03 4.698968e-03 -6.000000e+00 1.169839e-02 292.45 -2.00 20.00 -2.00 320.97 0.00e+00 5.799 0.003 302.00 328.00 3 2.2711e+00 1.6982e-02 7.0512e-02 -6.0000e+00 6.4567e-01 2.7772e-01 2.3505e-02 4.4016e-02 -6.0000e+00 6.9707e-01 -3.0211e-01 2.1571e-02 2.3166e-02 -6.0000e+00 4.1670e-01 1.1133e-01 1.0070e-02 6.9655e-03 -6.0000e+00 1.7769e-01 8.2871e-05 -1.8189e-05 2.3014e-04 1.3178e-04 -6.0000e+00 1.2131e-02 1.5056e-02 0.0000e+00 12 8 8 10 0 0 85.58 19.87 0.23 0.01506 0.01492 65 15 1 5 0 745.970 26.41 20.00 19.87 34.01 16.8 987.98 -197129 -132231 64834 -116266 -208832 -92841 -56998 -156101 -120448 -133257 -5998 -139434 60823 -133509 900000 -102468 -29044 -83403 36788 46373 -44622 -19786 16918 -20419 4868 -385 -40375 -18919 -38524 41394 -10859 35946 -1034 6964 17285 44904 10188 3844 20185 -5131 -3500 1707 21363 6300 26723 5435 2318 -7503 19494 9543 2328 -1844 4324 4217 8425 9592 6338 376 1669 8665 -3008 11729 142 10100 5470 7443 10397 1065 3990 2656 3519 3368 -99 -45 -1431 1342 6593 -4891 2235 -2860 -808 -2326 -3545 -643 1091 -1864 -1077 -679 153 523 -361 1104 -1193 653 -1427 -542 -405 1012 -243 -1560 -615 -602 -1537 -1106 -2471 -2178 -625 -182 -57 388 -204 246 261 810 -172 1189 915 143 -314 -379 -109 1212 490 585 -403 257 278 382 1054 199 344 -56 -7 77 -323 -393 80 127 52 -290 -320 -28 37 -3095 -1345 502 -1096 -4295 -719 -441 -2152 -1312 -1741 -46 -2227 471 -3238 900000 -2833 -464 -2430 382 464 -1066 -374 232 -420 84 -7 -1124 -426 -1035 570 -285 738 -35 234 517 1017 339 157 852 -323 -243 122 1342 470 1687 429 194 -712 1506 861 248 -228 553 584 1189 1391 972 61 262 1254 -500 1857 28 2077 1255 1668 2223 255 1016 783 1141 1152 -35 -15 -448 370 1608 -1337 632 -1002 -327 -1089 -1853 -349 619 -1161 -702 -456 103 340 -223 629 -667 366 -905 -394 -341 962 -257 -1706 -634 -564 -1329 -942 -2276 -2129 -635 -197 -66 508 -298 382 411 1240 -253 1664 1281 211 -492 -621 -179 1905 749 867 -583 357 373 528 1609 345 656 -114 -15 174 -783 -1005 210 339 139 -757 -794 -66 84 SS 20240810T205637.8Z 8988.872660 60 1 48.58 2 78.77 79.26 146.58 54.14 0.00 1 0.00 1 0 25 4.409e-01 6.997e-03 1.446e-01 3.448e-03 6.007637e-01 1.879288e-03 6.780078e-03 -6.000000e+00 2.573433e-01 231.58 -2.00 3.41 -2.00 321.21 0.00e+00 4.617727e-03 9.193077e-04 1.731820e-03 -6.000000e+00 1.165645e-02 292.45 -2.00 20.00 -2.00 320.52 0.00e+00 4.955 0.002 302.00 328.00 3 1.8865e+00 6.6786e-03 5.8493e-02 -6.0000e+00 6.4315e-01 1.2129e-01 9.0022e-03 3.2066e-02 -6.0000e+00 6.9419e-01 -1.0818e-01 8.2216e-03 1.7870e-02 -6.0000e+00 4.1482e-01 3.3079e-02 3.9380e-03 6.8911e-03 -6.0000e+00 1.7698e-01 2.9892e-04 -2.6788e-05 1.0092e-04 8.8841e-05 -6.0000e+00 1.2060e-02 1.4364e-02 0.0000e+00 11 8 0 10 0 0 -26.42 19.87 0.14 0.01436 0.01416 164 39 1 5 0 296.210 26.41 20.00 19.87 34.39 16.9 990.93 -164200 352860 -114666 -69372 -113043 -67503 -138584 -102777 -101057 -90069 -79825 -70931 -64978 -56072 27451 -47684 -17900 -37937 -14628 -38953 -3966 -22178 5553 -17915 -10622 -16778 -14249 -15424 -29787 -14536 -17915 -173 -8524 11944 -12190 -951 -10710 -3849 -10604 -1219 1928 -3976 6379 -2024 7777 296 10187 771 7877 3374 5627 6061 5573 2305 4075 1324 1257 2915 247 4020 1833 3651 1938 3918 2160 3195 -644 2301 474 -743 791 497 439 -336 921 -1748 -527 -1868 463 -1303 -558 -472 -902 -2000 -1100 -30 -666 394 -571 942 -167 1026 12 677 19 96 305 821 -309 -719 -439 -720 679 -205 -1313 -1591 -219 -996 172 -107 -132 -464 62 -9 287 1136 677 810 66 -274 -232 124 66 300 165 41 613 1108 531 21 231 -385 1 -171 99 -346 14 242 -213 -258 -213 107 127 -2272 1186 -1301 -520 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