File name: Pandora176s1_Tsukuba-NIES_20240828_L2Fit_fout2c4d20240516p1-8.txt File generation date: 20250127T233341.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Tamaki Fujinawa Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 176 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora176_OF_v3d20200605.txt Instrument calibration file used: Pandora176s1_CF_v4d20240516.txt Level 1 file used: Pandora176s1_Tsukuba-NIES_20240828_L1_smca1c4d20240516p1-8.txt Full location name: National Institute for Environmental Studies (NIES) Short location name: Tsukuba-NIES Country of location: Japan Location latitude [deg]: 36.0513 Location longitude [deg]: 140.1210 Location altitude [m]: 45 Local noon date: 20240828 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 3, but MLE correction for HCHO. First and last pixel inside fitting window: 256 398 Nominal wavelengths inside fitting window [nm]: 305.0215 305.1624 305.3032 305.4440 305.5848 305.7256 305.8664 306.0072 306.1480 306.2888 306.4295 306.5702 306.7110 306.8517 306.9924 307.1331 307.2737 307.4144 307.5551 307.6957 307.8363 307.9770 308.1176 308.2582 308.3987 308.5393 308.6799 308.8204 308.9610 309.1015 309.2420 309.3825 309.5230 309.6635 309.8039 309.9444 310.0848 310.2253 310.3657 310.5061 310.6465 310.7869 310.9272 311.0676 311.2079 311.3483 311.4886 311.6289 311.7692 311.9095 312.0498 312.1901 312.3303 312.4706 312.6108 312.7510 312.8912 313.0314 313.1716 313.3118 313.4519 313.5921 313.7322 313.8723 314.0124 314.1526 314.2926 314.4327 314.5728 314.7128 314.8529 314.9929 315.1329 315.2729 315.4129 315.5529 315.6929 315.8329 315.9728 316.1127 316.2527 316.3926 316.5325 316.6724 316.8122 316.9521 317.0920 317.2318 317.3716 317.5115 317.6513 317.7911 317.9308 318.0706 318.2104 318.3501 318.4899 318.6296 318.7693 318.9090 319.0487 319.1884 319.3280 319.4677 319.6073 319.7469 319.8866 320.0262 320.1658 320.3053 320.4449 320.5845 320.7240 320.8635 321.0031 321.1426 321.2821 321.4216 321.5610 321.7005 321.8400 321.9794 322.1188 322.2582 322.3976 322.5370 322.6764 322.8158 322.9551 323.0945 323.2338 323.3731 323.5124 323.6517 323.7910 323.9303 324.0696 324.2088 324.3481 324.4873 324.6265 324.7657 324.9049 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240827T203907.5Z 9005.860503 224 1 49.13 2 84.68 81.92 15.82 115.17 0.00 1 0.00 1 0 17 7.259e-01 9.784e-02 5.255e-01 8.179e-02 8.586102e-01 5.198573e-02 9.544961e-03 -6.000000e+00 4.624376e-01 230.58 -2.00 3.41 -2.00 321.91 0.00e+00 -2.184836e-03 2.230266e-02 1.856288e-03 -6.000000e+00 2.771954e-02 291.76 -2.00 20.00 -2.00 321.26 0.00e+00 9.348 0.013 302.00 328.00 3 1.5049e+00 1.8374e-01 1.0339e-01 -6.0000e+00 1.1713e+00 1.8833e+00 2.1664e-01 4.5473e-02 -6.0000e+00 1.2833e+00 -2.0725e+00 1.2368e-01 2.1482e-02 -6.0000e+00 7.5085e-01 7.7308e-01 6.7010e-02 6.3025e-03 -6.0000e+00 3.1581e-01 3.6801e-06 -1.3877e-04 2.5559e-03 8.4211e-05 -6.0000e+00 2.3780e-02 1.7896e-02 0.0000e+00 12 8 8 10 0 0 99.08 19.88 0.57 0.01790 0.01685 14 3 1 5 0 3509.030 26.41 20.00 19.88 32.56 17.1 977.87 115377 900000 61963 900000 900000 33537 66900 900000 900000 900000 900000 -5891 900000 -57800 900000 73461 900000 900000 900000 47466 900000 6099 900000 900000 120054 64428 900000 900000 35218 900000 -85325 900000 273782 900000 -80960 900000 -73462 900000 900000 900000 900000 146937 121158 292614 338575 13975 73627 41702 900000 -37944 184805 -10165 105351 -2536 52245 78991 39659 900000 -4839 80978 -19477 900000 -14011 900000 7990 53720 -11211 900000 49700 173486 34830 21574 -31200 66838 45494 -4350 57142 -9355 94267 -12710 -1633 -943 129992 -9160 8177 51515 17235 83685 -22656 104215 10002 41279 -14681 13736 -35603 5820 -21103 -5369 8290 2300 6134 20411 -2588 3201 16075 -13458 -4973 -3759 7826 -2027 16107 -10277 -286 -4884 8443 4113 -4054 2120 -1192 12354 -6449 722 -4788 18252 -13244 -2805 -671 8891 9977 1312 826 -2460 9235 -5712 1828 -2426 -1165 -1913 6124 -541 127 -3846 2121 9140 900000 6561 900000 900000 2710 5300 900000 900000 900000 900000 -618 900000 -12543 900000 5819 900000 900000 900000 4426 900000 700 900000 900000 9510 5104 900000 900000 2790 900000 -17913 900000 21688 900000 -18566 900000 -14487 900000 900000 900000 900000 11640 9598 23180 26821 1656 5833 3677 900000 -7437 14640 -1791 8346 -466 5954 7117 5168 900000 -860 6415 -3616 900000 -2876 900000 1557 6717 -2522 900000 7057 13743 6930 5004 -11564 9142 6810 -918 6263 -1931 8220 -3558 -483 -316 14063 -3878 3096 13660 6567 17450 -12767 17136 3733 10806 -6358 4756 -22274 2876 -15747 -3978 5971 1791 4374 11467 -1638 1879 8882 -10482 -3777 -3038 6293 -2051 15572 -13995 -365 -6487 9541 4711 -5052 2612 -1605 15184 -9412 942 -6329 18846 -18027 -3359 -768 9732 12375 2050 1460 -4883 17511 -13442 4306 -6306 -3066 -5144 15197 -1379 300 -8768 4359 SS 20240827T205036.6Z 9005.868479 227 1 48.25 2 82.38 83.58 13.81 120.81 0.00 1 0.00 1 0 17 5.141e-01 1.607e-02 3.120e-01 9.421e-03 7.787148e-01 5.420854e-03 8.650064e-03 -6.000000e+00 2.995698e-01 230.58 -2.00 3.41 -2.00 322.01 0.00e+00 4.180467e-03 3.318798e-03 3.023264e-03 -6.000000e+00 1.397104e-02 291.76 -2.00 20.00 -2.00 321.46 0.00e+00 6.992 0.005 302.00 328.00 3 1.1135e+00 2.2785e-02 8.1552e-02 -6.0000e+00 7.4728e-01 4.8079e-01 3.2616e-02 4.4653e-02 -6.0000e+00 8.0863e-01 -6.2033e-01 2.9207e-02 2.4399e-02 -6.0000e+00 4.8252e-01 2.5291e-01 1.3113e-02 8.0435e-03 -6.0000e+00 2.0702e-01 7.7593e-05 -8.2014e-04 2.7165e-04 1.2661e-04 -6.0000e+00 1.4321e-02 1.6647e-02 0.0000e+00 12 8 8 10 0 0 94.29 19.88 0.20 0.01665 0.01048 103 24 1 5 0 468.350 26.41 20.00 19.88 32.89 17.0 979.72 900000 -196181 18585 -94374 900000 -213873 -49874 -234938 -158830 -200516 -159525 -28474 -159820 -89146 -109113 104757 16768 2470 -25727 900000 -76672 -48980 -77263 -61712 -48426 -77912 -3104 -56485 -8510 -1776 2207 -19414 2408 -3379 -883 -7243 -22890 38719 48547 10489 -2118 57011 4825 55269 28335 26846 824 33103 29579 31435 14139 41666 5756 27238 20148 13168 20136 -2593 19762 7072 16762 1532 19654 7880 12311 3354 9514 8094 6609 8902 3113 10976 7266 10878 -4374 7895 -2491 677 -2561 4412 2439 1864 1176 -364 -90 -3268 3498 -1725 1173 -819 2512 -2856 -1758 -1056 538 -3241 -2223 -888 -2138 -824 -2128 -1303 -1785 -532 -2717 -680 -3046 -719 -638 -227 -1701 -436 822 -102 38 564 792 -75 525 -1229 250 2350 1410 781 1157 737 693 2126 154 76 28 391 185 351 183 286 107 85 -625 -396 -405 -339 -345 900000 -3603 171 -867 900000 -4091 -458 -6292 -2188 -4450 -2441 -261 -3424 -1228 -2338 962 154 29 -394 900000 -2053 -974 -2069 -1511 -1112 -2504 -52 -1426 -142 -30 42 -520 61 -98 -24 -205 -806 937 1297 449 -117 1876 281 1988 1344 1315 54 1621 1584 1780 1060 2678 541 2439 1907 1395 2048 -330 2102 764 1809 194 2374 1224 1983 592 1566 1401 1279 1943 803 2752 1878 2559 -1091 1556 -505 135 -592 1141 767 683 484 -163 -43 -1713 1806 -970 642 -444 1237 -1392 -819 -506 286 -2102 -1678 -768 -2087 -815 -2026 -1109 -1375 -397 -2203 -577 -2795 -694 -679 -274 -2358 -648 1239 -153 54 774 1085 -109 798 -1987 395 3499 2030 1097 1564 967 881 2756 231 132 54 817 411 833 466 773 297 238 -1774 -1083 -1037 -808 -784 SS 20240827T210821.1Z 9005.880800 232 1 13.43 2 78.81 86.15 10.99 132.85 0.00 1 0.00 1 0 25 3.919e-01 1.475e-02 2.915e-01 1.041e-02 5.953201e-01 5.615247e-03 6.813316e-03 -6.000000e+00 2.279824e-01 230.58 -2.00 3.41 -2.00 320.89 0.00e+00 3.697718e-03 2.463714e-03 2.126330e-03 -6.000000e+00 1.052097e-02 291.76 -2.00 20.00 -2.00 320.17 0.00e+00 4.969 0.002 302.00 328.00 3 3.2768e+00 1.8699e-02 5.8659e-02 -6.0000e+00 5.6848e-01 2.1804e-01 2.4389e-02 3.2629e-02 -6.0000e+00 6.1438e-01 -2.0577e-01 2.1373e-02 1.6896e-02 -6.0000e+00 3.6734e-01 7.8948e-02 1.0468e-02 5.1635e-03 -6.0000e+00 1.5857e-01 7.1699e-05 -3.2411e-04 2.9994e-04 7.3695e-05 -6.0000e+00 1.0804e-02 1.4288e-02 0.0000e+00 12 9 9 12 9 1 33.65 19.89 0.30 0.01429 0.01185 7 7 1 5 0 1678.510 26.41 20.00 19.89 33.66 17.1 984.71 900000 -156613 900000 -163874 57086 -60690 -119617 -92853 -77629 -126858 -104261 -27845 111846 152484 -108267 41012 -35861 59511 -15508 121771 -14258 91818 -20910 46244 -11318 -1405 15938 -20217 6428 -12595 70989 -23690 15879 -14495 21189 -5012 22661 -16108 8444 -3691 12031 -6695 3158 7769 2146 9994 5897 22996 -9037 9267 -1421 8412 4949 14248 8215 9538 -7853 -4518 10755 -2976 1577 2392 12642 4820 2742 -459 8272 -1196 1669 1674 888 322 1056 2577 -5024 2275 -2672 820 193 1951 -842 2692 -2441 -4452 -1135 -2076 -510 -225 1471 -959 1790 751 1661 490 723 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