File name: Pandora176s1_Tsukuba-NIES_20241017_L2Fit_fwvt1c4d20240516p1-8.txt File generation date: 20250127T235929.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Tamaki Fujinawa Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 176 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora176_OF_v3d20200605.txt Instrument calibration file used: Pandora176s1_CF_v4d20240516.txt Level 1 file used: Pandora176s1_Tsukuba-NIES_20241017_L1_smca1c4d20240516p1-8.txt Full location name: National Institute for Environmental Studies (NIES) Short location name: Tsukuba-NIES Country of location: Japan Location latitude [deg]: 36.0513 Location longitude [deg]: 140.1210 Location altitude [m]: 45 Local noon date: 20241017 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 3, but MLE correction for HCHO. First and last pixel inside fitting window: 1679 1828 Nominal wavelengths inside fitting window [nm]: 492.1082 492.2290 492.3498 492.4706 492.5914 492.7121 492.8328 492.9535 493.0742 493.1949 493.3156 493.4362 493.5569 493.6775 493.7981 493.9187 494.0392 494.1598 494.2803 494.4008 494.5213 494.6418 494.7623 494.8827 495.0032 495.1236 495.2440 495.3644 495.4847 495.6051 495.7254 495.8457 495.9660 496.0863 496.2065 496.3268 496.4470 496.5672 496.6874 496.8076 496.9278 497.0479 497.1680 497.2882 497.4082 497.5283 497.6484 497.7684 497.8885 498.0085 498.1285 498.2484 498.3684 498.4883 498.6083 498.7282 498.8481 498.9679 499.0878 499.2076 499.3275 499.4473 499.5671 499.6868 499.8066 499.9263 500.0460 500.1658 500.2854 500.4051 500.5248 500.6444 500.7640 500.8836 501.0032 501.1228 501.2423 501.3619 501.4814 501.6009 501.7204 501.8398 501.9593 502.0787 502.1981 502.3175 502.4369 502.5563 502.6756 502.7950 502.9143 503.0336 503.1529 503.2721 503.3914 503.5106 503.6298 503.7490 503.8682 503.9873 504.1065 504.2256 504.3447 504.4638 504.5829 504.7019 504.8210 504.9400 505.0590 505.1780 505.2970 505.4159 505.5349 505.6538 505.7727 505.8916 506.0104 506.1293 506.2481 506.3669 506.4857 506.6045 506.7233 506.8420 506.9608 507.0795 507.1982 507.3169 507.4355 507.5542 507.6728 507.7914 507.9100 508.0286 508.1471 508.2657 508.3842 508.5027 508.6212 508.7397 508.8581 508.9766 509.0950 509.2134 509.3318 509.4501 509.5685 509.6868 509.8051 509.9234 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241016T212704.7Z 9055.893804 256 1 48.58 2 83.20 106.77 105.48 290.04 0.00 1 0.00 1 0 22 2.756e-03 2.732e-03 5.000e-04 4.983e-04 1.560526e+04 3.602464e+01 1.012855e+03 -6.000000e+00 1.527910e+02 287.29 -2.00 20.00 -2.00 505.37 0.00e+00 1.658238e-03 1.388970e-05 1.118491e-04 -6.000000e+00 7.760763e-05 287.29 -2.00 20.00 -2.00 500.60 0.00e+00 6.876926e-01 9.752584e-03 9.573323e-02 -6.000000e+00 5.398177e-02 226.48 -2.00 3.41 -2.00 502.19 0.00e+00 7.702 0.007 489.00 513.00 1 5.7693e+00 7.4947e-04 1.3965e-02 -6.0000e+00 4.1393e-03 -1.5580e-02 1.8899e-04 2.4318e-03 -6.0000e+00 1.0826e-03 1.8516e-03 2.1588e-04 4.2450e-05 1.0969e-04 -6.0000e+00 2.6200e-04 2.8643e-04 2.5640e-05 10 0 0 10 0 0 99.83 19.97 0.83 0.00029 0.00178 132 31 1 4 0 367.970 26.51 20.00 19.97 26.51 17.5 973.99 -501 -253 40 106 274 555 525 443 399 272 213 -95 -231 -146 -227 -218 -78 117 102 134 162 174 154 282 309 368 155 -26 -197 -349 -363 -331 -120 236 14 24 -78 -160 -273 -236 -198 -78 55 97 225 238 203 64 -172 -319 -468 -536 -590 -332 -147 57 134 200 199 176 231 309 213 235 116 123 -43 -153 -193 -281 -202 -187 -173 97 10 -208 -293 -422 -361 -292 -337 -337 -350 -106 -128 -264 -236 -119 -88 3 60 331 390 300 385 305 -53 -117 -396 -560 -679 -577 -375 -200 -123 -134 -142 -271 -101 -158 -107 68 178 309 516 677 628 502 331 164 79 -39 175 280 55 231 262 15 90 147 -113 -96 -140 -386 -260 68 -97 63 157 171 78 213 327 246 269 158 -41 -264 -362 -406 -446 -230 37 103 274 564 542 460 412 278 215 -95 -227 -142 -220 -214 -78 120 107 142 171 184 163 300 331 394 165 -28 -201 -347 -357 -329 -122 249 14 25 -79 -170 -288 -247 -209 -83 55 99 230 244 206 64 -182 -328 -469 -526 -577 -329 -151 56 134 202 200 177 232 313 217 238 116 122 -42 -158 -197 -283 -203 -189 -177 94 9 -200 -296 -420 -355 -285 -331 -334 -350 -107 -122 -254 -227 -114 -83 2 57 319 379 287 383 293 -49 -106 -352 -492 -602 -526 -359 -188 -120 -132 -139 -262 -97 -154 -106 68 178 309 516 682 643 520 343 167 79 -38 170 273 54 228 259 15 89 145 -111 -93 -133 -367 -249 67 -97 64 161 179 83 226 350 263 287 167 -43 -271 -367 -411 SQ 20241016T235221.8Z 9055.994696 349 1 14.54 2 57.87 133.99 128.10 319.61 0.00 1 0.00 1 0 15 1.988e-03 1.983e-03 3.450e-04 3.443e-04 3.645608e+03 2.115844e+01 2.570722e+02 -6.000000e+00 1.102069e+02 287.28 -2.00 20.00 -2.00 505.26 0.00e+00 5.773593e-04 9.502978e-06 3.718405e-05 -6.000000e+00 5.597743e-05 287.28 -2.00 20.00 -2.00 500.47 0.00e+00 2.593387e-02 6.731021e-03 2.452912e-02 -6.000000e+00 3.893584e-02 226.48 -2.00 3.41 -2.00 502.05 0.00e+00 1.873 0.000 489.00 513.00 1 5.1260e+00 5.1600e-04 3.5024e-03 -6.0000e+00 2.9856e-03 1.2548e-02 1.3422e-04 6.0248e-04 -6.0000e+00 7.8076e-04 8.7889e-03 1.8928e-04 3.1767e-05 3.1900e-05 -6.0000e+00 1.8898e-04 3.3499e-04 2.9457e-05 12 1 1 12 1 1 89.92 20.00 0.74 0.00033 0.00165 69 55 1 4 0 207.700 26.51 20.00 20.00 30.22 17.6 998.25 -385 -182 56 109 231 415 345 257 410 234 129 -92 -150 -83 -219 -177 -17 209 184 51 201 132 124 261 254 255 151 -44 -198 -145 -346 -340 -59 51 -11 -72 -14 -119 -214 -187 -124 -131 20 156 166 122 195 36 -41 -246 -345 -384 -381 -264 -166 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230 130 -2 -195 -122 -241 -252 SQ 20241016T235624.4Z 9055.997504 352 1 48.31 2 57.29 134.95 128.59 320.66 0.00 1 0.00 1 0 15 2.031e-03 2.024e-03 6.111e-04 6.092e-04 3.711911e+03 3.804530e+01 2.620794e+02 -6.000000e+00 1.126125e+02 287.27 -2.00 20.00 -2.00 505.30 0.00e+00 5.514212e-04 1.679735e-05 3.517150e-05 -6.000000e+00 5.720276e-05 287.27 -2.00 20.00 -2.00 500.48 0.00e+00 7.583915e-02 1.189789e-02 2.483008e-02 -6.000000e+00 3.979234e-02 226.48 -2.00 3.41 -2.00 502.07 0.00e+00 1.844 0.000 489.00 513.00 1 7.2287e+00 9.1027e-04 3.4735e-03 -6.0000e+00 3.0512e-03 1.2100e-02 2.3699e-04 6.1154e-04 -6.0000e+00 7.9809e-04 1.0741e-03 4.6698e-04 5.6296e-05 3.1435e-05 -6.0000e+00 1.9313e-04 1.0379e-03 1.4276e-05 10 0 0 10 0 0 99.82 20.01 0.75 0.00104 0.00428 35 8 1 4 0 1380.150 26.51 20.00 20.01 30.35 17.6 998.41 -340 -247 29 -55 140 471 428 276 319 166 162 -174 -91 -131 -288 -95 -171 569 -94 17 146 197 158 115 208 279 26 -103 -143 -142 -217 -269 -115 239 -34 -42 -21 -94 -228 3 -222 -151 77 93 88 170 242 25 -55 -248 -399 -420 -350 -300 -348 156 63 -18 12 43 207 174 130 278 121 171 62 -167 -96 -179 -123 -242 -314 162 -48 -188 -51 -94 -215 -281 -284 -192 -197 -12 -114 -68 -246 -36 9 55 -71 224 195 96 317 163 -132 -46 -183 -286 -454 -278 -358 -122 -141 -37 -89 -245 -51 -151 -95 184 209 264 294 534 310 233 164 118 93 -95 110 20 -59 19 337 18 76 134 -64 12 -98 -172 -202 10 -91 -11 43 245 56 220 190 223 124 0 -70 -90 -210 -249 -333 -248 29 -55 143 489 451 292 336 172 166 -176 -91 -128 -283 -94 -173 585 -99 18 156 210 168 123 223 298 27 -108 -145 -139 -212 -265 -116 250 -36 -45 -22 -98 -236 3 -229 -157 81 98 93 180 255 26 -56 -246 -385 -396 -328 -286 -342 158 64 -19 12 45 213 180 135 287 124 172 61 -164 -93 -172 -117 -232 -305 159 -47 -184 -48 -89 -201 -263 -267 -182 -188 -12 -111 -67 -242 -36 9 55 -71 225 198 98 317 159 -126 -42 -167 -257 -409 -256 -342 -121 -143 -38 -89 -241 -50 -149 -95 186 213 272 304 554 324 228 170 120 94 -94 108 20 -58 19 334 17 75 132 -62 12 -93 -161 -190 9 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